CN102204556A - Pesticide composite containing enestroburin - Google Patents
Pesticide composite containing enestroburin Download PDFInfo
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- CN102204556A CN102204556A CN2011100901235A CN201110090123A CN102204556A CN 102204556 A CN102204556 A CN 102204556A CN 2011100901235 A CN2011100901235 A CN 2011100901235A CN 201110090123 A CN201110090123 A CN 201110090123A CN 102204556 A CN102204556 A CN 102204556A
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- enestroburin
- carbendazim
- methyl
- thiophanate
- active component
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Abstract
The invention provides a pesticide composite containing enestroburin. The pesticide composite comprises active components A and B, wherein the active component A is enestroburin and the active component B is one of carbendazin and thiophanate-methyl, and the ratio of the active component A to the active component B in parts by weight is 1:64-16:1. The pesticide composite can be prepared into wettable powder, water dispersible granule, suspending agent, suspending emulsifier and the like and has an ideal prevention effect on crop diseases such as powdery mildew, anthracnose, phytophthora blight, downy mildew, leaf spot, damping off, banded sclerotial blight, rice blast and the like.
Description
Technical field
The invention belongs to technical field of pesticide, be specifically related to the composite composition pesticide of a kind of Enestroburin and carbendazim or thiophanate-methyl, be used for the control of plant disease.
Technical background
Enestroburin (enostroburin), molecular formula: C
22H
27ClNO
4, chemical name: α-[[[[4-(4-chlorphenyl)-Ding-3-alkene-2-base-] imido grpup] methyl] phenyl-'beta '-methoxy acrylic acid methyl esters.
Enestroburin class wide-spectrum bactericide is a class novel agrochemical of successfully developing as the bactericide lead compound from natural products Strobilurins, belongs to methoxy acrylic bactericide.The action principle of this type of medicament is to suppress the mitochondrial breathing of fungi, the Q0 position by cytochrome b c1 complex in conjunction with suppressing mitochondrial current potential transmission, the germ energy is synthetic to play bactericidal action thereby destroy.Characteristics such as having efficient, wide spectrum, protection, treat, root out, infiltration, systemic activity, resistance of rainwater washing against, lasting period are long.To 1,4-demethylation enzyme inhibitor, benzamides, the bacterial strain of dicarboxyl amine and benzimidazole generation resistance is effective, does not have cross resistance with at present existing bactericide.Nearly all Mycophytes (Ascomycetes, Basidiomycetes, Oomycete and Fungi Imperfecti) disease such as powdery mildew, rust, Ying's rot, net blotch, eqpidemic disease, downy mildew, rice blast etc. all there is good activity.To crop safety, because of its at soil, capable of being fast degraded in the water, so environmentally safe.
Enestroburin is to all having good activity to nearly all Mycophytes disease, is easy to generate pesticide resistance and cost is higher but use separately, is unfavorable for that large tracts of land promotes the use of; Carbendazim, thiophanate-methyl fungicidal spectrum are wide, and use cost is lower, but in recent years because resistance rises to some extent, use the effect that preventive effect is undesirable, enlarge fungicidal spectrum, reduce cost separately.Field and indoor biometrics show, Enestroburin and carbendazim are composite, Enestroburin and thiophanate-methyl are composite all has a synergistic effect preferably, single with being significantly improved to more single agent such as the preventive effect of powdery mildew, anthracnose, eqpidemic disease, downy mildew, leaf spot, damping off, banded sclerotial blight, rice blast etc.
Summary of the invention
Enestroburin of the present invention and carbendazim or thiophanate-methyl complex preparation can be used for preventing and treating the multiple diseases on the crop, and crop is had excellent protection and therapeutic action, and field trial has showed extremely strong antibiotic and bactericidal activity.
The present invention realizes in the following manner:
A kind of composition pesticide that contains Enestroburin is characterized in that bactericidal composition effective active composition (A) Enestroburin and the weight ratio of (B) carbendazim or thiophanate-methyl are 1: 64 to 16: 1.
