CN102106350A - Compound bactericide containing jinggangmycin and difenoconazole - Google Patents
Compound bactericide containing jinggangmycin and difenoconazole Download PDFInfo
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- CN102106350A CN102106350A CN2009102430855A CN200910243085A CN102106350A CN 102106350 A CN102106350 A CN 102106350A CN 2009102430855 A CN2009102430855 A CN 2009102430855A CN 200910243085 A CN200910243085 A CN 200910243085A CN 102106350 A CN102106350 A CN 102106350A
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- difenoconazole
- jinggangmeisu
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Abstract
The invention discloses a compound bactericide containing jinggangmycin and difenoconazole. The bactericide comprises the following raw materials in percentage by weight: 0.1 to 70 percent of the jinggangmycin, 0.1 to 70 percent of the difenoconazole, 1 to 15 percent of dispersant, 1 to 15 percent of wetting agent, 1 to 5 percent of antifreeze agent, 0.1 to 5 percent of preservative, 0.1 to 5 percent of defoaming agent, 0.1 to 5 percent of thickener, and the balance of water. Tests prove that the compound bactericide can be used for effectively preventing and controlling rice sheath blight and other epiphyte diseases.
Description
Technical field
The present invention relates to a kind of agricultural double-crossed disinfectant, specifically a kind of composite bactericide that contains jinggangmeisu and Difenoconazole.This invention can be used for preventing and kill off fungal diseases such as rice sheath blight disease.
Technical background
Paddy rice is the important cereal crops of China, and sowing area accounts for 1/4 of national cereal crops, and output accounts for over half.Rice sheath blight disease claims moire disease again.Generally begin morbidity in tillering stage, occur water stain shape elliptical spot at first on the leaf sheath of the nearly water surface, later scab increases, and normal healing mutually becomes the moire shape spot of irregular big shape, and its edge is a brown, middle part celadon or filbert.Basic identical on symptom on the blade and the leaf sheath.Disease is expanded from bottom to top, can go up sword-like leave when serious, even causes the morbidity of fringe portion, large stretch of lodging.Banded sclerotial blight is mainly survived the winter in soil with sclerotium.The sclerotium of 1 year showy water surface is sprouted and is grown mycelia, immerses leaf sheath immediately and forms scab, grows mycelia again near the new scab of formation that spreads from scab.When sclerotium falls into the water and can borrow current to propagate.Excessive nitrogen fertilizer application, high dense planting, the dark too much or inclined to one side nitrogen fertilizer application of pouring water is the principal element of bringing out disease.Paddy rice reaches onset peak since the morbidity in tillering stage around the booting stage, the state of an illness descends after milk ripe stage.
Jinggangmeisu is the water soluble antibiotics-glucoside compounds that is produced by the mutation of water streptomycete well ridge.Have 6 components, main active substances is jinggangmycin A and B.Jinggangmeisu is the very strong agricultural antibiotic of a kind of systemic action, after the mycelia of rice sheath blight disease pathogen touches jinggangmeisu, can be absorbed very soon and in thalline, conduct, and disturb and the growth of inhibition somatic cells normal growth, thereby play therapeutic action by somatic cells.Difenoconazole is a kind of triazole bactericidal agent sterol demethylation inhibitor; to Ascomycetes, Basidiomycetes and comprise Alternaria, Ascochyta, the mould genus of tail spore, Colletotrichum, ball Cuo Pseudomonas, Phoma, Ramularia, Septoria, Venturia partly know disease, Erysiphaceae, Uredinales and some are planted and are passed pathogen lasting protection and therapeutic action are arranged.
Difenoconazole is a kind of low toxicity, have the bactericide of protection, treatment and interior suction; be characterized in wide spectrum, efficient, low toxicity, low-residual and to people and animals and Environmental security; to suppressing the biosynthesis of cell wall sterol; can stop the crop fungi growth; fungicidal spectrum is wide, thereby becomes one of present China suitability for industrialized production large-tonnage agricultural chemicals.
