CN103288476A - Pumice composite flame-retardant foaming agent - Google Patents
Pumice composite flame-retardant foaming agent Download PDFInfo
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- CN103288476A CN103288476A CN2013102304914A CN201310230491A CN103288476A CN 103288476 A CN103288476 A CN 103288476A CN 2013102304914 A CN2013102304914 A CN 2013102304914A CN 201310230491 A CN201310230491 A CN 201310230491A CN 103288476 A CN103288476 A CN 103288476A
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- Prior art keywords
- float stone
- compound flame
- expanded dose
- retardant expanded
- foaming agent
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 78
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 68
- 239000008262 pumice Substances 0.000 title claims abstract description 28
- 239000004088 foaming agent Substances 0.000 title abstract description 11
- 239000002131 composite material Substances 0.000 title abstract 9
- 229960000892 attapulgite Drugs 0.000 claims abstract description 44
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 44
- 239000000843 powder Substances 0.000 claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 24
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 8
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims abstract description 8
- -1 polyoxyethylene Polymers 0.000 claims abstract description 7
- 239000004575 stone Substances 0.000 claims description 77
- 150000001875 compounds Chemical class 0.000 claims description 61
- 239000004927 clay Substances 0.000 claims description 44
- 238000004519 manufacturing process Methods 0.000 claims description 27
- 238000003756 stirring Methods 0.000 claims description 22
- 238000004887 air purification Methods 0.000 claims description 17
- 239000004576 sand Substances 0.000 claims description 17
- 239000002245 particle Substances 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 238000010298 pulverizing process Methods 0.000 claims description 10
- 239000000725 suspension Substances 0.000 claims description 8
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 229920002545 silicone oil Polymers 0.000 claims description 7
- 239000004698 Polyethylene Substances 0.000 claims description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 6
- 235000011152 sodium sulphate Nutrition 0.000 claims description 6
- 240000002924 Platycladus orientalis Species 0.000 claims description 4
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000835 fiber Substances 0.000 claims description 4
- 235000012054 meals Nutrition 0.000 claims description 4
- 229920002401 polyacrylamide Polymers 0.000 claims description 4
- 230000000274 adsorptive effect Effects 0.000 claims description 3
- 239000004568 cement Substances 0.000 claims description 3
- 239000000428 dust Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000009775 high-speed stirring Methods 0.000 claims description 3
- 238000007654 immersion Methods 0.000 claims description 3
- 230000008676 import Effects 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 238000004033 diameter control Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 238000009413 insulation Methods 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- AMTWCFIAVKBGOD-UHFFFAOYSA-N dioxosilane;methoxy-dimethyl-trimethylsilyloxysilane Chemical compound O=[Si]=O.CO[Si](C)(C)O[Si](C)(C)C AMTWCFIAVKBGOD-UHFFFAOYSA-N 0.000 abstract 1
- 150000002191 fatty alcohols Chemical class 0.000 abstract 1
- 238000004321 preservation Methods 0.000 abstract 1
- 230000000979 retarding effect Effects 0.000 abstract 1
- 229940083037 simethicone Drugs 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 15
- 239000006260 foam Substances 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 206010000269 abscess Diseases 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- HIGRAKVNKLCVCA-UHFFFAOYSA-N alumine Chemical compound C1=CC=[Al]C=C1 HIGRAKVNKLCVCA-UHFFFAOYSA-N 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- CCEKAJIANROZEO-UHFFFAOYSA-N sulfluramid Chemical group CCNS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F CCEKAJIANROZEO-UHFFFAOYSA-N 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention discloses a pumice composite flame-retardant foaming agent. The technical scheme of the pumice composite flame-retardant foaming agent has the following key points that the pumice composite flame-retardant foaming agent is composed of pumice powder, attapulgite argil powder having an air purifying function, hydrogen peroxide, aluminium hydroxide, sodium polyoxyethylene fatty alcohol ether sulfate, superfine polyvinyl alcohol powder, simethicone and water; firstly, the paste raw materials of the pumice composite flame-retardant foaming agent are stirred into a paste at first and then the raw materials of the pumice composite flame-retardant foaming agent are stirred into the finished product of the pumice composite flame-retardant foaming agent. A product produced by using the pumice composite flame-retardant foaming agent has the effects of flame retarding, heat preservation, thermal insulation and sound insulation, and also has the air purifying function; and the pumice composite flame-retardant foaming agent is suitable for producing flame-retarding and fire-extinguishing products, light plates, light walls, and sound-attenuating and noise-reducing products.
