CN103274724A - Calcium carbonate compound type flame-retardant foaming agent - Google Patents
Calcium carbonate compound type flame-retardant foaming agent Download PDFInfo
- Publication number
- CN103274724A CN103274724A CN2013102304492A CN201310230449A CN103274724A CN 103274724 A CN103274724 A CN 103274724A CN 2013102304492 A CN2013102304492 A CN 2013102304492A CN 201310230449 A CN201310230449 A CN 201310230449A CN 103274724 A CN103274724 A CN 103274724A
- Authority
- CN
- China
- Prior art keywords
- calcium carbonate
- compound flame
- foaming agent
- expanded dose
- retardant expanded
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention discloses a calcium carbonate compound type flame-retardant foaming agent. The technical scheme of the foaming agent is characterized in that the calcium carbonate compound type flame-retardant foaming agent comprises light calcium carbonate, attapulgite clay powder having an air purification function, hydrogen peroxide, magnesium hydrate, sodium alcohol ether sulphate, superfine polyving akohol powder, dimethicone and water. Calcium carbonate compound type flame retardant foaming agent paste ingredients are stirred into a paste, and then the ingredients of the calcium carbonate compound type flame-retardant foaming agent are stirred into a finished product of the calcium carbonate compound type flame-retardant foaming agent. After the calcium carbonate compound type flame retardant foaming agent is stirred with water at a high speed, porous foamed slurry is formed and can rapidly isolate an inflammable material from being contacted with air, and the purposes of inflaming retarding and extinguishment are achieved; a product produced with the calcium carbonate compound type flame-retardant foaming agent not only has the effects of inflaming retarding, heat preservation, thermal insulation and sound insulation, but also has the air purification function; and the calcium carbonate compound type flame-retardant foaming agent is suitable for producing inflaming retarding and fire-extinguishing products, lightweight boards, lightweight walls and noise reduction products.
Description
Technical field
The present invention relates to whipping agent, be specifically related to compound flame-retardant expanded dose of a kind of calcium carbonate.
Background technology
Along with the reinforcement day by day of global safety environmental consciousness, people are more and more higher to the fire-retardant requirement of fire safety and goods, and the environment friendly flame retardant of Halogen, low cigarette, low toxicity has become the target that people pursue.
Fire retardant mainly contains organic and inorganic at present, halogen and non-halogen.Organic is to be some fire retardants of representative with bromine system, phosphorus nitrogen system, nitrogen system and red phosphorus and compound, and inorganic mainly is flame-retardant systems such as antimonous oxide, magnesium hydroxide, magnesium hydroxide, silicon system.
Whipping agent can be divided into chemical foaming agent, pneumatogen and tensio-active agent three major types, and the many whipping agents of purposes have cement blowing agent, concrete foamer, plastics blowing agent, polyurethane foams, rubber pange agent, glass whipping agent etc.
Though fire retardant and whipping agent kind are many, use also extensivelyr, exist performance comprehensive inadequately, can not satisfy the drawback of actual production and environmental protection needs, the function that existing fire retardant and whipping agent do not purify air.
Summary of the invention
The objective of the invention is to overcome weak point in the prior art, compound flame-retardant expanded dose of a kind of calcium carbonate is provided.
Calcium carbonate is made up of light calcium carbonate, the Attapulgite potter's clay powder with air purification function, hydrogen peroxide, magnesium hydroxide, polyoxyethylenated alcohol sodium sulfate, micronized polyethylene alcohol powder, dimethyl silicone oil and water for compound flame-retardant expanded dose.
The production method that calcium carbonate is compound flame-retardant expanded dose: be paste with stirring in the compound flame-retardant expanded dose of paste batching of the calcium carbonate input low-speed mixer earlier, be the compound flame-retardant expanded dose finished product of calcium carbonate with stirring in the compound flame-retardant expanded dose of batching input homogenizer of calcium carbonate again.
Light calcium carbonate is a kind of white powder or colourless crystallization, have nontoxic, odorlessness, nonirritant, whiteness than higher, easily disperse and characteristic such as good luster, be the commodity of using always.
