CN102217617A - Pesticide composition containing trifloxystrobin - Google Patents
Pesticide composition containing trifloxystrobin Download PDFInfo
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- CN102217617A CN102217617A CN2011100742169A CN201110074216A CN102217617A CN 102217617 A CN102217617 A CN 102217617A CN 2011100742169 A CN2011100742169 A CN 2011100742169A CN 201110074216 A CN201110074216 A CN 201110074216A CN 102217617 A CN102217617 A CN 102217617A
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- oxime bacterium
- bacterium ester
- carbendazim
- thiophanate
- methyl
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Abstract
The invention provides a pesticide composition containing trifloxystrobin, the composition comprises an effective active component A trifloxystrobin and an effective active component B which is one selected from carbendazim or thiophanate methyl, wherein the weight ratio of the active component A to the active component B is 1: 64 - 16:1. The pesticide composition of the invention can be prepared for wettable powders, water dispersion granules, suspending agents suspoemulsions and the like, and has ideal effect for preventing various crop diseases of powdery mildew, anthracnose, epidemic disease, downy mildew, leaf spot, rhizoctonia solani, sheath blight and rice blast.
Description
Technical field
The invention belongs to technical field of pesticide, be specifically related to a kind of oxime bacterium ester and carbendazim or the composite composition pesticide of thiophanate-methyl, be used for the control of plant disease.
Technical background
Fungi is topmost phytopathogen, and the plant disease more than 70% all is by fungus-caused, and because of its paathogenic factor complexity, difficulty of prevention and cure is very big.In recent years, along with the adjustment of rural area pattern of farming, the planting fruit trees area constantly increases, and the occurrence degree of many fungal diseases also increases thereupon on the fruit tree, has caused enormous economic loss.
Oxime bacterium ester (trifloxystrobin), molecular formula: C
20H
19F
3N
2O
4, chemical name: methyl (E)-methoxyl group imido grpup-(E)-and α-[1-(α, α-three fluoro-m-tolyl)-ethyleneimino oxygen base]-o-tolyl } ethyl acetate.Oxime bacterium ester class wide-spectrum bactericide is the new fluorine-containing bactericide of successfully developing as the bactericide lead compound from natural products Strobilurins of a class.Characteristics such as having efficient, wide spectrum, protection, treat, root out, infiltration, systemic activity, resistance of rainwater washing against, lasting period are long.To 1,4-demethylation enzyme inhibitor, benzamides, the bacterial strain of dicarboxyl amine and benzimidazole generation resistance is effective, does not have cross resistance with at present existing bactericide.Nearly all Mycophytes (Ascomycetes, Basidiomycetes, Oomycete and Fungi Imperfecti) disease such as powdery mildew, rust, Ying's rot, net blotch, downy mildew, rice blast etc. all there is good activity.To crop safety, because of its at soil, capable of being fast degraded in the water, so environmentally safe.
Oxime bacterium ester is to all having good activity to nearly all Mycophytes disease, is easy to generate pesticide resistance and cost is higher but use separately, is unfavorable for that large tracts of land promotes the use of; Carbendazim, thiophanate-methyl fungicidal spectrum are wide, and use cost is lower, but in recent years because resistance rises to some extent, use the effect that preventive effect is undesirable, enlarge fungicidal spectrum, reduce cost separately.Field and indoor biometrics show, oxime bacterium ester and carbendazim are composite, oxime bacterium ester and thiophanate-methyl are composite all has a synergistic effect preferably, single with being significantly improved to more single agent such as the preventive effect of powdery mildew, anthracnose, eqpidemic disease, downy mildew, leaf spot, damping off, banded sclerotial blight, rice blast etc.
Summary of the invention
Oxime bacterium ester of the present invention and carbendazim or thiophanate-methyl complex preparation can be used for preventing and treating the multiple diseases on the crop, and crop is had excellent protection and therapeutic action, and field trial has showed extremely strong antibiotic and bactericidal activity.
The present invention realizes in the following manner:
A kind of composition pesticide that contains oxime bacterium ester is characterized in that bactericidal composition effective active composition (A) the oxime bacterium ester and the weight ratio of (B) carbendazim or thiophanate-methyl are 1: 64 to 16: 1.
