CN102167559A - Quick-setting cement mortar and preparation method thereof - Google Patents

Quick-setting cement mortar and preparation method thereof Download PDF

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Publication number
CN102167559A
CN102167559A CN 201110030886 CN201110030886A CN102167559A CN 102167559 A CN102167559 A CN 102167559A CN 201110030886 CN201110030886 CN 201110030886 CN 201110030886 A CN201110030886 A CN 201110030886A CN 102167559 A CN102167559 A CN 102167559A
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parts
cement mortar
rapid hardening
emulsion
hardening cement
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CN 201110030886
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CN102167559B (en
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刘建华
付宏渊
刘冶球
康灵
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Changsha University of Science and Technology
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Changsha University of Science and Technology
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention relates to quick-setting cement mortar and a preparation method thereof. The quick-setting cement mortar is concretely prepared from materials such as sulphate aluminium cement, styrene butadiene rubber emulsion, polyurethane emulsion, a water reducer, trolamine, droxyethylcellulose, fibre, river sand, water and the like according to a certain weight ratio. The quick-setting cement mortar has the characteristics of quickness in setting at normal temperature, high strength in the early stage, crack resistance, good durability and the like, can be widely applied to the fields such as embankment reinforcement, channel impermeability, soil and water conservation, side slope protection, quick repair of concrete road surfaces, and the like.

