A kind of rapid hardening cement mortar and preparation method thereof
Technical field
The present invention relates to building material field, is specifically related to a kind of construction work with rapid hardening cement mortar and preparation method thereof.
Background technology
In building material field; Quick-drying time requirement to sand-cement slurry is fewer and feweri, simultaneously, must guarantee that the cement after the rapid drying has better characteristics such as anti-intensity; Therefore, the hot issue that to seek a kind of like this rapid hardening cement mortar be building material field always.Disclosing a kind of at US5753036 is the polyacrylate modified cement of stablizer with the Z 150PH, is that 5000~45000 Z 150PH, polyacrylic ester, cement and filler constitute by molecular-weight average.CN1730908 discloses a kind of method for reinforcing and protecting to inner surface of tunnel; Improve the surface strength of inner surface of tunnel through in cement waterproofing mortar, adding ROHM emulsion and polypropylene fibre, solved crack, infiltration and the high temperature explosion problem of inner surface of tunnel.CN1483692 discloses a kind of cement concrete mixture that adds polyacrylonitrile fibre.CN1415572 discloses a kind of polymer modification mortar patching material, is made up of Portland cement or short-term strength cement, styrene-butadiene rubber(SBR), yellow soda ash, trolamine.Polymkeric substance to the sand-cement slurry modification is mainly polyacrylate emulsion, EVA emulsion or styrene-butadiene emulsion at present.Polymer emulsion can effectively improve the impervious and anti-shrinkage cracking performance of sand-cement slurry; But in the process of preparation polymer cement mortar; Because of polymkeric substance and the cement consistency is relatively poor and reason such as polymkeric substance breakdown of emulsion; Cause prolong and the intensity reduction time of coagulation of sand-cement slurry, thereby influenced the net effect of sand-cement slurry.CN102167559 discloses and has a kind ofly combined to the sand-cement slurry modification with SBR emulsion and polyaminoester emulsion.But in the process of reality, polymkeric substance and cement consistency are still undesirable, cause prolong and the intensity reduction time of coagulation of sand-cement slurry, thereby have influenced the net effect of sand-cement slurry.
On the basis of these prior aries; The present invention is to polymer-modified, water reducer, fibrous packing component further experiment; Find when adopting SBR emulsion properties-correcting agent; A kind of water reducer of new proportioning and adopt a certain proportion of conjugated fibre, its experiment effect has obvious improvement than above-mentioned effect of the prior art, and has reduced cost.
Summary of the invention
The objective of the invention is to deficiency, solve and use the problems such as rate of set that exist in the polymer modification rapid hardening cement mortar at present, a kind of rapid hardening cement mortar and preparation method thereof is provided to prior art.
The rapid hardening cement mortar that the present invention proposes is the liquid form mixt that is formed according to a certain weight ratio by materials such as aluminosulfate cement, SBR emulsion, water reducer, fiber, sodium sulfate, river sand, water.The composition of raw material comprises:
100 parts of aluminosulfate cements
SBR emulsion 5-15 part
Water reducer 2-4 part
Fiber 6-7 part
Sodium sulfate 0.1-0.5 part
River sand 60-130 part
Water 160-200 part.
The solid content of described SBR emulsion is 30-35%.
Said water reducer is a trolamine 5-10%, vinylformic acid 15-20%, sodium sulfite anhy 96 surplus.Described fiber is: fiber is the mixture of organic fibre and steel fiber, and its ratio is 2:3; Organic fibre is a vinylon, and the long 10-20mm of organic fibre, diameter are less than 45 microns, and steel fiber is the high-strength steel fiber, the long 10-20mm of steel fiber, and diameter is less than 0.20mm.
It is further preferred,
100 parts of aluminosulfate cements
SBR emulsion 10-15 part
Water reducer 3-4 part
Fiber 6-7 part
Sodium sulfate 0.3-0.5 part
River sand 100-130 part
Water 160-200 part.
Further be preferably
100 parts of aluminosulfate cements
SBR emulsion 10-15 part
Water reducer 3-4 part
Fiber 6-7 part
Sodium sulfate 0.3-0.5 part
River sand 100-130 part
Water 160-200 part.
The preparation method of described above-mentioned rapid hardening cement mortar is characterized in that comprising the steps:
(1) according to above-mentioned ratio, takes by weighing aluminosulfate cement, water reducer, fiber and river sand, thorough mixing.
(2) take by weighing SBR emulsion, sodium sulfate, water again, the material in step (1) adds under whipped state gradually, and thorough mixing constantly stirs, and forms the rapid hardening cement mortar.
Compare with existing rapid hardening cement mortar, have following advantage and effect:
1, to compare sand-cement slurry of the prior art faster time of drying for the rapid hardening cement mortar that obtains of the present invention.
2, the rapid hardening cement mortar that obtains of the present invention compare sand-cement slurry ultimate compression strength of the prior art and folding strength stronger.
3, the rapid hardening cement mortar preparation cost that obtains of the present invention is lower, and flexibility is strong.
Embodiment
The present invention is not limited to aforesaid embodiment.The present invention expands to any new feature or any new combination that discloses in this manual, and any new method or the step in the process or any new combination that disclose.
The proportioning of embodiment 1 present embodiment rapid hardening cement mortar is following:
100 parts of aluminosulfate cements
5 parts of SBR emulsions
2 parts of water reducers
7 parts of fibers
0.5 part in sodium sulfate
100 parts of river sands
160 parts in water.
Said water reducer is a trolamine 5%, vinylformic acid 20%, sodium sulfite anhy 96 surplus.Described fiber is: fiber is the mixture of Z 150PH organic fibre and steel fiber, and its ratio is 2:3; The long 10-20mm of organic fibre, diameter be less than 45 microns, the long 10-20mm of steel fiber, and diameter is less than 0.20mm.
Employed aluminosulfate cement is 42.5 quick hardening sulphoaluminate cements that Tangshan six or nine cement ltds produce, and SBR emulsion is the PR 215 type SBR emulsions of Shanghai and assistant officer Industrial Co., Ltd..
The technical target of the product that present embodiment obtains:
The proportioning of embodiment 2 present embodiment rapid hardening cement mortars is following:
100 parts of aluminosulfate cements
10 parts of SBR emulsions
4 parts of water reducers
6 parts of fibers
0.3 part in sodium sulfate
120 parts of river sands
200 parts in water.
Said water reducer is a trolamine 10%, vinylformic acid 15%, sodium sulfite anhy 96 surplus.Described fiber is: fiber is the mixture of Z 150PH organic fibre and steel fiber, and its ratio is 2:3; The long 10-20mm of organic fibre, diameter be less than 45 microns, the long 10-20mm of steel fiber, and diameter is less than 0.20mm.
Employed aluminosulfate cement is 42.5 quick hardening sulphoaluminate cements that Tangshan six or nine cement ltds produce, and SBR emulsion is the PR 215 type SBR emulsions of Shanghai and assistant officer Industrial Co., Ltd..
The technical target of the product that present embodiment obtains: