CN102134410B - A kind of high-performance water-based anticorrosion paint and preparation method thereof - Google Patents
A kind of high-performance water-based anticorrosion paint and preparation method thereof Download PDFInfo
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- CN102134410B CN102134410B CN201010108989.XA CN201010108989A CN102134410B CN 102134410 B CN102134410 B CN 102134410B CN 201010108989 A CN201010108989 A CN 201010108989A CN 102134410 B CN102134410 B CN 102134410B
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- Prior art keywords
- acid
- silane
- oxide
- sodium
- phosphate
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 56
- 239000003973 paint Substances 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- 229920000767 polyaniline Polymers 0.000 claims abstract description 61
- 239000000463 material Substances 0.000 claims abstract description 40
- 239000002114 nanocomposite Substances 0.000 claims abstract description 33
- 239000011347 resin Substances 0.000 claims abstract description 30
- 229920005989 resin Polymers 0.000 claims abstract description 30
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- 239000006185 dispersion Substances 0.000 claims abstract description 21
- 229910010272 inorganic material Inorganic materials 0.000 claims abstract description 10
- 239000011147 inorganic material Substances 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 7
- 239000013530 defoamer Substances 0.000 claims abstract description 5
- 230000008569 process Effects 0.000 claims abstract description 4
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 44
- 239000012065 filter cake Substances 0.000 claims description 26
- 238000006243 chemical reaction Methods 0.000 claims description 23
- 238000003756 stirring Methods 0.000 claims description 21
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 20
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical group [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 18
- 239000000243 solution Substances 0.000 claims description 18
- 239000002253 acid Substances 0.000 claims description 17
- RGPUVZXXZFNFBF-UHFFFAOYSA-K diphosphonooxyalumanyl dihydrogen phosphate Chemical compound [Al+3].OP(O)([O-])=O.OP(O)([O-])=O.OP(O)([O-])=O RGPUVZXXZFNFBF-UHFFFAOYSA-K 0.000 claims description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- 239000002086 nanomaterial Substances 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 13
- 239000007864 aqueous solution Substances 0.000 claims description 13
- 229920000876 geopolymer Polymers 0.000 claims description 12
- 229920002545 silicone oil Polymers 0.000 claims description 12
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 10
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 10
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 10
- 239000000706 filtrate Substances 0.000 claims description 10
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 10
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 10
- 238000000967 suction filtration Methods 0.000 claims description 10
- 238000005406 washing Methods 0.000 claims description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 9
- 239000002041 carbon nanotube Substances 0.000 claims description 9
- 239000003921 oil Substances 0.000 claims description 9
- 235000019353 potassium silicate Nutrition 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 8
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 8
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 8
- JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 claims description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 7
- ZTFZSHLWORMEHO-UHFFFAOYSA-A pentaaluminum;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O ZTFZSHLWORMEHO-UHFFFAOYSA-A 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- 239000001488 sodium phosphate Substances 0.000 claims description 7
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 7
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- -1 Vltra tears Polymers 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 150000003016 phosphoric acids Chemical class 0.000 claims description 6
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 6
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 6
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 6
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 6
- 239000004111 Potassium silicate Substances 0.000 claims description 5
- 229920002125 Sokalan® Polymers 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 5
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 5
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 239000004584 polyacrylic acid Substances 0.000 claims description 5
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims description 5
- 229910052913 potassium silicate Inorganic materials 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000011787 zinc oxide Substances 0.000 claims description 5
- 239000005995 Aluminium silicate Substances 0.000 claims description 4
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 4
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 claims description 4
- 239000012190 activator Substances 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 4
- 229960000892 attapulgite Drugs 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 4
- 229910001701 hydrotalcite Inorganic materials 0.000 claims description 4
- 229960001545 hydrotalcite Drugs 0.000 claims description 4
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 4
- 229910052900 illite Inorganic materials 0.000 claims description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- 235000015110 jellies Nutrition 0.000 claims description 4
- 239000008274 jelly Substances 0.000 claims description 4
- 239000010445 mica Substances 0.000 claims description 4
- 229910052618 mica group Inorganic materials 0.000 claims description 4
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 claims description 4
- RZJRJXONCZWCBN-UHFFFAOYSA-N octadecane Chemical compound CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 claims description 4
- 239000007800 oxidant agent Substances 0.000 claims description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 4
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 4
- 229910052625 palygorskite Inorganic materials 0.000 claims description 4
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 4
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 4
- 229920000058 polyacrylate Polymers 0.000 claims description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims description 4
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 4
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 4
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 4
- 235000011008 sodium phosphates Nutrition 0.000 claims description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 4
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 4
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 4
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 4
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims description 4
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims description 4
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 3
