CN102171309A - 传热流体 - Google Patents
传热流体 Download PDFInfo
- Publication number
- CN102171309A CN102171309A CN2009801389067A CN200980138906A CN102171309A CN 102171309 A CN102171309 A CN 102171309A CN 2009801389067 A CN2009801389067 A CN 2009801389067A CN 200980138906 A CN200980138906 A CN 200980138906A CN 102171309 A CN102171309 A CN 102171309A
- Authority
- CN
- China
- Prior art keywords
- weight
- c2h4f2
- tetrafluoeopropene
- composition
- methylene fluoride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000013529 heat transfer fluid Substances 0.000 title claims abstract description 10
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 claims abstract description 58
- 239000000203 mixture Substances 0.000 claims abstract description 50
- 150000001875 compounds Chemical class 0.000 claims abstract description 8
- 238000004378 air conditioning Methods 0.000 claims description 7
- 238000005057 refrigeration Methods 0.000 claims description 3
- FXRLMCRCYDHQFW-UHFFFAOYSA-N 2,3,3,3-tetrafluoropropene Chemical compound FC(=C)C(F)(F)F FXRLMCRCYDHQFW-UHFFFAOYSA-N 0.000 abstract description 4
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 abstract description 2
- PGJHURKAWUJHLJ-UHFFFAOYSA-N 1,1,2,3-tetrafluoroprop-1-ene Chemical compound FCC(F)=C(F)F PGJHURKAWUJHLJ-UHFFFAOYSA-N 0.000 abstract 1
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 7
- 239000012530 fluid Substances 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000003507 refrigerant Substances 0.000 description 5
- -1 C2H4F2 C2H4F2 Chemical compound 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 235000011089 carbon dioxide Nutrition 0.000 description 4
- KLZDCUBZWUSEGO-UHFFFAOYSA-N CC.F.F.F.F.F Chemical compound CC.F.F.F.F.F KLZDCUBZWUSEGO-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- QBTUCBKAWGUMMK-UHFFFAOYSA-N C=CC.[F] Chemical group C=CC.[F] QBTUCBKAWGUMMK-UHFFFAOYSA-N 0.000 description 2
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 2
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 239000013526 supercooled liquid Substances 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- 238000009834 vaporization Methods 0.000 description 2
- 239000006200 vaporizer Substances 0.000 description 2
- NSGXIBWMJZWTPY-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane Chemical compound FC(F)(F)CC(F)(F)F NSGXIBWMJZWTPY-UHFFFAOYSA-N 0.000 description 1
- YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical compound CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 description 1
- LSWYGACWGAICNM-UHFFFAOYSA-N 2-(prop-2-enoxymethyl)oxirane Chemical compound C=CCOCC1CO1 LSWYGACWGAICNM-UHFFFAOYSA-N 0.000 description 1
- HJEORQYOUWYAMR-UHFFFAOYSA-N 2-[(2-butylphenoxy)methyl]oxirane Chemical compound CCCCC1=CC=CC=C1OCC1OC1 HJEORQYOUWYAMR-UHFFFAOYSA-N 0.000 description 1
- HSDVRWZKEDRBAG-UHFFFAOYSA-N 2-[1-(oxiran-2-ylmethoxy)hexoxymethyl]oxirane Chemical compound C1OC1COC(CCCCC)OCC1CO1 HSDVRWZKEDRBAG-UHFFFAOYSA-N 0.000 description 1
- XRCRJFOGPCJKPF-UHFFFAOYSA-N 2-butylbenzene-1,4-diol Chemical compound CCCCC1=CC(O)=CC=C1O XRCRJFOGPCJKPF-UHFFFAOYSA-N 0.000 description 1
- FDMFUZHCIRHGRG-UHFFFAOYSA-N 3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)C=C FDMFUZHCIRHGRG-UHFFFAOYSA-N 0.000 description 1
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 description 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- BCQZXOMGPXTTIC-UHFFFAOYSA-N halothane Chemical compound FC(F)(F)C(Cl)Br BCQZXOMGPXTTIC-UHFFFAOYSA-N 0.000 description 1
- 229960003132 halothane Drugs 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- UKACHOXRXFQJFN-UHFFFAOYSA-N heptafluoropropane Chemical compound FC(F)C(F)(F)C(F)(F)F UKACHOXRXFQJFN-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 150000003008 phosphonic acid esters Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M171/00—Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
- C10M171/008—Lubricant compositions compatible with refrigerants
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B31/00—Compressor arrangements
- F25B31/002—Lubrication
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B45/00—Arrangements for charging or discharging refrigerant
