CN102204554A - Antibacterial composition containing trifloxystrobin and carbamate compound - Google Patents
Antibacterial composition containing trifloxystrobin and carbamate compound Download PDFInfo
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- CN102204554A CN102204554A CN2011100885196A CN201110088519A CN102204554A CN 102204554 A CN102204554 A CN 102204554A CN 2011100885196 A CN2011100885196 A CN 2011100885196A CN 201110088519 A CN201110088519 A CN 201110088519A CN 102204554 A CN102204554 A CN 102204554A
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- bacterium ester
- oxime bacterium
- propamocarb
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- bactericidal composition
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Abstract
The invention relates to an antibacterial composition containing trifloxystrobin and a carbamate compound, which comprises an active component A and an active component B, wherein the active component A may be trifloxystrobin; the active component B may be propamocarb, propamocarb hydrochloride, diethofencarb or benthiavalicarbisopropyl; the weight percentage ratio of the active component A to the active component B is (1-60 percent):(1-80 percent); the active components is added with an additive and an excipient to form wettable powder, water dispersible granules, suspension, suspension emulsion, water emulsion and microemulsion for preventing and treating various diseases such as powdery mildew, Botrytis, downy mildew, rust disease, damping off, epidemic disease, late blight, stem rot, penicilliosis, Pythium aphanidermatum, Leptosphaeria maculans, apple scab and leaf spot, has an obvious synergetic effect and is safe for crops; and the antibacterial composition has the advantages of rain washing resistance, durable medicine effect and small dose.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of application of bactericidal composition on crop pest that contains oxime bacterium ester and carbamate compound.
Technical background
Oxime bacterium ester, English name: trifloxystrobin molecular formula: C
20H
19F
3N
2O
4Chemical name: methyl (E)-methoxyl group imido grpup-(E)-and α-[1-(α, α-three fluoro-m-tolyl)-ethyleneimino oxygen base]-o-tolyl } ethyl acetate.
Oxime bacterium ester is for belonging to methoxy acrylic bactericide, and it is the synthetic analogues of natural antibiotics strobilurin A (strobilurin tenacellus bacterium secondary metabolism thing) with bactericidal activity.Fungies such as ascomycetes, Fungi Imperfecti, basidiomycetes and Oomycete all there is good activity.Bactericide with chemical kinetics characteristic, it can be provided excellent protection activity to plant surface by plant wax coat strong adsorption.It is a kind of respiration inhibitor, stops cell ATP synthetic by the electronics transmission of pinning between cytochrome b and the c1, thereby suppresses its mitochondrial respiratory and bring into play bacteriostasis.
Propamocarb (propamocarb), molecular formula: C
9H
21N
2O
2Cl, chemical name: 3-(dimethylamino) propyl carbamic acid propyl ester.The mechanism of action is to suppress the phosphatide of germ cell membrane component and the biosynthesis of fatty acid, suppresses mycelial growth, sporangial formation and sprouting.Inhale the conductivity bactericide in Propamocarb belongs to, when as soil treatment, can also upwards be transported to whole plant very soon by root absorption.When handling as cauline leaf, can be absorbed very soon and be distributed in the blade by blade, this medicine also can be used as impregnation process and seed protectant.The above Propamocarb also comprises propamocarb.
Propamocarb (propamocarb hydrochloride), molecular formula: C
9H
21N
2O
2Cl chemical name: propyl group-3-(dimethylamino) propyl carbamic acid hydrochloride, the mechanism of action is similar to Propamocarb.
The mould prestige of second (diethofencarb), molecular formula: C
14H
21NO
4, chemical name: 3,4-diethoxy phenylcarbamic acid isopropyl ester, systemic fungicide suppresses the formation of botrytis cinerea gemma spindle, is used to prevent and treat the bacterial strain of anti-Bentazons such as grape, citrus, the double powdery mildew of controlling.
Benzene metsulfovax (benthiavalicarb-isopropyl), molecular formula: C
18H
24FN
3O
3S, chemical name: [(S)-1-[(R)-1-(6-fluoro benzothiazole-2-yl) ethylamino formoxyl]-the 2-methyl-propyl] carbamic acid isopropyl ester, supposition may be the cell wall synthetic inhibitor.The benzene metsulfovax is a kind of new type bactericide, the phytophthora root rot bacterium had excellent bactericidal activity, sprouting to its sporangial formation, spore, the good restraining effect is arranged under low concentration, and control has the phytophthora infestans of resistance and has the downy mildew of cucurbits of resistance that bactericidal activity is all arranged to methoxy acrylic the benzamide bactericide.
In the real process of agricultural production, preventing and treating the problem that disease is easy to generate most is the drug-fast generation of germ.The different cultivars composition carries out composite, is to prevent and treat the very common method of resistance germ.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals all is an additive effect, and the seldom composite of synergistic effect really arranged, especially synergistic effect very obviously, synergy ratio very high composite just still less.Through inventor's research, discovery is composite mutually with oxime bacterium ester and effective active composition B, good synergistic effect is arranged within the specific limits, and relevant composite about oxime bacterium ester and Propamocarb, propamocarb, the mould prestige of second, benzene metsulfovax, do not see relevant report at present at home and abroad as yet.
Summary of the invention
The objective of the invention is to propose a kind of have synergistic function, use cost is low, preventive effect the is good bactericidal composition that contains oxime bacterium ester and carbamate compound.
The present invention is achieved through the following technical solutions:
A kind of bactericidal composition that contains oxime bacterium ester, it is characterized in that: the percentage by weight of A, two kinds of active components of B is 1～60%: 1～80%, described A component is an oxime bacterium ester, and the B component is selected from a kind of in Propamocarb, propamocarb, the mould prestige of second or the benzene metsulfovax.
The described bactericidal composition that contains oxime bacterium ester is characterized in that: wherein the percentage by weight of oxime bacterium ester and effective active composition B is 3～60%: 5～70%.
The described bactericidal composition that contains oxime bacterium ester is characterized in that: the percentage by weight of oxime bacterium ester and Propamocarb is 5～15%: 10～60%.