The described bactericidal composition that contains oxime bacterium ester is characterized in that: wherein (A) oxime bacterium ester is 1: 32 to 4: 1 with the weight ratio of (B) carbendazim or thiophanate-methyl.
The described bactericidal composition that contains oxime bacterium ester is characterized in that: wherein the weight ratio of oxime bacterium ester and carbendazim is 1: 16 to 1: 2.
The described bactericidal composition that contains oxime bacterium ester is characterized in that: wherein the weight ratio of oxime bacterium ester and thiophanate-methyl is 1: 16 to 1: 2.
The described bactericidal composition that contains oxime bacterium ester is characterized in that: wherein the effective active component content accounts for 1～90% of gross weight, is preferably 10～80%.
The described composition pesticide that contains oxime bacterium ester can add auxiliary agent on demand and excipients is processed into acceptable forms on any agricultural chemicals, wherein excellently selects formulation to be: wetting powder, water dispersible granules, suspending agent, suspension emulsion.
The described oxime bacterium ester composition pesticide that contains is characterized in that auxiliary agent and excipients comprise: dispersant, wetting agent, disintegrant, emulsifier, thickener, antifreeze, defoamer, filler.
Described dispersant is selected from one or more in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, the fatty acid glyceride APEO.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, DBSA, Nekal BX, wetting and penetrating agent F, alkylnaphthalene sulfonate, polyoxyethylene triphenylethylene phosphenylic acid salt, spaonin powder, silkworm excrement, the soapberry powder.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, the sodium bicarbonate.
Described thickener is selected from: one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, the polyvinyl alcohol.
Described emulsifier is selected from one or more among alkyl benzene sulfonate calcium salt, styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, phenethyl phenol polyethenoxy ether, 506#, 600#, 700#, NP-10 phosphate, OP-10 phosphate, castor oil polyoxyethylene ether, sorbester p17, Tween 80, the 602#;
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, the glycerine.
Described defoamer is selected from: one or more in silicone oil, silicone compound, C10-20 saturated fat acid compounds, the C8-10 aliphatic alcohols compound.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
The described bactericidal composition that contains oxime bacterium ester is used to prevent and treat plant diseases such as powdery mildew, anthracnose, eqpidemic disease, downy mildew, leaf spot, damping off, banded sclerotial blight, rice blast, and the preventive effect ideal is compared with single agent, has obvious synergistic effect.
The present invention has following characteristics:
1. double action mechanism, germ are difficult for producing resistance;
2. synergistic effect is obvious.Indoor biometrics is tested the result and shown: oxime bacterium ester and carbendazim or thiophanate-methyl are composite by a certain percentage to have clearly synergistic effect to crop pest;
3. expansion fungicidal spectrum.Oxime bacterium ester and carbendazim or thiophanate-methyl be composite prevents and treats multiple main disease, as powdery mildew, anthracnose, eqpidemic disease, downy mildew, leaf spot, damping off, banded sclerotial blight, rice blast etc., has enlarged fungicidal spectrum.
4. reduction use cost.The independent use cost of oxime bacterium ester is higher, is mixed with lower-cost carbendazim, thiophanate-methyl and can reduces use cost, enlarges its scope of application.
5. genus environment friendly agricultural.Oxime bacterium ester, carbendazim, thiophanate-methyl all belong to low-toxin farm chemicals, its complex preparation, and high-efficiency low-toxicity to crop and Environmental security, helps the sustainable development of agricultural production.
Embodiment
The present invention will be further described for following examples, but the present invention is not limited thereto.
Embodiments of the invention are the methods that adopt indoor bioassay and field trial to combine.By indoor bioassay, the co-toxicity coefficient after clear and definite two kinds of medicaments are composite by a certain percentage on this basis, carries out field trial more earlier.
Implementation of an application example monoxime bacterium ester and carbendazim or thiophanate-methyl different proportion are used with target
The Toxicity Determination of germ
1, experimental condition
Target: apple mildew bacterium; Sigatoka.
The target germ kind that indoor 4 ℃ of refrigerators are preserved is transferred on the PDA medium, in 28 ℃ of incubators, cultivate and make its activation, through standby after twice switching.
