CN102763645B - Aqueous emulsion of a kind of benzene metsulfovax and preparation method thereof - Google Patents
Aqueous emulsion of a kind of benzene metsulfovax and preparation method thereof Download PDFInfo
- Publication number
- CN102763645B CN102763645B CN201210221314.5A CN201210221314A CN102763645B CN 102763645 B CN102763645 B CN 102763645B CN 201210221314 A CN201210221314 A CN 201210221314A CN 102763645 B CN102763645 B CN 102763645B
- Authority
- CN
- China
- Prior art keywords
- benzene metsulfovax
- aqueous emulsion
- preparation
- aqueous
- oil phase
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 title claims abstract description 117
- UDSJPFPDKCMYBD-UHFFFAOYSA-N Metsulfovax Chemical compound S1C(C)=NC(C)=C1C(=O)NC1=CC=CC=C1 UDSJPFPDKCMYBD-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 239000000839 emulsion Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000003921 oil Substances 0.000 claims abstract description 16
- 239000008346 aqueous phase Substances 0.000 claims abstract description 14
- 239000012071 phase Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000008367 deionised water Substances 0.000 claims abstract description 8
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 8
- -1 fatty acid ester Chemical class 0.000 claims description 13
- 235000019198 oils Nutrition 0.000 claims description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 235000019483 Peanut oil Nutrition 0.000 claims description 4
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 4
- 239000000312 peanut oil Substances 0.000 claims description 4
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 3
- GKVKQZRNDGUFSY-NSGFTINJSA-L [Na+].C(C)(CCCCCC)/C(=C(/C(=O)[O-])\C(C)CCCCCC)/C(=O)[O-].[Na+] Chemical compound [Na+].C(C)(CCCCCC)/C(=C(/C(=O)[O-])\C(C)CCCCCC)/C(=O)[O-].[Na+] GKVKQZRNDGUFSY-NSGFTINJSA-L 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 239000002904 solvent Substances 0.000 abstract description 11
- 238000004519 manufacturing process Methods 0.000 abstract description 9
- 239000003995 emulsifying agent Substances 0.000 abstract description 6
- 231100000053 low toxicity Toxicity 0.000 abstract description 6
- 239000003795 chemical substances by application Substances 0.000 abstract description 5
- 239000006184 cosolvent Substances 0.000 abstract description 5
- 239000002270 dispersing agent Substances 0.000 abstract description 5
- 239000003381 stabilizer Substances 0.000 abstract description 5
- 239000003814 drug Substances 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 244000144977 poultry Species 0.000 abstract description 4
- 229940079593 drug Drugs 0.000 abstract description 3
- 230000008569 process Effects 0.000 abstract description 3
- 230000036039 immunity Effects 0.000 abstract description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 9
- 229920000056 polyoxyethylene ether Polymers 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 4
- 239000004359 castor oil Substances 0.000 description 4
- 235000019438 castor oil Nutrition 0.000 description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000000575 pesticide Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 241000233679 Peronosporaceae Species 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 3
- 229920001568 phenolic resin Polymers 0.000 description 3
- 231100000572 poisoning Toxicity 0.000 description 3
- 230000000607 poisoning effect Effects 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 241000233614 Phytophthora Species 0.000 description 2
- 241000233622 Phytophthora infestans Species 0.000 description 2
- 241001281803 Plasmopara viticola Species 0.000 description 2
- 241001281805 Pseudoperonospora cubensis Species 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000004562 water dispersible granule Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- BDCFWIDZNLCTMF-UHFFFAOYSA-N 2-phenylpropan-2-ol Chemical compound CC(C)(O)C1=CC=CC=C1 BDCFWIDZNLCTMF-UHFFFAOYSA-N 0.000 description 1
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical group NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 1
- 241000219193 Brassicaceae Species 0.000 description 1
- 208000031968 Cadaver Diseases 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 241000549404 Hyaloperonospora parasitica Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 108091005461 Nucleic proteins Proteins 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000004920 integrated pest control Methods 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000008297 liquid dosage form Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000003090 pesticide formulation Substances 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses aqueous emulsion of a kind of benzene metsulfovax and preparation method thereof, in the aqueous emulsion of benzene metsulfovax, the percentage by weight of each component is: benzene metsulfovax: 1-20%; Solvent and cosolvent: 1-45%; Emulsifier: 1-15%; Dispersant: 0.5-2%; Stabilizing agent: 1-5%; Antifreezing agent: 1-5%; Surplus is deionized water.Its preparation method is: be dissolved in solvent and cosolvent by benzene metsulfovax, then adds emulsifier, stabilizing agent and dispersant, obtained oil phase; Antifreezing agent and deionized water are mixed to get aqueous phase, oil phase are slowly joined in aqueous phase or by aqueous phase under high shear conditions. and slowly join in oil phase, obtained benzene metsulfovax aqueous emulsion.The present invention has efficiently, low toxicity, environmentally friendly, person poultry safety, the feature such as not easily develop immunity to drugs.The technological process of production is simple, is easy to processing.