- YCPXWRQRBFJBPZ-UHFFFAOYSA-N 5-sulfosalicylic acid Chemical compound OC(=O)C1=CC(S(O)(=O)=O)=CC=C1O YCPXWRQRBFJBPZ-UHFFFAOYSA-N 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 239000010881 fly ash Substances 0.000 claims description 3
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims description 3
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 3
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 3
- OWUTVCVPEOXXHD-UHFFFAOYSA-N trimethoxy(prop-1-enyl)silane Chemical compound CO[Si](OC)(OC)C=CC OWUTVCVPEOXXHD-UHFFFAOYSA-N 0.000 claims description 3
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 3
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 3
- MIOPJNTWMNEORI-GMSGAONNSA-N (S)-camphorsulfonic acid Chemical compound C1C[C@@]2(CS(O)(=O)=O)C(=O)C[C@@H]1C2(C)C MIOPJNTWMNEORI-GMSGAONNSA-N 0.000 claims description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- DCQBZYNUSLHVJC-UHFFFAOYSA-N 3-triethoxysilylpropane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CCCS DCQBZYNUSLHVJC-UHFFFAOYSA-N 0.000 claims description 2
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 claims description 2
- 239000004160 Ammonium persulphate Substances 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 2
- AGUIILSGLFUTKG-UHFFFAOYSA-N CC(C)O.CC(C)O.CC(C)O.C=C[SiH3] Chemical compound CC(C)O.CC(C)O.CC(C)O.C=C[SiH3] AGUIILSGLFUTKG-UHFFFAOYSA-N 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 claims description 2
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims description 2
- 102000016397 Methyltransferase Human genes 0.000 claims description 2
- 108060004795 Methyltransferase Proteins 0.000 claims description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- CIVKKLRUDDHREQ-UHFFFAOYSA-N SC(CC[Si](OC)(OC)C)O Chemical compound SC(CC[Si](OC)(OC)C)O CIVKKLRUDDHREQ-UHFFFAOYSA-N 0.000 claims description 2
- WGKSJIPIXCVOON-UHFFFAOYSA-N SC(CC[Si](OCC)(OCC)C)O Chemical compound SC(CC[Si](OCC)(OCC)C)O WGKSJIPIXCVOON-UHFFFAOYSA-N 0.000 claims description 2
- 239000004113 Sepiolite Substances 0.000 claims description 2
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 2
- 229910021536 Zeolite Inorganic materials 0.000 claims description 2
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 claims description 2
- DBVZGGCAXLPUJM-UHFFFAOYSA-N [SiH4].C(CCCCCCC)[N+](C)(C)C Chemical compound [SiH4].C(CCCCCCC)[N+](C)(C)C DBVZGGCAXLPUJM-UHFFFAOYSA-N 0.000 claims description 2
- 229940115440 aluminum sodium silicate Drugs 0.000 claims description 2
- SXQXMCWCWVCFPC-UHFFFAOYSA-N aluminum;potassium;dioxido(oxo)silane Chemical compound [Al+3].[K+].[O-][Si]([O-])=O.[O-][Si]([O-])=O SXQXMCWCWVCFPC-UHFFFAOYSA-N 0.000 claims description 2
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 2
- SJKRCWUQJZIWQB-UHFFFAOYSA-N azane;chromium Chemical compound N.[Cr] SJKRCWUQJZIWQB-UHFFFAOYSA-N 0.000 claims description 2
- BEHLMOQXOSLGHN-UHFFFAOYSA-N benzenamine sulfate Chemical compound OS(=O)(=O)NC1=CC=CC=C1 BEHLMOQXOSLGHN-UHFFFAOYSA-N 0.000 claims description 2
- SXPLZNMUBFBFIA-UHFFFAOYSA-N butyl(trimethoxy)silane Chemical compound CCCC[Si](OC)(OC)OC SXPLZNMUBFBFIA-UHFFFAOYSA-N 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 239000001506 calcium phosphate Chemical group 0.000 claims description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 2
- 235000011010 calcium phosphates Nutrition 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- 239000004568 cement Substances 0.000 claims description 2
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 2
- 239000003818 cinder Substances 0.000 claims description 2
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 claims description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 2
- UMWWGWXBKUMWDH-UHFFFAOYSA-L disodium silicic acid carbonate Chemical compound C([O-])([O-])=O.[Na+].[Si](O)(O)(O)O.[Na+] UMWWGWXBKUMWDH-UHFFFAOYSA-L 0.000 claims description 2
- SCPWMSBAGXEGPW-UHFFFAOYSA-N dodecyl(trimethoxy)silane Chemical compound CCCCCCCCCCCC[Si](OC)(OC)OC SCPWMSBAGXEGPW-UHFFFAOYSA-N 0.000 claims description 2
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 2
- JEWCZPTVOYXPGG-UHFFFAOYSA-N ethenyl-ethoxy-dimethylsilane Chemical compound CCO[Si](C)(C)C=C JEWCZPTVOYXPGG-UHFFFAOYSA-N 0.000 claims description 2
- CJMZLCRLBNZJQR-UHFFFAOYSA-N ethyl 2-amino-4-(4-fluorophenyl)thiophene-3-carboxylate Chemical compound CCOC(=O)C1=C(N)SC=C1C1=CC=C(F)C=C1 CJMZLCRLBNZJQR-UHFFFAOYSA-N 0.000 claims description 2
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 claims description 2
- XLXGCFTYXICXJF-UHFFFAOYSA-N ethylsilicon Chemical compound CC[Si] XLXGCFTYXICXJF-UHFFFAOYSA-N 0.000 claims description 2
- 239000010433 feldspar Substances 0.000 claims description 2
- 229910021389 graphene Inorganic materials 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- RSKGMYDENCAJEN-UHFFFAOYSA-N hexadecyl(trimethoxy)silane Chemical compound CCCCCCCCCCCCCCCC[Si](OC)(OC)OC RSKGMYDENCAJEN-UHFFFAOYSA-N 0.000 claims description 2
- CZWLNMOIEMTDJY-UHFFFAOYSA-N hexyl(trimethoxy)silane Chemical compound CCCCCC[Si](OC)(OC)OC CZWLNMOIEMTDJY-UHFFFAOYSA-N 0.000 claims description 2
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims description 2
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims description 2
- 229910000398 iron phosphate Inorganic materials 0.000 claims description 2
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical group [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims description 2
- 229940045641 monobasic sodium phosphate Drugs 0.000 claims description 2
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims description 2
- 229940038384 octadecane Drugs 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 2
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims description 2
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims description 2
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 2
- 235000015320 potassium carbonate Nutrition 0.000 claims description 2
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 claims description 2
- 235000011118 potassium hydroxide Nutrition 0.000 claims description 2
- 229910000160 potassium phosphate Inorganic materials 0.000 claims description 2
- 229940093916 potassium phosphate Drugs 0.000 claims description 2
- 235000011009 potassium phosphates Nutrition 0.000 claims description 2
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 2
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 2
- 235000011151 potassium sulphates Nutrition 0.000 claims description 2
- 229910052903 pyrophyllite Inorganic materials 0.000 claims description 2
- 239000010453 quartz Substances 0.000 claims description 2
- 229910052624 sepiolite Inorganic materials 0.000 claims description 2
- 235000019355 sepiolite Nutrition 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 2
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 2
- 239000002893 slag Substances 0.000 claims description 2
- 239000000429 sodium aluminium silicate Substances 0.000 claims description 2
- 235000012217 sodium aluminium silicate Nutrition 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- 235000017550 sodium carbonate Nutrition 0.000 claims description 2
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 2
- 239000011775 sodium fluoride Substances 0.000 claims description 2