Suspending agent (SC) be insoluble or the former medicine that is slightly soluble in water by some auxiliary agent, be scattered in more equably in the water by the wet method ultramicro grinding, form a kind of particle higher suspension slightly, liquid-solid attitude system that can be fluidly stable.Suspending agent normally is made up of active ingredient and " five doses " (dispersant, thickener, antiprecipitant, defoamer, antifreezing agent) and water, and content of effective is generally 5%-50%, and the average particle diameter is about 3um.Because (dispersiveness and plate-out ability) is all relatively good, and the suspensibility height for " two property " of suspending agent, the ability that sticks to the plant corpus surface is more intense, resistance of rainwater washing against.So the drug effect of said preparation is remarkable than wetting powder, and the drug effect phase is longer.
Jinggangmeisu and Difenoconazole are carried out composite, not only can strengthen medicament in plant corpus surface adhesive capacity, and can also improve protection effect, reduce the loss that disease caused.
Up to the present, patent does not also have the composition of mentioning jinggangmeisu and two kinds of Fungicidal compounds of Difenoconazole both at home and abroad.
Summary of the invention
The object of the present invention is to provide a kind of composite bactericide that contains jinggangmeisu and Difenoconazole.
Another object of the present invention provides a kind ofly can effectively prevent and kill off the disinfectant use in agriculture of rice sheath blight disease.The objective of the invention is to be achieved through the following technical solutions:
Composite bactericide of the present invention is characterized in that it is to contain two kinds of active components, i.e. jinggangmeisu and Difenoconazole.
Composite bactericide of the present invention is characterized in that each constituent content of suspending agent of described jinggangmeisu and Difenoconazole is (mass fraction): jinggangmeisu 0.1-70%, Difenoconazole 0.1-70%, dispersant 1-15%, wetting agent 1-15%, antifreezing agent 1-5%, preservative 0.1-5%, defoamer 0.1-5%, thickener 0.1-5%, water surplus.
This is invented compared with prior art, has fully proved through land for growing field crops drug effect extend trial and has adopted composite bactericide of the present invention to have following advantage and good effect:
(1) composite bactericide of the present invention can be realized " two delay " (delay drug-fast development, delay the medicament life cycle).
(2) composite bactericide of the present invention can be realized " two reductions " (reducing agricultural chemicals usage amount, reduction plant protection cost on the unit are).
(3) composite bactericide of the present invention can be realized " two increases " (increase rice yield, increase farmers' income).
(4) composite bactericide of the present invention can be realized " two minimizings " (reduce the persticide residue of agricultural chemicals on paddy rice, reduce the pollution of agricultural chemicals to environment).
Substantive distinguishing features of the present invention can be embodied from following embodiment, but these embodiment only as an illustration, rather than limits the invention.
The selected dispersant of suspending agent of the present invention has: NNO, MF, sodium lignin sulfonate, di-2-ethylhexylphosphine oxide benzene sulfonic acid sodium salt, consumption 1-15%.
The selected wetting agent of suspending agent of the present invention has: SOPA, sldium lauryl sulfate, neopelex, consumption 1-15%.
The selected antifreezing agent of suspending agent of the present invention has: propane diols, ethylene glycol, glycerine, urea, consumption 1-5%.
The selected preservative of suspending agent of the present invention has: paraformaldehyde, triumphant pine, Sodium Benzoate, potassium sorbate, consumption 0.1-5%.
The selected defoamer of suspending agent of the present invention has: glycerine, dimethyl silicone polymer, benzyl carbinol oleate, consumption 0.1-5%.
The selected thickener of suspending agent of the present invention has: sodium carboxymethylcellulose, polyvinyl alcohol, xanthans, white carbon black, bentonite, consumption 0.1-5%.
Embodiment
26 kilograms in one: 24% jinggangmeisu mother liquor of embodiment, 15 kilograms of 95% difenoconazole technical materials, 1.5 kilograms of sodium lignin sulfonates, 1.2 kilograms of neopelexes, 0.7 kilogram of propane diols, 0.2 kilogram of Sodium Benzoate, 0.2 kilogram of glycerine, 0.2 kilogram of polyvinyl alcohol, 79.5 kilograms in water, by the known technology of persons skilled in the art promptly.