Description
Technical field
The present invention relates to a kind of pesticidal preparations, specifically, is aqueous emulsion of a kind of benzene metsulfovax and preparation method thereof.
Background technology
Benzene metsulfovax has good bactericidal activity to phytophthora root rot, has good inhibitory action at low concentrations, but do not act on the release of zoospore and the movement of zoospore the sporangial sprouting of its sporangial formation.Similar with the field test results of Cruciferae Pseudoperonospora cubensis (Peronospora parasitica Fr.) to Plasmopara viticola (Plasmopara viticola Berl) downy mildew of cucurbits bacterium (Pseudoperonospora cubensis Rostov.).The biological chemistry action mechanism of benzene metsulfovax just under study for action, benzene metsulfovax has the phytophthora infestans of resistance to benzamide functional group and has the downy mildew of cucurbits of resistance to have bactericidal activity to methoxy acrylic functional group, infers that benzene metsulfovax is different from the mechanism of action containing these functional group's bactericide.And benzene metsulfovax does not affect the oxidative synthesis of nucleic acid and protein, the function of phytophthora root rot bacterium protoplasmic membrane is not affected.
Current benzene metsulfovax mainly based on pulvis, wetting powder, water dispersible granules, due to and wetting powder, pulvis also exist big for environment pollution, there is the shortcomings such as power consumption of polymer processing is high in water dispersible granules.Preparation Forms of Modern Pesticide towards water baseization, ultramicronising, without efflorescence and Co ntrolled release aspect development, namely be the formulations of pesticide of matrix with water, wherein aqueous emulsion is that a kind of organic solvent is as far as possible few by even no, good drug efficacy, environmentally-friendly water-basedization novel pesticide formulation, is also a kind of excellent liquid dosage form replacing emulsifiable concentrates for agricultural chemicals.
The aqueous emulsion of benzene metsulfovax of the present invention has efficiently, low toxicity, environmentally friendly, person poultry safety, the feature of easy degraded, compared with traditional missible oil, greatly reduce production cost, save a large amount of fossil resources, and benzene metsulfovax aqueous emulsion of the present invention replaces a large amount of organic solvents with water, avoid producing pollution, explosive and poisoning problem in production, make that pesticide processing is low to be poisoned, ensure the mankind and mammiferous safety and health.
Summary of the invention
The object of the invention is to overcome exist in prior art environmental pollution, endanger the defects such as healthy and manufacturing cost is high and a kind of efficient, the low toxicity developed, environmentally friendly, person poultry safety and the benzene metsulfovax aqueous emulsion easily produced and use.
Technical scheme of the present invention: for achieving the above object, the invention provides a kind of benzene metsulfovax aqueous emulsion, each component is as follows by weight percentage: benzene metsulfovax: 1-20%; Solvent and cosolvent: 1-45%; Emulsifier: 1-15%; Dispersant: 0.5-2%; Stabilizing agent: 1-5%; Antifreezing agent: 1-5%; Surplus is deionized water.