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/122—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/126—Unsaturated fluorinated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/22—All components of a mixture being fluoro compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/40—Replacement mixtures
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/40—Replacement mixtures
- C09K2205/43—Type R22
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/003—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/06—Well-defined aromatic compounds
- C10M2203/065—Well-defined aromatic compounds used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical
- C10M2209/043—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/1033—Polyethers, i.e. containing di- or higher polyoxyalkylene groups used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/09—Characteristics associated with water
- C10N2020/097—Refrigerants
- C10N2020/101—Containing Hydrofluorocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/30—Refrigerators lubricants or compressors lubricants
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Lubricants (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
Abstract
本发明涉及包含四氟丙烯的组合物,更具体地涉及包含60~90重量%的2,3,3,3-四氟丙烯和10~40重量%的至少一种选自二氟乙烷和二氟甲烷的化合物的组合物,其可用作传热流体。
Description
本发明涉及包含氢氟烯烃的组合物和它们作为传热流体、发泡剂、溶剂和气溶胶的用途。
由减少大气臭氧层(ODP:臭氧损耗潜势)的物质所造成的问题在蒙特利尔(Montreal)得到处理,在那里签署了强制减少氯氟烃(CFC)的制造和使用的协议。该协议已为修改的主体,其强制放弃CFC并将所述规定延伸到其它产品,在所述产品中有氢氯氟烃(HCFC)。
制冷工业和空调工业已经在这些制冷剂流体的替代物方面进行了大量的投资,和该投资的产品是氢氟烃(HFC)的商业化。
用作膨胀剂(expandant)或溶剂的(氢)氯氟烃也已经被HFC所替代。
在汽车工业中,在许多国家销售的车辆的空调系统已经从氯氟烃(CFC-12)制冷剂流体转换为对臭氧层损害较少的氢氟烃(1,1,1,2-四氟乙烷:HFC-134a)。然而,考虑到京都议定书(Kyoto Protocol)设定的目标,HFC-134a(GWP=1300)被认为具有高的变暖潜势。流体对温室效应的贡献是通过标准GWP(全球变暖潜势)量化的,其通过以二氧化碳作为参考值1指出变暖潜势。
无毒、不可燃和具有非常低GWP的二氧化碳已经被提出作为空调系统的制冷剂流体来作为HFC-134a的替代物。然而,二氧化碳的使用带来许多缺点,特别是与其作为现有装置和技术中的制冷剂流体使用的非常高的压力有关。
而且,由44重量%的五氟乙烷、52重量%的三氟乙烷和4重量%的HFC-134a组成的混合物R-404A被广泛用作超级商店(超级市场)和冷冻运输中的制冷剂流体。然而,这种混合物具有3900的GWP。由52重量%的HFC-134a、25重量%的五氟乙烷和23重量%的二氟甲烷组成的混合物R-407C被用作空调和热泵中的传热流体。然而,这种混合物具有1800的GWP。
文献JP 4110388描述了其中m和n代表1~5(包括端点)的整数且m+n=6的式C3HmFn的氢氟丙烯,特别是四氟丙烯和三氟丙烯作为传热流体的用途。
文献WO 2004/037913公开了包含至少一种具有三个或四个碳原子的含氟链烯、更具体地五氟丙烯和四氟丙烯的组合物(优选具有不超过150的GWP)作为传热流体的用途。
文献WO 2005/105947教导了向四氟丙烯、优选1,3,3,3-四氟丙烯添加助发泡剂如二氟甲烷、五氟乙烷、四氟乙烷、二氟乙烷、七氟丙烷、六氟丙烷、五氟丙烷、五氟丁烷、水或二氧化碳。
文献WO 2006/094303公开了含有7.4重量%的2,3,3,3-四氟丙烯(1234yf)和92.6重量%的二氟甲烷(HFC-32)的共沸组合物。该文献同样地公开了含有91重量%的2,3,3,3-四氟丙烯和9重量%的二氟乙烷(HFC-152a)的共沸组合物。
现在申请人开发了含有氢氟丙烯的组合物,其可用作传热流体,不具有上述缺点并且同时具有零ODP与比现有传热流体如R-404A或R-407C或R22(氯二氟甲烷)低的GWP。
根据本发明的组合物特征在于它们包含60重量%~90重量%的2,3,3,3-四氟丙烯和10重量%~40重量%的至少一种选自二氟乙烷和二氟甲烷的化合物。
根据本发明的第一实施方式,所述组合物包含60重量%~79重量%的2,3,3,3-四氟丙烯和21重量%~40重量%的选自二氟乙烷和二氟甲烷的化合物。
根据该第一实施方式的组合物优选包含60重量%~70重量%的2,3,3,3-四氟丙烯和30重量%~40重量%的选自二氟乙烷和二氟甲烷的化合物。
有利地,根据该第一实施方式的组合物包含60重量%~65重量%的2,3,3,3-四氟丙烯和35重量%~40重量%的选自二氟乙烷和二氟甲烷的化合物。
根据该第一实施方式的特别优选的组合物包含2,3,3,3-四氟丙烯和二氟甲烷。
有利地,这些组合物基本上含有2,3,3,3-四氟丙烯和二氟甲烷。
根据本发明的第二实施方式,所述组合物包含60重量%~90重量%的2,3,3,3-四氟丙烯和10重量%~40重量%的由二氯甲烷和二氟乙烷组成的混合物。
根据该第二实施方式的优选组合物包含60重量%~80重量%的2,3,3,3-四氟丙烯和20重量%~40重量%的由二氟甲烷和二氟乙烷组成的混合物。
根据该第二实施方式的有利地优选的组合物包含60重量%~75重量%的2,3,3,3-四氟丙烯和25重量%~40重量%的由二氟甲烷和二氟乙烷组成的混合物。
特别优选的组合物包含60重量%~80重量%的2,3,3,3-四氟丙烯及5重量%~35重量%的二氟甲烷和5重量%~35重量%的二氟乙烷。
关注的组合物是基本上包含或含有60重量%~80重量%的2,3,3,3-四氟丙烯及10重量%~30重量%的二氟甲烷和10重量%~30重量%的二氟乙烷的那些。
根据本发明的组合物可包含用于2,3,3,3-四氟丙烯的稳定剂。所述稳定剂占相对于总组合物的不超过5重量%。
稳定剂更具体地包括硝基甲烷,抗坏血酸,对苯二甲酸,唑如甲苯三唑或苯并三唑,酚类化合物如生育酚、对苯二酚、叔丁基对苯二酚、2,6-二叔丁基-4-甲基苯酚,环氧化物(烷基环氧化物、任选地氟化或全氟化,或者链烯基或芳族环氧化物)如正丁基缩水甘油醚、己二醇二缩水甘油醚、烯丙基缩水甘油醚和丁基苯基缩水甘油醚,亚磷酸酯,磷酸酯,膦酸酯,硫醇和内酯。
根据本发明的组合物可包含润滑剂如矿物油、烷基苯、聚亚烷基二醇和聚乙烯基醚。
根据本发明的组合物适于替代在现有系统中的制冷中的R-404A和/或空调和热泵中的R-407C。它们也可适于替代采用级联压缩方式的制冷系统中的R-404A,其中用根据本发明的组合物运行至少一个阶段。特别关注的用于现有系统中的R-404A的替代物的组合物的实例包括基本上包含或含有60重量%的2,3,3,3-四氟丙烯和40重量%的二氟甲烷;70重量%的2,3,3,3-四氟丙烯和30重量%的二氟甲烷;以及60重量%的2,3,3,3-四氟丙烯、30重量%的二氟甲烷和10重量%的二氟乙烷的那些。
特别关注的用于以级联压缩方式运行的系统中的R-404A的替代物的组合物的实例包括基本上包含或含有60重量%的2,3,3,3-四氟丙烯和40重量%的二氟乙烷;70重量%的2,3,3,3-四氟丙烯和30重量%的二氟乙烷;以及75重量%的2,3,3,3-四氟丙烯、20重量%的二氟甲烷和5重量%的二氟乙烷的那些。
根据本发明的组合物也可用作例如热泵中的R-407C的替代物。
特别关注的用于现有系统中的R-407C的替代物的组合物的实例包括基本上包含或含有60重量%的2,3,3,3-四氟丙烯和40重量%的二氟甲烷;70重量%的2,3,3,3-四氟丙烯和30重量%的二氟甲烷;60重量%的2,3,3,3-四氟丙烯、30重量%的二氟甲烷和10重量%的二氟乙烷;以及70重量%的2,3,3,3-四氟丙烯、25重量%的二氟甲烷和5重量%的二氟乙烷的那些。
而且,根据本发明的组合物可用作发泡剂、气溶胶和溶剂。
实验部分
在制冷运行条件下的根据本发明的组合物的性能数据在表1中给出。各组合物的组分(1234yf、32和152a)的值以重量百分比给出。
