CN106947352A - A kind of automobile coating for taking into account environmental resistance and glossiness - Google Patents
A kind of automobile coating for taking into account environmental resistance and glossiness Download PDFInfo
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- CN106947352A CN106947352A CN201710229860.6A CN201710229860A CN106947352A CN 106947352 A CN106947352 A CN 106947352A CN 201710229860 A CN201710229860 A CN 201710229860A CN 106947352 A CN106947352 A CN 106947352A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
- C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention relates to polymer field of new materials, mainly to solve aqueous automobile paint resistance to acids and bases, water-resistance and corrosion-resistant difference and bad glossiness in the prior art the problem of, its major programme is a kind of automobile coating for taking into account environmental resistance and glossiness, including following parts by weight of component：18 22 parts by weight automobile coating water-based acrylic resins, the parts by weight of waterborne curing agent 23, the parts by weight of levelling agent 12, the parts by weight of defoamer 12；10 15 parts by weight of deionized water.Resistance to acids and bases, water-resistance and the good corrosion resistance of the automobile coating of the present invention have preferable glossiness simultaneously.
Description
Technical field
The present invention relates to polymer field of new materials, particularly a kind of automobile coating for taking into account environmental resistance and glossiness.
Background technology
Earliest commercialization water paint is that occur in 1930s.Compatibility and protection based on it to environment
Property, and have the advantages that to save resource, save the energy, water paint product is acceptable to the market soon, and gradually development expands.
Japan, U.S.'s water paint in 1986 account for the 18% and 22% of coating total sales volume, Britain's nineteen ninety-five water paint yield respectively
Account for the 64.5% of national coating total output.External water paint is mostly used for the industries such as building, automobile, woodenware, high-performance water
Property metallic paint is various with naval stores type, and paint film mechanical performance is excellent, salt spray resistance is good, generally replaces oleoresin
Protection applied to metal works.At present, main manufacturer has the companies such as BASF, Bayer, Lu Borun, Aksu.
Water-based acrylic resin is free by emulsion by esters of acrylic acid and methyl acrylic ester and other olefinic type monomers
Base atmospheric pressure polymerization copolymerization is made, by from different resin structures, different formulas and different production technologies and solvent
Composition, can synthesize the acrylic resin of different type, different performance and different application occasion.The species of wherein hard soft monomer and match somebody with somebody
Than the main framework for determining resin, the key property after resin film forming is determined；Function monomer is used to improve the synthesis of resin
Performance.Although the method technological operation of this emulsion polymerization is simple, most prominent shortcoming is the water-base resin that synthesis is obtained
Molecular weight distribution it is wider, the monomer with polar functional group of residual is more, thus the resistance to acids and bases of resin, water-resistance and resistance to
Corrosivity is poor.
It is found through experiments that, automobile coating obtained by acrylic resin is prepared on solving using sol-gel process high pressure
When resistance to acids and bases, water-resistance and the corrosion-resistant stated, glossiness can not obtain synchronous improvement again.
The content of the invention
It is an object of the invention to provide a kind of environmental resistance is strong, glossiness is good takes into account environmental resistance and glossiness
Automobile coating.
The technical scheme that the present invention is provided is：A kind of automobile coating for taking into account environmental resistance and glossiness, including it is following heavy
Measure part component：
18-22 parts by weight automobile coatings water-based acrylic resin, waterborne curing agent 2-3 parts by weight, levelling agent 1-2 weight
Part, defoamer 1-2 parts by weight；10-15 parts by weight of deionized water；
Described automobile coating is prepared with water-based acrylic resin by following steps：
Step 1：The preparation of sol solution：By the tetraethyl orthosilicate of 0.5-1 parts by weight and the hydrophobicity silicon of 1.5-2 parts by weight
Alkane is added in the absolute ethyl alcohol of 35-45 parts by weight, is warming up to 50 DEG C, and stirring reaction 3h, add 3-4 parts by weight it is cloudy from
Sub- emulsifying agent, continues to stir until material is completely dissolved；
Step 2：The preparation of single phase：By the butyl methacrylate of 10-15 parts by weight, the styrene of 3-5 parts by weight, 5-
10 parts by weight of ethylene base trimethoxy siloxanes, the acrylic acid of 10-15 parts by weight, the hydroxyethyl methacrylate second of 10-15 parts by weight
Ester, the vinyl pyrrolidone of 5-10 parts by weight, 2-5 parts by weight tetramethyl divinyl disiloxane, 1-3 parts by weight anion
Emulsifying agent, the initiator of 0.5-0.8 parts by weight are well mixed and obtain single phase；
Step 3：Sol solution is placed in reaction vessel, single phase is added dropwise and entered instead in 2-4MPa by Stress control
Answer in system, time for adding is 1-2h, reaction temperature is controlled at 55-65 DEG C；
Step 4：The pH value of the mixture system obtained by pH adjusting agent regulating step 3 is 6-7.
