CN102205999A - Method for killing fresh water moule in raw water transportation pipeline by utilizing potassium permanganate - Google Patents
Method for killing fresh water moule in raw water transportation pipeline by utilizing potassium permanganate Download PDFInfo
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- CN102205999A CN102205999A CN 201110108909 CN201110108909A CN102205999A CN 102205999 A CN102205999 A CN 102205999A CN 201110108909 CN201110108909 CN 201110108909 CN 201110108909 A CN201110108909 A CN 201110108909A CN 102205999 A CN102205999 A CN 102205999A
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- water
- potassium permanganate
- mussel
- former
- fresh water
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- 239000012286 potassium permanganate Substances 0.000 title claims abstract description 113
- 239000013505 freshwater Substances 0.000 title claims abstract description 86
- 238000000034 method Methods 0.000 title claims abstract description 70
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 68
- 230000002147 killing effect Effects 0.000 title abstract description 23
- 241000237536 Mytilus edulis Species 0.000 claims description 79
- 235000020638 mussel Nutrition 0.000 claims description 79
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 claims description 74
- 239000006227 byproduct Substances 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 12
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 12
- 230000016615 flocculation Effects 0.000 abstract description 9
- 238000005189 flocculation Methods 0.000 abstract description 9
- 239000003651 drinking water Substances 0.000 abstract description 5
- 235000020188 drinking water Nutrition 0.000 abstract description 5
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 230000015271 coagulation Effects 0.000 abstract 1
- 238000005345 coagulation Methods 0.000 abstract 1
- 239000003517 fume Substances 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 11
- 239000000460 chlorine Substances 0.000 description 11
- 229910052801 chlorine Inorganic materials 0.000 description 11
- 238000005516 engineering process Methods 0.000 description 11
- 239000000645 desinfectant Substances 0.000 description 10
- 230000001112 coagulating effect Effects 0.000 description 8
- 239000000796 flavoring agent Substances 0.000 description 8
- 235000019634 flavors Nutrition 0.000 description 8
- 230000001818 nuclear effect Effects 0.000 description 8
- 230000006378 damage Effects 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 230000007423 decrease Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000001311 chemical methods and process Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000000053 physical method Methods 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 229960004643 cupric oxide Drugs 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000003750 molluscacide Substances 0.000 description 1
- 230000002013 molluscicidal effect Effects 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
Abstract
The invention discloses a method for killing fresh water moule in a raw water transportation pipeline by utilizing potassium permanganate and relates to a method for killing the fresh water moule in the raw water transportation pipeline, solving the problems that the existing method for killing the fresh water moule in the raw water transportation pipeline is complicated in operation and is poor in feasibility, disinfection byproducts are generated by using a killing method in which a chloride-containing disinfector is used so as to threaten the safety of drinking water. The method comprises the step of continuously adding the potassium permanganate in the raw water transportation pipeline for 5-12 days, wherein the concentration of the potassium permanganate in each L of raw water is controlled to 1.2-1.5 mg, so that the fresh water moule in the raw water transportation pipeline is killed. The potassium permanganate can oxidize and kill the fresh water moule, the mortality of the fresh water moule is above 70%; and simultaneously, the potassium permanganate can remove fume in water and can exert a nuclear coagulation effect of manganese dioxide, thus the purposes of flocculation and precipitation are achieved in advance, and the difficulty of subsequently water treatment process is not increased. According to the invention, operation is simple, safe and stable, and no disinfection byproducts are generated, thus the method has an extremely high practicability.
Description
Technical field
The present invention relates to a kind of method of killing fresh water mussel in the former water water pipe.
Background technology
The fresh water mussel is the water treatment new problem that present China south runs into, and not only can influence the ecologic structure of local water body, the destruction of causing the ecosystem, and particularly in former water Long-distance Pipeline for Water Conveyance, the fresh water mussel can be bred in a large number, harm waterworks safety.The characteristic and have flourishing byssus because it is gregariousness can form the colony of stacked in multi-layers in pipeline, increase the water delivery resistance of pipeline, deterioration water quality.Simultaneously, the fresh water mussel that death comes off at the pipeline turning and the thief hatch place cause alluvial, influence the normal operation of pipeline discharge capacity and monitor and control facility.Therefore, the control for the fresh water mussel is significant.