The described bactericidal composition that contains Enestroburin is characterized in that: wherein (A) Enestroburin is 1: 32 to 4: 1 with the weight ratio of (B) carbendazim or thiophanate-methyl.
The described bactericidal composition that contains Enestroburin is characterized in that: wherein the weight ratio of Enestroburin and carbendazim is 1: 16 to 1: 2.
The described bactericidal composition that contains Enestroburin is characterized in that: wherein the weight ratio of Enestroburin and thiophanate-methyl is 1: 16 to 1: 2.
The described bactericidal composition that contains Enestroburin is characterized in that: wherein the effective active component content accounts for 1～90% of gross weight, is preferably 10～80%.
The described composition pesticide that contains Enestroburin can add auxiliary agent on demand and excipients is processed into acceptable forms on any agricultural chemicals, wherein excellently selects formulation to be: wetting powder, water dispersible granules, suspending agent, suspension emulsion.
The described Enestroburin composition pesticide that contains is characterized in that auxiliary agent and excipients comprise: dispersant, wetting agent, disintegrant, emulsifier, thickener, antifreeze, defoamer, filler.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, DBSA, Nekal BX, wetting and penetrating agent F, alkylnaphthalene sulfonate, polyoxyethylene triphenylethylene phosphenylic acid salt, spaonin powder, silkworm excrement, the soapberry powder.
Described dispersant is selected from one or more in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, the fatty acid glyceride APEO.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, the sodium bicarbonate.
Described thickener is selected from: one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, the polyvinyl alcohol.
Described emulsifier is selected from one or more among alkyl benzene sulfonate calcium salt, styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, phenethyl phenol polyethenoxy ether, 506#, 600#, 700#, NP-10 phosphate, OP-10 phosphate, castor oil polyoxyethylene ether, sorbester p17, Tween 80, the 602#;
Described defoamer is selected from: one or more in silicone oil, silicone compound, C10-20 saturated fat acid compounds, the C8-10 aliphatic alcohols compound.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, the glycerine.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
The described bactericidal composition that contains Enestroburin is used to prevent and treat plant diseases such as powdery mildew, anthracnose, eqpidemic disease, downy mildew, leaf spot, damping off, banded sclerotial blight, rice blast, and the preventive effect ideal is compared with single agent, has obvious synergistic effect.
The present invention has following characteristics:
1. double action mechanism, germ are difficult for producing resistance;
2. synergistic effect is obvious.Indoor biometrics is tested the result and shown: Enestroburin and carbendazim or thiophanate-methyl are composite by a certain percentage to have clearly synergistic effect to crop pest;
3. expansion fungicidal spectrum.Enestroburin and carbendazim or thiophanate-methyl be composite prevents and treats multiple main disease, as downy mildew, eqpidemic disease, powdery mildew, anthracnose, leaf spot, damping off, banded sclerotial blight, rice blast etc., has enlarged fungicidal spectrum.
4. reduction use cost.The independent use cost of Enestroburin is higher, is mixed with lower-cost carbendazim, thiophanate-methyl and can reduces use cost, enlarges its scope of application.
5. genus environment friendly agricultural.Enestroburin, carbendazim, thiophanate-methyl all belong to low-toxin farm chemicals, its complex preparation, and high-efficiency low-toxicity to crop and Environmental security, helps the sustainable development of agricultural production.
Embodiment
The present invention will be further described for following examples, but the present invention is not limited thereto.
Embodiments of the invention are the methods that adopt indoor bioassay and field trial to combine.By indoor bioassay, the co-toxicity coefficient after clear and definite two kinds of medicaments are composite by a certain percentage on this basis, carries out field trial more earlier.
Implementation of an application example one Enestroburin and carbendazim or thiophanate-methyl different proportion are used the Toxicity Determination to the target germ with
1, experimental condition
Target: apple mildew bacterium; Cucumber downy mildew.
The target germ kind that indoor 4 ℃ of refrigerators are preserved is transferred on the PDA medium, in 28 ℃ of incubators, cultivate and make its activation, through standby after twice switching.
2, test medicine
The former medicine of Enestroburin, content 90% (commercial)
Carbendazim active compound, content 98% (commercial)
The former medicine of thiophanate-methyl, content 95% (commercial)
3, experiment is handled
After the effective inhibition concentration scope of each medicament was determined in prerun, each medicament was established 5 dosage respectively by active constituent content and is handled, and established the clear water contrast, and concrete treatment dosage is as follows:
Enestroburin 0.1,0.2,0.5,1,2 μ g/mL
Carbendazim 0.5,1,2,5,10 μ g/mL
Thiophanate-methyl 0.5,1,2,5,10 μ g/mL
Enestroburin: carbendazim (1: 64) 0.1,0.2,0.5,1,2 μ g/mL
Enestroburin: carbendazim (1: 32) 0.1,0.2,0.5,1,2 μ g/mL
Enestroburin: carbendazim (1: 16) 0.1,0.2,0.5,1,2 μ g/mL
Enestroburin: carbendazim (1: 8) 0.1,0.2,0.5,1,2 μ g/mL
Enestroburin: carbendazim (1: 4) 0.1,0.2,0.5,1,2 μ g/mL
Enestroburin: carbendazim (1: 2) 0.1,0.2,0.5,1,2 μ g/mL
Enestroburin: carbendazim (2: 1) 0.1,0.2,0.5,1,2 μ g/mL
Enestroburin: carbendazim (4: 1) 0.1,0.2,0.5,1,2 μ g/mL
Enestroburin: carbendazim (8: 1) 0.1,0.2,0.5,1,2 μ g/mL
Enestroburin: carbendazim (16: 1) 0.1,0.2,0.5,1,2 μ g/mL
Enestroburin: thiophanate-methyl (1: 64) 0.1,0.2,0.5,1,2 μ g/mL
Enestroburin: thiophanate-methyl (1: 32) 0.1,0.2,0.5,1,2 μ g/mL
Enestroburin: thiophanate-methyl (1: 16) 0.1,0.2,0.5,1,2 μ g/mL
Enestroburin: thiophanate-methyl (1: 8) 0.1,0.2,0.5,1,2 μ g/mL
Enestroburin: thiophanate-methyl (1: 4) 0.1,0.2,0.5,1,2 μ g/mL
Enestroburin: thiophanate-methyl (1: 2) 0.1,0.2,0.5,1,2 μ g/mL
Enestroburin: thiophanate-methyl (2: 1) 0.1,0.2,0.5,1,2 μ g/mL
Enestroburin: thiophanate-methyl (4: 1) 0.1,0.2,0.5,1,2 μ g/mL
Enestroburin: thiophanate-methyl (8: 1) 0.1,0.2,0.5,1,2 μ g/mL
Enestroburin: thiophanate-methyl (16: 1) 0.1,0.2,0.5,1,2 μ g/mL
Each concentration is handled and is repeated 4 times.
4, test method
Carry out with reference to " agricultural chemicals indoor bioassay test rule bactericide ".This experiment adopts the mycelial growth rate method to measure the virulence of medicament to the target germ.Concrete grammar is as follows: the target germ bacterial strain through the switching spark is cultivated with PDA, when treating that bacterium colony grows to culture dish 3/4ths size, is that the card punch of 5mm punches from the edge with internal diameter, and the mycelia piece that breaks into is as inoculum.The soup 4ml that respectively handles that gets the concentration for preparing respectively and be 10 times of above-mentioned design concentrations evenly mixes with quantitative 36ml sterilization PDA medium, divide and pour in 3 sterilization culture dishes, make the pastille flat board after the cooling, be mixed into contrast, 4 repetitions of every Treatment Design with equivalent aqua sterilisa and culture dish.To inoculate mycelia and be inverted in dull and stereotyped central authorities, and put into 28 ℃ of incubators and cultivate.Measure colony diameter with the right-angled intersection method behind the 96h, calculate and respectively handle clean amount of growth, mycelial growth inhibition rate.