Attapulgite potter's clay powder with air purification function is made up of the sticking attapulgite clay of height, attapulite constant humidity amendment, natural-minerals adsorptive filter medium, Leafy twigs of Oriental Arborvitae, aluminium silicate fiber peacekeeping polyacrylamide; Have cohesiveness, plasticity-, thixotropy, resistivity against fire and thermostability preferably; Effectively objectionable impuritiess such as formaldehyde, ammonia and benzene in the absorbed air are protected environment and are promoted the healthy of people.
High sticking attapulgite clay is the attapulgite clay that adopts the complete processing production that improves viscosity of attapulgite clay, attapulgite clay soil property exquisiteness, oily soapy is arranged, light weight, property are crisp, fracture is conchoidal or irregular shape, and water-absorbent is strong, tool viscosity and plasticity-when wet, its viscosity can reach more than the 3000mPas, is conducive to the bonding between the raw material.
High sticking attapulgite clay powder refers to get 28.0g attapulgite clay powder sample, add in the suspension cup of homogenizer, add 372g water again, the suspension cup is placed on the homogenizer, under 11000 rev/mins rotating speed, stirred 20 minutes, to pour in the beaker of 250ml the viscosity of using NDJ-1 type rotational viscosimeter to test its suspension, tested viscosity value 〉=2200 again through the high-speed stirring sample suspension into
MPasThe attapulgite clay powder.
Hydrogen peroxide is commonly called as hydrogen peroxide, and outward appearance is colourless transparent liquid, is a kind of strong oxidizer, and the present invention selects massfraction 〉=35% of industrial hydrogen peroxide for use.Can generate a large amount of bubbles with light calcium carbonate with after having the batch mixes such as Attapulgite potter's clay powder of air purification function.
Magnesium hydroxide is a kind of white amorphous powder, discharge in conjunction with water during by decomposes, absorb a large amount of latent heat, reduce the surface temperature of synthetic materials in flame that it is filled, has the effect that suppresses polymer unwinds and the inflammable gas that produces is cooled off, the magnesium oxide that decompose to generate is again good refractory materials, also can help to improve the fire resistance of synthetic materials, and its water vapour of emitting also can be used as a kind of smoke suppressant simultaneously; That magnesium hydroxide has is fire-retardant, press down cigarette, fill the outstanding fire retardant of triple functions.
Polyoxyethylenated alcohol sodium sulfate is soluble in water, has good decontamination, emulsification, foam performance and anti-performance of hard water, is a kind of anion surfactant.
Micronized polyethylene alcohol powder is a kind of white, powdery, stable, nontoxic high molecular weight water soluble polymer, can be dissolved in fast in the normal-temperature water, forms stable colloid, and water is the good solvent of polyvinyl alcohol.Polyvinyl alcohol has the good film of making, the film that forms has excellent adhesion, solvent resistance, rub resistance, tensile strength and oxygen barrier performance, can improve the viscosity of foam, have certain steady bubble effect, and can improve the product bulk strength that adopts the compound flame-retardant expanded dose of production of calcium carbonate.
The dimethyl silicone oil surface tension is little, water insoluble, chemical stability is good, nontoxic, be a kind of defoamer and remover, be used for eliminating the invalid bubble that foaming process generates, improve the make rate of abscess, also help cast quick demoulding and prevent the mould that collapses during foam materials, be used for fire-extinguishing location and carry out flame-retarding fire-extinguishing, can not add dimethyl silicone oil.
The present invention is achieved by following technical proposals:
1, the compound flame-retardant expanded dose of batching of calcium carbonate is made up of following component by weight percentage: the compound flame-retardant expanded dose of paste 5～75% of calcium carbonate, hydrogen peroxide 1～35%, dimethyl silicone oil 0～5% and water 1～85%.
The production method that described calcium carbonate is compound flame-retardant expanded dose: will stir in the compound flame-retardant expanded dose of batching input homogenizer of calcium carbonate, the speed control of stirrer is at 1400～1800 rev/mins, churning time control was at 1～30 minute, stir the back for the compound flame-retardant expanded dose finished product of calcium carbonate, contain a large amount of stable intensive bubbles in compound flame-retardant expanded dose of the calcium carbonate.