The existing method of killing fresh water mussel in the pipeline mainly contains physical method and chemical process.Physical method comprises employing anti-adhesion coating, high-temperature water spraying method, sets up the pre-treatment facility, seals anoxic method and artificial mechanism removing method.But its complicated operation, effects limit is more, and feasibility is poor.Adopt anti-adhesion coating way to be only applicable to newly-built pipeline, it is big to set up pre-treatment facilities engineering amount.Chemical process mainly adopts the way that adds chemical agent, comprise chlorine, lime, copper sulfate, sylvite, cupric oxide, ozone and various molluscicides etc., but consider safety of drinking water, in the processing that a lot of medicaments can't be used for drinking water, though wherein chlorine-containing disinfectant can be used in water factory, but the generation of disinfection byproduct (DBP) is threatening safety of drinking water again, and dosage also is restricted.
Summary of the invention
It is poor to the objective of the invention is in order to solve existing method complicated operation, the feasibility of killing fresh water mussel in the former water water pipe, and adopt the method for killing of chlorine-containing disinfectant to produce disinfection byproduct (DBP), threaten the problem of drinking water safety, the invention provides the method that a kind of potassium permanganate is killed fresh water mussel in the former water water pipe.
Potassium permanganate of the present invention is killed the method for fresh water mussel in the former water water pipe, realize by following steps: in former water water pipe, add potassium permanganate, added continuously 5~12 days, control that potassium permanganate concentration reaches 1.2~1.8mg in every liter of former water, finish the method that potassium permanganate is killed fresh water mussel in the former water water pipe.
Potassium permanganate of the present invention is killed in the method for fresh water mussel in the former water water pipe, when former water water temperature is 21~25 ℃, adds potassium permanganate in former water water pipe, adds continuously 5~8 days.The mortality ratio of fresh water mussel reaches more than 80%.
Potassium permanganate of the present invention is killed in the method for fresh water mussel in the former water water pipe, when former water water temperature is 15~20 ℃, adds potassium permanganate in former water water pipe, adds continuously 8~12 days.The mortality ratio of fresh water mussel reaches more than 70%.
Potassium permanganate of the present invention is killed in the method for fresh water mussel in the former water water pipe, control potassium permanganate continuously the time of adding be 5~12 days, potassium permanganate concentration reaches 1.2~1.8mg in every liter of former water, the mortality ratio of fresh water mussel reaches more than 70%.Need the long period if fully the fresh water mussel is killed, from the economic angle analysis, and inadvisable, the time of adding is 5~12 days continuously therefore to control potassium permanganate.Also have, when the potassium permanganate concentration that adds reached 1.5mg/L, killing effect was best, and the mortality ratio of fresh water mussel reaches more than 80%; Rate of death has decline to density loss slightly to 1.2mg/L or when being increased to 1.8mg/L.If the concentration that increases potassium permanganate again is to more than the 1.8mg/L, the fresh water mussel just carries out closed shell self-protection, and the closed shell time can reach for 1 week when water temperature was 16 ℃, and during this period, any medicament is all inoperative.Only remain fresh water mussel closed shell with the idiotrophic material consumption totally, just dead successively, increased cost on the contrary, reduced the efficient of killing.Therefore, the invention provides the water treatment method of a kind of economy, safety.
Compare with the method for killing of chlorine-containing disinfectant, potassium permanganate has simple to operate, stable characteristics, and does not have the disinfection byproduct (DBP) generation.Simultaneously, potassium permanganate can be removed and smell flavor in the water, reaches the effect of deironing, demanganization, in addition, can also bring into play the nuclear effect of coagulating of Manganse Dioxide, reaches flocculation and sedimentary purpose in advance, and does not increase the difficulty of follow-up water technology.The most important thing is in former water water pipe, to add potassium permanganate, oxygenizement is carried out to greatest extent, kill the fresh water mussel, and then it is removed from pipeline, solve the problem of fresh water mussel harm water pipe water delivery effect.
The present invention can effectively control the quantity of fresh water mussel in former water and the pipeline, uses this technology, and easy-to-operate has high feasibility.
Embodiment
Technical solution of the present invention is not limited to following cited embodiment, also comprises the arbitrary combination between each embodiment.
Embodiment one: present embodiment is the method that potassium permanganate is killed fresh water mussel in the former water water pipe, it is realized by following steps: add potassium permanganate in former water water pipe, added continuously 5~12 days, control that potassium permanganate concentration reaches 1.2~1.8mg in every liter of former water, finish the method that potassium permanganate is killed fresh water mussel in the former water water pipe.