In the above-mentioned automobile coating for taking into account environmental resistance and glossiness, described hydrophobic silane is the ethoxy of methyl three
Base silane or dimethyldiethoxysilane.
The beneficial effect of this programme is to pass through colloidal sol -- the presoma of gel obtains active group and as connection
Point, temperature, pressure and the polymerization time of preferably soft or hard monomer, function monomer and copolymerization, obtain structure and molecular weight is all controllable
Water-based acrylic resin.Its reason is analyzed, may be non-mainly under pressure the condition of hydro-thermal reaction (its actually)
Homogeneous Raolical polymerizable portions turn is homogeneous reaction, thus the speed of polymerisation is easily controlled, residual monomer
Quantity is reduced, thus resistance to acids and bases, water-resistance and corrosion resistance get a promotion after resin film forming.Carried simultaneously using organic-silicon-modified
Its high glossiness, and the influence in reaction under high pressure to resinous luster degree can be avoided by multi-functional organosilicon.
Embodiment
With reference to embodiment, technical scheme is described in further detail, but not constituted pair
Any limitation of the present invention.
Embodiment 1：
A kind of automobile coating for taking into account environmental resistance and glossiness, including following parts by weight of component：
20 parts by weight automobile coating water-based acrylic resins, waterborne curing agent (Cohan wound Bayer water-based isocyanate solidification
Agent 3100) 2.5 parts by weight, the parts by weight of levelling agent (polysiloxane polyether copolymer TEGO410) 1.5, defoamer be (organically-modified poly-
Silicone T EGO900) 1.5 parts by weight；12 parts by weight of deionized water；
Above-mentioned automobile coating is prepared with water-based acrylic resin by following steps：
Step 1：The preparation of sol solution：By the tetraethyl orthosilicate of 0.8 parts by weight and the dimethyl diethoxy of 1.8 parts by weight
Base silane is added in the absolute ethyl alcohol of 40 parts by weight, is warming up to 50 DEG C, and stirring reaction 3h, is added the ten of 3.5 parts by weight
Dialkyl benzene sulfonic acids sodium, continues to stir until material is completely dissolved；
Step 2：The preparation of single phase：By the butyl methacrylate of 12 parts by weight, the styrene of 4 parts by weight, 8 parts by weight
Vinyl trimethoxy siloxanes, the acrylic acid of 12 parts by weight, the hydroxyethyl methacrylate of 13 parts by weight, the second of 7 parts by weight
Vinyl pyrrolidone, 2 parts by weight tetramethyl divinyl disiloxanes, 2 parts by weight neopelexes, 0.6 parts by weight
Initiator well mixed obtain single phase；
Step 3：Sol solution is placed in reaction vessel, single phase is added dropwise in 3MPa and enters reaction by Stress control
In system, time for adding is 2h, and reaction temperature is controlled at 55 DEG C；
Step 4：The pH value of the mixture system obtained by ammoniacal liquor regulating step 3 is 6-7.
Embodiment 2
A kind of automobile coating for taking into account environmental resistance and glossiness, including following parts by weight of component：
18 parts by weight automobile coating water-based acrylic resins, waterborne curing agent (Cohan wound Bayer water-based isocyanate solidification
Agent 3100) 2 parts by weight, the parts by weight of levelling agent (polysiloxane polyether copolymer TEGO410) 2, defoamer (organically-modified poly- silica
Alkane TEGO900) 1 parts by weight；10 parts by weight of deionized water；
Above-mentioned automobile coating is prepared with water-based acrylic resin by following steps：
Step 1：The preparation of sol solution：By the tetraethyl orthosilicate of 1 parts by weight and the dimethyl diethoxy of 1.5 parts by weight
Silane is added in the absolute ethyl alcohol of 35 parts by weight, is warming up to 50 DEG C, and stirring reaction 3h, is added the dodecane of 3 parts by weight
Base benzene sulfonic acid sodium salt, continues to stir until material is completely dissolved；
Step 2：The preparation of single phase：By the butyl methacrylate of 10 parts by weight, the styrene of 3 parts by weight, 10 weight
Part vinyl trimethoxy siloxanes, the acrylic acid of 10 parts by weight, the hydroxyethyl methacrylate of 11 parts by weight, 10 parts by weight
Vinyl pyrrolidone, 3 parts by weight tetramethyl divinyl disiloxanes, 3 parts by weight neopelexes, 0.8 weight
The initiator of part is well mixed to obtain single phase；
Step 3：Sol solution is placed in reaction vessel, single phase is added dropwise in 4MPa and enters reaction by Stress control
In system, time for adding is 2h, and reaction temperature is controlled at 55 DEG C；
Step 4：The pH value of the mixture system obtained by ammoniacal liquor regulating step 3 is 6-7.