2, test medicine
The former medicine of oxime bacterium ester, content 96% (commercial)
Carbendazim active compound, content 98% (commercial)
The former medicine of thiophanate-methyl, content 95% (commercial)
3, experiment is handled
After the effective inhibition concentration scope of each medicament was determined in prerun, each medicament was established 5 dosage respectively by active constituent content and is handled, and established the clear water contrast, and concrete treatment dosage is as follows:
Oxime bacterium ester 0.1,0.2,0.5,1,2 μ g/mL
Carbendazim 0.5,1,2,5,10 μ g/mL
Thiophanate-methyl 0.5,1,2,5,10 μ g/mL
Oxime bacterium ester: carbendazim (1: 64) 0.1,0.2,0.5,1,2 μ g/mL
Oxime bacterium ester: carbendazim (1: 32) 0.1,0.2,0.5,1,2 μ g/mL
Oxime bacterium ester: carbendazim (1: 16) 0.1,0.2,0.5,1,2 μ g/mL
Oxime bacterium ester: carbendazim (1: 8) 0.1,0.2,0.5,1,2 μ g/mL
Oxime bacterium ester: carbendazim (1: 4) 0.1,0.2,0.5,1,2 μ g/mL
Oxime bacterium ester: carbendazim (1: 2) 0.1,0.2,0.5,1,2 μ g/mL
Oxime bacterium ester: carbendazim (2: 1) 0.1,0.2,0.5,1,2 μ g/mL
Oxime bacterium ester: carbendazim (4: 1) 0.1,0.2,0.5,1,2 μ g/mL
Oxime bacterium ester: carbendazim (8: 1) 0.1,0.2,0.5,1,2 μ g/mL
Oxime bacterium ester: carbendazim (16: 1) 0.1,0.2,0.5,1,2 μ g/mL
Oxime bacterium ester: thiophanate-methyl (1: 64) 0.1,0.2,0.5,1,2 μ g/mL
Oxime bacterium ester: thiophanate-methyl (1: 32) 0.1,0.2,0.5,1,2 μ g/mL
Oxime bacterium ester: thiophanate-methyl (1: 16) 0.1,0.2,0.5,1,2 μ g/mL
Oxime bacterium ester: thiophanate-methyl (1: 8) 0.1,0.2,0.5,1,2 μ g/mL
Oxime bacterium ester: thiophanate-methyl (1: 4) 0.1,0.2,0.5,1,2 μ g/mL
Oxime bacterium ester: thiophanate-methyl (1: 2) 0.1,0.2,0.5,1,2 μ g/mL
Oxime bacterium ester: thiophanate-methyl (2: 1) 0.1,0.2,0.5,1,2 μ g/mL
Oxime bacterium ester: thiophanate-methyl (4: 1) 0.1,0.2,0.5,1,2 μ g/mL
Oxime bacterium ester: thiophanate-methyl (8: 1) 0.1,0.2,0.5,1,2 μ g/mL
Oxime bacterium ester: thiophanate-methyl (16: 1) 0.1,0.2,0.5,1,2 μ g/mL
Each concentration is handled and is repeated 4 times.
4, test method
Carry out with reference to " agricultural chemicals indoor bioassay test rule bactericide ".This experiment adopts the mycelial growth rate method to measure the virulence of medicament to the target germ.Concrete grammar is as follows: the target germ bacterial strain through the switching spark is cultivated with PDA, when treating that bacterium colony grows to culture dish 3/4ths size, is that the card punch of 5mm punches from the edge with internal diameter, and the mycelia piece that breaks into is as inoculum.The soup 4ml that respectively handles that gets the concentration for preparing respectively and be 10 times of above-mentioned design concentrations evenly mixes with quantitative 36ml sterilization PDA medium, divide and pour in 3 sterilization culture dishes, make the pastille flat board after the cooling, be mixed into contrast, 4 repetitions of every Treatment Design with equivalent aqua sterilisa and culture dish.To inoculate mycelia and be inverted in dull and stereotyped central authorities, and put into 28 ℃ of incubators and cultivate.Measure colony diameter with the right-angled intersection method behind the 96h, calculate and respectively handle clean amount of growth, mycelial growth inhibition rate.
