CN102205999B - Method for killing fresh water moule in raw water transportation pipeline by utilizing potassium permanganate - Google Patents
Method for killing fresh water moule in raw water transportation pipeline by utilizing potassium permanganate Download PDFInfo
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- CN102205999B CN102205999B CN2011101089095A CN201110108909A CN102205999B CN 102205999 B CN102205999 B CN 102205999B CN 2011101089095 A CN2011101089095 A CN 2011101089095A CN 201110108909 A CN201110108909 A CN 201110108909A CN 102205999 B CN102205999 B CN 102205999B
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Abstract
The invention discloses a method for killing fresh water moule in a raw water transportation pipeline by utilizing potassium permanganate and relates to a method for killing the fresh water moule in the raw water transportation pipeline, solving the problems that the existing method for killing the fresh water moule in the raw water transportation pipeline is complicated in operation and is poor in feasibility, disinfection byproducts are generated by using a killing method in which a chloride-containing disinfector is used so as to threaten the safety of drinking water. The method comprises the step of continuously adding the potassium permanganate in the raw water transportation pipeline for 5-12 days, wherein the concentration of the potassium permanganate in each L of raw water is controlled to 1.2-1.5 mg, so that the fresh water moule in the raw water transportation pipeline is killed. The potassium permanganate can oxidize and kill the fresh water moule, the mortality of the fresh water moule is above 70%; and simultaneously, the potassium permanganate can remove fume in water and can exert a nuclear coagulation effect of manganese dioxide, thus the purposes of flocculation and precipitation are achieved in advance, and the difficulty of subsequently water treatment process is not increased. According to the invention, operation is simple, safe and stable, and no disinfection byproducts are generated, thus the method has an extremely high practicability.
Description
Technical field
The present invention relates to a kind of method of killing fresh water mussel in the former water conduit.
Background technology
The fresh water mussel is the water treatment new problem that present China south runs into, and not only can influence the ecologic structure of local water body, the destruction of causing the ecosystem, and particularly in former water Long-distance Pipeline for Water Conveyance, the fresh water mussel can be bred in a large number, harm waterworks safety.The characteristic and have flourishing byssus because it is gregariousness can form the colony of stacked in multi-layers in pipeline, increase the water delivery resistance of pipeline, deterioration water quality.Simultaneously, the fresh water mussel that death comes off at the pipeline turning and the thief hatch place cause alluvial, influence the normal operation of pipeline discharge capacity and monitor and control facility.Therefore, the control for the fresh water mussel is significant.
The existing method of killing fresh water mussel in the pipeline mainly contains physical method and chemical process.Physical method comprise adopt anti-ly adhere to coating, high-temperature water spraying method, set up the pre-treatment facility, sealing anoxic method and artificial mechanism remove method.But its complicated operation, effects limit is more, and feasibility is poor.Adopt and anti-ly to adhere to the coating way and be only applicable to newly-built pipeline, it is big to set up pre-treatment facilities engineering amount.Chemical process mainly adopts the way that adds chemical agent; Comprise chlorine, lime, copper sulfate, sylvite, cupric oxide, ozone and various molluscicides etc.; But consider safety of drinking water property, in the processing that a lot of medicaments can't be used for drinking water, in water factory though wherein chlorine-containing disinfectant can be used; But the generation of DBPs is threatening safety of drinking water again, and dosage also is restricted.
Summary of the invention
It is poor to the objective of the invention is in order to solve existing method complicated operation, the feasibility of killing fresh water mussel in the former water conduit; And adopt the method for killing of chlorine-containing disinfectant to produce DBPs; Threaten the problem of drinking water safety, the invention provides the method that a kind of potassium permanganate is killed fresh water mussel in the former water conduit.
Potassium permanganate of the present invention is killed the method for fresh water mussel in the former water conduit; Realize through following steps: in former water conduit, add potassium permanganate; Added continuously 5~12 days; Control that potassium permanganate concentration reaches 1.2~1.8mg in every liter of former water, accomplish the method that potassium permanganate is killed fresh water mussel in the former water conduit.