- 235000013024 sodium fluoride Nutrition 0.000 claims description 2
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 2
- 235000019830 sodium polyphosphate Nutrition 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- 239000004575 stone Substances 0.000 claims description 2
- CCEKAJIANROZEO-UHFFFAOYSA-N sulfluramid Chemical group CCNS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F CCEKAJIANROZEO-UHFFFAOYSA-N 0.000 claims description 2
- 229940095064 tartrate Drugs 0.000 claims description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical group [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 2
- ALVYUZIFSCKIFP-UHFFFAOYSA-N triethoxy(2-methylpropyl)silane Chemical compound CCO[Si](CC(C)C)(OCC)OCC ALVYUZIFSCKIFP-UHFFFAOYSA-N 0.000 claims description 2
- HXOGQBSDPSMHJK-UHFFFAOYSA-N triethoxy(6-methylheptyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCCCC(C)C HXOGQBSDPSMHJK-UHFFFAOYSA-N 0.000 claims description 2
- DENFJSAFJTVPJR-UHFFFAOYSA-N triethoxy(ethyl)silane Chemical compound CCO[Si](CC)(OCC)OCC DENFJSAFJTVPJR-UHFFFAOYSA-N 0.000 claims description 2
- WUMSTCDLAYQDNO-UHFFFAOYSA-N triethoxy(hexyl)silane Chemical compound CCCCCC[Si](OCC)(OCC)OCC WUMSTCDLAYQDNO-UHFFFAOYSA-N 0.000 claims description 2
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims description 2
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 claims description 2
- BJDLPDPRMYAOCM-UHFFFAOYSA-N triethoxy(propan-2-yl)silane Chemical compound CCO[Si](OCC)(OCC)C(C)C BJDLPDPRMYAOCM-UHFFFAOYSA-N 0.000 claims description 2
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 claims description 2
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 claims description 2
- LGROXJWYRXANBB-UHFFFAOYSA-N trimethoxy(propan-2-yl)silane Chemical compound CO[Si](OC)(OC)C(C)C LGROXJWYRXANBB-UHFFFAOYSA-N 0.000 claims description 2
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 claims description 2
- 229910001930 tungsten oxide Inorganic materials 0.000 claims description 2
- 229910001935 vanadium oxide Inorganic materials 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 229910052882 wollastonite Inorganic materials 0.000 claims description 2
- 239000010456 wollastonite Substances 0.000 claims description 2
- 239000010457 zeolite Substances 0.000 claims description 2
- 239000011259 mixed solution Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 35
- 239000011248 coating agent Substances 0.000 abstract description 33
- 238000005260 corrosion Methods 0.000 abstract description 7
- 230000007797 corrosion Effects 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 239000003960 organic solvent Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 230000002265 prevention Effects 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 8
- 239000008367 deionised water Substances 0.000 description 8
- 229910021641 deionized water Inorganic materials 0.000 description 8
- 239000011159 matrix material Substances 0.000 description 8
- 239000004576 sand Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 230000003628 erosive effect Effects 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 239000011260 aqueous acid Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 231100001010 corrosive Toxicity 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000007908 nanoemulsion Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000002161 passivation Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 description 1
- 229910052912 lithium silicate Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- 238000006396 nitration reaction Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- AXJAWMUPFHKOHY-UHFFFAOYSA-N trimethyl(octadecyl)silane Chemical compound CCCCCCCCCCCCCCCCCC[Si](C)(C)C AXJAWMUPFHKOHY-UHFFFAOYSA-N 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of preparation method of high-performance water-based anticorrosion paint, comprise inorganic materials resin 30 ~ 60 parts, polyaniline nano composite material 0.5 ~ 30 part, 0 ~ 30 part, solidifying agent, defoamer 0.1 ~ 1 part, dispersion agent 0.1 ~ 1 part, flow agent 0.1 ~ 1 part.This coating is not because of containing organic resin and organic solvent, thus heat-resisting, wear-resisting, weather-proof, oil resistant, fire prevention, environmental protection; This coating manufacture process is simple, normal temperature solidified, strong with metallic cohesion, and with low cost, can be widely used in the protection against corrosion field of aviation, navigation, chemical industry, electronics etc.
Description
Technical field
The present invention relates to the preparation field in watery anti-corrosion paint field, specifically, relate to a kind of using polyaniline nano composite material as anticorrosive agent, using inorganic materials as the preparation method of the high-performance water-based anticorrosion paint of matrix resin.
Background technology
According to statistics, the hardware scrapped due to corrosion every year and material are equivalent to 1/3 of metal annual production, and the loss caused is very huge, and therefore the research of anticorrosive coating is an important topic of metal protection and coatings industry always.Conventional coatings is due to the restriction by own material character and technique, often undesirable to the corrosion prevention effect of metallic matrix, and have quite a few coating because of toxic substances such as leaded or chromic salt, in preparation and construction process, there is the danger of environmental pollution, the requirement of this and Sustainable Socioeconomic Development strategy is incompatible.Therefore, development of new highly corrosion resistant coated material and Green synthesis technology thereof become one of pursuing a goal of metal corrosion and protection field.
Polyaniline have structure diversification, environmental stability good, synthesize simple and easy, the advantage such as monomer is with low cost, excellent physical properties, particularly it has unique Protonic Acid Doping Mechanism and excellent conductivity, is considered to most one of conductive polymers having actual application prospect.Since DeBerry finds that polyaniline has protective effect so far to ferrous metals, the anticorrosion mechanism of existing large quantity research report polyaniline and preservative effect, so polyaniline becomes again one of anticorrosive agent having most application future.The anticorrosion mechanism of polyaniline coating mainly contains: 1. formed coating has completely cut off the contact of air, corrosives and metal base; 2. polyaniline can make the electrochemical corrosion potential of metal base shuffle and reach the electropotential of precious metal; 3. the polyaniline zone of oxidation that corresponding formation is form compact and stable to metal base generation passivation; 4. can also there is as shown in the figure with metal similar interaction in polyaniline, and this makes polyaniline under the condition of little consumption, can reach good anticorrosion ability, demonstrate good catalysis characteristics; 5. the maintenance of polyaniline conductivity in matrix resin, can also make whole coating can play passivation to any exposed metallic region.
