CN102153053A - 甲烷法二硫化碳生产过程中硫化氢副产物的提纯和综合利用方法 - Google Patents
甲烷法二硫化碳生产过程中硫化氢副产物的提纯和综合利用方法 Download PDFInfo
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- CN102153053A CN102153053A CN2010105590308A CN201010559030A CN102153053A CN 102153053 A CN102153053 A CN 102153053A CN 2010105590308 A CN2010105590308 A CN 2010105590308A CN 201010559030 A CN201010559030 A CN 201010559030A CN 102153053 A CN102153053 A CN 102153053A
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- 229910000037 hydrogen sulfide Inorganic materials 0.000 title claims abstract description 161
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title claims abstract description 160
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 title claims abstract description 65
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 238000000034 method Methods 0.000 title claims abstract description 60
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 35
- 239000006227 byproduct Substances 0.000 title claims abstract description 22
- 239000007789 gas Substances 0.000 claims abstract description 46
- 238000007670 refining Methods 0.000 claims abstract description 41
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- 239000000047 product Substances 0.000 claims abstract description 24
- 238000000926 separation method Methods 0.000 claims abstract description 14
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 40
- 239000012071 phase Substances 0.000 claims description 25
- FFEARJCKVFRZRR-BYPYZUCNSA-N L-methionine Chemical compound CSCC[C@H](N)C(O)=O FFEARJCKVFRZRR-BYPYZUCNSA-N 0.000 claims description 22
- 229930182817 methionine Natural products 0.000 claims description 22
- 238000005516 engineering process Methods 0.000 claims description 20
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 15
- 241000282326 Felis catus Species 0.000 claims description 14
- 239000007791 liquid phase Substances 0.000 claims description 14
- 239000005864 Sulphur Substances 0.000 claims description 12
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 10
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- 238000006243 chemical reaction Methods 0.000 claims description 9
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- 235000009508 confectionery Nutrition 0.000 claims description 7
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- 230000023556 desulfurization Effects 0.000 claims description 7
- 239000003345 natural gas Substances 0.000 claims description 7
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 6
- 238000012546 transfer Methods 0.000 claims description 6
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- 239000002699 waste material Substances 0.000 abstract description 4
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- 238000012545 processing Methods 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 5
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
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- 239000007795 chemical reaction product Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
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- 101710178035 Chorismate synthase 2 Proteins 0.000 description 2
- 101710152694 Cysteine synthase 2 Proteins 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- AEDZKIACDBYJLQ-UHFFFAOYSA-N ethane-1,2-diol;hydrate Chemical compound O.OCCO AEDZKIACDBYJLQ-UHFFFAOYSA-N 0.000 description 2
- 238000007701 flash-distillation Methods 0.000 description 2
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- 238000010297 mechanical methods and process Methods 0.000 description 2
- 230000005226 mechanical processes and functions Effects 0.000 description 2
- 238000012958 reprocessing Methods 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
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- 239000003507 refrigerant Substances 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