The described bactericidal composition that contains oxime bacterium ester is characterized in that: the percentage by weight of oxime bacterium ester and propamocarb is 5～20%: 10～60%.
The described bactericidal composition that contains oxime bacterium ester is characterized in that: the percentage by weight of oxime bacterium ester and the mould prestige of second is 5～20%: 10～60%.
The described bactericidal composition that contains oxime bacterium ester is characterized in that: the percentage by weight of oxime bacterium ester and benzene metsulfovax is 10～60%: 5～15%.
The described bactericidal composition that contains oxime bacterium ester, wherein the effective active component content accounts for 1～95% of gross weight, is preferably 5～80%.
The described bactericidal composition that contains oxime bacterium ester is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion.
Described bactericidal composition is mainly used in prevents and treats powdery mildew, gray mold, downy mildew, rust, damping off, eqpidemic disease, late blight, stem rot, penicilliosis, damping off, balck shank, scab, leaf spot plant disease.
Amount of application when the content of active component depends on independent use in the present composition also depends on the mixed ratio and the synergistic effect degree of a kind of compound and another kind of compound, and the while is also relevant with the target fungi.Usually active weight percentage is 0.5～90% of a gross weight in the composition, and preferable is 5%～85%.According to different preparation types, the active component content scope is different.Usually, liquid preparation contains 1～70% active substance by weight, preferably is 5～50%; Solid pharmaceutical preparation contains 5～85% active substance by weight, preferably is 10～80%.
At least contain a kind of surfactant in the bactericidal composition of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 5～30% of a total formulation weight amount, and surplus is solid or liquid diluent.
The selected surfactant of bactericidal composition of the present invention is known in those skilled in the art: can be selected from dispersant, wetting agent, thickener or the defoamer one or more.According to different dosage form, can also contain stabilizing agent known in those skilled in the art, antifreeze etc. in the preparation.
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, the naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, during the ester polyoxyethylene is phonetic one or more.
Described disintegrant is selected from: one or more in sodium bicarbonate, sodium carbonate, bentonite, urea, ammonium sulfate, the aluminium chloride.
Described wetting agent is selected from: lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, tea are withered, in the silkworm excrement, soapberry powder one or more.
Described thickener is selected from: one or more in xanthans, gelatin, gum Arabic, melon glue, sodium phosphate trimer, phenolic resins, sodium alginate, white dextrin, methylcellulose, PAA, polyvinylpyrrolidone, crospolyvinylpyrrolidone, polyethylene glycol, the polyvinyl alcohol.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, diethylene glycol (DEG), triethylene glycol, the polyethylene glycol.
Described defoamer is selected from: silicone, C
8～10Aliphatic alcohols, C
10～20In saturated fat acids (as capric acid) and acid amides, silicone oil, the silicone compound one or more.
Described emulsifier is selected from: agricultural newborn 500# (alkyl benzene calcium sulfonate), OP series phosphate (polyoxyethylene nonylphenol ether phosphate), 600# phosphate (phenyl phenol polyoxy ethyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, farming newborn 400# (benzyl dimethyl phenol polyoxy ethyl ether), farming newborn 600# (phenyl phenol polyoxy ethyl ether), Nongru-700 # (alkylphenol-formaldehyde resin polyoxy ethyl ether), farming newborn 36# (phenethyl fluosite polyoxy ethyl ether), farming newborn 1600# (phenethyl phenol polyoxy ethyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (polyoxyethylene nonylphenol ether), By series (castor oil polyoxyethylene ether), farming newborn 33# (alkylaryl polyoxyethylene polyoxypropylene ether), farming newborn 34# (alkylaryl polyoxyethylene poly-oxygen propylene aether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), in the AEO series (the pure APEO of fat) one or more.
Described stabilizing agent is selected from: one or more in BHT, triphenyl phosphite, epoxychloropropane, tributyl phosphate, triethanolamine, diethanol amine, the monoethanolamine.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Composition of the present invention can be by the user before use through dilution or directly use.Its preparation can be by the preparation of common processing method, is about to active substance and after liquid flux or solid carrier mix, and adds in surfactant such as dispersant, stabilizing agent, wetting agent, adhesive, defoamer, the stabilizing agent etc. one or more again.
Bactericidal composition of the present invention can be processed into acceptable forms on any agricultural chemicals on demand.Wherein preferred dosage form is wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion.
When making wetting powder, composition comprises following constituent content: oxime bacterium ester 1～60%, active component B 1～80%, dispersant 5～10%, wetting agent 2～10%, filler 8～91%.
The former medicine of oxime bacterium ester, the former medicine of active component B, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, promptly can be made into the wetting powder product of the present composition.
When making water dispersible granules, composition comprises following constituent content: oxime bacterium ester 1～60%, active component B 1～80%, dispersant 3～12%, wetting agent 1～8%, disintegrant 1～10%, binding agent 1～8%, filler 10～92%.
The former medicine of oxime bacterium ester, the former medicine of active component B, dispersant, wetting agent, disintegrant, filler etc. are obtained the particle diameter that needs through comminution by gas stream together, add other auxiliary agents such as binding agent again, obtain the preparation materials.It is interior through after granulation and the drying to expect that product are quantitatively sent the fluidized bed granulation dryer to, makes the water dispersible granules product of the present composition.
When making suspending agent, composition comprises following constituent content: oxime bacterium ester 1～40%, active component B 1～40%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～1%, thickener 0.1～2%, antifreeze 0.1～8%, stabilizing agent 0.05～3%, deionized water adds to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze in the above-mentioned prescription are mixed through high speed shear, add the former medicine of oxime bacterium ester, the former medicine of active component B, ball milling is 2～3 hours in ball mill, makes diameter of particle all below 5 μ m, makes the suspending agent product of the present composition.
Comprise following constituent content when composition is made suspension emulsion: oxime bacterium ester 1～40%, active component B 1～40%, emulsifier 2～12%, dispersant 2～10%, defoamer 0.1～2%, thickener 0.1～2%, antifreeze 0.1～8%, stabilizing agent 0.05～3%, water add to 100%.