40 kilograms of two: 24% former medicines of jinggangmeisu of embodiment, 13.7 kilograms of 95% difenoconazole technical materials, 1.8 kilograms of sodium lignin sulfonates, 2.0 kilograms of neopelexes, 0.8 kilogram of propane diols, 0.3 kilogram of Sodium Benzoate, 0.2 kilogram of glycerine, 0.2 kilogram of polyvinyl alcohol, 71.0 kilograms in water, by the known technology of persons skilled in the art promptly.
52 kilograms of three: 24% former medicines of jinggangmeisu of embodiment, 16.8 kilograms of 95% difenoconazole technical materials, 2.1 kilograms of sodium lignin sulfonates, 2.1 kilograms of neopelexes, 0.9 kilogram of propane diols, 0.5 kilogram of Sodium Benzoate, 0.2 kilogram of glycerine, 0.2 kilogram of polyvinyl alcohol, 64.2 kilograms in water, by the known technology of persons skilled in the art promptly.
68 kilograms of four: 24% former medicines of jinggangmeisu of embodiment, 24.8 kilograms of 95% difenoconazole technical materials, 1.9 kilograms of sodium lignin sulfonates, 2.7 kilograms of neopelexes, 1.8 kilograms of propane diols, 1.5 kilograms of Sodium Benzoates, 0.2 kilogram of glycerine, 0.2 kilogram of polyvinyl alcohol, 49.9 kilograms in water, by the known technology of persons skilled in the art promptly.
71.2 kilograms of five: 24% former medicines of jinggangmeisu of embodiment, 40.9 kilograms of 95% difenoconazole technical materials, 2.7 kilograms of sodium lignin sulfonates, 3.0 kilograms of neopelexes, 1.3 kilograms of propane diols, 0.9 kilogram of Sodium Benzoate, 0.2 kilogram of glycerine, 0.2 kilogram of polyvinyl alcohol, 33.4 kilograms in water, by the known technology of persons skilled in the art promptly.
Take by weighing each amount of substance with reference to the foregoing description,, can make the product of different content of the present invention with the method that those skilled in the art in this area know.Other embodiment of the present invention do not exemplify one by one at this.
The agent of six: 5% jinggangmeisu difenoconazole suspendings of embodiment prevents and treats the rice sheath blight disease bactericidal assay
1. reagent agent: 5% jinggangmeisu difenoconazole suspending agent (SC).
Contrast agent: 20% jinggangmeisu WP, 25% Difenoconazole EC.
Reagent agent dosage sees Table 1.
Table 1 reagent agent dosage
Medicament | Effective dose (gram/hectare) | Commodity amount (gram/mu) |
5% jinggangmeisu Difenoconazole SC | 60 | 80 |
5% jinggangmeisu Difenoconazole SC | 67.5 | 90 |
5% jinggangmeisu Difenoconazole SC | 75 | 100 |
20% jinggangmeisu WP | 150 | 50 |
25% Difenoconazole EC | 90 | 24 |
2. for studying thing: paddy rice, kind is for pressing down rice No. 2.
Controlling object: rice sheath blight disease (Alternaria mali Roberts)
Test is handled: this test reagent agent 5% jinggangmeisu Difenoconazole SC establishes 3 dosage of effective composition 60,67.5,75 gram/hectares and handles, contrast medicament 20% jinggangmeisu WP, 25% Difenoconazole EC respectively establish a routine dose and handle, other establishes one group of blank, totally 6 processing, repeat for 4 times, carry out test branch sub-district, 2 trees in every sub-district, and arrange sub-district district's group at random.
3. result of the test sees Table 2-1.