5, calculate
Clean amount of growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value (x) to, tries to achieve virulence regression equation (y=a+bx) with method of least squares, and calculates the EC of every kind of medicament thus
50Value.Calculate the different proportioning synergy ratios (SR) of two medicaments according to the Wadley method simultaneously, SR＜0.5 is an antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively Enestroburin and carbendazim or thiophanate-methyl shared ratio in combination
A is an Enestroburin
B is carbendazim or thiophanate-methyl
6, experimental result and analysis
Toxicity test result one
Table 1 Enestroburin, carbendazim and composite toxicity test analysis of results table thereof to cucumber downy mildew
As shown in Table 1, Enestroburin, carbendazim are to the EC of cucumber downy mildew germ
50Be respectively 0.98 μ g/mL and 21.57 μ g/mL.1: 64 to 16: 1 synergy ratio of Enestroburin and carbendazim proportioning shows as synergistic effect entirely greater than 1.5, especially when Enestroburin and carbendazim proportioning at 1: 16 between 2: 1 the time, synergistic effect is the most obvious.
Toxicity test result two
Table 2 Enestroburin, thiophanate-methyl and composite toxicity test analysis of results table thereof to apple mildew
As shown in Table 1, Enestroburin, carbendazim are to the EC of apple mildew germ
50Be respectively 1.24 μ g/mL and 19.78 μ g/mL.1: 64 to 16: 1 synergy ratio of Enestroburin and carbendazim proportioning shows as synergistic effect entirely greater than 1.5, especially when Enestroburin and carbendazim proportioning at 1: 16 between 2: 1 the time, synergistic effect is the most obvious.
Implementation of an application example two Enestroburins and carbendazim or thiophanate-methyl compounded formula material and field control effectiveness test
Embodiment 1:50% Enestroburin carbendazol wettable powder
Get Enestroburin 15g, carbendazim 35g, polycarboxylate 8g, neopelex 4g, white carbon 10g, kaolin adds to 100g, places agitator to stir, and promptly can be made into 50% Enestroburin carbendazol wettable powder through comminution by gas stream to 500 orders.
Embodiment 2:50% Enestroburin thiophanate-methyl wetting powder
Get Enestroburin 18g, thiophanate-methyl 32g, carboxymethyl cellulose 5g, di-2-ethylhexylphosphine oxide benzene sulfonic acid sodium salt 3g, neopelex 5g, white carbon 10g, diatomite adds to 100g, place agitator to stir, promptly can be made into 50% Enestroburin thiophanate-methyl wetting powder to 500 orders through comminution by gas stream.
50% Enestroburin carbendazim WP, Enestroburin thiophanate-methyl WP control the apple mildew field trial
1, test medicine
50% carbendazim Enestroburin WP (Shanxi Thompson Biological Technology Co., Ltd. provides)
2, contrast medicament
25% Enestroburin missible oil EC (commercial)
50% carbendazol wettable powder WP (commercial)
70% thiophanate-methyl wetting powder WP (commercial)
3, dosing and processing numbering
Table 3 reagent agent experimental scheme
| Handle numbering | Medicament | Extension rate |
| 1 | 50% Enestroburin carbendazim WP | 3000 times |
| 2 | 50% Enestroburin carbendazim WP | 2000 times |
| 3 | 50% Enestroburin carbendazim WP | 1000 times |
| 4 | 50% Enestroburin first sulphur WP | 3000 times |
| 5 | 50% Enestroburin first sulphur WP | 2000 times |
| 6 | 50% Enestroburin first sulphur WP | 1000 times |
| 7 | 25% Enestroburin EC (CK) | 1250 times |
| 8 | 50% carbendazim WP (CK) | 600 times |
| 9 | 70% thiophanate-methyl WP (CK) | 800 times |
| 10 | The clear water contrast | - |
4, spraying time and number of times
Totally three dispensers, dispenser for the first time when disease just takes place, the dispenser in 10 days of every interval is once.