Potassium permanganate of the present invention is killed in the method for fresh water mussel in the former water conduit, when former water water temperature is 21~25 ℃, in former water conduit, adds potassium permanganate, adds continuously 5~8 days.The mortality ratio of fresh water mussel reaches more than 80%.
Potassium permanganate of the present invention is killed in the method for fresh water mussel in the former water conduit, when former water water temperature is 15~20 ℃, in former water conduit, adds potassium permanganate, adds continuously 8~12 days.The mortality ratio of fresh water mussel reaches more than 70%.
Potassium permanganate of the present invention is killed in the method for fresh water mussel in the former water conduit, control potassium permanganate continuously the time of adding be 5~12 days, potassium permanganate concentration reaches 1.2~1.8mg in every liter of former water, the mortality ratio of fresh water mussel reaches more than 70%.Need the long period if fully the fresh water mussel is killed, from the economic angle analysis, and inadvisable, the time of adding is 5~12 days continuously therefore to control potassium permanganate.Also have, when the potassium permanganate concentration that adds reached 1.5mg/L, killing effect was best, and the mortality ratio of fresh water mussel reaches more than 80%; Rate of death had decline slightly when density loss perhaps was increased to 1.8mg/L to 1.2mg/L.If the concentration that increases potassium permanganate again is to more than the 1.8mg/L, the fresh water mussel just carries out closed shell self-protection, and the closed shell time can reach for 1 week when water temperature was 16 ℃, and during this period, any medicament is all inoperative.Only remain fresh water mussel closed shell with the idiotrophic material consumption totally, just dead successively, increased cost on the contrary, reduced the efficient of killing.Therefore, the invention provides the water treatment method of a kind of economy, safety.
Compare with the method for killing of chlorine-containing disinfectant, potassium permanganate has simple to operate, stable characteristics, and does not have the DBPs generation.Simultaneously, potassium permanganate can be removed and smell flavor in the water, reaches the effect of deironing, demanganization, in addition, can also bring into play the nuclear effect of coagulating of Manganse Dioxide, reaches flocculation and sedimentary purpose in advance, and does not increase the difficulty of follow-up water technology.The most important thing is in former water conduit, to add potassium permanganate, oxygenizement is carried out to greatest extent, kill the fresh water mussel, and then it is removed from pipeline, solve the problem of fresh water mussel harm conduit water delivery effect.
The present invention can effectively control the quantity of fresh water mussel in former water and the pipeline, and use should technology, and easy-to-operate has high feasibility.
Embodiment
Technical scheme of the present invention is not limited to following cited embodiment, also comprises the arbitrary combination between each embodiment.
Embodiment one: this embodiment is the method that potassium permanganate is killed fresh water mussel in the former water conduit; It is realized through following steps: in former water conduit, add potassium permanganate; Added continuously 5~12 days; Control that potassium permanganate concentration reaches 1.2~1.8mg in every liter of former water, accomplish the method that potassium permanganate is killed fresh water mussel in the former water conduit.
The potassium permanganate of this embodiment is killed in the method for fresh water mussel in the former water conduit, control potassium permanganate continuously the time of adding be 5~12 days, potassium permanganate concentration reaches 1.2~1.8mg in every liter of former water, the mortality ratio of fresh water mussel reaches more than 70%.Need the long period if fully the fresh water mussel is killed, from the economic angle analysis, and inadvisable, the time of adding is 5~12 days continuously therefore to control potassium permanganate.Also have, when the potassium permanganate concentration that adds reached 1.5mg/L, killing effect was best, and the mortality ratio of fresh water mussel reaches more than 90%; Rate of death had decline slightly when density loss perhaps was increased to 1.8mg/L to 1.2mg/L.If the concentration that increases potassium permanganate again is to more than the 1.8mg/L, the fresh water mussel just carries out closed shell self-protection, and the closed shell time can reach for 1 week when water temperature was 16 ℃, and during this period, any medicament is all inoperative.Only remain fresh water mussel closed shell with the idiotrophic material consumption totally, just dead successively, increased cost on the contrary, reduced the efficient of killing.