Dispersant, defoamer, thickener, antifreeze, stabilizing agent in the above-mentioned prescription are mixed through high speed shear, add the former medicine of active component B, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make active component B suspending agent, then with the former medicine of oxime bacterium ester, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make the suspension emulsion product of the present composition.
When making aqueous emulsion, composition comprises following constituent content: oxime bacterium ester 1～40%, active component B 1～40%, solvent 2～10%, emulsifier 2～12%, dispersant 2～10%, co-emulsifier 0.2～5%, antifreeze 0.1～8%, defoamer 0.1～2%, thickener 0.1～2%, deionized water adds to 100%.
Be dissolved into even oil phase with having former medicine, solvent, emulsifier, co-emulsifier to add together in the above-mentioned prescription, making.With deionized water, dispersant, antifreeze,, defoamer, thickener mix, and becomes the homogeneous water, under high-speed stirred, water slowly splashed into oil phase, makes the finely disseminated aqueous emulsion product of the present composition.
When making microemulsion, composition comprises following constituent content: oxime bacterium ester 1～20%, active component B 1～30%, emulsifier 5～15%, and solvent 2～10%, antifreeze 5～10%, stabilizing agent 0.5～3%, deionized water adds to 100%.
Above-mentioned prescription Central Plains medicine, solvent, emulsifier are added in the mother liquor modulation kettle, make even oil phase, deionized water, antifreeze etc. is mixed injection product modulation kettle,, mix and make the transparent or semitransparent microemulsion product of the present composition through high-speed stirred.
Beneficial effect of the present invention: (1) present composition effective active composition oxime bacterium ester and effective active composition B belong to the bactericide of two kinds of different mechanisms of action, and both are mixed mutually and can produce conflict; (2) present composition has good synergistic effect within the specific limits, and preventive effect is higher than single agent, and dosage is little; (3) the present invention not with an organic solvent is not difficult for producing poisoning, is convenient to transportation and storage; (4) present composition has enlarged fungicidal spectrum, and crop powdery mildew, gray mold, downy mildew, rust, damping off, eqpidemic disease, late blight, stem rot, penicilliosis, damping off, balck shank, scab, leaf spot are all had special efficacy.
Embodiment
To further instruction of the present invention, the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.
Application Example one
Example 180% oxime bacterium ester Propamocarb wetting powder
Oxime bacterium ester 12%, Propamocarb 68%, aliphatic amine polyoxyethylene are phonetic 6%, spaonin powder 5%, moistening bleeding agent F4%, bentonite add to 100%, and mixture carries out comminution by gas stream, makes 80% oxime bacterium ester Propamocarb wetting powder.
Example 260% oxime bacterium ester Propamocarb wetting powder
Oxime bacterium ester 15%, Propamocarb 45%, polycarboxylate 7.6%, white carbon 8%, bentonite adds to 100%, and mixture carries out comminution by gas stream, makes 60% oxime bacterium ester Propamocarb wetting powder.
Example 370% oxime bacterium ester Propamocarb water dispersible granules
Oxime bacterium ester 10%, Propamocarb 60%, alkyl benzene sulfonate calcium salt 6.5%, Nekal BX 5%, aluminium chloride 2.5%, kaolin add to 100%, the mixed 70% oxime bacterium ester Propamocarb water dispersible granules that gets.
Example 465% oxime bacterium ester Propamocarb water dispersible granules
Oxime bacterium ester 15%, Propamocarb 50%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%, spaonin powder 4%, bentonite add to 100%, the mixed 65% oxime bacterium ester Propamocarb water dispersible granules that gets.
Example 520% oxime bacterium ester Propamocarb suspending agent
Oxime bacterium ester 10%, Propamocarb 10%, lignosulfonates 4%, wetting and penetrating agent F 5%, C
8～10Aliphatic alcohols 0.5%, gum Arabic 2.5%, ethylene glycol 1.8%, deionized water add to 100%, the mixed 20% oxime bacterium ester Propamocarb suspending agent that gets.
Example 640% oxime bacterium ester Propamocarb suspending agent
Oxime bacterium ester 10%, Propamocarb 30%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, lauryl sodium sulfate 6%, C
10～20Saturated fat acids 0.4%, sodium phosphate trimer 1.5%, propane diols 1.6%, deionized water add to 100%, the mixed 40% oxime bacterium ester Propamocarb suspending agent that gets.
Example 732% oxime bacterium ester Propamocarb suspension emulsion
Oxime bacterium ester 8%, Propamocarb 24%, naphthalene sulfonic acid-formaldehyde condensation product 6%, tea are withered 5%, polyvinylpyrrolidone 1.6%, agricultural newborn 1600#7%, glycerine 2.2%, C
8～10Aliphatic alcohols 0.3%, water add to 100%, through the mixed 32% oxime bacterium ester Propamocarb suspension emulsion that gets.
Example 845% oxime bacterium ester Propamocarb suspension emulsion
Oxime bacterium ester 5%, Propamocarb 40%, the phonetic formaldehyde condensation products sulphate 5% of alkylphenol-polyethenoxy, wetting and penetrating agent F 4%, methylcellulose 1%, By series 4%, ethylene glycol 1.6%, silicone oil 0.5%, water add to 100%, through the mixed 45% oxime bacterium ester Propamocarb suspension emulsion that gets.
Example 930% oxime bacterium ester Propamocarb aqueous emulsion
Oxime bacterium ester 5%, Propamocarb 25%, N, dinethylformamide 8%, alkyl biphenyl ether disulfonic acid magnesium salts 5%, butanols 3%, ethylene glycol 5%, C
8～10Aliphatic alcohols 0.8%, deionized water adds to 100%, through the mixed 30% oxime bacterium ester Propamocarb aqueous emulsion that gets.