The potassium permanganate of present embodiment is killed in the method for fresh water mussel in the former water water pipe, control potassium permanganate continuously the time of adding be 5~12 days, potassium permanganate concentration reaches 1.2~1.8mg in every liter of former water, the mortality ratio of fresh water mussel reaches more than 70%.Need the long period if fully the fresh water mussel is killed, from the economic angle analysis, and inadvisable, the time of adding is 5~12 days continuously therefore to control potassium permanganate.Also have, when the potassium permanganate concentration that adds reached 1.5mg/L, killing effect was best, and the mortality ratio of fresh water mussel reaches more than 90%; Rate of death has decline to density loss slightly to 1.2mg/L or when being increased to 1.8mg/L.If the concentration that increases potassium permanganate again is to more than the 1.8mg/L, the fresh water mussel just carries out closed shell self-protection, and the closed shell time can reach for 1 week when water temperature was 16 ℃, and during this period, any medicament is all inoperative.Only remain fresh water mussel closed shell with the idiotrophic material consumption totally, just dead successively, increased cost on the contrary, reduced the efficient of killing.
Compare with the method for killing of chlorine-containing disinfectant, potassium permanganate has simple to operate, stable characteristics, and does not have the disinfection byproduct (DBP) generation.Simultaneously, potassium permanganate can be removed and smell flavor in the water, reaches the effect of deironing, demanganization, in addition, can also bring into play the nuclear effect of coagulating of Manganse Dioxide, reaches flocculation and sedimentary purpose in advance, and does not increase the difficulty of follow-up water technology.The most important thing is in former water water pipe, to add potassium permanganate, oxygenizement is carried out to greatest extent, kill the fresh water mussel, and then it is removed from pipeline, solve the problem of fresh water mussel harm water pipe water delivery effect.
Present embodiment can effectively be controlled the quantity of fresh water mussel in former water and the pipeline, uses this technology, and easy-to-operate has high feasibility.
Embodiment two: present embodiment and embodiment one are different is former water water temperature when being 21~25 ℃, adds potassium permanganate in former water water pipe, adds continuously 5~8 days.Other step and parameter are identical with embodiment one.
The mortality ratio that the potassium permanganate of present embodiment is killed the fresh water mussel of the method for fresh water mussel in the former water water pipe reaches more than 80%.
Embodiment three: present embodiment and embodiment one are different is to add potassium permanganate in former water water temperature is 21~25 ℃ former water water pipe, adds continuously 5~8 days, controls that potassium permanganate concentration reaches 1.5mg in every liter of former water.Other step and parameter are identical with embodiment one.
The mortality ratio that the potassium permanganate of present embodiment is killed the fresh water mussel of the method for fresh water mussel in the former water water pipe reaches more than 85%.
Embodiment four: present embodiment and embodiment one are different is former water water temperature when being 15~20 ℃, adds potassium permanganate in former water water pipe, adds continuously 8~12 days.Other step and parameter are identical with embodiment one.
The mortality ratio that the potassium permanganate of present embodiment is killed the fresh water mussel of the method for fresh water mussel in the former water water pipe reaches more than 70%.
Embodiment five: present embodiment and embodiment one are different is to add potassium permanganate in former water water temperature is 15~20 ℃ former water water pipe, adds continuously 8~12 days, controls that potassium permanganate concentration reaches 1.5mg in every liter of former water.Other step and parameter are identical with embodiment one.
The mortality ratio that the potassium permanganate of present embodiment is killed the fresh water mussel of the method for fresh water mussel in the former water water pipe reaches more than 80%.
Embodiment six: what present embodiment and embodiment one, two or three were different is that potassium permanganate concentration reaches 1.3~1.6mg in every liter of former water of control.Other step and parameter are identical with embodiment one, two or three.
Embodiment seven: what present embodiment and embodiment one, two or three were different is that potassium permanganate concentration reaches 1.5mg in every liter of former water of control.Other step and parameter are identical with embodiment one, two or three.
When the potassium permanganate concentration that adds reached 1.5mg/L, killing effect was best in the present embodiment, and the mortality ratio of fresh water mussel reaches more than 80%.Rate of death has decline to density loss slightly to 1.2mg/L or when being increased to 1.8mg/L; if the concentration that increases potassium permanganate again is to more than the 1.8mg/L, the fresh water mussel just carries out closed shell self-protection, and the closed shell time can reach for 1 week when water temperature was 16 ℃; during this period, any medicament is all inoperative.Only remain fresh water mussel closed shell with the idiotrophic material consumption totally, just dead successively, increased cost on the contrary, reduced the efficient of killing.