The compound flame-retardant expanded dose of paste batching of described calcium carbonate is made up of following component by weight percentage: light calcium carbonate 5～55%, the Attapulgite potter's clay powder 5～45% with air purification function, magnesium hydroxide 1～35%, polyoxyethylenated alcohol sodium sulfate 0.01～15%, micronized polyethylene alcohol powder 0.01～5% and water 5～55%.
The production method of the compound flame-retardant expanded dose of paste of described calcium carbonate: will stir in the compound flame-retardant expanded dose of paste batching of the calcium carbonate input low-speed mixer, the speed control of stirrer is at 600～800 rev/mins, churning time control was at 1～20 minute, stir the back for the compound flame-retardant expanded dose of paste of calcium carbonate, produced the part bubble in the compound flame-retardant expanded dose of paste of calcium carbonate.
Described batching with Attapulgite potter's clay powder of air purification function is made up of following component by weight percentage: high sticking attapulgite clay 35～60%, attapulite constant humidity amendment 10～35%, natural-minerals adsorptive filter medium 5～20%, Leafy twigs of Oriental Arborvitae 2～15%, aluminum silicate fiber 1～5% and polyacrylamide 0.1～3%.
Described production method with Attapulgite potter's clay powder of air purification function is, and: ⑴ will have after the batch mixes of Attapulgite potter's clay powder of air purification function and pulverize in the input pulverizer, and the compound particles fineness after the pulverizing is less than 0.5 millimeter; ⑵ soak the old work in-process that are treated to water in the old pond of pulverulent mixture adding immersion, soaks old time control at 7～30 days; ⑶ import work in-process and be squeezed into cylindrical strip thing in the vacuum-extruder, and the diameter control of cylindrical strip thing is at 2～10 millimeters; ⑷ be input to the cement threshing ground with cylindrical strip thing and carry out airing, and the cylindrical strip thing water content after the airing is less than 15%; ⑸ carrying out abrasive dust in the cylindrical strip thing input grinding machine after with airing is meal, and the particle fineness of meal is less than 0.074 millimeter.
Attapulgite potter's clay powder with air purification function is to adopt " the Attapulgite potter's clay powder with air purification function " in application on February 25th, 2011 by the inventor, the Chinese patent Granted publication number is: CN 102173743 B, Granted publication day: on July 25th, 2012.
The sticking attapulgite clay of described height is the attapulgite clay that adopts the complete processing production that improves viscosity of attapulgite clay, it is characterized in that, and from the attapulgite clay of mining area exploitation, need be through 30～120 days natural weathering; Modification processing method is: calculate by weight percentage, take from the attapulgite clay 94～98% after the right weathering, evenly add 2～6% yellow soda ash, import jointly in the fermentation vat, add clear water and soak ageing, soak time is 72～120 hours; Get the attapulgite clay after the immersion, stir in the input stirrer, and the attapulgite clay after will stirring, be extruded into thin slice through extrusion machine, its gauge control is at 0.5～2 millimeter, with the attapulgite clay thin slice, carry out airing, the attapulgite clay thin slice after the airing, its water content≤15%; Batching is calculated by weight percentage: the attapulgite clay 94～98% after the airing, High hydrophilous resin 0.5～5% and Mierocrystalline cellulose 0.5～3%, above-mentioned batching is stirred, and carry out abrasive dust in the back input grinding machine that stirs, particle fineness≤0.074 millimeter.
Above-mentioned production technique is to adopt " improving the complete processing of viscosity of attapulgite clay " in application on June 20th, 2005 by the inventor, and the Chinese patent Granted publication number is: CN 1317067C, Granted publication day: on May 23rd, 2007.
Described water content is weight percentage.
The present invention selects massfraction 〉=35% of industrial hydrogen peroxide for use, takes the production scene to add the batching per-cent that water is adjusted industrial hydrogen peroxide, is conducive to reduce trucking costs and production cost, improves the foaming quality of product.