But polyaniline comprehensive mechanical property is poor, solvability and meltability extreme difference and the bad shortcoming of rheological property make it be difficult to adopt the method for traditional forming process, this just seriously hampers its large-scale promotion application in every field.Therefore, the processing characteristics how improving polyaniline is the key promoting that polyaniline is practical.People have carried out unremitting effort for this reason, find that the composite modification technology of polyaniline and nano material can overcome the shortcoming of its poor in processability, and obtaining the nano composite material with several functions, these functional materialss can be widely used in the fields such as conductance, magnetic conductance, electricity display, electrostatic shielding, microwave absorbing, anti-corrosion of metal, photochemical catalysis and sensing.
In the preparation of polyaniline anticorrosion paint, substantially using organic resin as filmogen, the feature that ubiquity coating is high temperature resistant, wear resistance, fire prevention, weather-proof, resistance to wet goods performance are not good, thus can not find application in exceedingly odious corrosive environment.Such as, Chinese patent ZL01138153.1 proposes epoxy resin and polyaniline, mixing diluents, after grinding again with phenolic aldehyde amine, polymeric amide, mixing diluents evenly, obtain polyaniline anticorrosion paint, this patent makees thinner with organic solvent, to the pollution of environment and the injury of human body larger; Chinese patent CN101407650A proposes oligomer, reactive thinner, polyaniline, filler, light trigger, auxiliary agent to carry out blended, through stirring, grinding, filtration etc., obtain UV curing polyaniline anticorrosive coating, the solidification of this patent gained coating is limited to the penetration depth of UV-light, easy solidification is incomplete, thus causes coating performance not good; Chinese patent CN101418146A proposition oligomer, reactive thinner, polyurethane polyol, polyaniline, filler, light trigger and auxiliary agent obtain ultraviolet-heat dual curing polyaniline anticorrosion paint, this patent improves the performance of coating, but thinner is still organic solvent, is unfavorable for environmental protection.
Compared with the film formed with organic resin, the film that inorganic materials resin is formed has preferably flame retardant resistance, thermotolerance, weathering resistance, erosion resistance, insulativity, heat insulating ability, wear resistance etc.And different fillers is used in inorganic materials resin, film can be made to have antirust, protection against corrosion, conduction, anti-electrostatic, resistance to high temperature oxidation, absorption ultraviolet, thermoemitting, store light, antibacterial, antisweat, the various different specific function such as deodorizing, be satisfied with the particular requirement of the industries such as aerospace, electronics, information.At present, have not been reported using polyaniline nano composite material as anticorrosive agent, using inorganic materials as the preparation method of the high-performance water-based anticorrosion paint of matrix resin.
Summary of the invention
The object of this invention is to provide a kind of preparation method of high-performance water-based anticorrosion paint, the high-performance water-based anticorrosion paint that the method is prepared have high temperature resistant, wear-resistant, fire-retardant, oil resistant, weather-proof, can solidify at normal temperatures, heavy metal content is low, Diamond Search, the advantage such as with low cost.
The object of the invention is to be realized by following manner.
1. a high-performance water-based anticorrosion paint, is characterized in that comprising inorganic materials resin 30 ~ 60 parts, polyaniline nano composite material 0.5 ~ 30 part, 0 ~ 30 part, solidifying agent, defoamer 0.1 ~ 1 part, dispersion agent 0.1 ~ 1 part, flow agent 0.1 ~ 1 part.
Described inorganic materials resin is one or more in phosphoric acid salt, silicate, geopolymer, silicon sol, tetraethyl silicate.
In phosphoric acid salt resin, conventional has aluminium dihydrogen phosphate, its preparation method is: the phosphoric acid of 40 ~ 70 parts, the aluminium hydroxide of 10 ~ 30 parts, the water mix and blend of 20 ~ 30 parts are placed in 80 ~ 100 DEG C and react 1 ~ 4h, after cooling, water use regulation solution density is 1.1 ~ 1.6g/cm
3, obtain aluminium dihydrogen phosphate resin.Wherein, the mass percent concentration of phosphoric acid is 85%.
The preparation method of geopolymer resin is: be dissolved in by the alkali-activator of 10 ~ 50 parts in the water of 10 ~ 100 parts, forms solution, then joins in solution by the silica-alumina material of 50 ~ 80 parts, be stirred to formation jelly, obtain geopolymer.Wherein, alkali-activator is one or more in sodium hydroxide, potassium hydroxide, sodium carbonate, salt of wormwood, sodium sulfate, potassium sulfate, sodium phosphate, potassiumphosphate, Sodium Fluoride, Potassium monofluoride, water glass, potassium silicate, sodium aluminium silicate, aluminum potassium silicate, silicic acid sodium carbonate; Silica-alumina material is one or more in kaolin, metakaolin, flyash, slag, cinder, volcano float stone, montmorillonite, attapulgite, diatomite, mica, hydrotalcite, illite, pyrophyllite, zeolite, quartz, feldspar.
The preparation process of described polyaniline nano composite material is: nano material be distributed in water and form nano material dispersion liquid, then in nano material dispersion liquid, aniline and protonic acid aqueous solution is added respectively, stir, aqueous oxidizing agent solution is added at temperature of reaction is 0 ~ 50 DEG C, continuous stirring, after reaction 1 ~ 24h, through suction filtration, and washing is colourless to filtrate, gained filter cake is polyaniline nano composite material.Wherein, the mass ratio of nano material and water is 10 ~ 30: 100, the mass ratio of aniline and nano material is 0.3 ~ 1: 1, the mol ratio of protonic acid and aniline is 0.15 ~ 11.68: 1, the concentration of protonic acid is 1.0 ~ 4.0mol/L, the mol ratio of oxygenant and aniline is 0.8 ~ 1.2: 1, and the volumetric molar concentration of oxidizing agent solution is 0.8 ~ 1.2mol/L, nano material is titanium oxide, silicon oxide, zinc oxide, cerium oxide, zirconium white, stannic oxide, ferric oxide, manganese oxide, vanadium oxide, nickel oxide, molybdenum oxide, Tungsten oxide 99.999, yttrium oxide, titanium phosphate, tertiary iron phosphate, calcium phosphate, tripolyphosphate calcium, aluminium triphosphate, barium sulfate, calcium sulfate, graphite, carbon black, carbon nanotube, Graphene, attapulgite, montmorillonite, kaolin, diatomite, wollastonite, mica, hydrotalcite, illite, sepiolite, chromium nitride, silicon nitride, silicon carbide, polystyrene, one in polymethylmethacrylate, aniline is the aniline of aniline or replacement, protonic acid is one or more in p-methyl benzenesulfonic acid, camphorsulfonic acid, sulphosalicylic acid, Witco 1298 Soft Acid, naphthene sulfonic acid, dinonylnaphthalene sulfonic acid, polystyrolsulfon acid, thionamic acid, aniline sulfonic acid, oxalic acid, citric acid, tartrate, hydrochloric acid, sulfuric acid, nitric acid, perchloric acid and phosphoric acid, oxygenant is ammonium persulphate.