Table 2-120% jinggangmeisu Difenoconazole WP prevents and treats rice sheath blight disease result of the test table
Result of the test (seeing Table 1) shows: 5% jinggangmeisu Difenoconazole SC is remarkable to the rice sheath blight disease preventive effect.Using dosage 80-100 gram/mu sprays once in their early stage, sprays once after 8 days at interval again, and preventive effect reaches 71.92-87.59%.Wherein the preventive effect differences of 5% jinggangmeisu Difenoconazole SC, 90 gram/mu treatment region preventive effects and two contrast medicaments is not remarkable.Safety observe to show, this medicament in this experimental drug weight range to paddy growth safety.When suggestion was used, preparation consumption 80-100 gram/mu was converted 50 liters in water, begins to spray in the rice sheath blight disease their early stage, looked PD situation 2-4 medicine of dispenser altogether, and be advisable with 7-10 days interval.
Seven: 5% jinggangmeisu Difenoconazoles of embodiment mixture is to the indoor virulence test of Rhizoctonia solani Kuhn
1. reagent agent: 5% jinggangmeisu Difenoconazole mixture (2% jinggangmeisu+3% Difenoconazole)
Contrast agent: 20% jinggangmeisu WP, 25% Difenoconazole EC
2. be rice sheath blight disease (Thanatephorus cucumeris) for the examination bacterial classification
Test method is an inhibition zone method.
3. result of the test sees Table 2-2.
Table 2-25% jinggangmeisu Difenoconazole mixture is to the Toxicity Determination of Rhizoctonia solani Kuhn table as a result
Result of the test (seeing Table 2) shows that 2% jinggangmeisu+3% Difenoconazole mixture is to the virulence EC of Rhizoctonia solani Kuhn
50Be 0.3675g/mL, two single agent 20% jinggangmeisu WP and 25% Difenoconazole WP virulence EC
50Be respectively 0.4149g/mL and 0.8561g/mL.EC according to two single agent
50It is 1.64 to the coefficient of synergism of Rhizoctonia solani Kuhn that value adopts Wadley (1945,1967 years) method to obtain 46% jinggangmeisu Difenoconazole mixture, shows remarkable synergistic effect.
In sum, 2% jinggangmeisu+3% Difenoconazole mixture is as a kind of novel built bactericide, it is new reasonable to fill a prescription, synergistic effect is remarkable, rice sheath blight disease preventive effect excellence and use cost had advantage, cost performance is better than in the market great majority and prevents and treats the bactericide of rice sheath blight disease, is a kind of having a extensive future, and meets the preferred agents of sustainable development agricultural.
Claims (2)
1. a composite bactericide that contains jinggangmeisu and Difenoconazole is characterized in that this bactericide contains jinggangmeisu and two kinds of active components of Difenoconazole.
2. composite bactericide according to claim 1, the proportioning of its bactericidal composition is by percentage to the quality: jinggangmeisu 0.1-70%, Difenoconazole 0.1-70%, dispersant 1-15%, wetting agent 1-15%, antifreezing agent 1-5%, preservative 0.1-5%, defoamer 0.1-5%, thickener 0.1-5%, water surplus.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104757003A (en) * | 2015-04-24 | 2015-07-08 | 浙江世佳科技有限公司 | Sterilization composition containing tetramycin and difenoconazole as well as preparation and application thereof |
CN105707082A (en) * | 2016-01-20 | 2016-06-29 | 南京农业大学 | Application of pesticide compositions to preventing and treating wheat head blight |
-
2009
- 2009-12-25 CN CN2009102430855A patent/CN102106350A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104757003A (en) * | 2015-04-24 | 2015-07-08 | 浙江世佳科技有限公司 | Sterilization composition containing tetramycin and difenoconazole as well as preparation and application thereof |
CN105707082A (en) * | 2016-01-20 | 2016-06-29 | 南京农业大学 | Application of pesticide compositions to preventing and treating wheat head blight |
CN105707082B (en) * | 2016-01-20 | 2018-04-10 | 南京农业大学 | A kind of purposes of composition pesticide in gibberella zeaze petch of wheat and barley is prevented and treated |
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Application publication date: 20110629 |