Description
Technical field
The present invention relates to whipping agent, be specifically related to compound flame-retardant expanded dose of a kind of float stone.
Background technology
Along with the reinforcement day by day of global safety environmental consciousness, people are more and more higher to the fire-retardant requirement of fire safety and goods, and the environment friendly flame retardant of Halogen, low cigarette, low toxicity has become the target that people pursue.
Fire retardant mainly contains organic and inorganic at present, halogen and non-halogen.Organic is to be some fire retardants of representative with bromine system, phosphorus nitrogen system, nitrogen system and red phosphorus and compound, and inorganic mainly is flame-retardant systems such as antimonous oxide, magnesium hydroxide, aluminium hydroxide, silicon system.
Whipping agent can be divided into chemical foaming agent, pneumatogen and tensio-active agent three major types, and the many whipping agents of purposes have cement blowing agent, concrete foamer, plastics blowing agent, polyurethane foams, rubber pange agent, glass whipping agent etc.
Though fire retardant and whipping agent kind are many, use also extensivelyr, exist performance comprehensive inadequately, can not satisfy the drawback of actual production and environmental protection needs, the function that existing fire retardant and whipping agent do not purify air.
Summary of the invention
The objective of the invention is to overcome weak point in the prior art, compound flame-retardant expanded dose of a kind of float stone is provided.
Float stone is made up of pumice sand, the Attapulgite potter's clay powder with air purification function, hydrogen peroxide, aluminium hydroxide, polyoxyethylenated alcohol sodium sulfate, micronized polyethylene alcohol powder, dimethyl silicone oil and water for compound flame-retardant expanded dose.
The production method that float stone is compound flame-retardant expanded dose: be paste with stirring in the compound flame-retardant expanded dose of paste batching of the float stone input low-speed mixer earlier, be the compound flame-retardant expanded dose finished product of float stone with stirring in the compound flame-retardant expanded dose of batching input homogenizer of float stone again.
Float stone claims pumice or foam again, is a kind of acid volcano of glassiness extrusive rock of porous light, and the float stone surface irregularity because the hole multimass is light, can be bubbled through the water column and gains the name.Its feature is that quality is light, intensity is high, acid and alkali-resistance, corrosion-resistant, and pollution-free, "dead" etc., is the product of desirable natural, green and environmental protection.
Attapulgite potter's clay powder with air purification function is made up of the sticking attapulgite clay of height, attapulite constant humidity amendment, natural-minerals adsorptive filter medium, Leafy twigs of Oriental Arborvitae, aluminium silicate fiber peacekeeping polyacrylamide; Have cohesiveness, plasticity-, thixotropy, resistivity against fire and thermostability preferably; Effectively objectionable impuritiess such as formaldehyde, ammonia and benzene in the absorbed air are protected environment and are promoted the healthy of people.
High sticking attapulgite clay is the attapulgite clay that adopts the complete processing production that improves viscosity of attapulgite clay, attapulgite clay soil property exquisiteness, oily soapy is arranged, light weight, property are crisp, fracture is conchoidal or irregular shape, and water-absorbent is strong, tool viscosity and plasticity-when wet, its viscosity can reach more than the 3000mPas, is conducive to the bonding between the raw material.
High sticking attapulgite clay powder refers to get 28.0g attapulgite clay powder sample, add in the suspension cup of homogenizer, add 372g water again, the suspension cup is placed on the homogenizer, under 11000 rev/mins rotating speed, stirred 20 minutes, to pour in the beaker of 250ml the viscosity of using NDJ-1 type rotational viscosimeter to test its suspension, tested viscosity value 〉=2200 again through the high-speed stirring sample suspension into
MPasThe attapulgite clay powder.
Hydrogen peroxide is commonly called as hydrogen peroxide, and outward appearance is colourless transparent liquid, is a kind of strong oxidizer, and the present invention selects massfraction 〉=35% of industrial hydrogen peroxide for use.Can generate a large amount of bubbles with pumice sand with after having the batch mixes such as Attapulgite potter's clay powder of air purification function.
Aluminium hydroxide can not only be fire-retardant as fire retardant, and can prevent from being fuming, do not produce dropping, do not produce toxic gas.
Polyoxyethylenated alcohol sodium sulfate is soluble in water, has good decontamination, emulsification, foam performance and anti-performance of hard water, is a kind of anion surfactant.