Example 1045% oxime bacterium ester Propamocarb aqueous emulsion
Oxime bacterium ester 7%, Propamocarb 38%, N-octylpyrrolidone 9%, agricultural newborn 1600#7%, calcium chloride 5%, glycerine 4%, silicone 1.2%, deionized water adds to 100%, through the mixed 45% oxime bacterium ester Propamocarb aqueous emulsion that gets.
Example 1125% oxime bacterium ester Propamocarb microemulsion
Oxime bacterium ester 5%, Propamocarb 20%, styrene polyoxyethylene ether ammonium sulfate salt 9%, cyclohexanone 3%, glycerine 8%, silicone 1.2%, deionized water adds to 100%, through the mixed 25% oxime bacterium ester Propamocarb microemulsion that gets.
Example 1235% oxime bacterium ester Propamocarb microemulsion
Oxime bacterium ester 5%, Propamocarb 30%, By series 10%, ethylene glycol monomethyl ether 2%, polyethylene glycol 8%, C
8～10Aliphatic alcohols 1%, deionized water adds to 100%, through the mixed 35% oxime bacterium ester Propamocarb microemulsion that gets.
Example 1375% oxime bacterium ester propamocarb wetting powder
Oxime bacterium ester 5%, propamocarb 70%, aliphatic amine polyoxyethylene are phonetic 5%, spaonin powder 5.8%, moistening bleeding agent F6.2%, bentonite add to 100%, and mixture carries out comminution by gas stream, makes 75% oxime bacterium ester propamocarb wetting powder.
Example 1460% oxime bacterium ester propamocarb wetting powder
Oxime bacterium ester 10%, propamocarb 50%, polycarboxylate 6.6%, white carbon 7.4%, bentonite adds to 100%, the mixed 60% oxime bacterium ester propamocarb wetting powder that gets.
Example 1580% oxime bacterium ester propamocarb water dispersible granules
Oxime bacterium ester 20%, propamocarb 60%, alkyl benzene sulfonate calcium salt 7%, Nekal BX 7.8%, aluminium chloride 2.2%, kaolin add to 100%, the mixed 80% oxime bacterium ester propamocarb water dispersible granules that gets.
Example 1655% oxime bacterium ester propamocarb water dispersible granules
Oxime bacterium ester 15%, propamocarb 40%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, spaonin powder 6%, bentonite add to 100%, the mixed 55% oxime bacterium ester propamocarb water dispersible granules that gets.
Example 1740% oxime bacterium ester propamocarb suspending agent
Oxime bacterium ester 5%, propamocarb 35%, lignosulfonates 5%, wetting and penetrating agent F 5%, C
8～10Aliphatic alcohols 0.8%, gum Arabic 3%, ethylene glycol 2.2%, deionized water add to 100%, the mixed 40% oxime bacterium ester propamocarb suspending agent that gets.
Example 1835% oxime bacterium ester propamocarb suspending agent
Oxime bacterium ester 10%, propamocarb 25%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, lauryl sodium sulfate 5%, C
10～20Saturated fat acids 1.2%, sodium phosphate trimer 1.8%, propane diols 1.5%, deionized water add to 100%, the mixed 35% oxime bacterium ester propamocarb suspending agent that gets.
Example 1930% oxime bacterium ester propamocarb suspension emulsion
Oxime bacterium ester 5%, propamocarb 25%, naphthalene sulfonic acid-formaldehyde condensation product 7%, tea are withered 6%, polyvinylpyrrolidone 2.3%, agricultural newborn 1600#8%, glycerine 1.7%, C
8～10Aliphatic alcohols 1%, water add to 100%, the mixed 30% oxime bacterium ester propamocarb suspension emulsion that gets.
Example 2045% oxime bacterium ester propamocarb suspension emulsion
Oxime bacterium ester 5%, propamocarb 40%, the phonetic formaldehyde condensation products sulphate 5% of alkylphenol-polyethenoxy, wetting and penetrating agent F6%, methylcellulose 1.5%, By series 6.5%, ethylene glycol 1.6%, silicone oil 0.4%, water add to 100%, the mixed 45% oxime bacterium ester propamocarb suspension emulsion that gets.
Example 2125% oxime bacterium ester propamocarb aqueous emulsion
Oxime bacterium ester 5%, propamocarb 20%, N, dinethylformamide 8%, alkyl biphenyl ether disulfonic acid magnesium salts 5%, butanols 5%, ethylene glycol 3%, C
8～10Aliphatic alcohols 1.5%, deionized water adds to 100%, the mixed 25% oxime bacterium ester propamocarb aqueous emulsion that gets.
Example 2245% oxime bacterium ester propamocarb aqueous emulsion
Oxime bacterium ester 20%, propamocarb 25%, N-octylpyrrolidone 6%, agricultural newborn 1600#8%, calcium chloride 4.8%, glycerine 4%, silicone 1.2%, deionized water adds to 100%, the mixed 45% oxime bacterium ester propamocarb aqueous emulsion that gets.
Example 2320% oxime bacterium ester propamocarb microemulsion
Oxime bacterium ester 8%, propamocarb 12%, styrene polyoxyethylene ether ammonium sulfate salt 8%, cyclohexanone 5%, glycerine 8%, silicone 2.5%, deionized water adds to 100%, the mixed 20% oxime bacterium ester propamocarb microemulsion that gets.
Example 2440% oxime bacterium ester propamocarb microemulsion
Oxime bacterium ester 5%, propamocarb 35%, By series 8%, ethylene glycol monomethyl ether 5%, polyethylene glycol 5%, C
8～10Aliphatic alcohols 1.5%, deionized water adds to 100%, the mixed 40% oxime bacterium ester propamocarb microemulsion that gets.
The mould prestige wetting powder of example 2554% oxime bacterium ester second
Oxime bacterium ester 12%, the mould prestige 42% of second, aryl phenol polyoxyethylene succinate sulfonate 6%, silkworm excrement 5%, attapulgite add to 100%, and mixture carries out comminution by gas stream, make the mould prestige wetting powder of 54% oxime bacterium ester second.