对于R-404A,在下列运行条件下,标称运行压力为18巴,体积容量为1500kJ/m3且COP为1.8:
蒸发温度:-20℃
冷凝温度:40℃
压缩机入口温度:-5℃
过冷液温度:33℃
压缩机的等熵产率(效率,yield):70%
BP:蒸发器的压力
HP:冷凝器的压力
比:压缩比
T压缩机出口:压缩机出口的温度
COP:性能系数-为了制冷的目的定义为系统提供的有效冷却功率,作为系统提供或消耗的功率的比例。
CAP:体积容量(kJ/m3)
%CAP或COP是混合物的CAP或COP值相对于R-404A的同样值的比。
表1
在热泵和空调的运行条件下根据本发明的组合物的性能数据在表2中给出。各组合物的组分(1234yf、32和152a)的值以重量百分比给出。
对于R-407C,在下列运行条件下,标称运行压力为34巴,体积容量为1461kJ/m3且COP为2.1。
蒸发温度:-5℃
冷凝温度:70℃
压缩机入口温度:5℃
过冷液温度:65℃
压缩机的等熵产率(效率):70%
BP:蒸发器的压力
HP:冷凝器的压力
比:压缩比
T压缩机出口:压缩机出口的温度
COP:性能系数-为了热泵的目的定义为系统提供的有效加热功率,作为系统提供或消耗的功率的比例。
CAP:体积容量(kJ/m3)
%CAP或COP是混合物的CAP或COP值相对于R-407C的同一值的比。
表2
Claims (8)
1.组合物,其包含60重量%~90重量%的2,3,3,3-四氟丙烯和10重量%~40重量%的至少一种选自二氟乙烷和二氟甲烷的化合物。
2.权利要求1的组合物,特征在于其包含60重量%~79重量%的2,3,3,3-四氟丙烯和21重量%~40重量%的选自二氟乙烷和二氟甲烷的化合物。
3.权利要求1和2任一项的组合物,特征在于其包含60重量%~70重量%的2,3,3,3-四氟丙烯和30重量%~40重量%的选自二氟乙烷和二氟甲烷的化合物。
4.权利要求1的组合物,特征在于其包含60重量%~80重量%的2,3,3,3-四氟丙烯和20重量%~40重量%的由二氟甲烷和二氟乙烷组成的混合物。
5.权利要求1的组合物,特征在于其包含60重量%~80重量%的2,3,3,3-四氟丙烯及5重量%~35重量%的二氟甲烷和5重量%~35重量%的二氟乙烷。
6.权利要求1或5的组合物,特征在于其包含60重量%~80重量%的2,3,3,3-四氟丙烯及10重量%~30重量%的二氟甲烷和10重量%~30重量%的二氟乙烷。
7.包括前述权利要求中任一项的组合物的传热流体。
8.权利要求1~6中任一项的组合物,特征在于其用作制冷中的R-404A和/或热泵或空调中的R-407C的替代物。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR08.56817 | 2008-10-08 | ||
FR0856817A FR2936806B1 (fr) | 2008-10-08 | 2008-10-08 | Fluide refrigerant |
FR08.56836 | 2008-10-09 | ||
FR0856836A FR2936807B3 (fr) | 2008-10-08 | 2008-10-09 | Fluide de transfert de chaleur |
PCT/FR2009/051814 WO2010040928A1 (fr) | 2008-10-08 | 2009-09-24 | Fluide de transfert de chaleur |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102171309A true CN102171309A (zh) | 2011-08-31 |
CN102171309B CN102171309B (zh) | 2014-06-25 |
Family
ID=40627376
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200980138906.7A Ceased CN102171309B (zh) | 2008-10-08 | 2009-09-24 | 传热流体 |
Country Status (10)
Country | Link |
---|---|
US (4) | US20110186772A1 (zh) |
EP (2) | EP2331651B1 (zh) |
JP (5) | JP5591246B2 (zh) |
CN (1) | CN102171309B (zh) |
ES (1) | ES2663548T3 (zh) |
FR (2) | FR2936806B1 (zh) |
PL (1) | PL2331651T3 (zh) |
PT (1) | PT2331651T (zh) |
TW (1) | TWI406934B (zh) |
WO (1) | WO2010040928A1 (zh) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102639668A (zh) * | 2010-01-27 | 2012-08-15 | 大金工业株式会社 | 含二氟甲烷(hfc32)和2,3,3,3-四氟丙烯(hfo1234yf)的制冷剂组合物 |
CN104603228A (zh) * | 2012-09-04 | 2015-05-06 | 大金工业株式会社 | 含有2,3,3,3-四氟丙烯的混合制冷剂的填充方法 |
CN113383060A (zh) * | 2019-02-14 | 2021-09-10 | 出光兴产株式会社 | 冷冻机用组合物 |
CN113840893A (zh) * | 2019-05-17 | 2021-12-24 | 科慕埃弗西有限公司 | 用于制冷剂压缩机系统的制冷剂组合物 |
Families Citing this family (51)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2936806B1 (fr) | 2008-10-08 | 2012-08-31 | Arkema France | Fluide refrigerant |
FR2937328B1 (fr) | 2008-10-16 | 2010-11-12 | Arkema France | Procede de transfert de chaleur |
US20170080773A1 (en) | 2008-11-03 | 2017-03-23 | Arkema France | Vehicle Heating and/or Air Conditioning Method |
US20100122545A1 (en) * | 2008-11-19 | 2010-05-20 | E. I. Du Pont De Nemours And Company | Tetrafluoropropene compositions and uses thereof |
FR2942237B1 (fr) * | 2009-02-13 | 2013-01-04 | Arkema France | Procede de chauffage et/ou climatisation d'un vehicule |
US9845419B2 (en) | 2009-07-29 | 2017-12-19 | Honeywell International Inc. | Low GWP heat transfer compositions containing difluoromethane and 1,3,3,3-tetrafluoropropene |
US10035938B2 (en) | 2009-09-11 | 2018-07-31 | Arkema France | Heat transfer fluid replacing R-134a |
FR2950069B1 (fr) | 2009-09-11 | 2011-11-25 | Arkema France | Utilisation de compositions ternaires |
FR2950071B1 (fr) | 2009-09-11 | 2012-02-03 | Arkema France | Compositions ternaires pour refrigeration basse capacite |
FR2950065B1 (fr) * | 2009-09-11 | 2012-02-03 | Arkema France | Fluide refrigerant binaire |
FR2950068B1 (fr) * | 2009-09-11 | 2012-05-18 | Arkema France | Procede de transfert de chaleur |
FR2950067B1 (fr) | 2009-09-11 | 2011-10-28 | Arkema France | Fluide de transfert de chaleur en remplacement du r-410a |
FR2950070B1 (fr) | 2009-09-11 | 2011-10-28 | Arkema France | Compositions ternaires pour refrigeration haute capacite |
FR2950066B1 (fr) | 2009-09-11 | 2011-10-28 | Arkema France | Refrigeration basse et moyenne temperature |