5, calculate
Clean amount of growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value (x) to, tries to achieve virulence regression equation (y=a+bx) with method of least squares, and calculates the EC of every kind of medicament thus
50Value.Calculate the different proportioning synergy ratios (SR) of two medicaments according to the Wadley method simultaneously, SR＜0.5 is an antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively oxime bacterium ester and carbendazim or thiophanate-methyl shared ratio in combination
A is an oxime bacterium ester
B is carbendazim or thiophanate-methyl
6, experimental result and analysis
Toxicity test result one
Table 1 oxime bacterium ester, carbendazim and composite toxicity test analysis of results table thereof to sigatoka
As shown in Table 1, oxime bacterium ester, carbendazim are to the EC of sigatoka germ
50Be respectively 1.18 μ g/mL and 15.34 μ g/mL.1: 64 to 16: 1 synergy ratio of oxime bacterium ester and carbendazim proportioning shows as synergistic effect entirely greater than 1.5, especially when oxime bacterium ester and carbendazim proportioning at 1: 16 between 2: 1 the time, synergistic effect is the most obvious.
Toxicity test result two
Table 2 oxime bacterium ester, thiophanate-methyl and composite toxicity test analysis of results table thereof to apple mildew
As shown in Table 1, oxime bacterium ester, carbendazim are to the EC of apple mildew germ
50Be respectively 1.54 μ g/mL and 17.27 μ g/mL.1: 64 to 16: 1 synergy ratio of oxime bacterium ester and carbendazim proportioning shows as synergistic effect entirely greater than 1.5, especially when oxime bacterium ester and carbendazim proportioning at 1: 16 between 2: 1 the time, synergistic effect is the most obvious.
Implementation of an application example dioxime bacterium ester and carbendazim or thiophanate-methyl compounded formula material and field control effectiveness test
Embodiment 1:50% oxime bacterium ester carbendazol wettable powder
Get oxime bacterium ester 15g, carbendazim 35g, carboxymethyl cellulose 5g, di-2-ethylhexylphosphine oxide benzene sulfonic acid sodium salt 3g, neopelex 5g, white carbon black 10g, kaolin 27g places agitator to stir, and promptly can be made into 50% oxime bacterium ester carbendazol wettable powder through comminution by gas stream to 500 orders.
Embodiment 2:50% oxime bacterium METH thiophanate wetting powder
Get oxime bacterium ester 18g, thiophanate-methyl 32g, polycarboxylate 8g, neopelex 4g, white carbon 10g, diatomite 28g places agitator to stir, and promptly can be made into 50% oxime bacterium METH thiophanate wetting powder through comminution by gas stream to 500 orders.
50% oxime bacterium ester carbendazim WP, oxime bacterium METH thiophanate WP control the apple mildew field trial
1, test medicine
50% carbendazim oxime bacterium ester WP (Shanxi Thompson Biological Technology Co., Ltd. provides)
2, contrast medicament
12.5% oxime bacterium emulsifiable concentrate EC (commercial)
50% carbendazol wettable powder WP (commercial)
70% thiophanate-methyl wetting powder WP (commercial)
3, dosing and processing numbering
Table 3 reagent agent experimental scheme
4, spraying time and number of times
Totally three dispensers, dispenser for the first time when disease just takes place, the dispenser in 10 days of every interval is once.
5, control time and method
The dispenser " Invest, Then Investigate " was carried out in radix investigation before the dispenser in 10 days respectively after each dispenser.
According to apple tree leaf sheath and blade hazard symptoms grading, be unit with the strain, diagonal 5 samplings in every sub-district are investigated adjacent 5 clumps, totally 25 clumps, are write down total strain number, diseased plant number and sick progression for every.
Stage division:
0 grade: complete stool is anosis;
1 grade: quaterfoil and following each leaf sheath thereof, blade morbidity (is first leaf with sword-like leave);
3 grades: the 3rd blade and following each leaf sheath thereof, blade morbidity;
5 grades: second blade and following each leaf sheath thereof, blade morbidity;
7 grades: sword-like leave blade and following each leaf sheath, blade morbidity;
9 grades: full leaf morbidity, fall leaves.
6, drug effect computational methods
In the formula: CK
0Disease index before the dispenser of-blank district;
CK
1Disease index after the dispenser of-blank district;
PT
0Disease index before the dispenser of-chemicals treatment district;
PT
1Disease index after the dispenser of-chemicals treatment district.