The mould prestige wetting powder of example 2668% oxime bacterium ester second
Oxime bacterium ester 20%, the mould prestige 48% of second, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 5%, spaonin powder 3%, diatomite add to 100%, and mixture carries out comminution by gas stream, the mixed mould prestige wetting powder of 68% oxime bacterium ester second that gets.
The mould prestige water dispersible granules of example 2764% oxime bacterium ester second
Oxime bacterium ester 8%, the mould prestige 56% of second, polycarboxylate 8%, lauryl sodium sulfate 5%, ammonium sulfate 2%, diatomite add to 100%, the mixed mould prestige water dispersible granules of 64% oxime bacterium ester second that gets.
The mould prestige water dispersible granules of example 2875% oxime bacterium ester second
Oxime bacterium ester 20%, the mould prestige 55% of second, lignosulfonates 8%, neopelex 5%, bentonite add to 100%, the mixed mould prestige water dispersible granules of 75% oxime bacterium ester second that gets.
The mould prestige suspending agent of example 2934% oxime bacterium ester second
Oxime bacterium ester 6%, the mould prestige 28% of second, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%, silkworm excrement 5%, C
8～10Aliphatic alcohols 1.2%, xanthans 1.5%, propane diols 1.3%, deionized water add to 100%, the mixed mould prestige suspending agent of 34% oxime bacterium ester second that gets.
The mould prestige suspending agent of example 3040% oxime bacterium ester second
Oxime bacterium ester 10%, the mould prestige 30% of second, the phonetic formaldehyde condensation products sulphate 8% of alkylphenol-polyethenoxy, wetting and penetrating agent F 4%, silicone compound 0.4%, methylcellulose 1.6%, ethylene glycol 2.8%, deionized water add to 100%, the mixed mould prestige suspending agent of 40% oxime bacterium ester second that gets.
The mould prestige suspension emulsion of example 3125% oxime bacterium ester second
Oxime bacterium ester 5%, the mould prestige 20% of second, alkyl benzene sulfonate calcium salt 6.5%, Nekal BX 6%, silicone compound 0.2%, triphenyl phosphite 2%, polyvinylpyrrolidone 1.2%, Nongru-700 #7%, ethylene glycol 1.6%, water adds to 100%, the mixed mould prestige suspension emulsion of 25% oxime bacterium ester second that gets.
The mould prestige suspension emulsion of example 3242% oxime bacterium ester second
Oxime bacterium ester 20%, the mould prestige 22% of second, alkylphenol-polyethenoxy are phonetic 4.5%, neopelex 3.5%, silicone oil 0.3%, polyvinylpyrrolidone 1.5%, tween series 6%, polyethylene glycol 3%, water adds to 100%, the mixed mould prestige suspension emulsion of 42% oxime bacterium ester second that gets.
The mould prestige aqueous emulsion of example 3336% oxime bacterium ester second
Oxime bacterium ester 12%, the mould prestige 24% of second, N, dinethylformamide 7%, alkyl biphenyl ether disulfonic acid magnesium salts 6%, butanols 4%, ethylene glycol 3%, C
8～10Aliphatic alcohols 1.5%, deionized water adds to 100%, the mixed mould prestige aqueous emulsion of 36% oxime bacterium ester second that gets.
The mould prestige aqueous emulsion of example 3430% oxime bacterium ester second
Oxime bacterium ester 5%, the mould prestige 25% of second, N-octylpyrrolidone 8%, agricultural newborn 1600#7%, calcium chloride 5.2%, glycerine 4%, silicone 1.8%, deionized water adds to 100%, the mixed mould prestige aqueous emulsion of 30% oxime bacterium ester second that gets.
The mould prestige microemulsion of example 3528% oxime bacterium ester second
Oxime bacterium ester 6%, the mould prestige 22% of second, styrene polyoxyethylene ether ammonium sulfate salt 6%, cyclohexanone 5%, glycerine 6%, silicone 3%, deionized water adds to 100%, the mixed mould prestige microemulsion of 28% oxime bacterium ester second that gets.
The mould prestige microemulsion of example 3642% oxime bacterium ester second
Oxime bacterium ester 18%, the mould prestige 24% of second, By series 6%, ethylene glycol monomethyl ether 5%, polyethylene glycol 8%, C
8～10Aliphatic alcohols 2%, deionized water adds to 100%, the mixed mould prestige microemulsion of 42% oxime bacterium ester second that gets.
Example 3756% oxime bacterium ester benzene metsulfovax wetting powder
Oxime bacterium ester 50%, benzene metsulfovax 6%, naphthalene sulfonic acid-formaldehyde condensation product 6%, silkworm excrement 5%, starch add to 100%, and mixture carries out comminution by gas stream, make 56% oxime bacterium ester benzene metsulfovax wetting powder.
Example 3840% oxime bacterium ester benzene metsulfovax wetting powder
Oxime bacterium ester 38%, benzene metsulfovax 2%, polycarboxylate 5%, soapberry powder 4%, attapulgite add to 100%, and mixture carries out comminution by gas stream, make 40% oxime bacterium ester benzene metsulfovax wetting powder.
Example 3948% oxime bacterium ester benzene metsulfovax water dispersible granules
Oxime bacterium ester 40%, benzene metsulfovax 8%, lignosulfonates 7%, lauryl sodium sulfate 6%, aluminium chloride 1.5%, kaolin add to 100%, the mixed 48% oxime bacterium ester benzene metsulfovax water dispersible granules that gets.
Example 4035% oxime bacterium ester benzene metsulfovax water dispersible granules
Oxime bacterium ester 25%, benzene metsulfovax 10%, polyoxyethylene carboxylate 8%, neopelex 5%, bentonite add to 100%, the mixed 35% oxime bacterium ester benzene metsulfovax water dispersible granules that gets.
Example 4136% oxime bacterium ester benzene metsulfovax suspending agent
Oxime bacterium ester 30%, benzene metsulfovax 6%, aryl phenol polyoxyethylene succinate sulfonate 7%, wetting and penetrating agent F 6%, silicone compound 0.6%, polyvinylpyrrolidone 1.5%, polyethylene glycol 1.2%, deionized water adds to 100%, the mixed 36% oxime bacterium ester benzene metsulfovax suspending agent that gets.