FR2954342B1 (fr) | 2009-12-18 | 2012-03-16 | Arkema France | Fluides de transfert de chaleur a inflammabilite reduite |
AR079667A1 (es) * | 2009-12-21 | 2012-02-08 | Du Pont | Composiciones que comprenden tetrafluoropropeno y difluorometano y usos de estos |
FR2959998B1 (fr) | 2010-05-11 | 2012-06-01 | Arkema France | Fluides de transfert de chaleur ternaires comprenant du difluoromethane, du pentafluoroethane et du tetrafluoropropene |
FR2962442B1 (fr) | 2010-07-09 | 2016-02-26 | Arkema France | Composition stable de 2,3,3,3-tetrafluoropropene |
FR2964975B1 (fr) | 2010-09-20 | 2012-08-24 | Arkema France | Composition a base de 2,3,3,3-tetrafluoropropene |
US20120119136A1 (en) * | 2010-11-12 | 2012-05-17 | Honeywell International Inc. | Low gwp heat transfer compositions |
FR2971512B1 (fr) | 2011-02-10 | 2013-01-18 | Arkema France | Compositions binaires de 2,3,3,3-tetrafluoropropene et d'ammoniac |
FR2974812B1 (fr) | 2011-05-04 | 2014-08-08 | Arkema France | Compositions de transfert de chaleur presentant une miscibilite amelioree avec l'huile de lubrification |
US9169427B2 (en) | 2011-07-13 | 2015-10-27 | Honeywell International Inc. | Low GWP heat transfer compositions containing difluoromethane, a fluorinated ethane and 1,3,3,3-tetrafluoropropene |
TWI585065B (zh) * | 2011-08-26 | 2017-06-01 | 杜邦股份有限公司 | 含四氟丙烯之組成物及其使用方法 |
JP2013120029A (ja) * | 2011-12-08 | 2013-06-17 | Panasonic Corp | 空気調和機 |
FR2986236B1 (fr) | 2012-01-26 | 2014-01-10 | Arkema France | Compositions de transfert de chaleur presentant une miscibilite amelioree avec l'huile de lubrification |
US9783721B2 (en) | 2012-08-20 | 2017-10-10 | Honeywell International Inc. | Low GWP heat transfer compositions |
FR2998302B1 (fr) | 2012-11-20 | 2015-01-23 | Arkema France | Composition refrigerante |
US8940180B2 (en) | 2012-11-21 | 2015-01-27 | Honeywell International Inc. | Low GWP heat transfer compositions |
FR3000096B1 (fr) | 2012-12-26 | 2015-02-20 | Arkema France | Composition comprenant du 2,3,3,3-tetrafluoropropene |
FR3000095B1 (fr) | 2012-12-26 | 2015-02-20 | Arkema France | Composition comprenant du 2,3,3,3-tetrafluoropropene et du 1,2-difluoroethylene |
FR3000093B1 (fr) | 2012-12-26 | 2015-07-17 | Arkema France | Composition azeotropique ou quasi-azeotropique de chloromethane |
US9982180B2 (en) | 2013-02-13 | 2018-05-29 | Honeywell International Inc. | Heat transfer compositions and methods |
JP2016513749A (ja) * | 2013-03-15 | 2016-05-16 | ハネウェル・インターナショナル・インコーポレーテッド | 低gwpの熱伝達組成物 |
FR3003565B1 (fr) | 2013-03-20 | 2018-06-29 | Arkema France | Composition comprenant hf et 2,3,3,3-tetrafluoropropene |
FR3008419B1 (fr) | 2013-07-11 | 2015-07-17 | Arkema France | Compositions a base de 2,3,3,3-tetrafluoropropene presentant une miscibilite amelioree |
US9631779B2 (en) * | 2013-08-15 | 2017-04-25 | Star Headlight & Lantern Co., Inc. | Optical system utilizing LED illumination for a light bar, and light bar having same |
FR3010415B1 (fr) | 2013-09-11 | 2015-08-21 | Arkema France | Fluides de transfert de chaleur comprenant du difluoromethane, du pentafluoroethane, du tetrafluoropropene et eventuellement du propane |
FR3023286B1 (fr) * | 2014-07-02 | 2018-02-16 | Arkema France | Procede de fabrication de tetrafluoropropene |
MY182105A (en) * | 2015-02-19 | 2021-01-18 | Daikin Ind Ltd | Composition containing mixture of fluorinated hydrocarbons, and method for producing same |
FR3033791B1 (fr) | 2015-03-18 | 2017-04-14 | Arkema France | Stabilisation du 1-chloro-3,3,3-trifluoropropene |
FR3057271B1 (fr) | 2016-10-10 | 2020-01-17 | Arkema France | Utilisation de compositions a base de tetrafluoropropene |
FR3057272B1 (fr) | 2016-10-10 | 2020-05-08 | Arkema France | Compositions azeotropiques a base de tetrafluoropropene |
FR3064264B1 (fr) | 2017-03-21 | 2019-04-05 | Arkema France | Composition a base de tetrafluoropropene |
FR3064275B1 (fr) | 2017-03-21 | 2019-06-07 | Arkema France | Procede de chauffage et/ou climatisation d'un vehicule |
FR3070982B1 (fr) | 2017-09-12 | 2019-08-30 | Arkema France | Composition a base d'hydrochlorofluoroolefine et d'huile minerale |
FR3077572B1 (fr) | 2018-02-05 | 2021-10-08 | Arkema France | Composition azeotropique ou quasi-azeotropique ternaire comprenant hf, 2,3,3,3-tetrafluoropropene et 1,1,1,2,2,-pentafluoropropane. |