Calcium carbonate is a kind of paste whipping agent for compound flame-retardant expanded dose, after the water mixing and stirring, is used for on-the-spot fire-retardant and fire extinguishing fast; Also can directly use calcium carbonate to produce flame-retarding fire-extinguishing, light weight board, lightweight body of wall and sound-deadening and noise-reducing product for compound flame-retardant expanded dose, to save production cost at the construction field (site).
Calcium carbonate compound flame-retardant expanded dose after the flame-retarding fire-extinguishing scene adds the water high-speed stirring, discharge a large amount of gas fast, form cavernous foam mud, foam mud sprays by water blast gun, be directly used in flame-retarding fire-extinguishing, the stable top layer that covers combustible matl of foam mud forms a kind of foam mud film, and the foam mud film can completely cut off contacting of combustible matl and air rapidly, stop combustible matl to burn away, reach purpose fire-retardant and fire extinguishing.
When simple use hydrogen peroxide foams, the generation bubble is very fast, but it is also fast that the part bubble breaks and disappears, cause the less stable of foam, the present invention is a kind of compound foaming agent, the compound flame-retardant expanded dose of paste of calcium carbonate produced the part bubble in process of production, calcium carbonate is to foam again on the compound flame-retardant expanded dose of paste basis of calcium carbonate for compound flame-retardant expanded dose, and it is strong to have foaming power, the foam expansion height, unit volume product bubble amount is big, abscess is fine and smooth evenly difficult broken, product stripping speed is fast, the characteristics that surface smoothness is good and the product later strength is high.
Raw materials such as the wilkinite after the rice hulls of the Attapulgite potter's clay powder with air purification function after by the sticking attapulgite clay of height, quick dissolved sodium silicate, zeolite powder, acidifying, the zeolite after the acidifying, Concavo-convex excellent stone clay after the acidify, the acidifying, the calcium carbonate after the acidifying, volcanics, alumine, Leafy twigs of Oriental Arborvitae, aluminium silicate fiber peacekeeping polyacrylamide are formed; Have cohesiveness, plasticity-, thixotropy, resistivity against fire and thermostability preferably, effectively objectionable impuritiess such as formaldehyde, ammonia and benzene in the absorbed air are protected environment and are promoted the healthy of people.
Adopt the Attapulgite potter's clay powder with air purification function for mainly being raw material among the present invention, produce compound flame-retardant expanded dose of calcium carbonate, given full play to the effective efficiency of Attapulgite potter's clay powder.
Use the product of the compound flame-retardant expanded dose of production of calcium carbonate, the effect of fire-retardant, insulation, heat insulation, sound insulation is not only arranged, the function that purifies air in addition; These products are used for facilities such as motorway, viaduct, urban light rail, subway, factory, warehouse, public place.
Calcium carbonate is applicable to production flame-retarding fire-extinguishing, light weight board, lightweight body of wall and sound-deadening and noise-reducing product for compound flame-retardant expanded dose.
Embodiment
The invention will be further described below in conjunction with embodiment:
1, be used for the embodiment of flame-retarding fire-extinguishing, the compound flame-retardant expanded dose of batching of calcium carbonate is made up of following component by weight percentage: the compound flame-retardant expanded dose of paste 16% of calcium carbonate, hydrogen peroxide 6%, dimethyl silicone oil 0.0% and water 78%.
The production method that described calcium carbonate is compound flame-retardant expanded dose: will stir in the compound flame-retardant expanded dose of batching input homogenizer of calcium carbonate, the speed control of stirrer is at 1600～1800 rev/mins, churning time control was at 3 minutes, and the back that stirs is the compound flame-retardant expanded dose finished product of calcium carbonate.
The compound flame-retardant expanded dose of paste batching of described calcium carbonate is made up of following component by weight percentage: light calcium carbonate 26%, the Attapulgite potter's clay powder 12% with air purification function, magnesium hydroxide 16%, polyoxyethylenated alcohol sodium sulfate 5%, micronized polyethylene alcohol powder 0.8% and water 40.2%.