Embodiment eight: present embodiment is the method that potassium permanganate is killed fresh water mussel in the former water water pipe, it is realized by following steps: to former water temp is to add potassium permanganate in 25 ℃ of former water water pipes, added continuously 5 days, control that potassium permanganate concentration reaches 1.5mg in every liter of former water, finish the method that potassium permanganate is killed fresh water mussel in the former water water pipe.
The mortality ratio that the potassium permanganate of present embodiment is killed the method fresh water mussel of fresh water mussel in the former water water pipe reaches 90%~92%.
The method of present embodiment is compared with the method for killing of chlorine-containing disinfectant, and potassium permanganate has simple to operate, stable characteristics, and does not have the disinfection byproduct (DBP) generation.Simultaneously, potassium permanganate can be removed and smell flavor in the water, reaches the effect of deironing, demanganization, in addition, can also bring into play the nuclear effect of coagulating of Manganse Dioxide, reaches flocculation and sedimentary purpose in advance, and does not increase the difficulty of follow-up water technology.Easy-to-operate has high feasibility.
Embodiment nine: present embodiment is the method that potassium permanganate is killed fresh water mussel in the former water water pipe, it is realized by following steps: add potassium permanganate in former water temp is 25 ℃ former water water pipe, added continuously 6 days, control that potassium permanganate concentration reaches 1.8mg in every liter of former water, finish the method that potassium permanganate is killed fresh water mussel in the former water water pipe.
The mortality ratio that the potassium permanganate of present embodiment is killed the method fresh water mussel of fresh water mussel in the former water water pipe reaches 85%~89%.
The method of present embodiment is compared with the method for killing of chlorine-containing disinfectant, and potassium permanganate has simple to operate, stable characteristics, and does not have the disinfection byproduct (DBP) generation.Simultaneously, potassium permanganate can be removed and smell flavor in the water, reaches the effect of deironing, demanganization, in addition, can also bring into play the nuclear effect of coagulating of Manganse Dioxide, reaches flocculation and sedimentary purpose in advance, and does not increase the difficulty of follow-up water technology.Easy-to-operate has high feasibility.
Embodiment ten: present embodiment is the method that potassium permanganate is killed fresh water mussel in the former water water pipe, it is realized by following steps: to former water temp is to add potassium permanganate in 25 ℃ of former water water pipes, added continuously 7 days, control that potassium permanganate concentration reaches 1.2mg in every liter of former water, finish the method that potassium permanganate is killed fresh water mussel in the former water water pipe.
The mortality ratio that the potassium permanganate of present embodiment is killed the method fresh water mussel of fresh water mussel in the former water water pipe reaches 85%~89%.
The method of present embodiment is compared with the method for killing of chlorine-containing disinfectant, and potassium permanganate has simple to operate, stable characteristics, and does not have the disinfection byproduct (DBP) generation.Simultaneously, potassium permanganate can be removed and smell flavor in the water, reaches the effect of deironing, demanganization, in addition, can also bring into play the nuclear effect of coagulating of Manganse Dioxide, reaches flocculation and sedimentary purpose in advance, and does not increase the difficulty of follow-up water technology.Easy-to-operate has high feasibility.
Embodiment 11: present embodiment is the method that potassium permanganate is killed fresh water mussel in the former water water pipe, it is realized by following steps: to former water temp is to add potassium permanganate in 20 ℃ of former water water pipes, added continuously 8 days, control that potassium permanganate concentration reaches 1.5mg in every liter of former water, finish the method that potassium permanganate is killed fresh water mussel in the former water water pipe.
The mortality ratio that the potassium permanganate of present embodiment is killed the method fresh water mussel of fresh water mussel in the former water water pipe reaches 80%~84%.
The method of present embodiment is compared with the method for killing of chlorine-containing disinfectant, and potassium permanganate has simple to operate, stable characteristics, and does not have the disinfection byproduct (DBP) generation.Simultaneously, potassium permanganate can be removed and smell flavor in the water, reaches the effect of deironing, demanganization, in addition, can also bring into play the nuclear effect of coagulating of Manganse Dioxide, reaches flocculation and sedimentary purpose in advance, and does not increase the difficulty of follow-up water technology.Easy-to-operate has high feasibility.
Embodiment 12: present embodiment is the method that potassium permanganate is killed fresh water mussel in the former water water pipe, it is realized by following steps: to former water temp is to add potassium permanganate in 15 ℃ of former water water pipes, added continuously 12 days, control that potassium permanganate concentration reaches 1.2mg in every liter of former water, finish the method that potassium permanganate is killed fresh water mussel in the former water water pipe.
The mortality ratio that the potassium permanganate of present embodiment is killed the method fresh water mussel of fresh water mussel in the former water water pipe reaches 70%~75%.