FR3077822B1 (fr) | 2018-02-15 | 2020-07-24 | Arkema France | Compositions de transfert de chaleur en remplacement du r-134a |
WO2020072571A1 (en) * | 2018-10-04 | 2020-04-09 | The Chemours Company Fc, Llc | Azeotropic compositions of hfo-1234yf and propylene |
US11209196B2 (en) * | 2018-10-26 | 2021-12-28 | The Chemours Company Fc, Llc | HFO-1234ZE, HFO-1225ZC and HFO-1234YF compositions and processes for producing and using the compositions |
BR112021022059A2 (pt) * | 2018-10-26 | 2021-12-28 | Chemours Co Fc Llc | Composições de fluoropropeno, métodos de produção de uma mistura e de resfriamento, processos para transferência de calor, para tratamento de uma superfície e para formação de uma composição, sistema de refrigeração, aparelhos de refrigeração, uso da composição de fluoropropeno e método para substituição de um refrigerante |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1072715A (zh) * | 1991-10-11 | 1993-06-02 | 帝国化学工业公司 | 润滑剂 |
WO2006094303A2 (en) * | 2005-03-04 | 2006-09-08 | E.I. Dupont De Nemours And Company | Compositions comprising a fluoroolefin |
WO2007126414A2 (en) * | 2006-03-30 | 2007-11-08 | E. I. Du Pont De Nemours And Company | Compositions comprising a fluoroolefin |
Family Cites Families (94)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH549772A (de) | 1972-04-29 | 1974-05-31 | Bertrams Ag Hch | Kreuzgegenstromwaermeaustauscher und verfahren zu seiner herstellung. |
FR2256381A1 (en) | 1973-12-27 | 1975-07-25 | Tour Agenturer Ab | Arrangement for heating or cooling a flow medium - part of air currents diverted to a circuit containing e.g. ammonia in a heat exchanger |
JP2852362B2 (ja) | 1990-04-27 | 1999-02-03 | 日本電信電話株式会社 | ワード線駆動装置 |
JPH04110388A (ja) | 1990-08-31 | 1992-04-10 | Daikin Ind Ltd | 熱伝達用流体 |
JP3270706B2 (ja) | 1997-03-24 | 2002-04-02 | 三菱電機株式会社 | 多元冷凍装置 |
US6503417B1 (en) | 1998-04-13 | 2003-01-07 | E. I. Du Pont De Nemours And Company | Ternary compositions of ammonia, pentafluoroethane and difluoromethane |
JP2000161805A (ja) | 1998-11-27 | 2000-06-16 | Daikin Ind Ltd | 冷凍装置 |
US6176102B1 (en) | 1998-12-30 | 2001-01-23 | Praxair Technology, Inc. | Method for providing refrigeration |
US7279451B2 (en) | 2002-10-25 | 2007-10-09 | Honeywell International Inc. | Compositions containing fluorine substituted olefins |
US20090253820A1 (en) | 2006-03-21 | 2009-10-08 | Honeywell International Inc. | Foaming agents and compositions containing fluorine sustituted olefins and methods of foaming |
US20120097885A9 (en) * | 2003-10-27 | 2012-04-26 | Honeywell International Inc. | Compositions Containing Difluoromethane and Fluorine Substituted Olefins |
US9005467B2 (en) | 2003-10-27 | 2015-04-14 | Honeywell International Inc. | Methods of replacing heat transfer fluids |
ES2728672T3 (es) | 2002-10-25 | 2019-10-28 | Honeywell Int Inc | Composiciones que contienen olefinas sustituidas con flúor |
US20040089839A1 (en) | 2002-10-25 | 2004-05-13 | Honeywell International, Inc. | Fluorinated alkene refrigerant compositions |
US20140166923A1 (en) * | 2002-10-25 | 2014-06-19 | Honeywell International Inc. | Compositions containing difluoromethane and fluorine substituted olefins |
JP4110388B2 (ja) | 2003-01-10 | 2008-07-02 | 荒川化学工業株式会社 | 金めっき部品用洗浄剤およびすすぎ剤並びに洗浄方法およびすすぎ方法 |
JP2005202637A (ja) * | 2004-01-15 | 2005-07-28 | Matsushita Electric Ind Co Ltd | 自動販売機 |
JP4454324B2 (ja) | 2004-01-29 | 2010-04-21 | 三洋電機株式会社 | ブースタユニット |
JP4454323B2 (ja) | 2004-01-29 | 2010-04-21 | 三洋電機株式会社 | 冷凍システム |
JP4432654B2 (ja) | 2004-07-22 | 2010-03-17 | パナソニック株式会社 | 浴室用換気暖房機 |
JP4420807B2 (ja) * | 2004-12-14 | 2010-02-24 | 三洋電機株式会社 | 冷凍装置 |
ES2580080T3 (es) | 2005-03-18 | 2016-08-19 | Carrier Commercial Refrigeration, Inc. | Intercambiador de calor de múltiples partes |
JP2007169331A (ja) * | 2005-12-19 | 2007-07-05 | Kanou Reiki Kogyo:Kk | 超低温用非共沸混合冷媒及びそれを使用した超低温用一元式冷凍回路 |
GB0614080D0 (en) | 2006-07-17 | 2006-08-23 | Ineos Fluor Holdings Ltd | Heat transfer compositions |
CA2661007A1 (en) | 2006-09-01 | 2008-03-06 | E.I. Du Pont De Nemours And Company | Method for circulating selected heat transfer fluids through a closed loop cycle |
JP5008365B2 (ja) | 2006-09-21 | 2012-08-22 | 旭化成ケミカルズ株式会社 | 塩化ビニリデン系共重合体樹脂組成物 |