The solidifying agent of described aluminium dihydrogen phosphate be magnesium oxide, zinc oxide, aluminum oxide, ferric oxide, zirconium white, phosphoric acid salt, high-alumina cement one or more, wherein phosphoric acid salt comprises sodium phosphate, SODIUM PHOSPHATE, MONOBASIC, tripoly phosphate sodium STPP, sodium polyphosphate; The solidifying agent of described geopolymer is silicofluoride.
Described defoamer is one or more in tributyl phosphate, silicone oil, and wherein silicone oil comprises methyl-silicone oil, ethyl silicon oil, dimethyl silicone oil, hydrophilic silicon oil, described dispersion agent is one or more in tripoly phosphate sodium STPP, trisodium phosphate, Sodium hexametaphosphate 99, hydroxylated cellulose class, polyacrylate, BYK163, wherein hydroxylated cellulose comprises Walocel MT 20.000PV, Natvosol, hydroxypropylcellulose, hydroxyethylmethyl-cellulose, Vltra tears, and polyacrylate comprises sodium polyacrylate, polyacrylic acid potassium, described flow agent is silane coupling agent, polyacrylic, one or more in BYK371, wherein silane coupling agent is organoalkoxysilane, comprises methyltrimethoxy silane, Union carbide A-162, ethyl trimethoxy silane, ethyl triethoxysilane, n-propyl Trimethoxy silane, n-propyl triethoxyl silane, isopropyltri-methoxysilane, isopro-pyltriethoxysilane, n-butyltrimethoxysilane, ne-butyltriethoxysilaneand, n-hexyl Trimethoxy silane, trimethoxysilane, isobutyl triethoxy silane, n-hexyl triethoxyl silane, n-octyltrimethylammonium silane, n-octytriethoxysilane, isooctyltrimethoxysi,ane, isooctyltriethoxysilane, dodecyl Trimethoxy silane, n-hexadecyl Trimethoxy silane, Octadecane base Trimethoxy silane, phenyl triethoxysilane, dimethoxydiphenylsilane, vinyltrimethoxy silane, vinyltriacetoxy silane, vinyl dimethylethoxysilane, vinyl silane triisopropoxide, vinyltriacetoxy silane, propenyl Trimethoxy silane, vinyl three ('beta '-methoxy oxyethyl group) silane, γ-(methacryloxy) propyl trimethoxy silicane, γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-mercaptopropyl trimethoxysilane, gamma-mercaptopropyltriethoxysilane, α-thiopurine methyltransferase triethoxyl silane, γ-mercapto hydroxypropyl methyl dimethoxysilane, γ-mercapto hydroxypropyl methyl diethoxy silane, two-[γ-(triethoxysilicane) propyl group] disulphide, two-[γ-(triethoxysilicane) propyl group] tetrasulfide, methacryloxypropyl trimethoxy silane, polyacrylic comprises polyacrylic acid, polymethyl acrylic acid.
The invention has the beneficial effects as follows:
1. the high-performance water-based anticorrosion paint of gained of the present invention is not containing organic solvent, Diamond Search, and heavy metal content is low, is a kind of coating of environmental protection.
2. the high-performance water-based anticorrosion paint of gained of the present invention is not containing organic resin, and film forming matter is inorganic materials resin, has preferably thermotolerance, weathering resistance, wear resistance and oil-proofness.
3. the high-performance water-based anticorrosion paint of gained of the present invention is with polyaniline nano composite material for anticorrosive agent, improves the mechanical property of pure polyaniline on the one hand, thus improves the mechanical property of polyaniline coating; Give polyaniline nano composite material on the other hand with the performance of nano material, thus give polyaniline coating with new performance.
4. the high-performance water-based anticorrosion paint of gained of the present invention can solidify at normal temperatures, and with low cost, can use by heavy industrialization.
Accompanying drawing explanation
The invention will be further described in conjunction with the accompanying drawings and embodiments.
Fig. 1 polyaniline is to the katalysis figure of metal
The performance test table of table 1 film
Embodiment
High-performance water-based anticorrosion paint is coated on the metal foil of polishing, oil removing, rust cleaning by the present invention, after ambient cure, and testing coating performance.The sticking power of coating is measured according to GB1720-79 (89), according to the hardness of GB6739/86 testing coating, painting is placed in 950 DEG C and calcines the rate of weight loss after 2h to investigate the resistance to elevated temperatures of coating, adopt the wear resistance of NormanRCA wear-resistant tester (load 175g) testing coating, according to the salt spray resistance of GB1771/91 testing coating.
Embodiment 1:
10.00g nano-titanium oxide is distributed in 100.00g deionized water and forms nano-titanium oxide dispersion liquid, then in nano-titanium oxide dispersion liquid, 3.00g (0.03226mol) aniline and 95.80ml4.0mol/L aqueous hydrochloric acid is added respectively, stir, 32.30ml1.2mol/L ammonium persulfate aqueous solution is added at temperature of reaction is 0 DEG C, continuous stirring, after reaction 24h, through suction filtration, and washing is colourless to filtrate, obtains titanium oxide/polyaniline nano-composite material filter cake.
Get 70.00g mass percent concentration be 85% phosphoric acid, the aluminium hydroxide of 30.00g, the water of 20.00g be placed in 100 DEG C of mix and blends reaction 1h, after cooling, water use regulation solution density is 1.10g/cm
3, obtain aluminium dihydrogen phosphate resin.
By 60.00g aluminium dihydrogen phosphate resin, 30.00g titanium oxide/polyaniline nano-composite material filter cake, 1.00g Sodium hexametaphosphate 99,2h is mixed under homogenizer, add 30.00g zirconium white, 1.00g tributyl phosphate, 1.00g γ-methacryloxy Trimethoxy silane afterwards, continue to mix 4h under homogenizer, obtain high-performance water-based anticorrosion paint.