The method of present embodiment is compared with the method for killing of chlorine-containing disinfectant, and potassium permanganate has simple to operate, stable characteristics, and does not have the disinfection byproduct (DBP) generation.Simultaneously, potassium permanganate can be removed and smell flavor in the water, reaches the effect of deironing, demanganization, in addition, can also bring into play the nuclear effect of coagulating of Manganse Dioxide, reaches flocculation and sedimentary purpose in advance, and does not increase the difficulty of follow-up water technology.Easy-to-operate has high feasibility.
Embodiment 13: present embodiment is the method that potassium permanganate is killed fresh water mussel in the former water water pipe, it is realized by following steps: to former water temp is to add potassium permanganate in 18 ℃ of former water water pipes, added continuously 10 days, control that potassium permanganate concentration reaches 1.6mg in every liter of former water, finish the method that potassium permanganate is killed fresh water mussel in the former water water pipe.
The mortality ratio that the potassium permanganate of present embodiment is killed the method fresh water mussel of fresh water mussel in the former water water pipe reaches 76%~79%.
The method of present embodiment is compared with the method for killing of chlorine-containing disinfectant, and potassium permanganate has simple to operate, stable characteristics, and does not have the disinfection byproduct (DBP) generation.Simultaneously, potassium permanganate can be removed and smell flavor in the water, reaches the effect of deironing, demanganization, in addition, can also bring into play the nuclear effect of coagulating of Manganse Dioxide, reaches flocculation and sedimentary purpose in advance, and does not increase the difficulty of follow-up water technology.Easy-to-operate has high feasibility.
Claims (7)
1. potassium permanganate is killed the method for fresh water mussel in the former water water pipe, it is characterized in that potassium permanganate kills the method for fresh water mussel in the former water water pipe and realize by following steps: in former water water pipe, add potassium permanganate, added continuously 5~12 days, control that potassium permanganate concentration reaches 1.2~1.8mg in every liter of former water, finish the method that potassium permanganate is killed fresh water mussel in the former water water pipe.
2. potassium permanganate according to claim 1 is killed the method for fresh water mussel in the former water water pipe, it is characterized in that former water water temperature is 21~25 ℃, adds potassium permanganate in former water water pipe, adds continuously 5~8 days.
3. potassium permanganate according to claim 1 is killed the method for fresh water mussel in the former water water pipe, it is characterized in that in former water water temperature is 21~25 ℃ former water water pipe, adding potassium permanganate, added continuously 5~8 days, and controlled that potassium permanganate concentration reached 1.5mg in every liter of former water.
4. potassium permanganate according to claim 1 is killed the method for fresh water mussel in the former water water pipe, it is characterized in that former water water temperature is 15~20 ℃, adds potassium permanganate in former water water pipe, adds continuously 8~12 days.
5. potassium permanganate according to claim 1 is killed the method for fresh water mussel in the former water water pipe, it is characterized in that in former water water temperature is 15~20 ℃ former water water pipe, adding potassium permanganate, added continuously 8~12 days, and controlled that potassium permanganate concentration reached 1.5mg in every liter of former water.
6. kill the method for fresh water mussel in the former water water pipe according to claim 1,2 or 4 described potassium permanganate, it is characterized in that controlling that potassium permanganate concentration reaches 1.3~1.6mg in every liter of former water.
7. kill the method for fresh water mussel in the former water water pipe according to claim 1,2 or 4 described potassium permanganate, it is characterized in that controlling that potassium permanganate concentration reaches 1.5mg in every liter of former water.
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CN103523893A (en) * | 2013-10-24 | 2014-01-22 | 哈尔滨工业大学 | Method for killing limnoperna fortune in long-distance raw water delivery pipeline by combined effect of potassium permanganate and sodium hypochlorite |
CN104222050A (en) * | 2014-09-12 | 2014-12-24 | 南通大学 | Method for preventing and controlling limnoperna lacustris in raw water pipeline |
CN112320970A (en) * | 2020-10-22 | 2021-02-05 | 天津水务集团有限公司 | Method for removing limnoperna lacustris in raw water pipeline |
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Cited By (3)
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CN103523893A (en) * | 2013-10-24 | 2014-01-22 | 哈尔滨工业大学 | Method for killing limnoperna fortune in long-distance raw water delivery pipeline by combined effect of potassium permanganate and sodium hypochlorite |
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CN112320970A (en) * | 2020-10-22 | 2021-02-05 | 天津水务集团有限公司 | Method for removing limnoperna lacustris in raw water pipeline |
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