Compare with the method for killing of chlorine-containing disinfectant, potassium permanganate has simple to operate, stable characteristics, and does not have the DBPs generation.Simultaneously, potassium permanganate can be removed and smell flavor in the water, reaches the effect of deironing, demanganization, in addition, can also bring into play the nuclear effect of coagulating of Manganse Dioxide, reaches flocculation and sedimentary purpose in advance, and does not increase the difficulty of follow-up water technology.The most important thing is in former water conduit, to add potassium permanganate, oxygenizement is carried out to greatest extent, kill the fresh water mussel, and then it is removed from pipeline, solve the problem of fresh water mussel harm conduit water delivery effect.
This embodiment can effectively be controlled the quantity of fresh water mussel in former water and the pipeline, and use should technology, and easy-to-operate has high feasibility.
Embodiment two: this embodiment and embodiment one are different is former water water temperature when being 21~25 ℃, in former water conduit, adds potassium permanganate, adds continuously 5~8 days.Other step and parameter are identical with embodiment one.
The mortality ratio that the potassium permanganate of this embodiment is killed the fresh water mussel of the method for fresh water mussel in the former water conduit reaches more than 80%.
Embodiment three: this embodiment and embodiment one are different is in former water water temperature is 21~25 ℃ former water conduit, to add potassium permanganate, adds continuously 5~8 days, controls that potassium permanganate concentration reaches 1.5mg in every liter of former water.Other step and parameter are identical with embodiment one.
The mortality ratio that the potassium permanganate of this embodiment is killed the fresh water mussel of the method for fresh water mussel in the former water conduit reaches more than 85%.
Embodiment four: this embodiment and embodiment one are different is former water water temperature when being 15~20 ℃, in former water conduit, adds potassium permanganate, adds continuously 8~12 days.Other step and parameter are identical with embodiment one.
The mortality ratio that the potassium permanganate of this embodiment is killed the fresh water mussel of the method for fresh water mussel in the former water conduit reaches more than 70%.
Embodiment five: this embodiment and embodiment one are different is in former water water temperature is 15~20 ℃ former water conduit, to add potassium permanganate, adds continuously 8~12 days, controls that potassium permanganate concentration reaches 1.5mg in every liter of former water.Other step and parameter are identical with embodiment one.
The mortality ratio that the potassium permanganate of this embodiment is killed the fresh water mussel of the method for fresh water mussel in the former water conduit reaches more than 80%.
Embodiment six: what this embodiment and embodiment one, two or three were different is that potassium permanganate concentration reaches 1.3~1.6mg in every liter of former water of control.Other step and parameter are identical with embodiment one, two or three.
Embodiment seven: what this embodiment and embodiment one, two or three were different is that potassium permanganate concentration reaches 1.5mg in every liter of former water of control.Other step and parameter are identical with embodiment one, two or three.
When the potassium permanganate concentration that adds reached 1.5mg/L, killing effect was best in this embodiment, and the mortality ratio of fresh water mussel reaches more than 80%.Rate of death had decline slightly when density loss perhaps was increased to 1.8mg/L to 1.2mg/L; If the concentration that increases potassium permanganate again is to more than the 1.8mg/L, the fresh water mussel just carries out closed shell self-protection, and the closed shell time can reach for 1 week when water temperature was 16 ℃; During this period, any medicament is all inoperative.Only remain fresh water mussel closed shell with the idiotrophic material consumption totally, just dead successively, increased cost on the contrary, reduced the efficient of killing.
Embodiment eight: this embodiment is the method that potassium permanganate is killed fresh water mussel in the former water conduit; It is realized through following steps: to former water temp is to add potassium permanganate in 25 ℃ of former water conduits; Added continuously 5 days; Control that potassium permanganate concentration reaches 1.5mg in every liter of former water, accomplish the method that potassium permanganate is killed fresh water mussel in the former water conduit.
The mortality ratio that the potassium permanganate of this embodiment is killed the method fresh water mussel of fresh water mussel in the former water conduit reaches 90%~92%.