Example 4225% oxime bacterium ester benzene metsulfovax suspending agent
Oxime bacterium ester 15%, benzene metsulfovax 10%, polycarboxylate 6%, lauryl sodium sulfate 5%, silicone oil 0.4%, gum Arabic 1%, glycerine 1.6%, deionized water adds to 100%, the mixed 25% oxime bacterium ester benzene metsulfovax suspending agent that gets.
Example 4320% oxime bacterium ester benzene metsulfovax suspension emulsion
Oxime bacterium ester 15%, benzene metsulfovax 5%, polyoxyethylene carboxylate 6%, wetting and penetrating agent F 5%, polyvinylpyrrolidone 1.4%, polyethylene glycol 2%, C
8～10Aliphatic alcohols 0.2%, agricultural newborn 600#7%, water add to 100%, the mixed 20% oxime bacterium ester benzene metsulfovax suspension emulsion that gets.
Example 4445% oxime bacterium ester benzene metsulfovax suspension emulsion
Oxime bacterium ester 35%, benzene metsulfovax 10%, aryl phenol polyoxyethylene succinate sulfonate 7%, soapberry powder 5%, sodium phosphate trimer 1.2%, ethylene glycol 1.3%, C
10～20Saturated fat acids 0.6%, agricultural newborn 1600#6%, water add to 100%, the mixed 45% oxime bacterium ester benzene metsulfovax suspension emulsion that gets.
Example 4536% oxime bacterium ester benzene metsulfovax aqueous emulsion
Oxime bacterium ester 30%, benzene metsulfovax 6%, N, dinethylformamide 7%, alkyl biphenyl ether disulfonic acid magnesium salts 6%, butanols 4%, ethylene glycol 3%, C
8～10Aliphatic alcohols 1.5%, deionized water adds to 100%, the mixed 36% oxime bacterium ester benzene metsulfovax aqueous emulsion that gets.
Example 4620% oxime bacterium ester benzene metsulfovax aqueous emulsion
Oxime bacterium ester 16%, benzene metsulfovax 4%, N-octylpyrrolidone 8%, agricultural newborn 1600#7%, calcium chloride 5.2%, glycerine 4%, silicone 1.8%, deionized water adds to 100%, the mixed 20% oxime bacterium ester benzene metsulfovax aqueous emulsion that gets.
Example 4735% oxime bacterium ester benzene metsulfovax microemulsion
Oxime bacterium ester 30%, benzene metsulfovax 5%, styrene polyoxyethylene ether ammonium sulfate salt 6%, cyclohexanone 5%, glycerine 6%, silicone 3%, deionized water adds to 100%, the mixed 35% oxime bacterium ester benzene metsulfovax microemulsion that gets.
Example 4820% oxime bacterium ester benzene metsulfovax microemulsion
Oxime bacterium ester 15%, benzene metsulfovax 5%, By series 6%, ethylene glycol monomethyl ether 5%, polyethylene glycol 8%, C
8～10Aliphatic alcohols 2%, deionized water adds to 100%, the mixed 20% oxime bacterium ester benzene metsulfovax microemulsion that gets.
Wetting powder the key technical indexes of the present invention:
Table 1
Water dispersible granules the key technical indexes of the present invention:
Table 2
Suspending agent the key technical indexes of the present invention:
Table 3
Suspension emulsion the key technical indexes of the present invention:
Table 4
Aqueous emulsion the key technical indexes of the present invention:
Table 5
Microemulsion the key technical indexes of the present invention:
Table 6
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Pass through Toxicity Determination earlier, the synergy ratio (SR) after clear and definite two kinds of medicaments are composite by a certain percentage, SR＜0.5 is an antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect, on this basis, carry out field trial again.
Oxime bacterium ester and active component B (B be selected from Propamocarb, propamocarb, the mould prestige of second, the benzene metsulfovax a kind of) are composite to the crop pest Toxicity Determination.
After the effective inhibition concentration scope of each medicament was determined in prerun, each medicament was established 5 dosage respectively by active constituent content and is handled, and established the clear water contrast.Carry out with reference to " agricultural chemicals indoor bioassay test rule bactericide ", adopt the mycelial growth rate method to measure the virulence of medicament the crop germ.Measure colony diameter with the right-angled intersection method behind the 72h, calculate and respectively handle clean amount of growth, mycelial growth inhibition rate.
Clean amount of growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value (x) to, tries to achieve virulence regression equation (y=a+bx) with method of least squares, and calculates the EC of every kind of medicament thus
50Value.Calculate the different proportioning synergy ratios (SR) of two medicaments according to the Wadley method simultaneously, SR＜0.5 is an antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively active component oxime bacterium ester and active component B (Propamocarb, propamocarb, the mould prestige of second, benzene metsulfovax) shared ratio in combination;
A is an oxime bacterium ester;
B is a kind of in Propamocarb, propamocarb, the mould prestige of second, the benzene metsulfovax.
Implementation of an application example two:
Oxime bacterium ester and Propamocarb are composite to rose rust Toxicity Determination.
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective inhibition concentration scope of determining oxime bacterium ester, the former medicine of Propamocarb and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 7 oxime bacterium ester, Propamocarb and composite toxicity test analysis of results table thereof to the rose rust
As shown in Table 7, oxime bacterium ester, Propamocarb are to the EC of rose rust
50Be respectively 2.78mg/L and 25.36mg/L.Oxime bacterium ester and Propamocarb proportioning were at 60: 1 to 1: 80 o'clock, synergy ratio SR is all greater than 1.5, illustrating that oxime bacterium ester and Propamocarb were mixed in the scope at 60: 1 to 1: 80 all shows synergistic effect, especially when the two proportioning during at 4: 1 to 1: 16, synergistic effect is more obviously outstanding, synergy ratio SR maximum when oxime bacterium ester and Propamocarb percentage by weight are 1: 4 wherein, synergistic effect is the most obvious.