JP2008134031A (ja) | 2006-11-29 | 2008-06-12 | Hitachi Appliances Inc | 非共沸混合冷媒を用いた冷凍装置 |
JP2010513843A (ja) | 2006-12-19 | 2010-04-30 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 二重列熱交換器およびそれを組み込んでいる自動車バンパー |
JP2008159353A (ja) | 2006-12-22 | 2008-07-10 | Matsushita Electric Ind Co Ltd | ボタン型空気亜鉛電池の製造方法およびその製造装置 |
CA2682312C (en) | 2007-05-11 | 2016-11-22 | E. I. Du Pont De Nemours And Company | Method for exchanging heat in a vapor compression heat transfer system and a vapor compression heat transfer system comprising an intermediate heat exchanger with a dual-row evaporator or condenser |
AR067115A1 (es) | 2007-06-21 | 2009-09-30 | Du Pont | Metodo para detectar fugas en un sistema de transferencia de calor |
WO2009018117A1 (en) | 2007-07-27 | 2009-02-05 | E. I. Du Pont De Nemours And Company | Compositions comprising fluoroolefins and uses thereof |
JP4556001B2 (ja) | 2007-12-27 | 2010-10-06 | 日立化成工業株式会社 | フレキシブル配線板の表面保護膜の形成方法 |
JP2009177860A (ja) * | 2008-01-21 | 2009-08-06 | Toyota Motor Corp | 車両の制御装置およびそれを備える車両 |
JP2009257652A (ja) | 2008-02-29 | 2009-11-05 | Daikin Ind Ltd | 冷凍装置 |
JP2009257655A (ja) | 2008-03-04 | 2009-11-05 | Daikin Ind Ltd | 冷凍装置 |
JP2009257742A (ja) * | 2008-03-25 | 2009-11-05 | Daikin Ind Ltd | 冷凍装置および冷凍装置の製造方法 |
JP2009257601A (ja) * | 2008-04-11 | 2009-11-05 | Daikin Ind Ltd | 空気調和装置 |
US8038899B2 (en) | 2008-04-28 | 2011-10-18 | Honeywell International Inc. | Refrigerant compositions having a siloxane solubilizing agent |
FR2932492B1 (fr) | 2008-06-11 | 2010-07-30 | Arkema France | Compositions a base d'hydrofluoroolefines |
FR2932493B1 (fr) | 2008-06-11 | 2010-07-30 | Arkema France | Compositions a base d'hydrofluoroolefines |
FR2932494B1 (fr) | 2008-06-11 | 2011-02-25 | Arkema France | Compositions a base d'hydrofluoroolefines |
JP2010002074A (ja) * | 2008-06-18 | 2010-01-07 | Mitsubishi Electric Corp | 混合冷媒とそれを用いた冷凍サイクル装置 |
WO2010002023A1 (en) | 2008-07-01 | 2010-01-07 | Daikin Industries, Ltd. | REFRIGERANT COMPOSITION COMPRISING DIFLUOROMETHANE (HFC32), 2,3,3,3-TETRAFLUOROPROPENE (HFO1234yf) AND 1,1,1,2-TETRAFLUOROETHANE (HFC134a) |
WO2010002016A1 (en) | 2008-07-01 | 2010-01-07 | Daikin Industries, Ltd. | REFRIGERANT COMPOSITION COMPRISING DIFLUOROMETHANE (HFC32) AND 2,3,3,3-TETRAFLUOROPROPENE (HFO1234yf) |
EP3473691A1 (en) * | 2008-07-30 | 2019-04-24 | Honeywell International Inc. | Compositions containing difluoromethane and fluorine substituted olefins |
US11214720B2 (en) | 2009-07-29 | 2022-01-04 | Honeywell International Inc. | Compositions containing difluoromethane and fluorine substituted olefins |
CN104059613A (zh) * | 2008-07-30 | 2014-09-24 | 霍尼韦尔国际公司 | 含有二氟甲烷和氟取代的烯烃的组合物 |
FR2936806B1 (fr) | 2008-10-08 | 2012-08-31 | Arkema France | Fluide refrigerant |
FR2937906B1 (fr) | 2008-11-03 | 2010-11-19 | Arkema France | Procede de chauffage et/ou climatisation d'un vehicule. |
US20170080773A1 (en) | 2008-11-03 | 2017-03-23 | Arkema France | Vehicle Heating and/or Air Conditioning Method |
DE202009019200U1 (de) | 2008-11-19 | 2018-10-15 | The Chemours Company Fc, Llc | Tetrafluorpropen-Zusammensetzungen und Ihre Verwendungen |
US20100122545A1 (en) | 2008-11-19 | 2010-05-20 | E. I. Du Pont De Nemours And Company | Tetrafluoropropene compositions and uses thereof |
FR2938550B1 (fr) | 2008-11-20 | 2010-11-12 | Arkema France | Composition comprenant du 2,3,3,3-tetrafluoropropene procede de chauffage et/ou climatisation d'un vehicule |
FR2938551B1 (fr) | 2008-11-20 | 2010-11-12 | Arkema France | Procede de chauffage et/ou climatisation d'un vehicule |
FR2941039B1 (fr) | 2009-01-14 | 2013-02-08 | Arkema France | Procede de transfert de chaleur |
JP2010203759A (ja) | 2009-02-04 | 2010-09-16 | Panasonic Corp | 冷凍装置 |
FR2942237B1 (fr) | 2009-02-13 | 2013-01-04 | Arkema France | Procede de chauffage et/ou climatisation d'un vehicule |
US9845419B2 (en) | 2009-07-29 | 2017-12-19 | Honeywell International Inc. | Low GWP heat transfer compositions containing difluoromethane and 1,3,3,3-tetrafluoropropene |
FR2950070B1 (fr) | 2009-09-11 | 2011-10-28 | Arkema France | Compositions ternaires pour refrigeration haute capacite |
FR2950066B1 (fr) | 2009-09-11 | 2011-10-28 | Arkema France | Refrigeration basse et moyenne temperature |