7, test results and analysis
The composite apple mildew result of the test of preventing and treating of table 4 oxime bacterium ester and carbendazim or thiophanate-methyl
As shown in Table 4, oxime bacterium ester and carbendazim or thiophanate-methyl are composite remarkable to the apple mildew control efficiency, compare with single agent, have preventive effect height, long, residual little advantage of lasting period, in the test scope of medication, the target crop are had no adverse effects.
Embodiment 3:80% oxime bacterium ester carbendazim water dispersing granule
Get oxime bacterium ester 20g, carbendazim 60g, sodium lignin sulfonate 5g, lauryl sodium sulfate 8g, ammonium sulfate 4g, starch 3g, formulation material is mixed, pulverize, through mediating with micro jet, add then and carry out granulation, drying, screening in the fluidized bed prilling dryer after sample analysis can be made into 80% oxime bacterium ester carbendazim water dispersing granule.
Embodiment 4:80% oxime bacterium METH thiophanate water dispersible granules
Get oxime bacterium ester 30g, thiophanate-methyl 50g, alkyl benzene sulfonate calcium salt 5g, wetting and penetrating agent F 3g, neopelex 5g, starch 2g, kaolin 5g mixes formulation material, pulverize with micro jet, through mediating, add then and carry out granulation, drying, screening in the fluidized bed prilling dryer after sample analysis can be made into 80% oxime bacterium METH thiophanate water dispersible granules.
Composite sigatoka test of pesticide effectiveness result such as the table 5 prevented and treated of oxime bacterium ester and carbendazim or thiophanate-methyl:
The composite sigatoka result of the test of preventing and treating of table 5 oxime bacterium ester and carbendazim or thiophanate-methyl
As shown in Table 5, oxime bacterium ester and carbendazim or thiophanate-methyl are composite remarkable to the sigatoka control efficiency, compare with single agent, have preventive effect height, long, residual little advantage of lasting period.In this experimental drug weight range,, have no adverse effects to the target crop safety.
Embodiment 5:20% oxime bacterium ester carbendazim suspending agent
Get oxime bacterium ester 5g, carbendazim 15g, neopelex 5g, ethylene glycol 3g, aluminium-magnesium silicate 0.8g, xanthans 0.1g, silicone defoaming agent 0.1g, white carbon 1g, water surplus.With in the above-mentioned formulation material except that crossing all the other components of active ingredient, mix through high speed shear, adding active ingredient, ball milling is 2～3 hours in ball mill, makes particle diameter all below 5 μ m, makes 20% oxime bacterium ester carbendazim suspending agent.
Embodiment 6:30% oxime bacterium METH thiophanate suspending agent
Get oxime bacterium ester 10g, thiophanate-methyl 20g, alkyl benzene calcium sulfonate 5g, glycerine 3g, aluminium-magnesium silicate 0.8g, xanthans 0.1g, silicone defoaming agent 0.1g, white carbon 1g, water surplus.Back in the above-mentioned formulation material except that crossing all the other components of active ingredient, is mixed through high speed shear, adding active ingredient, ball milling is 2～3 hours in ball mill, makes particle diameter all below 5 μ m, makes 30% oxime bacterium METH thiophanate suspending agent.
Composite downy mildew of garpe test of pesticide effectiveness result such as the table 6 prevented and treated of oxime bacterium ester and carbendazim or thiophanate-methyl:
The composite downy mildew of garpe result of the test of preventing and treating of table 6 oxime bacterium ester and carbendazim or thiophanate-methyl
As shown in Table 6, oxime bacterium ester and carbendazim or thiophanate-methyl are composite remarkable to the downy mildew of garpe control efficiency, compare with single agent, have preventive effect height, long, residual little advantage of lasting period.In this experimental drug weight range,, have no adverse effects to grape safety.