Description

A kind of rapid hardening cement mortar and preparation method thereof
Technical field
The invention belongs to building material technical field, be specifically related to a kind of construction work rapid hardening cement mortar and preparation method thereof.
Background technology
The aluminosulfate cement mortar has outstanding does powerful feature early soon, and has performances such as volume microdilatancy, anticorrosive and low basicity, is normally used for making anticorrosion impervious material, fast repairing material etc.But, the anticorrosion impervious and patching material made from the aluminosulfate cement mortar only, the porosity of lower, the easy shrinkage cracking of its later strength, hydration and hardening slurry causes the resistance to corrosion can not engineering demands more greatly.In sand-cement slurry, add a small amount of organic high molecular polymer and fiber, can effectively reduce the hole in the sand-cement slurry, make sand-cement slurry obtain highly dense solidity, be unlikely to make the fragility of sand-cement slurry to strengthen again, obtain fast dried, high-strength, impervious, corrosion resistant cement mortar material, thus the use field of having widened sand-cement slurry.
It is the polyacrylate modified cement of stablizer with the polyvinyl alcohol that US5753036 discloses a kind of, is that 5000~45000 polyvinyl alcohol, polyacrylic ester, cement and filler constitute by molecular-weight average.CN1730908 discloses a kind of method for reinforcing and protecting to inner surface of tunnel, improve the surface strength of inner surface of tunnel by in cement waterproofing mortar, adding polyacrylic acid emulsion and polypropylene fibre, solved crack, infiltration and the high temperature explosion problem of inner surface of tunnel.CN1483692 discloses a kind of cement concrete mixture that adds polyacrylonitrile fibre.CN1415572 discloses a kind of polymer modification mortar patching material, is made of Portland cement or short-term strength cement, styrene-butadiene rubber(SBR), yellow soda ash, trolamine.Polymkeric substance to the sand-cement slurry modification is mainly polyacrylate dispersion, EVA emulsion or styrene-butadiene emulsion at present.Polymer emulsion can effectively improve the impervious and anti-shrinkage cracking performance of sand-cement slurry, but in the process of preparation polymer cement mortar, because of polymkeric substance and the cement consistency is relatively poor and reason such as polymkeric substance breakdown of emulsion, cause prolong and the intensity reduction time of coagulation of sand-cement slurry, thereby influenced the net effect of sand-cement slurry.
Summary of the invention
The objective of the invention is to solve the problem of the rate of set that exists in the present use polymer modification rapid hardening cement mortar, a kind of rapid hardening cement mortar and preparation method thereof is provided.
The rapid hardening cement mortar that the present invention proposes is the liquid form mixt that is formed according to a certain weight ratio by materials such as aluminosulfate cement, SBR emulsion, polyaminoester emulsion, water reducer, trolamine, Natvosol, fiber, river sand, water.Comprising of raw material:
100 parts of aluminosulfate cements
2~10 parts of SBR emulsions
2~10 parts of polyaminoester emulsions
0.5~2 part of water reducer
0.5~2 part of trolamine
0.2~1 part of Natvosol
1~5 part of fiber
50~150 parts of river sands
150~250 parts in water
Described SBR emulsion, the solid content of described SBR emulsion are 20~40%.
Described polyaminoester emulsion, described polyaminoester emulsion are the cation type polyurethane emulsion, and its solid content is 30~60%.Second-order transition temperature is-30 ℃~-10 ℃.
Described water reducer is a kind of in poly carboxylic acid, the naphthalene sulfonic salt or their mixture.
Described fiber, described fiber are a kind of in polypropylene fibre or the carbon fiber or their mixture.
Described polymer cement waterproof preparation methods is characterized in that comprising the steps:
(1) takes by weighing the material of following deal: 100 parts aluminosulfate cement, 0.5~2 part water reducer, 1~5 part fiber and 50~150 parts river sand, thorough mixing;
(2) take by weighing the material of following deal: 2~10 parts SBR emulsion, 2~10 parts polyaminoester emulsion, 0.5~2 part trolamine, 0.2~1 part Natvosol, 150~250 parts water, thorough mixing;
(3) material in the step (1) adds the material in the step (2) gradually under whipped state, and churning time is 1~6 minute, forms the rapid hardening cement mortar.
The present invention is by selected the determining of proportioning content that reach of above composition, promptly by adding the elasticity of SBR emulsion raising sand-cement slurry, add polyaminoester emulsion and improve the consistency of itself and cement, add the rate of set of trolamine raising cement, add the stability of Natvosol raising polymer cement mortar, cooperatively interact acting in conjunction between each composition, and the effective checking by embodiment, efficiently solve the problem of the rate of set that exists in the present sand-cement slurry.
Specific implementation method
Following examples are intended to illustrate the present invention rather than limitation of the invention further.
Embodiment 1.
The proportioning of this routine polymer cement waterproof paint is:
100 parts of aluminosulfate cements
2 parts of SBR emulsions
5 parts of polyaminoester emulsions
0.5 part of water reducer
0.5 part of trolamine
0.2 part of Natvosol
1 part of fiber
80 parts of river sands
200 parts in water
Concrete preparation method comprises the steps:
(1) takes by weighing the material of following deal: 100 parts aluminosulfate cement, 0.5 part water reducer, 1 part fiber and 80 parts river sand, thorough mixing;
(2) take by weighing the material of following deal: 2 parts SBR emulsion, 5 parts polyaminoester emulsion, 0.5 part trolamine, 0.2 part Natvosol, 200 parts water, thorough mixing;
(3) material in the step (1) adds the material in the step (2) gradually under whipped state, and churning time is 6 minutes, forms the rapid hardening cement mortar.
Employed aluminosulfate cement is 42.5 quick hardening sulphoaluminate cements that Tangshan six or nine cement company limiteds produce; Employed SBR emulsion is the PR 215 type SBR emulsions of Shanghai and assistant officer Industrial Co., Ltd.; Employed polyaminoester emulsion closes the PUA-102 type cation aqueous polyurethane of sincere polyurethane production for Taizhou Huangyan.
The technical target of the product that present embodiment obtains:
Embodiment 2
The proportioning of this routine polymer cement waterproof paint is:
100 parts of aluminosulfate cements
5 parts of SBR emulsions
5 parts of polyaminoester emulsions
1 part of water reducer
0.5 part of trolamine
0.2 part of Natvosol
1 part of fiber
80 parts of river sands
200 parts in water
Concrete preparation method comprises the steps:
(1) takes by weighing the material of following deal: 100 parts aluminosulfate cement, 1 part water reducer, 1 part fiber and 80 parts river sand, thorough mixing;
(2) take by weighing the material of following deal: 5 parts SBR emulsion, 5 parts polyaminoester emulsion, 0.5 part trolamine, 0.2 part Natvosol, 200 parts water, thorough mixing;
(3) material in the step (1) adds the material in the step (2) gradually under whipped state, and churning time is 6 minutes, forms the rapid hardening cement mortar.
Employed aluminosulfate cement is 42.5 quick hardening sulphoaluminate cements that Tangshan six or nine cement company limiteds produce; The PR 215 type SBR emulsions of big Shanghai of employed SBR emulsion and assistant officer Industrial Co., Ltd.; Employed polyaminoester emulsion closes the PUA-102 type cation aqueous polyurethane of sincere polyurethane production for Taizhou Huangyan.
The technical target of the product that present embodiment obtains:
Figure BDA0000045875120000041
Figure BDA0000045875120000051

Claims (7)

1. rapid hardening cement mortar is characterized in that raw material comprises: by weight,
100 parts of aluminosulfate cements
2~10 parts of SBR emulsions
2~10 parts of polyaminoester emulsions
0.5~2 part of water reducer
0.5~2 part of trolamine
0.2~1 part of Natvosol
1~5 part of fiber
50~150 parts of river sands
150~250 parts in water.
2. a kind of rapid hardening cement mortar according to claim 1, the solid content that it is characterized in that described SBR emulsion is 20~40%.
3. a kind of rapid hardening cement mortar according to claim 1 is characterized in that described polyaminoester emulsion is the cation type polyurethane emulsion, and its solid content is 30~60%.
4. a kind of rapid hardening cement mortar according to claim 3 is characterized in that second-order transition temperature is-30 ℃~-10 ℃.
5. a kind of rapid hardening cement mortar according to claim 1 is characterized in that described water reducer is a kind of in poly carboxylic acid, the naphthalene sulfonic salt or their mixture.
6. according to claim 1 a kind of rapid hardening cement mortar,, it is characterized in that described fiber is a kind of in polypropylene fibre or the carbon fiber or their mixture.
7. the preparation method of each described rapid hardening cement mortar of claim 1-6 is characterized in that comprising the steps:
(1) takes by weighing the material of following deal: 100 parts aluminosulfate cement, 0.5~2 part water reducer, 1~5 part fiber and 50~150 parts river sand, thorough mixing;
(2) take by weighing the material of following deal: 2~10 parts SBR emulsion, 2~10 parts polyaminoester emulsion, 0.5~2 part trolamine, 0.2~1 part Natvosol, 150~250 parts water, thorough mixing;
(3) material in the step (1) adds the material in the step (2) gradually under whipped state, and churning time is 1~6 minute, forms the rapid hardening cement mortar.
CN 201110030886 2011-01-28 2011-01-28 Quick-setting cement mortar and preparation method thereof Expired - Fee Related CN102167559B (en)