The production method of the compound flame-retardant expanded dose of paste of described calcium carbonate: will stir in the compound flame-retardant expanded dose of paste batching of the calcium carbonate input low-speed mixer, the speed control of stirrer is at 700～800 rev/mins, churning time control was at 5 minutes, and the back that stirs is the compound flame-retardant expanded dose of paste of calcium carbonate.
2, for the production of the embodiment of light weight board, the compound flame-retardant expanded dose of batching of calcium carbonate is made up of following component by weight percentage: the compound flame-retardant expanded dose of paste 68% of calcium carbonate, hydrogen peroxide 23.95%, dimethyl silicone oil 0.05% and water 8%.
The production method that described calcium carbonate is compound flame-retardant expanded dose: will stir in the compound flame-retardant expanded dose of batching input homogenizer of calcium carbonate, the speed control of stirrer is at 1500～1600 rev/mins, churning time control was at 6 minutes, and the back that stirs is the compound flame-retardant expanded dose finished product of calcium carbonate.
The compound flame-retardant expanded dose of paste batching of described calcium carbonate is made up of following component by weight percentage: light calcium carbonate 26%, the Attapulgite potter's clay powder 22% with air purification function, magnesium hydroxide 5%, polyoxyethylenated alcohol sodium sulfate 3%, micronized polyethylene alcohol powder 0.5% and water 43.5%.
The production method of the compound flame-retardant expanded dose of paste of described calcium carbonate: will stir in the compound flame-retardant expanded dose of paste batching of the calcium carbonate input low-speed mixer, the speed control of stirrer is at 650～750 rev/mins, churning time control was at 8 minutes, and the back that stirs is the compound flame-retardant expanded dose of paste of calcium carbonate.
Claims (1)
1. a calcium carbonate is compound flame-retardant expanded dose, it is characterized in that the compound flame-retardant expanded dose of batching of calcium carbonate is made up of following component by weight percentage: the compound flame-retardant expanded dose of paste 5～75% of calcium carbonate, hydrogen peroxide 1～35%, dimethyl silicone oil 0～5% and water 1～85%;
The production method that described calcium carbonate is compound flame-retardant expanded dose: will stir in the compound flame-retardant expanded dose of batching input homogenizer of calcium carbonate, the speed control of stirrer is at 1400～1800 rev/mins, churning time control was at 1～30 minute, and the back that stirs is the compound flame-retardant expanded dose finished product of calcium carbonate;
The compound flame-retardant expanded dose of paste batching of described calcium carbonate is made up of following component by weight percentage: light calcium carbonate 5～55%, the Attapulgite potter's clay powder 5～45% with air purification function, magnesium hydroxide 1～35%, polyoxyethylenated alcohol sodium sulfate 0.01～15%, micronized polyethylene alcohol powder 0.01～5% and water 5～55%;
The production method of the compound flame-retardant expanded dose of paste of described calcium carbonate: will stir in the compound flame-retardant expanded dose of paste batching of the calcium carbonate input low-speed mixer, the speed control of stirrer is at 600～800 rev/mins, churning time control was at 1～20 minute, and the back that stirs is the compound flame-retardant expanded dose of paste of calcium carbonate;
Described batching with Attapulgite potter's clay powder of air purification function is made up of following component by weight percentage: high sticking attapulgite clay 35～60%, attapulite constant humidity amendment 10～35%, natural-minerals adsorptive filter medium 5～20%, Leafy twigs of Oriental Arborvitae 2～15%, aluminum silicate fiber 1～5% and polyacrylamide 0.1～3%;
