CN102173743A - Attapulgite argil powder with air purifying function - Google Patents

Attapulgite argil powder with air purifying function Download PDF

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Publication number
CN102173743A
CN102173743A CN 201110044975 CN201110044975A CN102173743A CN 102173743 A CN102173743 A CN 102173743A CN 201110044975 CN201110044975 CN 201110044975 CN 201110044975 A CN201110044975 A CN 201110044975A CN 102173743 A CN102173743 A CN 102173743A
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China
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attapulgite
clay
powder
batching
acidifying
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CN 201110044975
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Chinese (zh)
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CN102173743B (en
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许庆华
柏正基
许盛英
林光霞
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Jiangsu Shiao Nonmetallic Application Technology Co., Ltd.
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许庆华
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Abstract

The invention discloses an attapulgite argil powder with an air purifying function. The technical scheme is as follows: the attapulgite argil powder with an air purifying function is prepared from high-viscosity attapulgite clay, an attapulgite constant-humidity conditioner, a natural mineral adsorbing/filtering agent, Cacumen Biotae, aluminum silicate fiber and polyacrylamide. The attapulgite argil powder is prepared by the following steps: pulverizing the materials, soaking and aging to obtain a wet mixture, extruding the wet mixture into a strip, airing the strip, pulverizing to obtain powder, and packaging to obtain the finished product. The attapulgite argil powder has favorable cohesive property, plasticity, thixotropy, fire resistance and thermal stability; the pottery prepared from the attapulgite argil powder with an air purifying function contains a great deal of micropores and activated carbon, thus, has the characteristics of low shrinkage, no cracking or deformation and favorable adsorbability, and can effectively adsorb formaldehyde, ammonia, benzene and other harmful substances in the air, thereby protecting the environment and improving good health of people. The invention is suitable for producing pottery artware with an air purifying function.