Implementation of an application example three:
Oxime bacterium ester and propamocarb are composite to the wheat powdery mildew Toxicity Determination.
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective inhibition concentration scope of determining oxime bacterium ester, the former medicine of propamocarb and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 8 oxime bacterium ester, propamocarb and composite toxicity test analysis of results table thereof to wheat powdery mildew
As shown in Table 8, oxime bacterium ester, propamocarb are to the EC of wheat powdery mildew
50Be respectively 2.56mg/L and 22.18mg/L.Oxime bacterium ester and propamocarb proportioning were at 60: 1 to 1: 80 o'clock, synergy ratio SR is all greater than 1.5, illustrating that oxime bacterium ester and propamocarb were mixed in the scope at 60: 1 to 1: 80 all shows synergistic effect, wherein synergistic effect is the most remarkable when oxime bacterium ester and propamocarb proportioning are 6: 1 to 1: 9, especially when the proportioning of oxime bacterium ester and propamocarb during at 1: 3, synergy ratio SR maximum, synergistic effect is the most obvious.
Implementation of an application example four
The mould prestige of oxime bacterium ester and second is composite to the gray mold of cucumber Toxicity Determination.
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective inhibition concentration scope of determining oxime bacterium ester, the former medicine of the mould prestige of second and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 9 oxime bacterium ester, the mould prestige of second and composite toxicity test analysis of results table thereof to gray mold of cucumber
As shown in Table 9, oxime bacterium ester, the mould prestige of second are to the EC of gray mold of cucumber
50Be respectively 2.61mg/L and 8.91mg/L.The mould prestige proportioning of oxime bacterium ester and second was at 60: 1 to 1: 80 o'clock, synergy ratio SR is all greater than 1.5, illustrating that the mould prestige of oxime bacterium ester and second was mixed in the scope at 60: 1 to 1: 80 all shows synergistic effect, wherein synergistic effect is the most remarkable when oxime bacterium ester and the mould prestige proportioning of second are 6: 1 to 1: 9, especially when the proportioning of oxime bacterium ester and the mould prestige of second during at 1: 3, synergy ratio SR maximum, synergistic effect is the most obvious.
Implementation of an application example five
Oxime bacterium ester and benzene metsulfovax are composite to the apple scab Toxicity Determination.
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective inhibition concentration scope of determining oxime bacterium ester, the former medicine of benzene metsulfovax and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 10 oxime bacterium ester, benzene metsulfovax and composite toxicity test analysis of results table thereof to apple scab
As shown in Table 10, oxime bacterium ester, benzene metsulfovax are to the EC of apple scab
50Be respectively 2.68mg/L and 0.67mg/L.Oxime bacterium ester and benzene metsulfovax proportioning were at 60: 1 to 1: 80 o'clock, synergy ratio SR is all greater than 1.5, illustrating that oxime bacterium ester and benzene metsulfovax were mixed in the scope at 60: 1 to 1: 80 all shows synergistic effect, wherein synergistic effect is the most remarkable when oxime bacterium ester and benzene metsulfovax proportioning are 16: 1 to 1: 4, especially when the proportioning of oxime bacterium ester and benzene metsulfovax during at 4: 1, synergy ratio SR maximum, synergistic effect is the most obvious.
Application Example six oxime bacterium esters and Propamocarb and the composite control rose rust test of pesticide effectiveness thereof
This experimental establishment is in Chenggong County, Kunming, Yunnan Province, and test medicine is researched and developed, provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 12.5% oxime bacterium emulsifiable concentrate (commercial), 72.2% Propamocarb aqua (commercial).
The investigation rose rust state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 2 times.Investigated disease index respectively and calculated preventive effect in 7 days, 14 days, 30 days after the dispenser for the second time.Experimental result is as follows:
Table 11 oxime bacterium ester, Propamocarb and the composite control rose rust test of pesticide effectiveness thereof
As can be seen from Table 11, can effectively prevent and treat the rose rust after oxime bacterium ester and Propamocarb are composite, control efficiency all is better than the preventive effect of single agent, and the preventive effect phase reached more than 30 days.In the test scope of medication, the target crop is had no adverse effects.
Application Example seven oxime bacterium esters and propamocarb and the composite control wheat powdery mildew test of pesticide effectiveness thereof
This experimental establishment is in Sanyuan County, Xianyang, Shanxi province city, and test medicine is researched and developed, provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 12.5% oxime bacterium emulsifiable concentrate (commercial), 72.2% propamocarb aqua (commercial).
The investigation wheat powdery mildew state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 2 times.Investigated disease index respectively and calculated preventive effect in 7 days, 14 days, 30 days after the dispenser for the second time.Experimental result is as follows:
Table 12 oxime bacterium ester, propamocarb and the composite control wheat powdery mildew test of pesticide effectiveness thereof
As can be seen from Table 12, can effectively prevent and treat wheat powdery mildew after oxime bacterium ester and propamocarb are composite, control efficiency all is better than the preventive effect of single agent, and the preventive effect phase reached more than 30 days.In the test scope of medication, the target crop is had no adverse effects.
Application Example eight oxime bacterium esters and the mould prestige of second and the composite control gray mold of cucumber test of pesticide effectiveness thereof
This experimental establishment is in suburb, Shouguang City, Shandong Province, and test medicine is researched and developed, provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 12.5% oxime bacterium emulsifiable concentrate (commercial), the mould prestige wetting powder of 50% second (commercial).
The investigation gray mold of cucumber state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 2 times.Investigated disease index respectively and calculated preventive effect in 3 days, 14 days, 30 days after the dispenser for the second time.Experimental result is as follows:
Table 13 oxime bacterium ester, the mould prestige of second and the composite control gray mold of cucumber test of pesticide effectiveness thereof
As can be seen from Table 13, can effectively prevent and treat the gray mold of cucumber disease after the mould prestige of oxime bacterium ester and second is composite, control efficiency all is better than the preventive effect of single agent, and the preventive effect phase reached more than 30 days.In the test scope of medication, the target crop is had no adverse effects.
