CN102140151B - 制备均一的聚合物珠粒的方法 - Google Patents
制备均一的聚合物珠粒的方法 Download PDFInfo
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- CN102140151B CN102140151B CN201010624713.7A CN201010624713A CN102140151B CN 102140151 B CN102140151 B CN 102140151B CN 201010624713 A CN201010624713 A CN 201010624713A CN 102140151 B CN102140151 B CN 102140151B
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- Prior art keywords
- monomer
- polymer beads
- stablizer
- emulsifying agent
- emulsion
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- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical group C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- 239000004160 Ammonium persulphate Substances 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- UKMBKKFLJMFCSA-UHFFFAOYSA-N [3-hydroxy-2-(2-methylprop-2-enoyloxy)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(CO)OC(=O)C(C)=C UKMBKKFLJMFCSA-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000001042 affinity chromatography Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- 235000019395 ammonium persulphate Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 description 1
- 229940043232 butyl acetate Drugs 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 150000001983 dialkylethers Chemical class 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- VIKNJXKGJWUCNN-XGXHKTLJSA-N norethisterone Chemical compound O=C1CC[C@@H]2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1 VIKNJXKGJWUCNN-XGXHKTLJSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 238000010532 solid phase synthesis reaction Methods 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US33501309P | 2009-12-30 | 2009-12-30 | |
| US61/335,013 | 2009-12-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102140151A CN102140151A (zh) | 2011-08-03 |
| CN102140151B true CN102140151B (zh) | 2015-01-14 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201010624713.7A Expired - Fee Related CN102140151B (zh) | 2009-12-30 | 2010-12-29 | 制备均一的聚合物珠粒的方法 |
Country Status (5)
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| US (1) | US20110160328A1 (enExample) |
| EP (1) | EP2341081A1 (enExample) |
| JP (2) | JP5483451B2 (enExample) |
| KR (1) | KR101223272B1 (enExample) |
| CN (1) | CN102140151B (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2557661B1 (en) | 2011-08-10 | 2020-03-11 | LG Innotek Co., Ltd. | Rotor core of motor |
| RU2723949C2 (ru) * | 2015-07-31 | 2020-06-18 | Ром Энд Хаас Компани | Олигомерная затравка для синтеза унимодальных акриловых гранулированных частиц |
| JP6886467B2 (ja) * | 2015-12-22 | 2021-06-16 | ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ | 水性媒体中に分散された液滴 |
| US10988558B2 (en) | 2016-11-08 | 2021-04-27 | DDP Specialty Electronic Materials US, Inc. | Controlled particle size distribution |
| KR102858687B1 (ko) * | 2017-11-10 | 2025-09-12 | 디디피 스페셜티 일렉트로닉 머티리얼즈 유에스, 엘엘씨 | 성분 첨가 중합 |
| KR102105479B1 (ko) * | 2018-09-05 | 2020-04-28 | (주)지엘테크 | 광학장치 흡착판용 다공플레이트 및 이를 포함하는 광학장치용 흡착판 |
| US12436080B2 (en) | 2020-02-24 | 2025-10-07 | Corning Incorporated | Calibration set including nanoparticles of nylon-6 and dyes |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1059913A (zh) * | 1990-03-22 | 1992-04-01 | 罗姆和哈斯公司 | 粒度可均匀控制在1到50微米范围的颗粒的制造方法 |
| CN1582314A (zh) * | 2001-11-02 | 2005-02-16 | 三洋化成工业株式会社 | 复合树脂粒子 |
| CN1935851A (zh) * | 2005-09-16 | 2007-03-28 | 罗门哈斯公司 | 可溶胀颗粒 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3922255A (en) * | 1972-05-15 | 1975-11-25 | Rohm & Haas | Method of producing uniform polymer beads |
| CA1166413A (en) * | 1980-10-30 | 1984-05-01 | Edward E. Timm | Process and apparatus for preparing uniform size polymer beads |
| US4623706A (en) * | 1984-08-23 | 1986-11-18 | The Dow Chemical Company | Process for preparing uniformly sized polymer particles by suspension polymerization of vibratorily excited monomers in a gaseous or liquid stream |
| US5231115A (en) * | 1991-12-19 | 1993-07-27 | The Dow Chemical Company | Seeded porous copolymers and ion-exchange resins prepared therefrom |
| US5835174A (en) * | 1995-10-12 | 1998-11-10 | Rohm And Haas Company | Droplets and particles containing liquid crystal and films and apparatus containing the same |
| GB9721603D0 (en) * | 1997-10-10 | 1997-12-10 | Dyno Ind Asa | Method |
| EP1177231B1 (en) | 1999-04-09 | 2009-08-19 | Invitrogen Dynal AS | Process for the preparation of monodisperse polymer particles |
| GB9908163D0 (en) * | 1999-04-09 | 1999-06-02 | Dyno Ind Asa | Process |
| JP4779186B2 (ja) * | 1999-04-23 | 2011-09-28 | 東ソー株式会社 | 粒径単分散粒子、その製造方法及びそれを用いた用途 |
| US7098252B2 (en) * | 2002-04-01 | 2006-08-29 | Rohm And Haas Company | Preparation of macroreticular polymers |
| US20060052529A1 (en) * | 2003-02-07 | 2006-03-09 | Surface Specialties S.A. | Aqueous polymer dispersion and process |
| DE602005025268D1 (de) * | 2004-02-24 | 2011-01-27 | Rohm & Haas | Verfahren zur Entfernung von Arsen aus Wasser |
| KR101400322B1 (ko) * | 2007-11-02 | 2014-05-28 | 코오롱인더스트리 주식회사 | 단분산 입자 및 그의 제조 방법 |
-
2010
- 2010-12-03 JP JP2010270350A patent/JP5483451B2/ja not_active Expired - Fee Related
- 2010-12-08 EP EP10194230A patent/EP2341081A1/en not_active Withdrawn
- 2010-12-29 KR KR1020100137683A patent/KR101223272B1/ko not_active Expired - Fee Related
- 2010-12-29 US US12/980,595 patent/US20110160328A1/en not_active Abandoned
- 2010-12-29 CN CN201010624713.7A patent/CN102140151B/zh not_active Expired - Fee Related
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2014
- 2014-01-14 JP JP2014004595A patent/JP2014098158A/ja not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1059913A (zh) * | 1990-03-22 | 1992-04-01 | 罗姆和哈斯公司 | 粒度可均匀控制在1到50微米范围的颗粒的制造方法 |
| CN1582314A (zh) * | 2001-11-02 | 2005-02-16 | 三洋化成工业株式会社 | 复合树脂粒子 |
| CN1935851A (zh) * | 2005-09-16 | 2007-03-28 | 罗门哈斯公司 | 可溶胀颗粒 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102140151A (zh) | 2011-08-03 |
| JP2014098158A (ja) | 2014-05-29 |
| KR20110079538A (ko) | 2011-07-07 |
| US20110160328A1 (en) | 2011-06-30 |
| JP2011137147A (ja) | 2011-07-14 |
| JP5483451B2 (ja) | 2014-05-07 |
| KR101223272B1 (ko) | 2013-01-18 |
| EP2341081A1 (en) | 2011-07-06 |
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