Wherein:
Solvent and cosolvent are the mixing of one or more of dimethylbenzene, toluene, isobutanol, ethyl acetate, NOP, repefral, diethyl phthalate, dibutyl phthalate, aromatic hydrocarbon solvent Solvesso100, aromatic hydrocarbon solvent Solvesso150, aromatic hydrocarbon solvent Solvesso200.
Emulsifier is the mixing of one or more in alkylphenol polyoxyethylene, alkaryl phenol polyethenoxy ether phosphate, castor oil polyoxyethylene ether, alkylbenzenesulfonate, alkylphenol-polyethenoxy phosphate, polyoxyethylene sorbitan fatty acid ester, sorbitan ester, fatty alcohol-polyoxyethylene ether, disecoctylmaleate sodium sulfonate, castor oil, lauryl sodium sulfate.
Dispersant is alkyl phenol formaldehyde resin polyoxyethylene ether sulphate.
Stabilizing agent is the mixing of one or more in peanut oil, antioxidant 264, epoxidized soybean oil, epoxidized linseed oil, epoxy fat, pentaerythrite, xylitol, pyrogallic acid.
Antifreezing agent is the mixing of one or more in ethylene glycol, propane diols, glycerine, diethylene glycol.
Benzene metsulfovax method for producing aqueous emulsion provided by the invention is: be dissolved in solvent and cosolvent by benzene metsulfovax, then add emulsifier, stabilizing agent and dispersant, obtained oil phase; Antifreezing agent and deionized water are mixed to get aqueous phase, oil phase are slowly joined in aqueous phase or by aqueous phase under high shear conditions. and slowly join in oil phase, obtained benzene metsulfovax aqueous emulsion.
Compared with prior art, benzene metsulfovax aqueous emulsion provided by the invention, as the water base chemical preparation of one, has efficient, low toxicity, environmentally friendly, person poultry safety, and the feature such as not easily develop immunity to drugs.Adopt solvent and the emulsifier of low toxicity, stable performance, easily degrades, high to corps diseases activity, and environmental pollution is very little.The technological process of production is simple, and investment of production equipment expense is low, is easy to processing.
Benzene metsulfovax aqueous emulsion provided by the invention has following advantage:
1, benzene metsulfovax aqueous emulsion provided by the invention carrys out alternative most organic solvent with deionized water; reduce environmental pollution; be conducive to ecological environmental protection; also greatly can reduce production cost, save a large amount of fossil resources, and adopt the solvent of low toxicity; greatly reduce organic solvent to the pollution of human body and environment and residual; avoid producing pollution, explosive and poisoning problem in production, make pesticide processing produce low poisoning, ensure the safety and health of people and animals.
2, benzene metsulfovax aqueous emulsion provided by the invention not only has well attachment and permeability to crop, and properties of product are stablized, and activity is higher, improves drug effect, reduces the dosage of medicament simultaneously.
3, benzene metsulfovax aqueous emulsion provided by the invention completely can as the desirable public nuisance-free agricultural chemicals preparation of integrated pest control in agriculture.
Accompanying drawing explanation
Fig. 1 is the process chart of preparation method of the present invention.
Embodiment
The present invention is described by following specific embodiment, but the invention is not restricted to following specific embodiment.In these embodiments, unless otherwise indicated, all percentage is all weight percentage.
Embodiment one: benzene metsulfovax 5%, dimethyl phenyl carbinol 12%, the two mixing, fully dissolves and obtains oil phase; Castor oil polyoxyethylene ether 3%, fatty alcohol-polyoxyethylene ether 2%, alkyl phenol formaldehyde resin polyoxyethylene ether sulphate 1%, pyrogallic acid 2%, peanut oil 2% and ethylene glycol 4%, throw into together in deionized water, aqueous phase is made after fully stirring in preparation still, open after stirring and oil phase is slowly joined in aqueous phase, shear 30 minutes for 6000 revs/min, obtained 5% benzene metsulfovax aqueous emulsion.