FR2950069B1 (fr) | 2009-09-11 | 2011-11-25 | Arkema France | Utilisation de compositions ternaires |
FR2950071B1 (fr) | 2009-09-11 | 2012-02-03 | Arkema France | Compositions ternaires pour refrigeration basse capacite |
FR2950067B1 (fr) | 2009-09-11 | 2011-10-28 | Arkema France | Fluide de transfert de chaleur en remplacement du r-410a |
FR2950068B1 (fr) | 2009-09-11 | 2012-05-18 | Arkema France | Procede de transfert de chaleur |
FR2950065B1 (fr) | 2009-09-11 | 2012-02-03 | Arkema France | Fluide refrigerant binaire |
US10035938B2 (en) | 2009-09-11 | 2018-07-31 | Arkema France | Heat transfer fluid replacing R-134a |
FR2954342B1 (fr) | 2009-12-18 | 2012-03-16 | Arkema France | Fluides de transfert de chaleur a inflammabilite reduite |
FR2957083B1 (fr) | 2010-03-02 | 2015-12-11 | Arkema France | Fluide de transfert de chaleur pour compresseur centrifuge |
FR2959997B1 (fr) | 2010-05-11 | 2012-06-08 | Arkema France | Fluides de transfert de chaleur et leur utilisation dans des echangeurs de chaleur a contre-courant |
FR2959999B1 (fr) | 2010-05-11 | 2012-07-20 | Arkema France | Fluides de transfert de chaleur et leur utilisation dans des echangeurs de chaleur a contre-courant |
FR2959998B1 (fr) | 2010-05-11 | 2012-06-01 | Arkema France | Fluides de transfert de chaleur ternaires comprenant du difluoromethane, du pentafluoroethane et du tetrafluoropropene |
EP2585550A4 (en) | 2010-06-22 | 2014-10-08 | Arkema Inc | Heat transfer compositions of liquid hydrocarbons and a hydrofluoroolefin |
FR2962130B1 (fr) | 2010-06-30 | 2012-07-20 | Arkema France | Composition a base de 2,3,3,3-tetrafluoropropene |
FR2962442B1 (fr) | 2010-07-09 | 2016-02-26 | Arkema France | Composition stable de 2,3,3,3-tetrafluoropropene |
FR2964975B1 (fr) | 2010-09-20 | 2012-08-24 | Arkema France | Composition a base de 2,3,3,3-tetrafluoropropene |
FR2971512B1 (fr) | 2011-02-10 | 2013-01-18 | Arkema France | Compositions binaires de 2,3,3,3-tetrafluoropropene et d'ammoniac |
FR2974812B1 (fr) | 2011-05-04 | 2014-08-08 | Arkema France | Compositions de transfert de chaleur presentant une miscibilite amelioree avec l'huile de lubrification |
FR2986007B1 (fr) | 2012-01-25 | 2015-01-23 | Arkema France | Compositions de transfert de chaleur presentant une miscibilite amelioree avec l'huile de lubrification |
FR2986236B1 (fr) | 2012-01-26 | 2014-01-10 | Arkema France | Compositions de transfert de chaleur presentant une miscibilite amelioree avec l'huile de lubrification |
FR3000096B1 (fr) | 2012-12-26 | 2015-02-20 | Arkema France | Composition comprenant du 2,3,3,3-tetrafluoropropene |
FR3000093B1 (fr) | 2012-12-26 | 2015-07-17 | Arkema France | Composition azeotropique ou quasi-azeotropique de chloromethane |
FR3000095B1 (fr) | 2012-12-26 | 2015-02-20 | Arkema France | Composition comprenant du 2,3,3,3-tetrafluoropropene et du 1,2-difluoroethylene |
FR3003565B1 (fr) | 2013-03-20 | 2018-06-29 | Arkema France | Composition comprenant hf et 2,3,3,3-tetrafluoropropene |
FR3008419B1 (fr) | 2013-07-11 | 2015-07-17 | Arkema France | Compositions a base de 2,3,3,3-tetrafluoropropene presentant une miscibilite amelioree |
FR3033791B1 (fr) | 2015-03-18 | 2017-04-14 | Arkema France | Stabilisation du 1-chloro-3,3,3-trifluoropropene |
FR3057272B1 (fr) | 2016-10-10 | 2020-05-08 | Arkema France | Compositions azeotropiques a base de tetrafluoropropene |
FR3057271B1 (fr) | 2016-10-10 | 2020-01-17 | Arkema France | Utilisation de compositions a base de tetrafluoropropene |
FR3061906B1 (fr) | 2017-01-19 | 2019-03-15 | Arkema France | Composition comprenant du 2,3,3,3-tetrafluoropropene |
FR3061905B1 (fr) | 2017-01-19 | 2019-05-17 | Arkema France | Composition comprenant du 2,3,3,3-tetrafluoropropene |
FR3070982B1 (fr) | 2017-09-12 | 2019-08-30 | Arkema France | Composition a base d'hydrochlorofluoroolefine et d'huile minerale |
FR3077572B1 (fr) | 2018-02-05 | 2021-10-08 | Arkema France | Composition azeotropique ou quasi-azeotropique ternaire comprenant hf, 2,3,3,3-tetrafluoropropene et 1,1,1,2,2,-pentafluoropropane. |
FR3077822B1 (fr) | 2018-02-15 | 2020-07-24 | Arkema France | Compositions de transfert de chaleur en remplacement du r-134a |