Application Example nine oxime bacterium esters and benzene metsulfovax and the composite apple scab test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is at the Jinhua, Zhejiang Province suburban area, and test medicine is researched and developed, provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 12.5% oxime bacterium emulsifiable concentrate (commercial), 10% benzene metsulfovax suspending agent (commercial).
Investigation apple scab disease index before the medicine, in the their early stage dispenser, every dispenser on the 7th once, dispenser is 3 times altogether, for the third time 3 days, 14 days, 30 days investigation disease indexs and calculate preventive effect after the dispenser.Experimental result is as follows:
Table 14 oxime bacterium ester, the composite apple scab test of pesticide effectiveness of preventing and treating of benzene metsulfovax
As can be seen from Table 14, can effectively prevent and treat apple scab after oxime bacterium ester and benzene metsulfovax are composite, control efficiency all is better than the preventive effect of single agent, and the preventive effect phase reached more than 30 days.In the test scope of medication, the target crop is had no adverse effects.
Claims (9)
1. bactericidal composition that contains oxime bacterium ester and carbamate compound, it is characterized in that: the percentage by weight of A, two kinds of active components of B is 1～60%: 1～80%, described active component A is an oxime bacterium ester, and active component B is selected from a kind of in Propamocarb, propamocarb, the mould prestige of second or the benzene metsulfovax.
2. a kind of bactericidal composition that contains oxime bacterium ester according to claim 1 is characterized in that: wherein the percentage by weight of oxime bacterium ester and effective active composition B is 3～60%: 5～70%.
3. a kind of bactericidal composition that contains oxime bacterium ester according to claim 2 is characterized in that: the percentage by weight of oxime bacterium ester and Propamocarb is 5～15%: 10～60%.
4. a kind of bactericidal composition that contains oxime bacterium ester according to claim 2 is characterized in that: the percentage by weight of oxime bacterium ester and propamocarb is 5～20%: 10～60%.
5. a kind of bactericidal composition that contains oxime bacterium ester according to claim 2 is characterized in that: the percentage by weight of oxime bacterium ester and the mould prestige of second is 5～20%: 10～60%.
6. a kind of bactericidal composition that contains oxime bacterium ester according to claim 2 is characterized in that: the percentage by weight of oxime bacterium ester and benzene metsulfovax is 10～60%: 5～15%.
7. a kind of bactericidal composition that contains oxime bacterium ester according to claim 1, it is characterized in that: the formulation of microbicide compositions is selected from: wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion.
8. a kind of bactericidal composition that contains oxime bacterium ester according to claim 1 is used to prevent and treat grass family class crop, views and admires the disease on class flowers, vegetables and the fruit tree.
9. a kind of bactericidal composition that contains oxime bacterium ester according to claim 8 is used to prevent and treat the application of powdery mildew, gray mold, downy mildew, rust, damping off, eqpidemic disease, late blight, stem rot, penicilliosis, damping off, balck shank, scab, leaf spot plant disease.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102550548A (en) * | 2012-01-17 | 2012-07-11 | 广东中迅农科股份有限公司 | Benthiavalicarb-isopropyl water suspension and preparation method thereof |
| CN102763645A (en) * | 2012-06-30 | 2012-11-07 | 广东中迅农科股份有限公司 | Benthiavalicarb-isopropyl emulsion in water and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101102672A (en) * | 2004-12-09 | 2008-01-09 | 辛根塔参与股份公司 | Method for improving seed lot quality |
| EP2036438A1 (en) * | 2007-09-12 | 2009-03-18 | Bayer CropScience AG | Post-harvest treatment |
| CN101541175A (en) * | 2006-12-22 | 2009-09-23 | 拜尔农作物科学股份公司 | Pesticide composition comprising propamocarb-hydrochloride and an insecticide active substance |
| CN101953347A (en) * | 2010-06-03 | 2011-01-26 | 深圳诺普信农化股份有限公司 | Pesticide composition and application thereof |
-
2011
- 2011-04-09 CN CN2011100885196A patent/CN102204554A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101102672A (en) * | 2004-12-09 | 2008-01-09 | 辛根塔参与股份公司 | Method for improving seed lot quality |
| CN101541175A (en) * | 2006-12-22 | 2009-09-23 | 拜尔农作物科学股份公司 | Pesticide composition comprising propamocarb-hydrochloride and an insecticide active substance |
| EP2036438A1 (en) * | 2007-09-12 | 2009-03-18 | Bayer CropScience AG | Post-harvest treatment |
| CN101953347A (en) * | 2010-06-03 | 2011-01-26 | 深圳诺普信农化股份有限公司 | Pesticide composition and application thereof |
Non-Patent Citations (2)
| Title |
|---|
| 《农药》 20031025 司乃国等 创制杀菌剂烯肟菌酯生物活性及应用研究(Ⅰ)__黄瓜霜霉病 1-9 , 第10期 * |
| 司乃国等: "创制杀菌剂烯肟菌酯生物活性及应用研究(Ⅰ)――黄瓜霜霉病", 《农药》, no. 10, 25 October 2003 (2003-10-25) * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102550548A (en) * | 2012-01-17 | 2012-07-11 | 广东中迅农科股份有限公司 | Benthiavalicarb-isopropyl water suspension and preparation method thereof |
| CN102763645A (en) * | 2012-06-30 | 2012-11-07 | 广东中迅农科股份有限公司 | Benthiavalicarb-isopropyl emulsion in water and preparation method thereof |
| CN102763645B (en) * | 2012-06-30 | 2015-09-16 | 广东中迅农科股份有限公司 | Aqueous emulsion of a kind of benzene metsulfovax and preparation method thereof |
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Address after: 715500 middle section of North Ring Road, Pucheng County, Shaanxi Applicant after: Shanxi Thompson Biological Technology Co., Ltd. Address before: 710075, C, 15 floor, Jinqiao International Plaza, science and technology road, hi tech Zone, Shaanxi, Xi'an Applicant before: Shanxi Thompson Biological Technology Co., Ltd. |
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Application publication date: 20111005 |