Embodiment two: benzene metsulfovax 10%, dimethylbenzene 10%, diethyl phthalate 10%, three mixes, and fully dissolves and obtains oil phase; Polyoxyethylene sorbitan fatty acid ester 2%, polyol fatty acid ester and ethylene oxide adduct thereof 1.5%, disecoctylmaleate sodium sulfonate 1%, antioxidant 264 2%, peanut oil 4.0g and glycerine 4%, throw into together in deionized water, aqueous phase is made after fully stirring in preparation still, open after stirring and oil phase is slowly joined in aqueous phase, shear 15 minutes for 6000 revs/min, obtained 10% benzene metsulfovax aqueous emulsion.
Embodiment three: benzene metsulfovax 20%, NOP 10%, aromatic hydrocarbon solvent Solvesso150 25%, three mixes, and fully dissolves and obtains oil phase; Castor oil polyoxyethylene ether 4%, polyoxyethylene sorbitan fatty acid ester 2%, fatty alcohol-polyoxyethylene ether 1%, alkyl phenol formaldehyde resin polyoxyethylene ether sulphate 1%, epoxidized soybean oil 5% and glycerine 4%, aqueous phase is made after fully stirring in preparation still, open after stirring and oil phase is slowly joined in aqueous phase, shear 20 minutes for 6000 revs/min, obtained 20% benzene metsulfovax aqueous emulsion.
Benzene metsulfovax aqueous emulsion of the present invention overcomes the deficiency of the conventional dosage forms such as missible oil and pulvis, has had both environmental protection and the low advantage of use cost, in processing and use procedure, has reduced the pollution to environment, and reduce peasant's use cost.Prove through field control effectiveness test, benzene metsulfovax aqueous emulsion of the present invention all has good control efficiency to veterinary antibiotics downy mildew, potato late blight etc.
Claims (1)
1. a benzene metsulfovax aqueous emulsion, it effectively becomes benzene metsulfovax, it is characterized in that, each component is as follows by weight percentage: benzene metsulfovax 10%, dimethylbenzene 10%, diethyl phthalate 10%, and three mixes, and fully dissolves and obtains oil phase; Polyoxyethylene sorbitan fatty acid ester 2%, polyol fatty acid ester and ethylene oxide adduct thereof 1.5%, disecoctylmaleate sodium sulfonate 1%, antioxidant 264 2%, peanut oil 4.0g and glycerine 4%, throw into together in deionized water, aqueous phase is made after fully stirring in preparation still, open after stirring and oil phase is slowly joined in aqueous phase, shear 15 minutes for 6000 revs/min, obtained 10% benzene metsulfovax aqueous emulsion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210221314.5A CN102763645B (en) | 2012-06-30 | 2012-06-30 | Aqueous emulsion of a kind of benzene metsulfovax and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210221314.5A CN102763645B (en) | 2012-06-30 | 2012-06-30 | Aqueous emulsion of a kind of benzene metsulfovax and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102763645A CN102763645A (en) | 2012-11-07 |
| CN102763645B true CN102763645B (en) | 2015-09-16 |
Family
ID=47091410
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210221314.5A Active CN102763645B (en) | 2012-06-30 | 2012-06-30 | Aqueous emulsion of a kind of benzene metsulfovax and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102763645B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102177889A (en) * | 2011-03-15 | 2011-09-14 | 广东中迅农科股份有限公司 | Difenoconazole water emulsion and preparation method thereof |
| CN102204554A (en) * | 2011-04-09 | 2011-10-05 | 陕西汤普森生物科技有限公司 | Antibacterial composition containing trifloxystrobin and carbamate compound |
-
2012
- 2012-06-30 CN CN201210221314.5A patent/CN102763645B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102177889A (en) * | 2011-03-15 | 2011-09-14 | 广东中迅农科股份有限公司 | Difenoconazole water emulsion and preparation method thereof |
| CN102204554A (en) * | 2011-04-09 | 2011-10-05 | 陕西汤普森生物科技有限公司 | Antibacterial composition containing trifloxystrobin and carbamate compound |
Non-Patent Citations (1)
| Title |
|---|
| 新型杀菌剂苯噻菌胺;刘允萍等;《农药》;20111031;第50卷(第10期);第576-578页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102763645A (en) | 2012-11-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102742607B (en) | Paecilomyces lilacinus fungal spore oil suspending agent and preparation method as well as application thereof | |
