CN103210909B - Ring worm hydrazides aqueous emulsion and preparation method thereof - Google Patents
Ring worm hydrazides aqueous emulsion and preparation method thereof Download PDFInfo
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- CN103210909B CN103210909B CN201310094556.7A CN201310094556A CN103210909B CN 103210909 B CN103210909 B CN 103210909B CN 201310094556 A CN201310094556 A CN 201310094556A CN 103210909 B CN103210909 B CN 103210909B
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- worm hydrazides
- ring worm
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- aqueous emulsion
- polyoxyethylene ether
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- 208000002474 Tinea Diseases 0.000 title claims abstract description 25
- 241000893966 Trichophyton verrucosum Species 0.000 title claims abstract description 25
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 239000000839 emulsion Substances 0.000 title claims abstract description 17
- 238000004945 emulsification Methods 0.000 title abstract description 4
- 239000003921 oil Substances 0.000 claims abstract description 13
- 239000008346 aqueous phase Substances 0.000 claims abstract description 12
- 239000012071 phase Substances 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000008367 deionised water Substances 0.000 claims abstract description 5
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 5
- -1 alkyl phenol formaldehyde resin Chemical compound 0.000 claims description 12
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 12
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 12
- 235000019198 oils Nutrition 0.000 claims description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 8
- 239000003814 drug Substances 0.000 claims description 7
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 6
- 239000004359 castor oil Substances 0.000 claims description 5
- 235000019438 castor oil Nutrition 0.000 claims description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 5
- 235000019483 Peanut oil Nutrition 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
- 239000000312 peanut oil Substances 0.000 claims description 4
- 229920001568 phenolic resin Polymers 0.000 claims description 4
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 4
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 claims description 3
- 229910045601 alloy Inorganic materials 0.000 claims 1
- 239000000956 alloy Substances 0.000 claims 1
- 229910000679 solder Inorganic materials 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 239000002904 solvent Substances 0.000 abstract description 6
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 239000002270 dispersing agent Substances 0.000 abstract description 3
- 239000003995 emulsifying agent Substances 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- 239000003381 stabilizer Substances 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 231100000053 low toxicity Toxicity 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- 231100000572 poisoning Toxicity 0.000 description 3
- 230000000607 poisoning effect Effects 0.000 description 3
- 244000144977 poultry Species 0.000 description 3
- 241001124076 Aphididae Species 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 229920001214 Polysorbate 60 Polymers 0.000 description 2
- GKVKQZRNDGUFSY-NSGFTINJSA-L [Na+].C(C)(CCCCCC)/C(=C(/C(=O)[O-])\C(C)CCCCCC)/C(=O)[O-].[Na+] Chemical compound [Na+].C(C)(CCCCCC)/C(=C(/C(=O)[O-])\C(C)CCCCCC)/C(=O)[O-].[Na+] GKVKQZRNDGUFSY-NSGFTINJSA-L 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- 241001674939 Caulanthus Species 0.000 description 1
- 241000675108 Citrus tangerina Species 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000008297 liquid dosage form Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000003090 pesticide formulation Substances 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of ring worm hydrazides aqueous emulsion and preparation method thereof, the weight percentage of each component is: ring worm hydrazides 1-25%, and solvent 3-25%, emulsifier 4-15%, stabilizing agent 1-5%, dispersant 0.5-2%, antifreezing agent 1-5%, surplus is deionized water.Its preparation method is: be dissolved in solvent by ring worm hydrazides and obtain oil phase, all the other components and water are mixed to get aqueous phase, by oil phase and aqueous phase obtained finished product under high shear conditions..The invention provides a kind of environmental friendliness preparation, its preparation method technique is simple, cost is low, is convenient to suitability for industrialized production, has wide production application prospect.
Description
Technical field
The present invention relates to a kind of pesticidal preparations and preparation method thereof, specifically a kind of aqueous emulsion and preparation method thereof of ring worm hydrazides.
Background technology
Ring worm hydrazides, molecular formula C
24h
30n
2o
3chemical name: the 2'-tert-butyl group-5-methyl-2'-(3; 5-dimethylbenzoyl) chroman-6-formylhydrazine; be mainly used on vegetables, tealeaves, fruit tree, rice field, other crop and ornamental plant; not only to described plant safety; not having poisoning, and do not have harmful effect to environment and ecology, is the desirable medicament in Integrated Pest improvement system.
Preparation Forms of Modern Pesticide towards water baseization, ultramicronising, without efflorescence and Co ntrolled release aspect development, namely be the formulations of pesticide of matrix with water, wherein aqueous emulsion is a kind of organic solvent can, less by even no, good drug efficacy, environmentally-friendly water-basedization novel pesticide formulation, also be a kind of excellent liquid dosage form replacing emulsifiable concentrates for agricultural chemicals.Ring worm hydrazides aqueous emulsion of the present invention has efficiently, low toxicity, environmentally friendly, person poultry safety, the feature of easy degraded, compared with traditional missible oil, greatly reduce production cost, save a large amount of fossil resources, and the present invention adopts the solvent of low toxicity, greatly reduce organic solvent to the pollution of human body and environment and residual, produce in avoiding producing pollute, explosive and poisoning problem, make that pesticide processing is low to be poisoned, ensure the mankind and mammiferous safety and health.