Described production method with Attapulgite potter's clay powder of air purification function is, and: ⑴ will have after the batch mixes of Attapulgite potter's clay powder of air purification function and pulverize in the input pulverizer, and the compound particles fineness after the pulverizing is less than 0.5 millimeter; ⑵ soak the old work in-process that are treated to water in the old pond of pulverulent mixture adding immersion, soaks old time control at 7～30 days; ⑶ import work in-process and be squeezed into cylindrical strip thing in the vacuum-extruder, and the diameter control of cylindrical strip thing is at 2～10 millimeters; ⑷ be input to the cement threshing ground with cylindrical strip thing and carry out airing, and the cylindrical strip thing water content after the airing is less than 15%; ⑸ carrying out abrasive dust in the cylindrical strip thing input grinding machine after with airing is meal, and the particle fineness of meal is less than 0.074 millimeter;
The sticking attapulgite clay powder of described height refers to get 28.0g attapulgite clay powder sample, add in the suspension cup of homogenizer, add 372g water again, the suspension cup is placed on the homogenizer, under 11000 rev/mins rotating speed, stirred 20 minutes, to pour in the beaker of 250ml the viscosity of using NDJ-1 type rotational viscosimeter to test its suspension, tested viscosity value 〉=2200 again through the high-speed stirring sample suspension into
MPasThe attapulgite clay powder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310230449.2A CN103274724B (en) | 2013-06-12 | 2013-06-12 | Calcium carbonate compound type flame-retardant foaming agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310230449.2A CN103274724B (en) | 2013-06-12 | 2013-06-12 | Calcium carbonate compound type flame-retardant foaming agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103274724A true CN103274724A (en) | 2013-09-04 |
| CN103274724B CN103274724B (en) | 2014-04-09 |
Family
ID=49057383
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310230449.2A Active CN103274724B (en) | 2013-06-12 | 2013-06-12 | Calcium carbonate compound type flame-retardant foaming agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103274724B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104056395A (en) * | 2014-06-22 | 2014-09-24 | 许盛英 | Calcium carbonate mesh gel foam mud fire prevention and extinguishing agent |
| WO2015058259A1 (en) * | 2013-10-22 | 2015-04-30 | Infernoshield Pty Ltd | Fire protection composition, use thereof, and method of producing and applying same |
| CN105218138A (en) * | 2015-09-15 | 2016-01-06 | 江苏锦宇环境工程有限公司 | A kind of method utilizing discarded bone to prepare flame-retardant expanded dose |
| CN106861107A (en) * | 2017-04-11 | 2017-06-20 | 明光市安盛非金属材料厂 | A kind of attapulgite gel fire foam and preparation method thereof |
| CN107043226A (en) * | 2017-04-28 | 2017-08-15 | 重庆大学 | One kind is with CO2Foam concrete foamer for foamed gas and preparation method thereof |
| CN109432684A (en) * | 2018-08-30 | 2019-03-08 | 浙江工业大学 | A kind of water-based extinguishing agent |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007153695A (en) * | 2005-12-07 | 2007-06-21 | Sumitomo Kinzoku Kozan Siporex Kk | Method of manufacturing zonotlite based calcium silicate hydrate porous formed body |
| JP2007217208A (en) * | 2006-02-15 | 2007-08-30 | Sumitomo Kinzoku Kozan Siporex Kk | Method of manufacturing xonotlite based calcium silicate hydrate porous formed body |
| CN102101787A (en) * | 2010-11-26 | 2011-06-22 | 中国科学院青海盐湖研究所 | Magnesium cement foam material |
| CN102643486A (en) * | 2012-04-18 | 2012-08-22 | 东莞市克雷斯橡塑复合材料有限公司 | Novel ethylene-propylene copolymer foamed material and production technique thereof |
-
2013
- 2013-06-12 CN CN201310230449.2A patent/CN103274724B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007153695A (en) * | 2005-12-07 | 2007-06-21 | Sumitomo Kinzoku Kozan Siporex Kk | Method of manufacturing zonotlite based calcium silicate hydrate porous formed body |
| JP2007217208A (en) * | 2006-02-15 | 2007-08-30 | Sumitomo Kinzoku Kozan Siporex Kk | Method of manufacturing xonotlite based calcium silicate hydrate porous formed body |