Comparative example 1:
In the preparation process of embodiment 1 coating, do not add titanium oxide/polyaniline nano-composite material filter cake, obtain aqueous inorganic paint.
Embodiment 2:
10.00g nano zircite is distributed in 33.30g deionized water and forms nano zircite dispersion liquid, then in nano zircite dispersion liquid, 10.00g (0.10753mol) aniline and 16.13ml1.0mol/L sulfosalisylic aqueous acid is added respectively, stir, 107.53ml0.8mol/L ammonium persulfate aqueous solution is added at temperature of reaction is 50 DEG C, continuous stirring, after reaction 1h, through suction filtration, and washing is colourless to filtrate, obtains zirconium white/polyaniline nano-composite material filter cake.
The water glass of 40.00g and the sodium hydroxide of 10.00g are dissolved in the water of 100g, form solution, then the metakaolin of 80g is joined in solution, be stirred to formation jelly, obtain geopolymer.
By 30.00g geopolymer, 0.50g zirconium white/polyaniline nano-composite material filter cake, 0.10g Walocel MT 20.000PV, 0.5h is uniformly mixed under sand mill, add 10.00g fluorine silication potassium, 0.10g silicone oil, 0.10g methyltrimethoxy silane afterwards, continue to be uniformly mixed 1h under sand mill, obtain high-performance water-based anticorrosion paint.
Comparative example 2:
In the preparation process of embodiment 2 coating, do not add zirconium white/polyaniline nano-composite material filter cake, obtain aqueous inorganic paint.
Embodiment 3:
10.00g titanium phosphate is distributed in 80.00g deionized water and forms titanium phosphate dispersion liquid, then in titanium phosphate dispersion liquid, 3.00g (0.03226mol) aniline and the 83.40ml1.5mol/L tosic acid aqueous solution is added respectively, stir, 32.30ml1.0mol/L ammonium persulfate aqueous solution is added at temperature of reaction is 20 DEG C, continuous stirring, after reaction 4h, through suction filtration, and washing is colourless to filtrate, obtains titanium phosphate/polyaniline nano-composite material filter cake.
Get 40.00g mass percent concentration be 85% phosphoric acid, the aluminium hydroxide of 10.00g, the water of 30.00g be placed in 80 DEG C of mix and blends reaction 4h, after cooling, water use regulation solution density is 1.6g/cm
3, obtain aluminium dihydrogen phosphate resin.
By 50.00g aluminium dihydrogen phosphate resin, 1.00g titanium phosphate/polyaniline nano-composite material filter cake, 0.50g tripoly phosphate sodium STPP, 1h is mixed under homogenizer, add 15.00g aluminum oxide, 0.50g methyl-silicone oil, 0.50g sodium polyacrylate afterwards, continue to mix 2h under homogenizer, obtain high-performance water-based anticorrosion paint.
Comparative example 3:
In the preparation process of embodiment 3 coating, do not add titanium phosphate/polyaniline nano-composite material filter cake, obtain aqueous inorganic paint.
Comparative example 4:
In the preparation process of embodiment 3 coating, aluminium dihydrogen phosphate resin is replaced with aqueous epoxy resins, solidifying agent aluminum oxide replaces with polymeric amide, obtains water-based organic anti-corrosive erosion coating.
Embodiment 4:
10.00g nanometer silicon carbide is distributed in 60.00g deionized water and forms nanometer silicon carbide dispersion liquid, then in nanometer silicon carbide dispersion liquid, add the mixed acid solution prepared by phosphoric acid of 3.00g (0.03226mol) aniline, 6.4g (0.0196mol) Witco 1298 Soft Acid and 60mL0.5M (0.03mol) respectively, stir, 30.00ml1.0mol/L ammonium persulfate aqueous solution is added at temperature of reaction is 20 DEG C, continuous stirring, after reaction 6h, through suction filtration, and washing is colourless to filtrate, obtains silicon carbide/polyaniline nano-composite material filter cake.
The potassium hydroxide of 10g is dissolved in the water of 10g, forms solution, then the flyash of 50g is joined in solution, be stirred to formation jelly, obtain geopolymer.
By 50.00g geopolymer, 2.50g silicon carbide/polyaniline nano-composite material filter cake, 0.90g trisodium phosphate, 0.5h is uniformly mixed under ball mill, add 10.00g sodium silicofluoride, 0.50g tributyl phosphate, 0.30g octadecyl trimethyl silane afterwards, continue to be uniformly mixed 1h under ball mill, obtain high-performance water-based anticorrosion paint.
Comparative example 5:
In the preparation process of embodiment 4 coating, do not add silicon carbide/polyaniline nano-composite material filter cake, obtain aqueous inorganic paint.
Embodiment 5:
10.00g montmorillonite is distributed in 60.00g deionized water and forms montmorillonite dispersion liquid, then in montmorillonite dispersion liquid, 4.00g (0.04301mol) aniline and 83.30ml3.0mol/L phosphate aqueous solution is added respectively, stir, 43.01ml1.0mol/L ammonium persulfate aqueous solution is added at temperature of reaction is 20 DEG C, continuous stirring, after reaction 8h, through suction filtration, and washing is colourless to filtrate, obtains montmorillonite/polyaniline nano-composite material filter cake.
By 50.00g silicon sol, 2.00g montmorillonite/polyaniline nano-composite material filter cake, 0.80g dimethyl silicone oil, 2h is mixed under sand mill, add 0.50g methyl-silicone oil, 0.50g propenyl Trimethoxy silane afterwards, continue to mix 2h under sand mill, obtain high-performance water-based anticorrosion paint.
Comparative example 6:
In the preparation process of embodiment 5 coating, do not add montmorillonite/polyaniline nano-composite material filter cake, obtain aqueous inorganic paint.
Embodiment 6:
10.00g carbon nanotube dispersed is formed carbon nano tube dispersion liquid in 80.00g deionized water, then in carbon nano tube dispersion liquid, add 3.00g (0.03226mol) aniline, 28.67mL1.0mol/L sulfosalisylic aqueous acid respectively, stir, 30.00ml1.0mol/L ammonium persulfate aqueous solution is added at temperature of reaction is 10 DEG C, continuous stirring, after reaction 5h, through suction filtration, and washing is colourless to filtrate, obtains carbon nano-tube/poly aniline nano matrix material filter cake.