Summary of the invention
The present invention is directed to exist in prior art environmental pollution, endanger the shortcomings such as healthy and manufacturing cost is high, a kind of efficient, low toxicity, environmentally friendly, person poultry safety and easily producing and ring worm hydrazides aqueous emulsion of using and preparation method thereof are provided.
Technical scheme of the present invention: for achieving the above object, the invention provides a kind of ring worm hydrazides aqueous emulsion, each component is as follows by weight percentage: ring worm hydrazides 1-25%, solvent 3-25%, emulsifier 4-15%, stabilizing agent 1-5%, dispersant 0.5-2%, antifreezing agent 1-5%, surplus is deionized water.
Wherein, described solvent is the mixing of one or more in dimethylbenzene, methyl alcohol, ethanol, n-butanol, ethyl acetate, NOP, repefral, diethyl phthalate, dibutyl phthalate, Solvesso100, Solvesso150, Solvesso200.
Described emulsifier is alkylphenol polyoxyethylene, styryl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, alkaryl phenol polyethenoxy ether phosphate, castor oil polyoxyethylene ether, alkylbenzenesulfonate, alkylphenol-polyethenoxy phosphate, polyoxyethylene sorbitan fatty acid ketone, sorbitan ester, fatty alcohol-polyoxyethylene ether, disecoctylmaleate sodium sulfonate, polyol fatty acid ester and ethylene oxide adduct thereof, castor oil, the mixing of one or more in lauryl sodium sulfate.
Described dispersant is one or both the mixing in polycarboxylic acid salt, alkyl phenol formaldehyde resin polyoxyethylene ether sulphate.
Described stabilizing agent is the mixing of one or more in peanut oil, antioxidant 264, epoxidized soybean oil, epoxidized linseed oil, epoxy fat, pentaerythrite, xylitol, pyrogallic acid.
Described antifreezing agent is the mixing of one or more in ethylene glycol, propane diols, glycerine, diethylene glycol.
Ring worm hydrazides method for producing aqueous emulsion of the present invention: be dissolved in solvent by ring worm hydrazides and obtain oil phase, all the other components and water are mixed to get aqueous phase, by oil phase and aqueous phase obtained finished product under high shear conditions..
Ring worm hydrazides aqueous emulsion of the present invention as the water base chemical preparation of one, compared with prior art, its dosage form is efficient, low toxicity, environmentally friendly, person poultry safety, not easily develop immunity to drugs.In addition, the stable performance of a kind of ring worm hydrazides aqueous emulsion preparation, easily degrades, and the technological process of production is simple, investment and cost of equipment low, can carry out production strictly in line with rules and regulations.
Accompanying drawing explanation
Fig. 1 is the process chart of preparation method of the present invention.
Embodiment
The present invention is described by following specific embodiment, but the invention is not restricted to following specific embodiment.In these embodiments, unless otherwise indicated, all percentage is all weight percentage.
Embodiment one:
According to technical scheme of the present invention, take the former medicine 10g of 95% ring worm hydrazides, methyl alcohol 5.0g, dimethylbenzene 10.0g, three mixes, and fully dissolves and obtains oil phase; Castor oil polyoxyethylene ether 3.0g, fatty alcohol-polyoxyethylene ether 2.0, alkyl phenol formaldehyde resin polyoxyethylene ether sulphate 1.0g, pyrogallic acid 2.0g, peanut oil 2.0g and ethylene glycol 4.0g, throw into together in deionized water, aqueous phase is made after fully stirring in preparation still, open after stirring and oil phase is slowly joined in aqueous phase, shear 30 minutes, obtain milky 10% ring worm hydrazides aqueous emulsion for 6000 revs/min.
Embodiment two:
According to technical scheme of the present invention, take the former medicine 15g of 95% ring worm hydrazides, ethyl acetate 3.0g, Solvesso20015.0g, three mixes, and fully dissolves and obtains oil phase; Alkylphenol polyoxyethylene 2.0g, polyol fatty acid ester and ethylene oxide adduct 1.5g thereof, disecoctylmaleate sodium sulfonate 2.0g, antioxidant 264 2g, peanut oil 4.0g and glycerine 4.0g, throw into together in deionized water, aqueous phase is made after fully stirring in preparation still, open after stirring and oil phase is slowly joined in aqueous phase, shear 15 minutes, obtain milky 15% ring worm hydrazides aqueous emulsion for 6000 revs/min.
Embodiment three:
According to technical scheme of the present invention, take the former medicine 25g of 95% ring worm hydrazides, ethanol 3.0g, Solvesso15025.0g, three mixes, and fully dissolves and obtains oil phase; Castor oil polyoxyethylene ether 4.0g, polyoxyethylene sorbitan fatty acid ketone 2.0g, fatty alcohol-polyoxyethylene ether 1.0g, alkyl phenol formaldehyde resin polyoxyethylene ether sulphate 1.0g, epoxidized soybean oil 5.0g and glycerine 4.0g, aqueous phase is made after fully stirring in preparation still, open after stirring and oil phase is slowly joined in aqueous phase, shear 20 minutes, obtain milky 25% ring worm hydrazides aqueous emulsion for 6000 revs/min.