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Application Number Priority Date Filing Date Title
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102584149A (en) * 2012-01-12 2012-07-18 中煤建筑安装工程公司 Quick-setting cement mortar and preparation method for quick-setting cement mortar
CN103553419A (en) * 2013-10-23 2014-02-05 湖州中辰建设有限公司 Rapid cement hardening agent
CN103553405A (en) * 2013-10-22 2014-02-05 湖州中辰建设有限公司 Cement mortar hardener
CN103739249A (en) * 2013-12-20 2014-04-23 安徽省美域节能环保技术应用有限公司 Quick-dry anti-crack composite cement mortar and preparation method thereof
CN104163594A (en) * 2014-07-24 2014-11-26 广州市景龙装饰工程有限公司 Cement-based finishing slurry and preparation method thereof
CN104692744A (en) * 2015-03-12 2015-06-10 北京元泰达环保建材科技有限责任公司 Road patching material with favorable elasticity and abrasion resistance and application thereof
CN105645875A (en) * 2016-01-04 2016-06-08 哈尔滨工程大学 Water-based polyurethane-carbon fiber polymer modified concrete for high-pile wharf slabs and preparation method thereof
CN106747067A (en) * 2016-12-01 2017-05-31 芜湖浩权建筑工程有限公司 A kind of Anti-crack composite cement mortar and preparation method thereof
CN106939583A (en) * 2017-04-27 2017-07-11 中冶华天工程技术有限公司 Seepage structure and its method
CN110240453A (en) * 2019-07-17 2019-09-17 李大为 A kind of mineral filler modified high-strength polymer cement mortar and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090011207A1 (en) * 2007-07-05 2009-01-08 United States Gypsum Company Lightweight cementitious compositions and building products and methods for making same
CN101857416A (en) * 2010-06-13 2010-10-13 中国建筑材料科学研究总院 Polymer emulsion modified rapid repair mortar and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090011207A1 (en) * 2007-07-05 2009-01-08 United States Gypsum Company Lightweight cementitious compositions and building products and methods for making same
CN101857416A (en) * 2010-06-13 2010-10-13 中国建筑材料科学研究总院 Polymer emulsion modified rapid repair mortar and preparation method thereof

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102584149B (en) * 2012-01-12 2013-06-05 中煤建筑安装工程公司 Quick-setting cement mortar and preparation method for quick-setting cement mortar
CN102584149A (en) * 2012-01-12 2012-07-18 中煤建筑安装工程公司 Quick-setting cement mortar and preparation method for quick-setting cement mortar
CN103553405A (en) * 2013-10-22 2014-02-05 湖州中辰建设有限公司 Cement mortar hardener
CN103553419A (en) * 2013-10-23 2014-02-05 湖州中辰建设有限公司 Rapid cement hardening agent
CN103553419B (en) * 2013-10-23 2015-11-25 新昌县达科机电产品设计有限公司 The fast hard agent of a kind of cement
CN103739249A (en) * 2013-12-20 2014-04-23 安徽省美域节能环保技术应用有限公司 Quick-dry anti-crack composite cement mortar and preparation method thereof
CN104163594B (en) * 2014-07-24 2016-03-02 广州市景龙装饰工程有限公司 A kind of cement based finishing slurry and preparation method thereof
CN104163594A (en) * 2014-07-24 2014-11-26 广州市景龙装饰工程有限公司 Cement-based finishing slurry and preparation method thereof
CN104692744A (en) * 2015-03-12 2015-06-10 北京元泰达环保建材科技有限责任公司 Road patching material with favorable elasticity and abrasion resistance and application thereof
CN105645875A (en) * 2016-01-04 2016-06-08 哈尔滨工程大学 Water-based polyurethane-carbon fiber polymer modified concrete for high-pile wharf slabs and preparation method thereof
CN105645875B (en) * 2016-01-04 2018-03-13 哈尔滨工程大学 Long piled wharf panel aqueous polyurethane carbon fiber polymer modification concrete and preparation method
CN106747067A (en) * 2016-12-01 2017-05-31 芜湖浩权建筑工程有限公司 A kind of Anti-crack composite cement mortar and preparation method thereof
CN106939583A (en) * 2017-04-27 2017-07-11 中冶华天工程技术有限公司 Seepage structure and its method
CN110240453A (en) * 2019-07-17 2019-09-17 李大为 A kind of mineral filler modified high-strength polymer cement mortar and preparation method thereof

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