By 40.00g tetraethyl silicate, 5.00g carbon nano-tube/poly aniline nano matrix material filter cake, 0.60gBYK163,2h is mixed under homogenizer, add 0.40g hydrophilic silicon oil, 0.40gBYK371 afterwards, continue to mix 2h under homogenizer, obtain high-performance water-based anticorrosion paint.
Comparative example 7:
In the preparation process of embodiment 6 coating, do not add carbon nano-tube/poly aniline nano matrix material filter cake, obtain aqueous inorganic paint.
Embodiment 7:
10.00g aluminium triphosphate is distributed in 80.00g deionized water and forms aluminium triphosphate dispersion liquid, then in aluminium triphosphate dispersion liquid, add the nitration mixture aqueous solution prepared by hydrochloric acid of 3.00g (0.03226mol) aniline, 3.75g (0.01720mol) sulphosalicylic acid and 37.5ml4.0mol/L respectively, stir, 30.00ml1.0mol/L ammonium persulfate aqueous solution is added at temperature of reaction is 10 DEG C, continuous stirring, after reaction 5h, through suction filtration, and washing is colourless to filtrate, obtains carbon nano-tube/poly aniline nano matrix material filter cake.
By 60.00g potassium silicate resin, 1.50g aluminium triphosphate/polyaniline nano-composite material filter cake, 0.60g Natvosol, 2h is mixed under sand mill, add 0.40g hydrophilic silicon oil, 0.40g methacryloxypropyl trimethoxy silane afterwards, continue to mix 2h under sand mill, obtain high-performance water-based anticorrosion paint.
Comparative example 8:
In the preparation process of embodiment 7 coating, do not add aluminium triphosphate/polyaniline nano-composite material filter cake, obtain aqueous inorganic paint.
Comparative example 9:
In the preparation process of embodiment 7 coating, potassium silicate resin is replaced with water-borne acrylic resin, obtain water-based organic anti-corrosive erosion coating.
Embodiment 8:
Get the nanoemulsions containing 10.00g polymethylmethacrylate, 60.00g deionized water, then in nanoemulsions, 3.00g (0.03226mol) aniline and 60.00ml2.0mol/L aqueous sulfamic acid is added respectively, stir, 32.00ml1.0mol/L ammonium persulfate aqueous solution is added at temperature of reaction is 30 DEG C, continuous stirring, after reaction 4h, through suction filtration, and washing is colourless to filtrate, obtains polymethyl methacrylate/polyaniline nano composite material filter cake.
Get 60.00g mass percent concentration be 85% phosphoric acid, the aluminium hydroxide of 30.00g, the water of 20.00g be placed in 90 DEG C of mix and blends reaction 2h, after cooling, water use regulation solution density is 1.25g/cm
3, obtain aluminium dihydrogen phosphate resin.
By 20.00g potassium silicate resin, 10.00g lithium silicate resin, 10.00g polymethyl methacrylate/polyaniline nano composite material filter cake, 1.00g Sodium hexametaphosphate 99,1h is mixed under ball mill, add 30.00g zinc oxide, 20.00g aluminium dihydrogen phosphate, 0.50g hydrophilic silicon oil, 1.00g polyacrylic acid afterwards, continue to mix 2h under ball mill, obtain high-performance water-based anticorrosion paint.
Comparative example 10:
In the preparation process of embodiment 8 coating, do not add polymethyl methacrylate/polyaniline nano composite material filter cake, obtain aqueous inorganic paint.
The performance test table of table 1 film
Claims (7)
1. a high-performance water-based anticorrosion paint, it is characterized in that comprising inorganic materials resin 30 ~ 60 mass parts, polyaniline nano composite material 0.5 ~ 30 mass parts, solidifying agent 0 ~ 30 mass parts, defoamer 0.1 ~ 1 mass parts, dispersion agent 0.1 ~ 1 mass parts, flow agent 0.1 ~ 1 mass parts, wherein, inorganic materials resin is one or more in the mixed solution of aluminium dihydrogen phosphate, silicate resin, geopolymer and water glass; The preparation process of polyaniline nano composite material is: nano material be distributed in water and form nano material dispersion liquid, then in nano material dispersion liquid, aniline and protonic acid aqueous solution is added respectively, stir, aqueous oxidizing agent solution is added at temperature of reaction is 0 ~ 50 DEG C, continuous stirring, after reaction 1 ~ 24h, through suction filtration, and washing is colourless to filtrate, gained filter cake is polyaniline nano composite material; The solidifying agent of aluminium dihydrogen phosphate be magnesium oxide, zinc oxide, aluminum oxide, ferric oxide, zirconium white, phosphoric acid salt, high-alumina cement one or more; The solidifying agent of geopolymer is silicofluoride.
2. a kind of high-performance water-based anticorrosion paint according to claim 1, it is characterized in that the mass ratio of nano material and water in polyaniline Nano-composite materials process is 10 ~ 30: 100, the mass ratio of aniline and nano material is 0.3 ~ 1: 1, the mol ratio of protonic acid and aniline is 0.15 ~ 11.68: 1, the concentration of protonic acid is 1.0 ~ 4.0mol/L, the mol ratio of oxygenant and aniline is 0.8 ~ 1.2: 1, and the volumetric molar concentration of oxidizing agent solution is 0.8 ~ 1.2mol/L.
3. a kind of high-performance water-based anticorrosion paint according to claim 1, is characterized in that in the solidifying agent of aluminium dihydrogen phosphate, phosphoric acid salt comprises sodium phosphate, SODIUM PHOSPHATE, MONOBASIC and sodium polyphosphate.