Description

Attapulgite potter's clay powder with air purification function
Technical field
The present invention relates to potter's clay, be specifically related to a kind of Attapulgite potter's clay powder with air purification function.
Background technology
Potter's clay raw material mineralogical composition complexity mainly is made up of kaolinite, hydromuscovite, montmorillonite, quartz and feldspar, and granular size is inconsistent, often contains sand grains, flour sand and yellow clay etc.
The potter's clay color has tones such as tawny, canescence, red-violet colour, and potter's clay has water-absorbent, plasticity-is arranged after adding water.
The pottery quality of using potter's clay to fire is more loose, and many holes are arranged, thereby stronger water-absorbent is arranged, but the pottery base substrate that is to use common potter's clay to make, dry post-shrinkage ratio is bigger, is easy to generate crackle, and the pottery finished product absorption property of firing is relatively poor.
Summary of the invention
The objective of the invention is to overcome weak point in the prior art, a kind of Attapulgite potter's clay powder with air purification function is provided.
Attapulgite potter's clay powder with air purification function is made up of the sticking attapulgite clay of height, attapulite constant humidity amendment, natural-minerals adsorptive filter medium, Leafy twigs of Oriental Arborvitae, aluminium silicate fiber peacekeeping polyacrylamide.
Production method with Attapulgite potter's clay powder of air purification function is: pulverize after will having the batch mixes of Attapulgite potter's clay powder of air purification function earlier, mixture water after the pulverizing soaks the old moistening shape mixture that is treated to, moistening shape mixture is squeezed into bar, pulverize thing after the bar airing is packaged as the finished product of the Attapulgite potter's clay powder with air purification function.
The sticking attapulgite clay of described height is the attapulgite clay that adopts the complete processing production that improves viscosity of attapulgite clay, attapulgite clay be a kind of layer of chain-like structure contain Shuifu County's zeopan clay mineral, color is white in color, canescence, Steel Gray, greyish-green or weak satin luster, attapulgite clay soil property exquisiteness, oily soapy is arranged, and light weight, property are crisp, and fracture is conchoidal or irregular shape, water-absorbent is strong, tool viscosity and plasticity-when wet, its viscosity can reach more than the 3000mPas, helps the bonding between the raw material;
Attapulgite clay has unique dispersing property, suspension is met dielectric medium and do not produced flocculation sediment, and dry post shrinkage is little, does not produce be full of cracks, and has good, the high temperature resistant and anti-good properties such as saline and alkaline of thixotropy; Also contain a spot of hydromica, quartz, feldspar, kaolinite, sepiolite and opal in the attapulgite clay, these compositions are used for developing the Attapulgite expensive goods and belong to the impurity class, need to get rid of through the screening of purifying, and in the present invention, these compositions help reducing the dry shrinkage of base substrate, shorten time of drying and prevent blank deformation.
Rice hulls, quick dissolved sodium silicate and the zeolite powder of attapulite constant humidity amendment after by attapulgite clay, montmorillonite, acidifying formed.Attapulite constant humidity amendment not only rate of moisture absorption is good, and after ambient moisture descends, has been adsorbed on the moisture in its duct, will outwards discharge slowly, remains a more stable rate of moisture absorption, is a kind of constant humidity amendment of superior performance.Objectionable impuritiess such as formaldehyde, ammonia and benzene reduce the infringement healthy to people in the effective absorbed air of attapulite constant humidity amendment energy.
Wilkinite, the diatomite after the acidifying, volcanics and alumine after the zeolite of the batching of natural-minerals adsorptive filter medium after by acidifying, Concavo-convex excellent stone clay after the acidify, the acidifying are formed.The natural-minerals adsorptive filter medium particle surface is coarse, and there is a large amount of micropores inside, has light specific gravity, specific surface area is big and absorption property is good characteristics.
Leafy twigs of Oriental Arborvitae is spray and the leaf of Cupressaceae plant arbor-vitae, and summer, autumn gather, and the clip sprig is dried.The Leafy twigs of Oriental Arborvitae multi-branched, sprig is flat, and the tiny flakey of leaf alternately to life, is pasted and is lied prostrate on branch, deep green or yellow-green colour, matter is crisp, frangibility, gas delicate fragrance, bitter and puckery flavor, little suffering.It is the Cacumen Platycladi preparata that Leafy twigs of Oriental Arborvitae is generated chocolate after anoxycausis that Leafy twigs of Oriental Arborvitae is used for the present invention, has the characteristic of gac, has not only increased the porosity of terra cotta, has also improved the adsorptive power of terra cotta.
Aluminum silicate fiber is ceramic fiber again, and this material has that thermal capacitance is little, fiber long, in light weight, characteristics such as tensile strength big, the slag ball is few, thermostability is high, anti-erosion and sound absorption qualities are good.Be used for cracking and improving when the present invention helps avoiding making base substrate the intensity of terra cotta.
Polyacrylamide has good water-solubility and thickening property, the plasticity-when being used for the present invention and helping improving the potter's clay powder and make base substrate.
The present invention is achieved by following technical proposals:
1, the batching with Attapulgite potter's clay powder of air purification function is made up of following component by weight percentage: high sticking attapulgite clay 35～60%, attapulite constant humidity amendment 10～35%, natural-minerals adsorptive filter medium 5～20%, Leafy twigs of Oriental Arborvitae 2～15%, aluminum silicate fiber 1～5% and polyacrylamide 0.1～3%.
Production method with Attapulgite potter's clay powder of air purification function is: (1) will have after the batch mixes of Attapulgite potter's clay powder of air purification function and pulverize in the input pulverizer, and the compound particles fineness after the pulverizing is less than 0.5 millimeter; (2) pulverulent mixture add is soaked water soaks the old work in-process that are treated in the old pond, soak the old time to be controlled at 7～30 days; (3) work in-process are imported be squeezed into cylindrical strip thing in the vacuum-extruder, the diameter of cylindrical strip thing is controlled at 2～10 millimeters; (4) cylindrical strip thing is input to the cement threshing ground and carries out airing, the cylindrical strip thing water content after the airing is less than 15%; (5) be meal with carrying out abrasive dust in the cylindrical strip thing input grinding machine after the airing, the particle fineness of meal is packaged as the finished product of the Attapulgite potter's clay powder with air purification function less than 0.074 millimeter.