Embodiment 7:
Table 7 oxime bacterium ester and carbendazol wettable powder are prevented and treated the powdery mildew of cucumber result of the test
Table 8 oxime bacterium ester and thiophanate-methyl wetting powder control cucumber downy mildew result of the test
Embodiment 8:
Table 7 oxime bacterium ester and carbendazim water dispersing granule are prevented and treated the ring rot of apple result of the test
Table 8 oxime bacterium ester and thiophanate-methyl water dispersible granules control capsicum epidemic disease result of the test
Embodiment 9:
Table 11 oxime bacterium ester and carbendazim suspension emulsion are prevented and treated the wheat rust result of the test
Table 12 oxime bacterium ester and thiophanate-methyl suspension emulsion control rice blast result of the test
Claims (7)
1. composition pesticide that contains oxime bacterium ester is characterized in that bactericidal composition effective active composition (A) the oxime bacterium ester and (B) weight ratio of carbendazim or thiophanate-methyl are 1: 64 to 16: 1.
2. the bactericidal composition that contains oxime bacterium ester according to claim 1 is characterized in that: wherein (A) oxime bacterium ester is 1: 32 to 4: 1 with the weight ratio of (B) carbendazim or thiophanate-methyl.
3. the bactericidal composition that contains oxime bacterium ester according to claim 2 is characterized in that: wherein (A) oxime bacterium ester is 1: 16 to 1: 2 with (B) weight ratio of carbendazim.
4. the bactericidal composition that contains oxime bacterium ester according to claim 2 is characterized in that: wherein (A) oxime bacterium ester is 1: 16 to 1: 2 with (B) weight ratio of thiophanate-methyl.
5. the bactericidal composition that contains oxime bacterium ester according to claim 1 is characterized in that: wherein the effective active component content accounts for 1～90% of gross weight.
6. the bactericidal composition that contains oxime bacterium ester according to claim 4 is characterized in that: wherein the effective active component content accounts for 10～80% of gross weight.
7. the bactericidal composition that contains oxime bacterium ester according to claim 1 is used to prevent and treat plant diseases such as powdery mildew, anthracnose, eqpidemic disease, downy mildew, leaf spot, damping off, banded sclerotial blight, rice blast.
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| CN2011100742169A CN102217617A (en) | 2011-03-25 | 2011-03-25 | Pesticide composition containing trifloxystrobin |
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| CN2011100742169A CN102217617A (en) | 2011-03-25 | 2011-03-25 | Pesticide composition containing trifloxystrobin |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103168785A (en) * | 2013-03-22 | 2013-06-26 | 江苏七洲绿色化工股份有限公司 | Ternary compound sterilizing composition containing trifloxystrobin and application of sterilizing composition |
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| US6407100B1 (en) * | 1990-06-05 | 2002-06-18 | Bayer Aktiengesellschaft | Fungicidal aromatic oximes |
| CN101321463A (en) * | 2005-12-03 | 2008-12-10 | 拜尔农作物科学股份公司 | Fungicidal active ingredient combination |
| CN101325877A (en) * | 2005-12-09 | 2008-12-17 | 拜尔农作物科学股份公司 | Fungicidal active substance combination |
| CN101330827A (en) * | 2005-12-16 | 2008-12-24 | 拜尔农作物科学股份公司 | Fungicidal active compound combination |
| CN102781234A (en) * | 2010-02-05 | 2012-11-14 | 龙灯农业化工国际有限公司 | Method for treating fungal infections, fungicidal compositions and their use |
-
2011
- 2011-03-25 CN CN2011100742169A patent/CN102217617A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6407100B1 (en) * | 1990-06-05 | 2002-06-18 | Bayer Aktiengesellschaft | Fungicidal aromatic oximes |
| CN101321463A (en) * | 2005-12-03 | 2008-12-10 | 拜尔农作物科学股份公司 | Fungicidal active ingredient combination |
| CN101325877A (en) * | 2005-12-09 | 2008-12-17 | 拜尔农作物科学股份公司 | Fungicidal active substance combination |
| CN101330827A (en) * | 2005-12-16 | 2008-12-24 | 拜尔农作物科学股份公司 | Fungicidal active compound combination |
| CN102781234A (en) * | 2010-02-05 | 2012-11-14 | 龙灯农业化工国际有限公司 | Method for treating fungal infections, fungicidal compositions and their use |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103168785A (en) * | 2013-03-22 | 2013-06-26 | 江苏七洲绿色化工股份有限公司 | Ternary compound sterilizing composition containing trifloxystrobin and application of sterilizing composition |
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