4. a kind of high-performance water-based anticorrosion paint according to claim 1, it is characterized in that defoamer is one or more in tributyl phosphate, silicone oil, wherein silicone oil comprises methyl-silicone oil, ethyl silicon oil, dimethyl silicone oil, hydrophilic silicon oil, dispersion agent is one or more in tripoly phosphate sodium STPP, trisodium phosphate, Sodium hexametaphosphate 99, hydroxylated cellulose class, polyacrylate, BYK163, wherein hydroxylated cellulose comprises Walocel MT 20.000PV, Natvosol, hydroxypropylcellulose, hydroxyethylmethyl-cellulose, Vltra tears, and polyacrylate comprises sodium polyacrylate, polyacrylic acid potassium, flow agent is silane coupling agent, polyacrylic, one or more in BYK371, wherein silane coupling agent is organoalkoxysilane, comprises methyltrimethoxy silane, Union carbide A-162, ethyl trimethoxy silane, ethyl triethoxysilane, n-propyl Trimethoxy silane, n-propyl triethoxyl silane, isopropyltri-methoxysilane, isopro-pyltriethoxysilane, n-butyltrimethoxysilane, ne-butyltriethoxysilaneand, n-hexyl Trimethoxy silane, trimethoxysilane, isobutyl triethoxy silane, n-hexyl triethoxyl silane, n-octyltrimethylammonium silane, n-octytriethoxysilane, isooctyltrimethoxysi,ane, isooctyltriethoxysilane, dodecyl Trimethoxy silane, n-hexadecyl Trimethoxy silane, Octadecane base Trimethoxy silane, phenyl triethoxysilane, dimethoxydiphenylsilane, vinyltrimethoxy silane, vinyltriacetoxy silane, vinyl dimethylethoxysilane, vinyl silane triisopropoxide, vinyltriacetoxy silane, propenyl Trimethoxy silane, vinyl three ('beta '-methoxy oxyethyl group) silane, γ-(methacryloxy) propyl trimethoxy silicane, γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-mercaptopropyl trimethoxysilane, gamma-mercaptopropyltriethoxysilane, α-thiopurine methyltransferase triethoxyl silane, γ-mercapto hydroxypropyl methyl dimethoxysilane, γ-mercapto hydroxypropyl methyl diethoxy silane, two-[γ-(triethoxysilicane) propyl group] disulphide, two-[γ-(triethoxysilicane) propyl group] tetrasulfide, methacryloxypropyl trimethoxy silane, polyacrylic comprises polyacrylic acid, polymethyl acrylic acid.
5. a kind of high-performance water-based anticorrosion paint according to claim 1, it is characterized in that the preparation method of aluminium dihydrogen phosphate is: the aluminium hydroxide of the phosphoric acid of 40 ~ 70 mass parts, 10 ~ 30 mass parts, the water mix and blend of 20 ~ 30 mass parts are placed in 80 ~ 100 DEG C and react 1 ~ 4h, after cooling, water use regulation solution density is 1.1 ~ 1.6g/cm
3, obtain aluminium dihydrogen phosphate resin, wherein, the mass percent concentration of phosphoric acid is 85%.
6. a kind of high-performance water-based anticorrosion paint according to claim 1, it is characterized in that the preparation method of geopolymer is: be dissolved in by the alkali-activator of 10 ~ 50 mass parts in the water of 10 ~ 100 mass parts, form solution, then the silica-alumina material of 50 ~ 80 mass parts is joined in solution, be stirred to formation jelly, obtain geopolymer, wherein, alkali-activator is sodium hydroxide, potassium hydroxide, sodium carbonate, salt of wormwood, sodium sulfate, potassium sulfate, sodium phosphate, potassiumphosphate, Sodium Fluoride, Potassium monofluoride, water glass, potassium silicate, sodium aluminium silicate, aluminum potassium silicate, one or more in silicic acid sodium carbonate, silica-alumina material is one or more in kaolin, metakaolin, flyash, slag, cinder, volcano float stone, montmorillonite, attapulgite, diatomite, mica, hydrotalcite, illite, pyrophyllite, zeolite, quartz, feldspar.
7. a kind of high-performance water-based anticorrosion paint according to claim 2, it is characterized in that nano material is titanium oxide, silicon oxide, zinc oxide, cerium oxide, zirconium white, stannic oxide, ferric oxide, manganese oxide, vanadium oxide, nickel oxide, molybdenum oxide, Tungsten oxide 99.999, yttrium oxide, titanium phosphate, tertiary iron phosphate, calcium phosphate, tripolyphosphate calcium, aluminium triphosphate, barium sulfate, calcium sulfate, graphite, carbon black, carbon nanotube, Graphene, attapulgite, montmorillonite, kaolin, diatomite, wollastonite, mica, hydrotalcite, illite, sepiolite, chromium nitride, silicon nitride, silicon carbide, polystyrene, one in polymethylmethacrylate, described aniline is the aniline of aniline or replacement, protonic acid is one or more in p-methyl benzenesulfonic acid, camphorsulfonic acid, sulphosalicylic acid, Witco 1298 Soft Acid, naphthene sulfonic acid, dinonylnaphthalene sulfonic acid, polystyrolsulfon acid, thionamic acid, aniline sulfonic acid, oxalic acid, citric acid, tartrate, hydrochloric acid, sulfuric acid, nitric acid, perchloric acid and phosphoric acid, oxygenant is ammonium persulphate.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1923910A (en) * | 2005-08-31 | 2007-03-07 | 宝山钢铁股份有限公司 | Fire resistant water-based self-adhesion coating |
| CN101139179A (en) * | 2007-08-14 | 2008-03-12 | 陈云 | Ceramic coating burning colorful sand and method for making same |
| CN101376712A (en) * | 2008-09-12 | 2009-03-04 | 江苏工业学院 | Method for improving conductive heat stability of polyaniline/inorganic nano conductive composite material |
| CN101628791A (en) * | 2009-06-25 | 2010-01-20 | 深圳航天科技创新研究院 | Geopolymer gel material for rush repairs and rush constructions |
-
2010
- 2010-01-27 CN CN201010108989.XA patent/CN102134410B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1923910A (en) * | 2005-08-31 | 2007-03-07 | 宝山钢铁股份有限公司 | Fire resistant water-based self-adhesion coating |
| CN101139179A (en) * | 2007-08-14 | 2008-03-12 | 陈云 | Ceramic coating burning colorful sand and method for making same |
| CN101376712A (en) * | 2008-09-12 | 2009-03-04 | 江苏工业学院 | Method for improving conductive heat stability of polyaniline/inorganic nano conductive composite material |
| CN101628791A (en) * | 2009-06-25 | 2010-01-20 | 深圳航天科技创新研究院 | Geopolymer gel material for rush repairs and rush constructions |
Non-Patent Citations (1)
| Title |
|---|
| 聚苯胺/无机纳米复合材料的研究进展;姚超等;《化工进展》;20081231;第27卷(第12期);第1942-1947页和第1958页 * |
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