FR3080169B1 (fr) | 2018-04-13 | 2020-12-18 | Arkema France | Procede de refroidissement et/ou de chauffage d'un corps ou d'un fluide dans un vehicule automobile |
-
2008
- 2008-10-08 FR FR0856817A patent/FR2936806B1/fr active Active
- 2008-10-09 FR FR0856836A patent/FR2936807B3/fr not_active Expired - Lifetime
-
2009
- 2009-09-24 PL PL09759757T patent/PL2331651T3/pl unknown
- 2009-09-24 ES ES09759757.9T patent/ES2663548T3/es active Active
- 2009-09-24 JP JP2011530523A patent/JP5591246B2/ja active Active
- 2009-09-24 EP EP09759757.9A patent/EP2331651B1/fr active Active
- 2009-09-24 PT PT97597579T patent/PT2331651T/pt unknown
- 2009-09-24 CN CN200980138906.7A patent/CN102171309B/zh not_active Ceased
- 2009-09-24 EP EP13152355.7A patent/EP2586842A3/fr not_active Withdrawn
- 2009-09-24 WO PCT/FR2009/051814 patent/WO2010040928A1/fr active Application Filing
- 2009-09-24 US US13/122,606 patent/US20110186772A1/en not_active Abandoned
- 2009-10-06 TW TW098133850A patent/TWI406934B/zh active
-
2014
- 2014-03-12 JP JP2014049419A patent/JP2014141681A/ja active Pending
-
2015
- 2015-10-02 US US14/873,855 patent/US9599381B2/en active Active
-
2016
- 2016-05-26 JP JP2016104908A patent/JP2016176082A/ja active Pending
-
2017
- 2017-01-03 US US15/396,855 patent/US20170145276A1/en not_active Abandoned
-
2018
- 2018-09-26 US US16/142,492 patent/US11130893B2/en active Active
- 2018-11-16 JP JP2018215896A patent/JP2019052317A/ja active Pending
-
2021
- 2021-01-14 JP JP2021003960A patent/JP2021066889A/ja active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1072715A (zh) * | 1991-10-11 | 1993-06-02 | 帝国化学工业公司 | 润滑剂 |
WO2006094303A2 (en) * | 2005-03-04 | 2006-09-08 | E.I. Dupont De Nemours And Company | Compositions comprising a fluoroolefin |
WO2007126414A2 (en) * | 2006-03-30 | 2007-11-08 | E. I. Du Pont De Nemours And Company | Compositions comprising a fluoroolefin |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102639668A (zh) * | 2010-01-27 | 2012-08-15 | 大金工业株式会社 | 含二氟甲烷(hfc32)和2,3,3,3-四氟丙烯(hfo1234yf)的制冷剂组合物 |
CN102639668B (zh) * | 2010-01-27 | 2016-02-24 | 大金工业株式会社 | 含二氟甲烷(hfc32)和2,3,3,3-四氟丙烯(hfo1234yf)的制冷剂组合物 |
CN104603228A (zh) * | 2012-09-04 | 2015-05-06 | 大金工业株式会社 | 含有2,3,3,3-四氟丙烯的混合制冷剂的填充方法 |
US9528735B2 (en) | 2012-09-04 | 2016-12-27 | Daikin Industries, Ltd. | Method for filling mixed refrigerant containing 2,3,3,3-tetrafluoropropene |
CN104603228B (zh) * | 2012-09-04 | 2018-04-06 | 大金工业株式会社 | 含有2,3,3,3‑四氟丙烯的混合制冷剂的填充方法 |
CN113383060A (zh) * | 2019-02-14 | 2021-09-10 | 出光兴产株式会社 | 冷冻机用组合物 |
CN113383060B (zh) * | 2019-02-14 | 2023-02-21 | 出光兴产株式会社 | 冷冻机用组合物 |
CN113840893A (zh) * | 2019-05-17 | 2021-12-24 | 科慕埃弗西有限公司 | 用于制冷剂压缩机系统的制冷剂组合物 |
CN113840893B (zh) * | 2019-05-17 | 2024-04-16 | 科慕埃弗西有限公司 | 用于制冷剂压缩机系统的制冷剂组合物 |
Also Published As
Publication number | Publication date |
---|---|
ES2663548T3 (es) | 2018-04-13 |
JP2014141681A (ja) | 2014-08-07 |
PT2331651T (pt) | 2018-03-28 |
EP2331651B1 (fr) | 2018-02-21 |
JP2012505279A (ja) | 2012-03-01 |
EP2586842A3 (fr) | 2017-03-08 |
US20170145276A1 (en) | 2017-05-25 |
US20160025394A1 (en) | 2016-01-28 |
FR2936806B1 (fr) | 2012-08-31 |
JP5591246B2 (ja) | 2014-09-17 |
WO2010040928A1 (fr) | 2010-04-15 |
PL2331651T3 (pl) | 2018-06-29 |
FR2936807B3 (fr) | 2012-10-26 |
US9599381B2 (en) | 2017-03-21 |
FR2936806A1 (fr) | 2010-04-09 |
US11130893B2 (en) | 2021-09-28 |
JP2016176082A (ja) | 2016-10-06 |
JP2019052317A (ja) | 2019-04-04 |
US20110186772A1 (en) | 2011-08-04 |
FR2936807A1 (fr) | 2010-04-09 |
EP2331651A1 (fr) | 2011-06-15 |
JP2021066889A (ja) | 2021-04-30 |
EP2586842A2 (fr) | 2013-05-01 |
US20190203094A1 (en) | 2019-07-04 |
CN102171309B (zh) | 2014-06-25 |
TWI406934B (zh) | 2013-09-01 |
TW201026835A (en) | 2010-07-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102171309B (zh) | 传热流体 | |
CN102066519B (zh) | 基于氢氟烯烃的组合物 | |
CN102066520B (zh) | 基于氢氟烯烃的组合物 | |
CN102066518B (zh) | 基于氢氟烯烃的组合物 | |
CN102471670B (zh) | 传热方法 | |
CN102177215A (zh) | 传热方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
IW01 | Full invalidation of patent right |
Decision date of declaring invalidation: 20240109 Decision number of declaring invalidation: 565753 Granted publication date: 20140625 |
|
IW01 | Full invalidation of patent right |