Embodiment 3
A kind of automobile coating for taking into account environmental resistance and glossiness, including following parts by weight of component：
22 parts by weight automobile coating water-based acrylic resins, waterborne curing agent (Cohan wound Bayer water-based isocyanate solidification
Agent 3100) 3 parts by weight, the parts by weight of levelling agent (polysiloxane polyether copolymer TEGO410) 1, defoamer (organically-modified poly- silica
Alkane TEGO900) 2 parts by weight；15 parts by weight of deionized water；
Above-mentioned automobile coating is prepared with water-based acrylic resin by following steps：
Step 1：The preparation of sol solution：By the tetraethyl orthosilicate of 0.5 parts by weight and the dimethyl diethoxy of 2 parts by weight
Silane is added in the absolute ethyl alcohol of 45 parts by weight, is warming up to 50 DEG C, and stirring reaction 3h, is added the dodecane of 4 parts by weight
Base benzene sulfonic acid sodium salt, continues to stir until material is completely dissolved；
Step 2：The preparation of single phase：By the butyl methacrylate of 15 parts by weight, the styrene of 5 parts by weight, 5 parts by weight
Vinyl trimethoxy siloxanes, the acrylic acid of 15 parts by weight, the hydroxyethyl methacrylate of 15 parts by weight, the second of 5 parts by weight
Vinyl pyrrolidone, 4 parts by weight tetramethyl divinyl disiloxanes, 1 parts by weight neopelex, 0.5 parts by weight
Initiator well mixed obtain single phase；
Step 3：Sol solution is placed in reaction vessel, single phase is added dropwise in 2MPa and enters reaction by Stress control
In system, time for adding is 2h, and reaction temperature is controlled at 60 DEG C；
Step 4：The pH value of the mixture system obtained by ammoniacal liquor regulating step 3 is 6-7.
Comparative example 1
It is substantially the same with embodiment 1, different places is the list in automobile coating water-based acrylic resin preparation process
The composition of body phase is as follows：By the butyl methacrylate of 12 parts by weight, the styrene of 4 parts by weight, 10 parts by weight of ethylene base front threes
Epoxide siloxanes, the acrylic acid of 12 parts by weight, the hydroxyethyl methacrylate of 13 parts by weight, the ethenyl pyrrolidone of 7 parts by weight
Ketone, 2 parts by weight neopelexes, the initiator of 0.6 parts by weight are well mixed and obtain single phase.
Coating is handled using conventional car paint spraying baking method, it is 100-110 microns to obtain thickness
Coating, coating hardness (GB/T1730-93) is more than 2H, and glossiness (GB/T9754) is 92-93% at 20 °, after soaking 24 hours,
Paint film is non-foaming and adhesive force is measured after 1 hour more than 2 grades, and surface drying time is less than 0.5h, does solid work the time less than 15h, 1000h
Salt spray resistance test is not fallen off by the way that paint film is non-foaming, and 10d organic solvent-resistants (benzene, volatile oil) test does not take off by the way that paint film is non-foaming
Fall, 30d corrosion resistances (10% sodium hydroxide solution) test is not fallen off by the way that paint film is non-foaming.
The data of comparative example 1 and embodiment 1-3 data are substantially the same, and different places are, glossiness (GB/ at 20 °
T9754) it is 89-90%.
Above-described embodiment is preferably embodiment, but embodiments of the present invention are not by above-described embodiment of the invention
Limitation, other any Spirit Essences without departing from the present invention and the change made under principle, modification, replacement, combine, simplification,
Equivalent substitute mode is should be, is included within protection scope of the present invention.