Ring worm hydrazides aqueous emulsion properties of product of the present invention are stablized, and are easy to produce storage, environmentally friendly, use safety.Prove through test, all have good preventive effect to the vegetable aphid such as cucumber, wild cabbage and the fruit aphid such as apple, oranges and tangerines, after dispenser, the average preventive effect of 7 days is more than 98%; Safety is good, to crops without poisoning, is a kind of nuisanceless agricultural insecticide be worthy of popularization.
Claims (1)
1. a ring worm hydrazides aqueous emulsion, is characterized in that: each Ni lead-free solder alloy is as follows:
Take the former medicine 10g of 95% ring worm hydrazides, methyl alcohol 5.0g, dimethylbenzene 10.0g, three mixes, and fully dissolves and obtains oil phase; Castor oil polyoxyethylene ether 3.0g, fatty alcohol-polyoxyethylene ether 2.0, alkyl phenol formaldehyde resin polyoxyethylene ether sulphate 1.0g, pyrogallic acid 2.0g, peanut oil 2.0g and ethylene glycol 4.0g, throw into together in deionized water, aqueous phase is made after fully stirring in preparation still, open after stirring and oil phase is slowly joined in aqueous phase, shear 30 minutes, obtain milky 10% ring worm hydrazides aqueous emulsion for 6000 revs/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310094556.7A CN103210909B (en) | 2013-03-24 | 2013-03-24 | Ring worm hydrazides aqueous emulsion and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310094556.7A CN103210909B (en) | 2013-03-24 | 2013-03-24 | Ring worm hydrazides aqueous emulsion and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103210909A CN103210909A (en) | 2013-07-24 |
| CN103210909B true CN103210909B (en) | 2016-04-27 |
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| CN201310094556.7A Expired - Fee Related CN103210909B (en) | 2013-03-24 | 2013-03-24 | Ring worm hydrazides aqueous emulsion and preparation method thereof |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104322523B (en) * | 2014-10-24 | 2016-01-13 | 青岛瀚生生物科技股份有限公司 | Ring worm hydrazides and bistrifluron complex insecticidal composition |
| CN105145549A (en) * | 2015-08-12 | 2015-12-16 | 广东中迅农科股份有限公司 | Water emulsion containing styrene-acrylic emulsion and preparation method of water emulsion |
| CN110663687B (en) * | 2019-10-23 | 2021-06-29 | 河北天发生物科技有限公司 | Emulsifier and application of auxiliary agent containing emulsifier in pesticide preparation processing |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1063488A (en) * | 1991-01-25 | 1992-08-12 | 日本化药株式会社 | It is the insect-killing composition of active ingredient that hydrazine derivative reaches with this derivative |
| CN1399876A (en) * | 2001-07-31 | 2003-03-05 | 马韵升 | Tebufenozide pesticide composition |
| CN102428922A (en) * | 2011-12-10 | 2012-05-02 | 海利尔药业集团股份有限公司 | Diacylhydrazine pesticide compounded pesticidal composition |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1131750B (en) * | 1980-06-06 | 1986-06-25 | Montedison Spa | STABLE FORMULATIONS OF N- (3,4-DICHLOROFENYL) -N'METOXY-N'-METHYLENE (LINORUN) AND 2,6-DINITOR-N, N-DIPROPYL-4-TRIFLUOR METHYLANILINE (TRIFLURALIN) IN EMULSION |
-
2013
- 2013-03-24 CN CN201310094556.7A patent/CN103210909B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1063488A (en) * | 1991-01-25 | 1992-08-12 | 日本化药株式会社 | It is the insect-killing composition of active ingredient that hydrazine derivative reaches with this derivative |
| CN1399876A (en) * | 2001-07-31 | 2003-03-05 | 马韵升 | Tebufenozide pesticide composition |
| CN102428922A (en) * | 2011-12-10 | 2012-05-02 | 海利尔药业集团股份有限公司 | Diacylhydrazine pesticide compounded pesticidal composition |
Non-Patent Citations (1)
| Title |
|---|
| 新型昆虫生长调节剂———环虫酰肼;聂开晟等;《农药》;20011231;第40卷(第2期);42-43 * |
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| CN103210909A (en) | 2013-07-24 |
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Inventor after: Chen Yanxia Inventor before: Zhou Bin Inventor before: Yan Gongcheng Inventor before: Peng Shuming |
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Effective date of registration: 20171227 Address after: 300000 Tianjin city Wuqing District Zhu Zhuang Jie Guang Xian Road West Fuxing garden 6-1-307 Patentee after: Chen Yanxia Address before: 516000 Guangdong province Huizhou Zhongkai hi tech Development Zone No. 24 District Patentee before: Guangdong Zhongxun Agricultural Technology Co., Ltd. |
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