Micronized polyethylene alcohol powder is a kind of white, powdery, stable, nontoxic high molecular weight water soluble polymer, can be dissolved in fast in the normal-temperature water, forms stable colloid, and water is the good solvent of polyvinyl alcohol.Polyvinyl alcohol has the good film of making, and the film of formation has excellent adhesion, solvent resistance, rub resistance, tensile strength and oxygen barrier performance can improve the viscosity of foam, have certain steady bubble effect, and can improve the product bulk strength that adopts the compound flame-retardant expanded dose of production of float stone.
The dimethyl silicone oil surface tension is little, water insoluble, chemical stability is good, nontoxic, be a kind of defoamer and remover, be used for eliminating the invalid bubble that foaming process generates, improve the make rate of abscess, also help cast quick demoulding and prevent the mould that collapses during foam materials, be used for fire-extinguishing location and carry out flame-retarding fire-extinguishing, can not add dimethyl silicone oil.
The present invention is achieved by following technical proposals:
1, the compound flame-retardant expanded dose of batching of float stone is made up of following component by weight percentage: the compound flame-retardant expanded dose of paste 5～75% of float stone, hydrogen peroxide 1～35%, dimethyl silicone oil 0～5% and water 1～85%.
The production method that described float stone is compound flame-retardant expanded dose: will stir in the compound flame-retardant expanded dose of batching input homogenizer of float stone, the speed control of stirrer is at 1400～1800 rev/mins, churning time control was at 1～30 minute, stir the back for the compound flame-retardant expanded dose finished product of float stone, contain a large amount of stable intensive bubbles in compound flame-retardant expanded dose of the float stone.
The compound flame-retardant expanded dose of paste batching of described float stone is made up of following component by weight percentage: pumice sand 5～55%, the Attapulgite potter's clay powder 5～45% with air purification function, aluminium hydroxide 1～35%, polyoxyethylenated alcohol sodium sulfate 0.01～15%, micronized polyethylene alcohol powder 0.01～5% and water 5～55%.
The production method of the compound flame-retardant expanded dose of paste of described float stone: will stir in the compound flame-retardant expanded dose of paste batching of the float stone input low-speed mixer, the speed control of stirrer is at 600～800 rev/mins, churning time control was at 1～20 minute, stir the back for the compound flame-retardant expanded dose of paste of float stone, produced the part bubble in the compound flame-retardant expanded dose of paste of float stone.
Described pumice sand production method is: 1. float stone is imported in the pulverizer and pulverized, particle fineness≤2 millimeter; 2. the float stone after will pulverizing is transported to and carries out roasting in the rotary type stoving oven, and roasting time is 1～3 hour, and maturing temperature is controlled at 300～450 ℃, float stone water content≤5% after the roasting; 3. will the float stone after the roasting be processed as pumice sand in the input pulverizing mill, the particle fineness of pumice sand≤0.074 millimeter.
Described batching with Attapulgite potter's clay powder of air purification function is made up of following component by weight percentage: high sticking attapulgite clay 35～60%, attapulite constant humidity amendment 10～35%, natural-minerals adsorptive filter medium 5～20%, Leafy twigs of Oriental Arborvitae 2～15%, aluminum silicate fiber 1～5% and polyacrylamide 0.1～3%;
Described production method with Attapulgite potter's clay powder of air purification function is, and: ⑴ will have after the batch mixes of Attapulgite potter's clay powder of air purification function and pulverize in the input pulverizer, and the compound particles fineness after the pulverizing is less than 0.5 millimeter; ⑵ soak the old work in-process that are treated to water in the old pond of pulverulent mixture adding immersion, soaks old time control at 7～30 days; ⑶ import work in-process and be squeezed into cylindrical strip thing in the vacuum-extruder, and the diameter control of cylindrical strip thing is at 2～10 millimeters; ⑷ be input to the cement threshing ground with cylindrical strip thing and carry out airing, and the cylindrical strip thing water content after the airing is less than 15%; ⑸ carrying out abrasive dust in the cylindrical strip thing input grinding machine after with airing is meal, and the particle fineness of meal is less than 0.074 millimeter.
Attapulgite potter's clay powder with air purification function is to adopt " the Attapulgite potter's clay powder with air purification function " in application on February 25th, 2011 by the inventor, the Chinese patent Granted publication number is: CN 102173743 B, Granted publication day: on July 25th, 2012.