The method of this embodiment is compared with the method for killing of chlorine-containing disinfectant, and potassium permanganate has simple to operate, stable characteristics, and does not have the DBPs generation.Simultaneously, potassium permanganate can be removed and smell flavor in the water, reaches the effect of deironing, demanganization, in addition, can also bring into play the nuclear effect of coagulating of Manganse Dioxide, reaches flocculation and sedimentary purpose in advance, and does not increase the difficulty of follow-up water technology.Easy-to-operate has high feasibility.
Embodiment nine: this embodiment is the method that potassium permanganate is killed fresh water mussel in the former water conduit; It is realized through following steps: in former water temp is 25 ℃ former water conduit, add potassium permanganate; Added continuously 6 days; Control that potassium permanganate concentration reaches 1.8mg in every liter of former water, accomplish the method that potassium permanganate is killed fresh water mussel in the former water conduit.
The mortality ratio that the potassium permanganate of this embodiment is killed the method fresh water mussel of fresh water mussel in the former water conduit reaches 85%~89%.
The method of this embodiment is compared with the method for killing of chlorine-containing disinfectant, and potassium permanganate has simple to operate, stable characteristics, and does not have the DBPs generation.Simultaneously, potassium permanganate can be removed and smell flavor in the water, reaches the effect of deironing, demanganization, in addition, can also bring into play the nuclear effect of coagulating of Manganse Dioxide, reaches flocculation and sedimentary purpose in advance, and does not increase the difficulty of follow-up water technology.Easy-to-operate has high feasibility.
Embodiment ten: this embodiment is the method that potassium permanganate is killed fresh water mussel in the former water conduit; It is realized through following steps: to former water temp is to add potassium permanganate in 25 ℃ of former water conduits; Added continuously 7 days; Control that potassium permanganate concentration reaches 1.2mg in every liter of former water, accomplish the method that potassium permanganate is killed fresh water mussel in the former water conduit.
The mortality ratio that the potassium permanganate of this embodiment is killed the method fresh water mussel of fresh water mussel in the former water conduit reaches 85%~89%.
The method of this embodiment is compared with the method for killing of chlorine-containing disinfectant, and potassium permanganate has simple to operate, stable characteristics, and does not have the DBPs generation.Simultaneously, potassium permanganate can be removed and smell flavor in the water, reaches the effect of deironing, demanganization, in addition, can also bring into play the nuclear effect of coagulating of Manganse Dioxide, reaches flocculation and sedimentary purpose in advance, and does not increase the difficulty of follow-up water technology.Easy-to-operate has high feasibility.
Embodiment 11: this embodiment is the method that potassium permanganate is killed fresh water mussel in the former water conduit; It is realized through following steps: to former water temp is to add potassium permanganate in 20 ℃ of former water conduits; Added continuously 8 days; Control that potassium permanganate concentration reaches 1.5mg in every liter of former water, accomplish the method that potassium permanganate is killed fresh water mussel in the former water conduit.
The mortality ratio that the potassium permanganate of this embodiment is killed the method fresh water mussel of fresh water mussel in the former water conduit reaches 80%~84%.
The method of this embodiment is compared with the method for killing of chlorine-containing disinfectant, and potassium permanganate has simple to operate, stable characteristics, and does not have the DBPs generation.Simultaneously, potassium permanganate can be removed and smell flavor in the water, reaches the effect of deironing, demanganization, in addition, can also bring into play the nuclear effect of coagulating of Manganse Dioxide, reaches flocculation and sedimentary purpose in advance, and does not increase the difficulty of follow-up water technology.Easy-to-operate has high feasibility.
Embodiment 12: this embodiment is the method that potassium permanganate is killed fresh water mussel in the former water conduit; It is realized through following steps: to former water temp is to add potassium permanganate in 15 ℃ of former water conduits; Added continuously 12 days; Control that potassium permanganate concentration reaches 1.2mg in every liter of former water, accomplish the method that potassium permanganate is killed fresh water mussel in the former water conduit.
The mortality ratio that the potassium permanganate of this embodiment is killed the method fresh water mussel of fresh water mussel in the former water conduit reaches 70%~75%.