| CN102101787A (en) * | 2010-11-26 | 2011-06-22 | 中国科学院青海盐湖研究所 | Magnesium cement foam material |
| CN102643486A (en) * | 2012-04-18 | 2012-08-22 | 东莞市克雷斯橡塑复合材料有限公司 | Novel ethylene-propylene copolymer foamed material and production technique thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015058259A1 (en) * | 2013-10-22 | 2015-04-30 | Infernoshield Pty Ltd | Fire protection composition, use thereof, and method of producing and applying same |
| CN104056395A (en) * | 2014-06-22 | 2014-09-24 | 许盛英 | Calcium carbonate mesh gel foam mud fire prevention and extinguishing agent |
| CN104056395B (en) * | 2014-06-22 | 2016-12-21 | 青岛玉兰祥商务服务有限公司 | Calcium carbonate network gel foam mud fire-prevention extinguishing agent |
| CN105218138A (en) * | 2015-09-15 | 2016-01-06 | 江苏锦宇环境工程有限公司 | A kind of method utilizing discarded bone to prepare flame-retardant expanded dose |
| CN106861107A (en) * | 2017-04-11 | 2017-06-20 | 明光市安盛非金属材料厂 | A kind of attapulgite gel fire foam and preparation method thereof |
| CN107043226A (en) * | 2017-04-28 | 2017-08-15 | 重庆大学 | One kind is with CO2Foam concrete foamer for foamed gas and preparation method thereof |
| CN109432684A (en) * | 2018-08-30 | 2019-03-08 | 浙江工业大学 | A kind of water-based extinguishing agent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103274724B (en) | 2014-04-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103288480B (en) | Attapulgite composite flame-retardant foaming agent | |
| CN103274724B (en) | Calcium carbonate compound type flame-retardant foaming agent | |
| CN103274734A (en) | Ardealite composite type foaming agent | |
| CN103288484A (en) | Composite type kaolin flame-retardant foaming agent | |
| CN103274755A (en) | Coal ash composite type flame-retardant foaming agent | |
| CN103288479A (en) | Red mud composite-type inflaming retarding foaming agent | |
| CN103274745B (en) | Bentonite compound type flame-retardant foaming agent | |
| CN103274741B (en) | Mica compound type flame retardant foaming agent | |
| CN103288482A (en) | Composite type diatomite flame-retardant foaming agent | |
| CN103288474B (en) | Bauxite composite type fire-retardant foaming agent | |
| CN103253979B (en) | Serpentine composite type flame-retardant foaming agent | |
| CN103288472B (en) | Composite trass anti-flaming foaming agent | |
| CN103288486B (en) | Sepiolite composite type flame retardant foaming agent | |
| CN103274725B (en) | Gypsum compound type flame-retardant foaming agent | |
| CN103274730B (en) | Cement compound type flame-retardant foaming agent | |
| CN103274727B (en) | Pyroclastic rock compound type antiflaming foaming agent | |
| CN103253977B (en) | Boron mud composite type flame-retardant foaming agent | |
| CN103274731B (en) | Water quenching slag compound type flame-retardant foaming agent | |
| CN103274728B (en) | Compound type shale flame retardant foaming agent | |
| CN103253975B (en) | Lime composite type flame-retardant foaming agent | |
| CN103288476A (en) | Pumice composite flame-retardant foaming agent | |
| CN103265326B (en) | Talcum composite flame-retardant foaming agent | |
| CN103274729B (en) | Compound type tailing flame retardant foaming agent | |
| CN103274722A (en) | Medical stone compound type flame-retardant foaming agent | |
| CN103274723B (en) | Compound type basalt flame retardant foaming agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: XINJIANG TEKUO PIAOZHENG (NANTONG) CO., LTD. Free format text: FORMER OWNER: XU QINGHUA Effective date: 20141113 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 211700 HUAIAN, JIANGSU PROVINCE TO: 226300 NANTONG, JIANGSU PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20141113 Address after: 226300 Industrial Park, Xianfeng Town, Nantong, Jiangsu, Tongzhou District Patentee after: XINJIANG TEKUO BLEACHING AND FINISHING (NANTONG) CO., LTD. Address before: 211700 Huaian, Xuyi province Timor King international residential area, building 2, unit 202 room 18 Patentee before: Xu Qinghua |