5, control time and method
The dispenser " Invest, Then Investigate " was carried out in radix investigation before the dispenser in 10 days respectively after each dispenser.
According to apple tree leaf sheath and blade hazard symptoms grading, be unit with the strain, diagonal 5 samplings in every sub-district are investigated adjacent 5 clumps, totally 25 clumps, are write down total strain number, diseased plant number and sick progression for every.
Stage division:
0 grade: complete stool is anosis;
1 grade: quaterfoil and following each leaf sheath thereof, blade morbidity (is first leaf with sword-like leave);
3 grades: the 3rd blade and following each leaf sheath thereof, blade morbidity;
5 grades: second blade and following each leaf sheath thereof, blade morbidity;
7 grades: sword-like leave blade and following each leaf sheath, blade morbidity;
9 grades: full leaf morbidity, fall leaves.
6, drug effect computational methods
In the formula: CK
0Disease index before the dispenser of-blank district;
CK
1Disease index after the dispenser of-blank district;
PT
0Disease index before the dispenser of-chemicals treatment district;
PT
1Disease index after the dispenser of-chemicals treatment district.
7, test results and analysis
The composite apple mildew result of the test of preventing and treating of table 4 Enestroburin and carbendazim or thiophanate-methyl
As shown in Table 4, Enestroburin and carbendazim or thiophanate-methyl are composite remarkable to the apple mildew control efficiency, compare with single agent, have preventive effect height, long, residual little advantage of lasting period, in the test scope of medication, the target crop are had no adverse effects.
Embodiment 3:80% Enestroburin carbendazim water dispersing granule
Get Enestroburin 20g, carbendazim 60g, sodium lignin sulfonate 5g, lauryl sodium sulfate 5g, ammonium sulfate 4g, starch 6g, formulation material is mixed, pulverize, through mediating with micro jet, add then and carry out granulation, drying, screening in the fluidized bed prilling dryer after sample analysis can be made into 80% Enestroburin carbendazim water dispersing granule.
Embodiment 4:80% Enestroburin thiophanate-methyl water dispersible granules
Get Enestroburin 15g, thiophanate-methyl 65g, alkyl benzene sulfonate calcium salt 5g, wetting and penetrating agent F 3g, neopelex 5g, starch 2g, kaolin 5g mixes formulation material, pulverize with micro jet, through mediating, add then and carry out granulation, drying, screening in the fluidized bed prilling dryer after sample analysis can be made into 80% Enestroburin thiophanate-methyl water dispersible granules.
Composite downy mildew of garpe test of pesticide effectiveness result such as the table 5 prevented and treated of Enestroburin and carbendazim or thiophanate-methyl:
The composite downy mildew of garpe result of the test of preventing and treating of table 5 Enestroburin and carbendazim or thiophanate-methyl
As shown in Table 5, Enestroburin and carbendazim or thiophanate-methyl are composite remarkable to the downy mildew of garpe control efficiency, compare with single agent, have preventive effect height, long, residual little advantage of lasting period.In this experimental drug weight range,, have no adverse effects to the target crop safety.
Embodiment 5:20% Enestroburin carbendazim suspending agent
Get Enestroburin 5g, carbendazim 15g, neopelex 5g, ethylene glycol 3g, aluminium-magnesium silicate 0.8g, xanthans 0.1g, silicone defoaming agent 0.1g, white carbon 1g, water surplus.With in the above-mentioned formulation material except that crossing all the other components of active ingredient, mix through high speed shear, adding active ingredient, ball milling is 2～3 hours in ball mill, makes particle diameter all below 5 μ m, makes 20% Enestroburin carbendazim suspending agent.
Embodiment 6:30% Enestroburin thiophanate-methyl suspending agent
Get Enestroburin 10g, thiophanate-methyl 20g, alkyl benzene calcium sulfonate 5g, glycerine 3g, aluminium-magnesium silicate 0.8g, xanthans 0.1g, silicone defoaming agent 0.1g, white carbon 1g, water surplus.Back in the above-mentioned formulation material except that crossing all the other components of active ingredient, is mixed through high speed shear, adding active ingredient, ball milling is 2～3 hours in ball mill, makes particle diameter all below 5 μ m, makes 30% Enestroburin thiophanate-methyl suspending agent.