The sticking attapulgite clay of described height is the attapulgite clay that adopts the complete processing production that improves viscosity of attapulgite clay, it is characterized in that, and from the attapulgite clay of mining area exploitation, need be through 30～120 days natural weathering; Modification processing method is: calculate by weight percentage, take from the attapulgite clay 94～98% after the right weathering, evenly add 2～6% yellow soda ash, import jointly in the fermentation vat, add clear water and soak ageing, soak time is 72～120 hours; Get the attapulgite clay after the immersion, stir in the input stirrer, and the attapulgite clay after will stirring, be extruded into thin slice through extrusion machine, its gauge control is at 0.5～2 millimeter, with the attapulgite clay thin slice, carry out airing, the attapulgite clay thin slice after the airing, its water content≤15%; Batching is calculated by weight percentage: the attapulgite clay 94～98% after the airing, High hydrophilous resin 0.5～5% and Mierocrystalline cellulose 0.5～3%, above-mentioned batching is stirred, and carry out abrasive dust in the back input grinding machine that stirs, particle fineness≤0.074 millimeter.
Above-mentioned production technique is to adopt " improving the complete processing of viscosity of attapulgite clay " in application on June 20th, 2005 by the inventor, and the Chinese patent Granted publication number is: CN 1317067C, Granted publication day: on May 23rd, 2007.
Described water content is weight percentage.
The present invention selects massfraction 〉=35% of industrial hydrogen peroxide for use, takes the production scene to add the batching per-cent that water is adjusted industrial hydrogen peroxide, is conducive to reduce trucking costs and production cost, improves the foaming quality of product.
Float stone is a kind of paste whipping agent for compound flame-retardant expanded dose, after the water mixing and stirring, is used for on-the-spot fire-retardant and fire extinguishing fast; Also can directly use float stone to produce flame-retarding fire-extinguishing, light weight board, lightweight body of wall and sound-deadening and noise-reducing product for compound flame-retardant expanded dose, to save production cost at the construction field (site).
Float stone compound flame-retardant expanded dose after the flame-retarding fire-extinguishing scene adds the water high-speed stirring, discharge a large amount of gas fast, form cavernous foam mud, foam mud sprays by water blast gun, be directly used in flame-retarding fire-extinguishing, the stable top layer that covers combustible matl of foam mud forms a kind of foam mud film, and the foam mud film can completely cut off contacting of combustible matl and air rapidly, stop combustible matl to burn away, reach purpose fire-retardant and fire extinguishing.
When simple use hydrogen peroxide foams, the generation bubble is very fast, but it is also fast that the part bubble breaks and disappears, cause the less stable of foam, the present invention is a kind of compound foaming agent, the compound flame-retardant expanded dose of paste of float stone produced the part bubble in process of production, float stone is to foam again on the compound flame-retardant expanded dose of paste basis of float stone for compound flame-retardant expanded dose, and it is strong to have foaming power, the foam expansion height, unit volume product bubble amount is big, abscess is fine and smooth evenly difficult broken, product stripping speed is fast, the characteristics that surface smoothness is good and the product later strength is high.
Raw materials such as the wilkinite after the rice hulls of the Attapulgite potter's clay powder with air purification function after by the sticking attapulgite clay of height, quick dissolved sodium silicate, zeolite powder, acidifying, the zeolite after the acidifying, Concavo-convex excellent stone clay after the acidify, the acidifying, the diatomite after the acidifying, volcanics, alumine, Leafy twigs of Oriental Arborvitae, aluminium silicate fiber peacekeeping polyacrylamide are formed; Have cohesiveness, plasticity-, thixotropy, resistivity against fire and thermostability preferably, effectively objectionable impuritiess such as formaldehyde, ammonia and benzene in the absorbed air are protected environment and are promoted the healthy of people.
Adopt the Attapulgite potter's clay powder with air purification function for mainly being raw material among the present invention, produce compound flame-retardant expanded dose of float stone, given full play to the effective efficiency of Attapulgite potter's clay powder.
Use the product of the compound flame-retardant expanded dose of production of float stone, the effect of fire-retardant, insulation, heat insulation, sound insulation is not only arranged, the function that purifies air in addition; These products are used for facilities such as motorway, viaduct, urban light rail, subway, factory, warehouse, public place.
Float stone is applicable to production flame-retarding fire-extinguishing, light weight board, lightweight body of wall and sound-deadening and noise-reducing product for compound flame-retardant expanded dose.