Claims (2)
1. a kind of automobile coating for taking into account environmental resistance and glossiness, it is characterised in that：Including following parts by weight of component：
18-22 parts by weight automobile coatings water-based acrylic resin, waterborne curing agent 2-3 parts by weight, levelling agent 1-2 parts by weight, disappear
Infusion 1-2 parts by weight；10-15 parts by weight of deionized water；
Described automobile coating is prepared with water-based acrylic resin by following steps：
Step 1：The preparation of sol solution：The hydrophobic silane of the tetraethyl orthosilicate of 0.5-1 parts by weight and 1.5-2 parts by weight is added
Enter into the absolute ethyl alcohol of 35-45 parts by weight, be warming up to 50 DEG C, and stirring reaction 3h, add the anion breast of 3-4 parts by weight
Agent, continues to stir until material is completely dissolved；
Step 2：The preparation of single phase：By the butyl methacrylate of 10-15 parts by weight, the styrene of 3-5 parts by weight, 5-10 weights
Measure part vinyl trimethoxy siloxanes, the acrylic acid of 10-15 parts by weight, the hydroxyethyl methacrylate of 10-15 parts by weight, 5-
The vinyl pyrrolidone of 10 parts by weight, 2-5 parts by weight tetramethyl divinyl disiloxane, 1-3 parts by weight are anionic emulsifying
Agent, the initiator of 0.5-0.8 parts by weight are well mixed and obtain single phase；
Step 3：Sol solution is placed in reaction vessel, single phase is added dropwise in 2-4MPa and enters reactant by Stress control
In system, time for adding is 1-2h, and reaction temperature is controlled at 55-65 DEG C；
Step 4：The pH value of the mixture system obtained by pH adjusting agent regulating step 3 is 6-7.
2. the automobile coating according to claim 1 for taking into account environmental resistance and glossiness, it is characterised in that：Described is hydrophobic
Property silane be MTES or dimethyldiethoxysilane.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2017100697103 | 2017-02-08 | ||
| CN201710069710 | 2017-02-08 |
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| CN106947352A true CN106947352A (en) | 2017-07-14 |
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| CN201710229860.6A Pending CN106947352A (en) | 2017-02-08 | 2017-04-10 | A kind of automobile coating for taking into account environmental resistance and glossiness |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109306218A (en) * | 2018-08-23 | 2019-02-05 | 太仓怡泰霖智能科技有限公司 | A kind of aqueous diatom ooze automobile coating of acid-alkali-corrosive-resisting and preparation method thereof |
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| CN101560353A (en) * | 2009-05-05 | 2009-10-21 | 陕西科技大学 | Method for preparing water-resistant and solvent-resistant acrylics coating agent |
| CN101831230A (en) * | 2010-04-09 | 2010-09-15 | 陕西科技大学 | Method for preparing polyacrylate/nano-SiO2 compound coating agent by using reactive emulsifier |
| CN102234476A (en) * | 2010-05-06 | 2011-11-09 | 天津五一天立油漆有限公司 | Waterborne acrylic polyurethane surface paint |
| CN102604135A (en) * | 2012-03-02 | 2012-07-25 | 上海交通大学 | Preparation method of polymethyl methacrylate/titanium dioxide nano-grade composite material |
| CN103059313A (en) * | 2012-12-17 | 2013-04-24 | 中山大桥化工集团有限公司 | Method for preparing organosilicon modified acrylic resin |
| WO2014140846A2 (en) * | 2013-03-15 | 2014-09-18 | HENKEL AG & CO . KGaA | Inorganic composite coatings comprising novel functionalized acrylics |
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2017
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| CN101560353A (en) * | 2009-05-05 | 2009-10-21 | 陕西科技大学 | Method for preparing water-resistant and solvent-resistant acrylics coating agent |
| CN101831230A (en) * | 2010-04-09 | 2010-09-15 | 陕西科技大学 | Method for preparing polyacrylate/nano-SiO2 compound coating agent by using reactive emulsifier |
| CN102234476A (en) * | 2010-05-06 | 2011-11-09 | 天津五一天立油漆有限公司 | Waterborne acrylic polyurethane surface paint |
| CN102604135A (en) * | 2012-03-02 | 2012-07-25 | 上海交通大学 | Preparation method of polymethyl methacrylate/titanium dioxide nano-grade composite material |
| CN103059313A (en) * | 2012-12-17 | 2013-04-24 | 中山大桥化工集团有限公司 | Method for preparing organosilicon modified acrylic resin |
| WO2014140846A2 (en) * | 2013-03-15 | 2014-09-18 | HENKEL AG & CO . KGaA | Inorganic composite coatings comprising novel functionalized acrylics |
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| Title |
|---|
| 丁泽扬 汤宗兰: "《聚合物化学》", 31 December 1990, 成都科技大学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109306218A (en) * | 2018-08-23 | 2019-02-05 | 太仓怡泰霖智能科技有限公司 | A kind of aqueous diatom ooze automobile coating of acid-alkali-corrosive-resisting and preparation method thereof |
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