The sticking attapulgite clay of described height is the attapulgite clay that adopts the complete processing production that improves viscosity of attapulgite clay, it is characterized in that, and from the attapulgite clay of mining area exploitation, need be through 30～120 days natural weathering; Modification processing method is: calculate by weight percentage, take from the attapulgite clay 94～98% after the right weathering, evenly add 2～6% yellow soda ash, import jointly in the fermentation vat, add clear water and soak ageing, soak time is 72～120 hours; Get the attapulgite clay after the immersion, stir in the input stirrer, and the attapulgite clay after will stirring, be extruded into thin slice through extrusion machine, its gauge control is at 0.5～2 millimeter, with the attapulgite clay thin slice, carry out airing, the attapulgite clay thin slice after the airing, its water content≤15%; Batching is calculated by weight percentage: the attapulgite clay 94～98% after the airing, High hydrophilous resin 0.5～5% and Mierocrystalline cellulose 0.5～3%, above-mentioned batching is stirred, and carry out abrasive dust in the back input grinding machine that stirs, particle fineness≤0.074 millimeter.
Above-mentioned production technique is to adopt " improving the complete processing of viscosity of attapulgite clay " in application on June 20th, 2005 by the inventor, and the Chinese patent Granted publication number is: CN 1317067C, Granted publication day: on May 23rd, 2007.
Rice hulls, quick dissolved sodium silicate and the zeolite powder of described attapulite constant humidity amendment after by attapulgite clay, montmorillonite, acidifying formed; The production method of attapulite constant humidity amendment is: the rice hulls after the acidifying and attapulgite clay and montmorillonite are mixed by batching, extrusion modification slabbing mixture, abrasive dust after airing, mix by batching with quick dissolved sodium silicate and zeolite powder again, be packaged as attapulite constant humidity amendment;
The batching of attapulite constant humidity amendment is made up of following component by weight percentage: the work in-process 55～90% of attapulite constant humidity amendment, quick dissolved sodium silicate 2～8% and zeolite powder 5～40%; The half-finished batching of attapulite constant humidity amendment is made up of following component: the rice hulls 5～15% after the acidifying, attapulgite clay 35～55%, montmorillonite 5～15% and water 35～55% by weight percentage;
Aforementioned production method is to adopt " production method of attapulite constant humidity amendment " in application on August 30th, 2007 by the inventor, and the Chinese patent Granted publication number is: CN100528337C, Granted publication day: on August 19th, 2009.
Wilkinite, the diatomite after the acidifying, volcanics and alumine after the zeolite of the batching of described natural-minerals adsorptive filter medium after by acidifying, Concavo-convex excellent stone clay after the acidify, the acidifying are formed; The preparation method of natural-minerals adsorptive filter medium is: natural-minerals adsorptive filter medium is mixed, pulverized, sieves, is packaged as to the batching process of natural-minerals adsorptive filter medium.
The batching of natural-minerals adsorptive filter medium is made up of following component by weight percentage: the wilkinite 15～25% after the zeolite 15～35% after the acidifying, Concavo-convex excellent stone clay after the acidify 15～35%, the acidifying, the diatomite 10～20% after the acidifying, volcanics 5～10% and alumine 5～10%.
Natural-minerals adsorptive filter medium adopts " natural-minerals adsorptive filter medium " in application on May 30th, 2006 by the inventor, and the Chinese patent Granted publication number is: CN100502999C, Granted publication day: on June 24th, 2009.
The Attapulgite potter's clay powder with air purification function that the present invention produces has cohesiveness, plasticity-, thixotropy, resistivity against fire and thermostability preferably; Use has in the pottery of Attapulgite potter's clay powder production of air purification function a large amount of micropores and gac is arranged; have shrinking percentage little, do not crack, indeformable and characteristics that absorption property is good; effectively objectionable impuritiess such as formaldehyde, ammonia and benzene in the absorbed air are protected environment and are promoted the healthy of people.
The production method technology of Attapulgite potter's clay powder with air purification function is simple, low production cost, and quality product reaches the relevant technologies standard.
Attapulgite potter's clay powder with air purification function is applicable to the pottery craft product with air purification function of producing.
Embodiment
The invention will be further described below in conjunction with embodiment:
1, the batching with Attapulgite potter's clay powder of air purification function is made up of following component by weight percentage: high sticking attapulgite clay 52%, attapulite constant humidity amendment 25%, natural-minerals adsorptive filter medium 16%, Leafy twigs of Oriental Arborvitae 4%, aluminum silicate fiber 2.6% and polyacrylamide 0.4%.
Production method with Attapulgite potter's clay powder of air purification function is: (1) will have after the batch mixes of Attapulgite potter's clay powder of air purification function and pulverize in the input pulverizer, and the compound particles fineness after the pulverizing is less than 0.5 millimeter; (2) pulverulent mixture add is soaked water soaks the old work in-process that are treated in the old pond, soak the old time to be controlled at 10 days; (3) work in-process are imported be squeezed into cylindrical strip thing in the vacuum-extruder, the diameter of cylindrical strip thing is controlled at 4 millimeters; (4) cylindrical strip thing is input to the cement threshing ground and carries out airing, the cylindrical strip thing water content after the airing is less than 15%; (5) be meal with carrying out abrasive dust in the cylindrical strip thing input grinding machine after the airing, the particle fineness of meal is packaged as the finished product of the Attapulgite potter's clay powder with air purification function less than 0.074 millimeter.

Claims (1)

1. Attapulgite potter's clay powder with air purification function, it is characterized in that the batching with Attapulgite potter's clay powder of air purification function is made up of following component by weight percentage: high sticking attapulgite clay 35～60%, attapulite constant humidity amendment 10～35%, natural-minerals adsorptive filter medium 5～20%, Leafy twigs of Oriental Arborvitae 2～15%, aluminum silicate fiber 1～5% and polyacrylamide 0.1～3%;
Described production method with Attapulgite potter's clay powder of air purification function is: (1) will have after the batch mixes of Attapulgite potter's clay powder of air purification function and pulverize in the input pulverizer, and the compound particles fineness after the pulverizing is less than 0.5 millimeter; (2) pulverulent mixture add is soaked water soaks the old work in-process that are treated in the old pond, soak the old time to be controlled at 7～30 days; (3) work in-process are imported be squeezed into cylindrical strip thing in the vacuum-extruder, the diameter of cylindrical strip thing is controlled at 2～10 millimeters; (4) cylindrical strip thing is input to the cement threshing ground and carries out airing, the cylindrical strip thing water content after the airing is less than 15%; (5) be meal with carrying out abrasive dust in the cylindrical strip thing input grinding machine after the airing, the particle fineness of meal is packaged as the finished product of the Attapulgite potter's clay powder with air purification function less than 0.074 millimeter;
The sticking attapulgite clay of described height is the attapulgite clay that adopts the complete processing production that improves viscosity of attapulgite clay, it is characterized in that, and from the attapulgite clay of mining area exploitation, need be through 30～120 days natural weathering; Modification processing method is: calculate by weight percentage, take from the attapulgite clay 94～98% after the right weathering, evenly add 2～6% yellow soda ash, import jointly in the fermentation vat, add clear water and soak ageing, soak time is 72～120 hours; Get the attapulgite clay after the immersion, stir in the input stirrer, and the attapulgite clay after will stirring, be extruded into thin slice through extrusion machine, its gauge control is at 0.5～2 millimeter, with the attapulgite clay thin slice, carry out airing, the attapulgite clay thin slice after the airing, its water content≤15%; Batching is calculated by weight percentage: the attapulgite clay 94～98% after the airing, High hydrophilous resin 0.5～5% and Mierocrystalline cellulose 0.5～3%, above-mentioned batching is stirred, and carry out abrasive dust in the back input grinding machine that stirs, particle fineness≤0.074 millimeter;
Rice hulls, quick dissolved sodium silicate and the zeolite powder of described attapulite constant humidity amendment after by attapulgite clay, montmorillonite, acidifying formed; The production method of attapulite constant humidity amendment is: the rice hulls after the acidifying and attapulgite clay and montmorillonite are mixed by batching, extrusion modification slabbing mixture, abrasive dust after airing, mix by batching with quick dissolved sodium silicate and zeolite powder again, be packaged as attapulite constant humidity amendment; The batching of attapulite constant humidity amendment is made up of following component by weight percentage: the work in-process 55～90% of attapulite constant humidity amendment, quick dissolved sodium silicate 2～8% and zeolite powder 5～40%; The half-finished batching of attapulite constant humidity amendment is made up of following component: the rice hulls 5～15% after the acidifying, attapulgite clay 35～55%, montmorillonite 5～15% and water 35～55% by weight percentage;
Wilkinite, the diatomite after the acidifying, volcanics and alumine after the zeolite of the batching of described natural-minerals adsorptive filter medium after by acidifying, Concavo-convex excellent stone clay after the acidify, the acidifying are formed; The preparation method of natural-minerals adsorptive filter medium is: natural-minerals adsorptive filter medium is mixed, pulverized, sieves, is packaged as to the batching process of natural-minerals adsorptive filter medium; The batching of natural-minerals adsorptive filter medium is made up of following component by weight percentage: the wilkinite 15～25% after the zeolite 15～35% after the acidifying, Concavo-convex excellent stone clay after the acidify 15～35%, the acidifying, the diatomite 10～20% after the acidifying, volcanics 5～10% and alumine 5～10%.
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CN105272053A (en) * 2015-11-14 2016-01-27 蒋文兰 Active carbon coating powder having air-purifying function
CN106423104A (en) * 2016-12-22 2017-02-22 安徽乐金环境科技有限公司 Formaldehyde adsorbent and preparation method thereof
CN107056130A (en) * 2017-04-11 2017-08-18 安徽省明美矿物化工有限公司 A kind of attapulgite clay powder with air purification function

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