The method of this embodiment is compared with the method for killing of chlorine-containing disinfectant, and potassium permanganate has simple to operate, stable characteristics, and does not have the DBPs generation.Simultaneously, potassium permanganate can be removed and smell flavor in the water, reaches the effect of deironing, demanganization, in addition, can also bring into play the nuclear effect of coagulating of Manganse Dioxide, reaches flocculation and sedimentary purpose in advance, and does not increase the difficulty of follow-up water technology.Easy-to-operate has high feasibility.
Embodiment 13: this embodiment is the method that potassium permanganate is killed fresh water mussel in the former water conduit; It is realized through following steps: to former water temp is to add potassium permanganate in 18 ℃ of former water conduits; Added continuously 10 days; Control that potassium permanganate concentration reaches 1.6mg in every liter of former water, accomplish the method that potassium permanganate is killed fresh water mussel in the former water conduit.
The mortality ratio that the potassium permanganate of this embodiment is killed the method fresh water mussel of fresh water mussel in the former water conduit reaches 76%~79%.
The method of this embodiment is compared with the method for killing of chlorine-containing disinfectant, and potassium permanganate has simple to operate, stable characteristics, and does not have the DBPs generation.Simultaneously, potassium permanganate can be removed and smell flavor in the water, reaches the effect of deironing, demanganization, in addition, can also bring into play the nuclear effect of coagulating of Manganse Dioxide, reaches flocculation and sedimentary purpose in advance, and does not increase the difficulty of follow-up water technology.Easy-to-operate has high feasibility.
Claims (7)
1. potassium permanganate is killed the method for fresh water mussel in the former water conduit; It is characterized in that potassium permanganate kills the method for fresh water mussel in the former water conduit and realize through following steps: in former water conduit, add potassium permanganate; Added continuously 5~12 days; Control that potassium permanganate concentration reaches 1.2~1.8mg in every liter of former water, accomplish the method that potassium permanganate is killed fresh water mussel in the former water conduit.
2. potassium permanganate according to claim 1 is killed the method for fresh water mussel in the former water conduit, it is characterized in that former water water temperature is 21~25 ℃, in former water conduit, adds potassium permanganate, adds continuously 5~8 days.
3. potassium permanganate according to claim 1 is killed the method for fresh water mussel in the former water conduit; It is characterized in that in former water water temperature is 21~25 ℃ former water conduit, adding potassium permanganate; Added continuously 5~8 days, and controlled that potassium permanganate concentration reached 1.5mg in every liter of former water.
4. potassium permanganate according to claim 1 is killed the method for fresh water mussel in the former water conduit, it is characterized in that former water water temperature is 15~20 ℃, in former water conduit, adds potassium permanganate, adds continuously 8~12 days.
5. potassium permanganate according to claim 1 is killed the method for fresh water mussel in the former water conduit; It is characterized in that in former water water temperature is 15~20 ℃ former water conduit, adding potassium permanganate; Added continuously 8~12 days, and controlled that potassium permanganate concentration reached 1.5mg in every liter of former water.
6. kill the method for fresh water mussel in the former water conduit according to claim 1,2 or 4 described potassium permanganate, it is characterized in that controlling that potassium permanganate concentration reaches 1.3~1.6mg in every liter of former water.
7. kill the method for fresh water mussel in the former water conduit according to claim 1,2 or 4 described potassium permanganate, it is characterized in that controlling that potassium permanganate concentration reaches 1.5mg in every liter of former water.
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CN103523893A (en) * | 2013-10-24 | 2014-01-22 | 哈尔滨工业大学 | Method for killing limnoperna fortune in long-distance raw water delivery pipeline by combined effect of potassium permanganate and sodium hypochlorite |
CN104222050B (en) * | 2014-09-12 | 2016-08-24 | 南通大学 | A kind of method preventing and treating raw water pipeline fresh water mussel |
CN112320970B (en) * | 2020-10-22 | 2022-08-26 | 天津水务集团有限公司 | Method for removing limnoperna lacustris in raw water pipeline |
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