Composite downy mildew of garpe test of pesticide effectiveness result such as the table 6 prevented and treated of Enestroburin and carbendazim or thiophanate-methyl:
The composite downy mildew of garpe result of the test of preventing and treating of table 6 Enestroburin and carbendazim or thiophanate-methyl
As shown in Table 6, Enestroburin and carbendazim or thiophanate-methyl are composite remarkable to the downy mildew of garpe control efficiency, compare with single agent, have preventive effect height, long, residual little advantage of lasting period.
In this experimental drug weight range,, have no adverse effects to grape safety.
Embodiment 7:
Table 7 Enestroburin and carbendazol wettable powder are prevented and treated the powdery mildew of cucumber result of the test
Table 8 Enestroburin and thiophanate-methyl wetting powder control cucumber downy mildew result of the test
Embodiment 8:
Table 7 Enestroburin and carbendazim water dispersing granule are prevented and treated the ring rot of apple result of the test
Table 8 Enestroburin and thiophanate-methyl water dispersible granules control capsicum epidemic disease result of the test
Embodiment 9:
Table 11 Enestroburin and carbendazim suspension emulsion are prevented and treated the wheat rust result of the test
Table 12 Enestroburin and thiophanate-methyl suspension emulsion control rice blast result of the test
Claims (7)
1. composition pesticide that contains Enestroburin is characterized in that bactericidal composition effective active composition (A) Enestroburin and (B) weight ratio of carbendazim or thiophanate-methyl are 1: 64 to 16: 1.
2. the bactericidal composition that contains Enestroburin according to claim 1 is characterized in that: wherein (A) Enestroburin is 1: 32 to 4: 1 with the weight ratio of (B) carbendazim or thiophanate-methyl.
3. the bactericidal composition that contains Enestroburin according to claim 2 is characterized in that: wherein (A) Enestroburin is 1: 16 to 1: 2 with (B) weight ratio of carbendazim.
4. the bactericidal composition that contains Enestroburin according to claim 2 is characterized in that: wherein (A) Enestroburin is 1: 16 to 1: 2 with (B) weight ratio of thiophanate-methyl.
5. the bactericidal composition that contains Enestroburin according to claim 1 is characterized in that: wherein the effective active component content accounts for 1～90% of gross weight.
6. the bactericidal composition that contains Enestroburin according to claim 5 is characterized in that: wherein the effective active component content accounts for 10～80% of gross weight.
7. the bactericidal composition that contains Enestroburin according to claim 1 is used to prevent and treat plant diseases such as powdery mildew, anthracnose, eqpidemic disease, downy mildew, leaf spot, damping off, banded sclerotial blight, rice blast.
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| WO2012046877A3 (en) * | 2010-10-07 | 2012-11-08 | Sumitomo Chemical Company, Limited | Plant disease controlling composition and method for controlling plant disease |
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| CN1608464A (en) * | 2003-10-24 | 2005-04-27 | 沈阳化工研究院 | Bactericide composition containing enostroburin |
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| CN1608464A (en) * | 2003-10-24 | 2005-04-27 | 沈阳化工研究院 | Bactericide composition containing enostroburin |
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| WO2012046877A3 (en) * | 2010-10-07 | 2012-11-08 | Sumitomo Chemical Company, Limited | Plant disease controlling composition and method for controlling plant disease |
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Address after: 715500 middle section of North Ring Road, Pucheng County, Shaanxi Applicant after: Shanxi Thompson Biological Technology Co., Ltd. Address before: 710075, C, 15 floor, Jinqiao International Plaza, science and technology road, hi tech Zone, Shaanxi, Xi'an Applicant before: Shanxi Thompson Biological Technology Co., Ltd. |
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Application publication date: 20111005 |