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- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010977 unit operation Methods 0.000 description 1
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CN 201010559030 CN102153053B (zh) | 2010-11-20 | 2010-11-20 | 甲烷法二硫化碳生产过程中硫化氢副产物的提纯和综合利用方法 |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104003389A (zh) * | 2014-06-16 | 2014-08-27 | 成都丽雅纤维股份有限公司 | 一种二硫化碳制备工艺中液硫的分离方法 |
CN105129799A (zh) * | 2015-06-25 | 2015-12-09 | 辽宁瑞兴化工集团有限公司 | 甲烷法二硫化碳生产过程中产物二硫化碳的精制提纯 |
CN106744709A (zh) * | 2017-01-20 | 2017-05-31 | 山东金典化工有限公司 | 利用天然气法生产二硫化碳的副产物硫化氢制取高纯度硫化氢的方法 |
CN106829876A (zh) * | 2017-03-02 | 2017-06-13 | 洛阳九成新材料技术有限公司 | 炼油厂脱硫车间硫蒸汽的回收利用方法 |
CN108128776A (zh) * | 2017-04-14 | 2018-06-08 | 阳城县瑞兴化工有限公司 | 一种以煤层气为原料合成二硫化碳的方法 |
CN109095468A (zh) * | 2017-12-27 | 2018-12-28 | 山西铁峰化工有限公司 | 一种以硫化氢为原料制备二硫化碳的方法 |
CN112239208A (zh) * | 2020-12-09 | 2021-01-19 | 吉林三源化工有限公司 | 二硫化碳生产系统 |
CN112408392A (zh) * | 2020-12-09 | 2021-02-26 | 吉林三源化工有限公司 | 二硫化碳储运系统 |
CN113428861A (zh) * | 2021-07-19 | 2021-09-24 | 华东理工大学 | 一种甲烷与硫化氢重整制氢工艺 |
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CN1042883A (zh) * | 1989-10-17 | 1990-06-13 | 成都化学纤维厂 | 二硫化碳生产过程中反应生成物的分离处理方法 |
CN1088131A (zh) * | 1993-09-12 | 1994-06-22 | 浙江大学 | 脱除高浓度硫化氢与二硫化碳废气并回收硫的方法及系统 |
CN1264318A (zh) * | 1997-05-21 | 2000-08-23 | 特博塔克技术有限公司 | 从人造纤维生产过程的气流中除去污染物 |
CN1324327A (zh) * | 1998-10-21 | 2001-11-28 | 金属技术股份有限公司 | 由含nh3和酸性气体的废水获得氨的方法 |
CN1935645A (zh) * | 2006-09-18 | 2007-03-28 | 孔庆然 | 一种粗品二硫化碳的精馏设备及方法 |
CN101274203A (zh) * | 2007-12-27 | 2008-10-01 | 唐山三友集团兴达化纤有限公司 | 去除粘胶纤维生产过程中二硫化碳气体的方法 |
US20100011958A1 (en) * | 2005-12-22 | 2010-01-21 | Renaud Cadours | Method of Deacidizing a Gas with a Fractional Regeneration Absorbent Solution with Control of the Water Content of the Solution |
CN101829484A (zh) * | 2010-05-27 | 2010-09-15 | 重庆紫光化工股份有限公司 | 一种二硫化碳精制系统尾气回收的方法 |
-
2010
- 2010-11-20 CN CN 201010559030 patent/CN102153053B/zh active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1042883A (zh) * | 1989-10-17 | 1990-06-13 | 成都化学纤维厂 | 二硫化碳生产过程中反应生成物的分离处理方法 |
CN1088131A (zh) * | 1993-09-12 | 1994-06-22 | 浙江大学 | 脱除高浓度硫化氢与二硫化碳废气并回收硫的方法及系统 |
CN1264318A (zh) * | 1997-05-21 | 2000-08-23 | 特博塔克技术有限公司 | 从人造纤维生产过程的气流中除去污染物 |
CN1324327A (zh) * | 1998-10-21 | 2001-11-28 | 金属技术股份有限公司 | 由含nh3和酸性气体的废水获得氨的方法 |
US20100011958A1 (en) * | 2005-12-22 | 2010-01-21 | Renaud Cadours | Method of Deacidizing a Gas with a Fractional Regeneration Absorbent Solution with Control of the Water Content of the Solution |
CN1935645A (zh) * | 2006-09-18 | 2007-03-28 | 孔庆然 | 一种粗品二硫化碳的精馏设备及方法 |
CN101274203A (zh) * | 2007-12-27 | 2008-10-01 | 唐山三友集团兴达化纤有限公司 | 去除粘胶纤维生产过程中二硫化碳气体的方法 |
CN101829484A (zh) * | 2010-05-27 | 2010-09-15 | 重庆紫光化工股份有限公司 | 一种二硫化碳精制系统尾气回收的方法 |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104003389A (zh) * | 2014-06-16 | 2014-08-27 | 成都丽雅纤维股份有限公司 | 一种二硫化碳制备工艺中液硫的分离方法 |
CN105129799A (zh) * | 2015-06-25 | 2015-12-09 | 辽宁瑞兴化工集团有限公司 | 甲烷法二硫化碳生产过程中产物二硫化碳的精制提纯 |
CN106744709A (zh) * | 2017-01-20 | 2017-05-31 | 山东金典化工有限公司 | 利用天然气法生产二硫化碳的副产物硫化氢制取高纯度硫化氢的方法 |
CN106829876A (zh) * | 2017-03-02 | 2017-06-13 | 洛阳九成新材料技术有限公司 | 炼油厂脱硫车间硫蒸汽的回收利用方法 |
CN106829876B (zh) * | 2017-03-02 | 2018-09-04 | 洛阳九成新材料技术有限公司 | 炼油厂脱硫车间硫蒸汽的回收利用方法 |
CN108128776A (zh) * | 2017-04-14 | 2018-06-08 | 阳城县瑞兴化工有限公司 | 一种以煤层气为原料合成二硫化碳的方法 |
CN109095468A (zh) * | 2017-12-27 | 2018-12-28 | 山西铁峰化工有限公司 | 一种以硫化氢为原料制备二硫化碳的方法 |
CN112239208A (zh) * | 2020-12-09 | 2021-01-19 | 吉林三源化工有限公司 | 二硫化碳生产系统 |
CN112408392A (zh) * | 2020-12-09 | 2021-02-26 | 吉林三源化工有限公司 | 二硫化碳储运系统 |
CN112408392B (zh) * | 2020-12-09 | 2023-04-25 | 吉林三源化工有限公司 | 二硫化碳储运系统 |
CN113428861A (zh) * | 2021-07-19 | 2021-09-24 | 华东理工大学 | 一种甲烷与硫化氢重整制氢工艺 |
CN113428861B (zh) * | 2021-07-19 | 2024-01-02 | 华东理工大学 | 一种甲烷与硫化氢重整制氢工艺 |
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