Embodiment
The invention will be further described below in conjunction with embodiment:
1, be used for the embodiment of flame-retarding fire-extinguishing, the compound flame-retardant expanded dose of batching of float stone is made up of following component by weight percentage: the compound flame-retardant expanded dose of paste 15% of float stone, hydrogen peroxide 5%, dimethyl silicone oil 0.0% and water 80%.
The production method that described float stone is compound flame-retardant expanded dose: will stir in the compound flame-retardant expanded dose of batching input homogenizer of float stone, the speed control of stirrer is at 1600～1800 rev/mins, churning time control was at 3 minutes, and the back that stirs is the compound flame-retardant expanded dose finished product of float stone.
The compound flame-retardant expanded dose of paste batching of described float stone is made up of following component by weight percentage: pumice sand 30%, the Attapulgite potter's clay powder 10% with air purification function, aluminium hydroxide 14%, polyoxyethylenated alcohol sodium sulfate 5%, micronized polyethylene alcohol powder 0.6% and water 40.4%.
The production method of the compound flame-retardant expanded dose of paste of described float stone: will stir in the compound flame-retardant expanded dose of paste batching of the float stone input low-speed mixer, the speed control of stirrer is at 700～800 rev/mins, churning time control was at 5 minutes, and the back that stirs is the compound flame-retardant expanded dose of paste of float stone.
Described pumice sand production method is: 1. float stone is imported in the pulverizer and pulverized, particle fineness≤2 millimeter; 2. the float stone after will pulverizing is transported to and carries out roasting in the rotary type stoving oven, and roasting time is 2 hours, and maturing temperature is controlled at 300～350 ℃, float stone water content≤3% after the roasting; 3. will the float stone after the roasting be processed as pumice sand in the input pulverizing mill, the particle fineness of pumice sand≤0.044 millimeter.
2, for the production of the embodiment of light weight board, the compound flame-retardant expanded dose of batching of float stone is made up of following component by weight percentage: the compound flame-retardant expanded dose of paste 72% of float stone, hydrogen peroxide 21.95%, dimethyl silicone oil 0.05% and water 6%.
The production method that described float stone is compound flame-retardant expanded dose: will stir in the compound flame-retardant expanded dose of batching input homogenizer of float stone, the speed control of stirrer is at 1500～1600 rev/mins, churning time control was at 6 minutes, and the back that stirs is the compound flame-retardant expanded dose finished product of float stone.
The compound flame-retardant expanded dose of paste batching of described float stone is made up of following component by weight percentage: pumice sand 40%, the Attapulgite potter's clay powder 14% with air purification function, aluminium hydroxide 2%, polyoxyethylenated alcohol sodium sulfate 2%, micronized polyethylene alcohol powder 0.5% and water 41.5%.
The production method of the compound flame-retardant expanded dose of paste of described float stone: will stir in the compound flame-retardant expanded dose of paste batching of the float stone input low-speed mixer, the speed control of stirrer is at 650～750 rev/mins, churning time control was at 10 minutes, and the back that stirs is the compound flame-retardant expanded dose of paste of float stone.
Described pumice sand production method is: 1. float stone is imported in the pulverizer and pulverized, particle fineness≤2 millimeter, the float stone after 2. will pulverizing is transported to and carries out roasting in the rotary type stoving oven, and roasting time is 2 hours, maturing temperature is controlled at 300～350 ℃, float stone water content≤3% after the roasting; 3. will the float stone after the roasting be processed as pumice sand in the input pulverizing mill, the particle fineness of pumice sand≤0.074 millimeter.