| CN101554156A (en) | Fomesafen microemulsion and preparation method thereof | |
| CN102379300A (en) | Acaricidal combination containing bifenazate and spirodiclofen | |
| CN104824017A (en) | Pesticide composition containing fosthiazate and cyhalothrin | |
| CN102177887A (en) | Diafenthiuron emulsion in water and preparation method thereof | |
| CN102388912A (en) | Fosthiazate aqueous emulsion and preparation method thereof | |
| CN102177889A (en) | Difenoconazole water emulsion and preparation method thereof | |
| CN106106444A (en) | A kind of agricultural insecticidal microemulsion of anti-light solution and preparation method thereof | |
| CN102763645B (en) | Aqueous emulsion of a kind of benzene metsulfovax and preparation method thereof | |
| CN105076144A (en) | Microcapsule suspending agent containing metalaxyl-M and azoxystrobin | |
| CN105017913B (en) | Special antibiotic property resin of a kind of environment-friendly type coating, paint and preparation method thereof | |
| CN102726396B (en) | A kind of spinosad microemulsion and preparation method thereof | |
| CN102670649B (en) | Drug for preventing and treating ichthyophthiriasis of pet fish | |
| CN103210909B (en) | Ring worm hydrazides aqueous emulsion and preparation method thereof | |
| CN102986696A (en) | Acaricidal composition containing fluacrypyrim and bifenazate | |
| CN102763647B (en) | A kind of benzene metsulfovax microemulsion and preparation method thereof | |
| CN104255746A (en) | Botanical insecticide composition and preparation method thereof | |
| CN102696608B (en) | A kind of flonicamid aqueous emulsion and preparation method thereof | |
| CN103518735A (en) | Quizalofop-p-ethyl emulsion in water | |
| CN102696607B (en) | A kind of flonicamid microemulsion and preparation method thereof | |
| CN102763644A (en) | Cyazofamid microemulsion and preparation method thereof | |
| CN102763651A (en) | Metalaxyl microemulsion and preparation method thereof | |
| CN102177888A (en) | Micellar emulsion of dimethomorph and method for preparing same | |
| CN102972416A (en) | Acaricidal composition containing fluacrypyrim and spirodiclofen | |
| CN108042558A (en) | Avermectin preparation used for aquiculture and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190826 Address after: 225400 West of Daiwang Road, Taixing High-tech Industrial Development Zone, Taizhou City, Jiangsu Province Patentee after: Jiangsu yuan Qing Environmental Protection Technology Co.,Ltd. Address before: 516000 Guangdong province Huizhou Zhongkai hi tech Development Zone No. 24 District Patentee before: GUANGDONG ZHONGXUN AGRICULTURAL TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20201207 Address after: Room 315, No.8 Nujiang Road, Hexi District, Tianjin 300202 Patentee after: Nantong Zhonggao (Tianjin) Intellectual Property Management Co.,Ltd. Address before: 225400 West of Daiwang Road, Taixing High-tech Industrial Development Zone, Taizhou City, Jiangsu Province Patentee before: Jiangsu yuan Qing Environmental Protection Technology Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| CP03 | Change of name, title or address |
Address after: Room 315, No. 8 Nujiang Road, Hexi District, Tianjin, with a budget of 300000 RMB Patentee after: Zhonggao (Tianjin) Intellectual Property Management Co.,Ltd. Country or region after: China Address before: Room 315, No.8 Nujiang Road, Hexi District, Tianjin 300202 Patentee before: Nantong Zhonggao (Tianjin) Intellectual Property Management Co.,Ltd. Country or region before: China |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20240919 Address after: Room 425, Building 32, No. 8 Nujiang Road, Hexi District, Tianjin, with a budget of 300000 RMB Patentee after: Heyuan (Tianjin) Data Technology Co.,Ltd. Country or region after: China Address before: Room 315, No. 8 Nujiang Road, Hexi District, Tianjin, with a budget of 300000 RMB Patentee before: Zhonggao (Tianjin) Intellectual Property Management Co.,Ltd. Country or region before: China |