Claims (1)
1. a float stone is compound flame-retardant expanded dose, it is characterized in that the compound flame-retardant expanded dose of batching of float stone is made up of following component by weight percentage: the compound flame-retardant expanded dose of paste 5～75% of float stone, hydrogen peroxide 1～35%, dimethyl silicone oil 0～5% and water 1～85%;
The production method that described float stone is compound flame-retardant expanded dose: will stir in the compound flame-retardant expanded dose of batching input homogenizer of float stone, the speed control of stirrer is at 1400～1800 rev/mins, churning time control was at 1～30 minute, and the back that stirs is the compound flame-retardant expanded dose finished product of float stone;
The compound flame-retardant expanded dose of paste batching of described float stone is made up of following component by weight percentage: float stone 15～55%, the Attapulgite potter's clay powder 5～45% with air purification function, aluminium hydroxide 1～35%, polyoxyethylenated alcohol sodium sulfate 0.01～15%, micronized polyethylene alcohol powder 0.01～5% and water 5～55%;
The production method of the compound flame-retardant expanded dose of paste of described float stone: will stir in the compound flame-retardant expanded dose of paste batching of the float stone input low-speed mixer, the speed control of stirrer is at 600～800 rev/mins, churning time control was at 1～20 minute, and the back that stirs is the compound flame-retardant expanded dose of paste of float stone;
Described pumice sand production method is: 1. float stone is imported in the pulverizer and pulverized, particle fineness≤2 millimeter; 2. the float stone after will pulverizing is transported to and carries out roasting in the rotary type stoving oven, and roasting time is 1～3 hour, and maturing temperature is controlled at 300～450 ℃, float stone water content≤5% after the roasting; 3. will the float stone after the roasting be processed as pumice sand in the input pulverizing mill, the particle fineness of pumice sand≤0.074 millimeter;
Described batching with Attapulgite potter's clay powder of air purification function is made up of following component by weight percentage: high sticking attapulgite clay 35～60%, attapulite constant humidity amendment 10～35%, natural-minerals adsorptive filter medium 5～20%, Leafy twigs of Oriental Arborvitae 2～15%, aluminum silicate fiber 1～5% and polyacrylamide 0.1～3%;
Described production method with Attapulgite potter's clay powder of air purification function is, and: ⑴ will have after the batch mixes of Attapulgite potter's clay powder of air purification function and pulverize in the input pulverizer, and the compound particles fineness after the pulverizing is less than 0.5 millimeter; ⑵ soak the old work in-process that are treated to water in the old pond of pulverulent mixture adding immersion, soaks old time control at 7～30 days; ⑶ import work in-process and be squeezed into cylindrical strip thing in the vacuum-extruder, and the diameter control of cylindrical strip thing is at 2～10 millimeters; ⑷ be input to the cement threshing ground with cylindrical strip thing and carry out airing, and the cylindrical strip thing water content after the airing is less than 15%; ⑸ carrying out abrasive dust in the cylindrical strip thing input grinding machine after with airing is meal, and the particle fineness of meal is less than 0.074 millimeter;
The sticking attapulgite clay powder of described height refers to get 28.0g attapulgite clay powder sample, add in the suspension cup of homogenizer, add 372g water again, the suspension cup is placed on the homogenizer, under 11000 rev/mins rotating speed, stirred 20 minutes, to pour in the beaker of 250ml the viscosity of using NDJ-1 type rotational viscosimeter to test its suspension, tested viscosity value 〉=2200 again through the high-speed stirring sample suspension into
MPasThe attapulgite clay powder.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104056396A (en) * | 2014-06-22 | 2014-09-24 | 许盛英 | Pumice mesh gel foam mud fire prevention and extinguishing agent |
| CN111192716A (en) * | 2020-01-06 | 2020-05-22 | 浙江中大元通特种电缆有限公司 | Flame-retardant cable for underground coal mine |
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|---|---|---|---|---|
| CN102173743A (en) * | 2011-02-25 | 2011-09-07 | 许庆华 | Attapulgite argil powder with air purifying function |
| CN102633455A (en) * | 2012-04-16 | 2012-08-15 | 南京信息工程大学 | Composite type foam concrete foaming agent and preparation method thereof |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102173743A (en) * | 2011-02-25 | 2011-09-07 | 许庆华 | Attapulgite argil powder with air purifying function |
| CN102633455A (en) * | 2012-04-16 | 2012-08-15 | 南京信息工程大学 | Composite type foam concrete foaming agent and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104056396A (en) * | 2014-06-22 | 2014-09-24 | 许盛英 | Pumice mesh gel foam mud fire prevention and extinguishing agent |
| CN104056396B (en) * | 2014-06-22 | 2016-09-07 | 许盛英 | Pumex network gel foam mud fire-prevention extinguishing agent |
| CN111192716A (en) * | 2020-01-06 | 2020-05-22 | 浙江中大元通特种电缆有限公司 | Flame-retardant cable for underground coal mine |
| CN111192716B (en) * | 2020-01-06 | 2021-09-14 | 浙江中大元通特种电缆有限公司 | Flame-retardant cable for underground coal mine |
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Application publication date: 20130911 Assignee: HUNAN MINGSHU ARCHITECTURAL TECHNOLOGY Co.,Ltd. Assignor: Gu Xiang Contract record no.: X2023980047919 Denomination of invention: Fume composite flame retardant foaming agent Granted publication date: 20150401 License type: Common License Record date: 20231124 |