CN102105546B - Interim fixing/stripping means of component and be suitable to the interim fixing of its and stick with glue agent - Google Patents

Interim fixing/stripping means of component and be suitable to the interim fixing of its and stick with glue agent Download PDF

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Publication number
CN102105546B
CN102105546B CN200980128706.3A CN200980128706A CN102105546B CN 102105546 B CN102105546 B CN 102105546B CN 200980128706 A CN200980128706 A CN 200980128706A CN 102105546 B CN102105546 B CN 102105546B
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methyl
fixing
acrylate
component
interim
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CN102105546A (en
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栗村启之
金井朋之
大岛和宏
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Denka Co Ltd
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Denki Kagaku Kogyo KK
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C09J175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J201/00—Adhesives based on unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/416—Additional features of adhesives in the form of films or foils characterized by the presence of essential components use of irradiation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2433/00—Presence of (meth)acrylic polymer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2475/00—Presence of polyurethane

Abstract

The present invention provides a kind of method of temporarily fixing, and it can obtain significant effect in terms of the dimensional accuracy of tooling member.Described method of temporarily fixing, have: by temporarily fixing stick with glue agent be applied to the painting process on fixing component, processed component is mounted in interim fixing the lift-launchs operation sticking with glue in agent and carries operation after fixing stick with glue agent to interim and irradiate at least one in visible ray or ultraviolet and improve and fix the irradiation process of the adhesive tension sticking with glue agent temporarily, also there is one or both from fixing component and processed component and execute stressed pressurization operation, it is characterized in that, pressurization operation and irradiation process are at least while implemented certain time.Interim fixing sticks with glue agent for containing (A) multifunctional (methyl) acrylate, (B) simple function (methyl) acrylate and the compositions of (C) Photoepolymerizationinitiater initiater.

Description

Interim fixing/stripping means of component and be suitable to the interim fixing of its and stick with glue agent
Technical field
The present invention relates to process interim fixing/stripping means during various component, further relate to be suitable to the interim solid of the method Interim the fixing determined sticks with glue agent.Such as, method and the stripping side temporarily fixing this component when processing optical component is related to Method is temporarily fixing with the light solidity being suitable to this purposes sticks with glue agent.
Background technology
Interim fixing as optical lens, prism, array, silicon wafer, quasiconductor installation component etc. sticks with glue agent, uses Two-sided tape or hot melt system adhesive, will engage with these adhesive or after the shape that component machining is regulation of stacking, Remove adhesive, manufacture tooling member.Such as, in quasiconductor installation component, these component two-sided tapes are fixed on base After on material, it is cut into required component, and then by the stripping that two-sided tape irradiation ultraviolet radiation is carried out from component. It addition, in the case of hot melt system adhesive, after engagement member, after making adhesive penetrate in gap by heating, cutting adds Component needed for work one-tenth, carries out the stripping of adhesive in organic solvent.
But, in the case of two-sided tape, there are the following problems: is difficult to obtain dimensional accuracy, or owing to adhesive strength is low And it is poor to cause component to add cutting in man-hour (チ Star ピ Application グ), or it is not heated to more than 100 DEG C and cannot peel off.Utilizing purple Outside line is irradiated in the case of making it peel off, and there is the problem can not peeled off when the transmittance deficiency of adherend.
In the case of using hot melt system adhesive, needing to use organic solvent during stripping, alkaline solution or halogen system have The cleaning treatment operation of machine solvent is numerous and diverse, additionally, working environment also becomes problem.
In order to solve these defects, it is proposed that interim containing water soluble compounds such as water-soluble vinyl monomers is fixed Light curable type or heating type glue stick.Use in the method for temporarily fixing of these adhesive, solve the fissility in water, But in contrast, have that adhesive strength when component is fixed is low, problem that the dimensional accuracy of component after machining is not enough.
It addition, propose a kind of interim fixing to stick with glue agent, it is by using (methyl) propylene that specific hydrophilic is high Acid esters improves adhesivity, utilizes swelling simultaneously or is partly dissolved and improves fissility.This is fixed temporarily and sticks with glue agent, in cutting Add man-hour, produce the frictional heat of component and the cutting element such as blade or diamond cutter, it is therefore desirable to make it with substantial amounts of water Cool down.There are the following problems for the high compositions of above-mentioned hydrophilic: owing to during cutting, solidfied material is swelling and limber up, because of This, it is impossible to reach higher dimensional accuracy.Further, since the member upper peeled off divides the solidfied material generation of adhesive deposit of dissolving, therefore Outward appearance aspect goes wrong (with reference to patent documentation 1,2,3).
Patent documentation 1: Japanese Unexamined Patent Publication 6-116534 publication
Patent documentation 2: Japanese Unexamined Patent Publication 11-71553 publication
Patent documentation 3: Japanese Unexamined Patent Publication 2001-226641 publication
Summary of the invention
In order to improve the dimensional accuracy of the component after machining, expect hydrophobicity, high adhesive strength and the stripping in water Excellent from property, peel off in rear part without generation of adhesive deposit, in terms of environment operability also excellent fix temporarily/stripping means and Be suitable to the interim fixing of the method and stick with glue agent.
The present invention is to solve that the problem of these prior aries has carried out various research, it was found that by have from One or both in fixing component and processed component executes stressed operation, and this is executed stressed operation and this is carried out The operation irradiated at least while is implemented certain time, thus, adds the dimensional accuracy that can obtain excellence man-hour, such that it is able to realize The present invention.
That is, the present invention has following composition.
(1) a kind of method of temporarily fixing, including: by temporarily fixing stick with glue operation that agent is applied on fixing component (with Be referred to as down painting process), processed component is mounted in interim fixing stick with glue in agent operation (hereinafter referred to as carrying operation), With after this lift-launch, interim at least one sticked with glue in agent irradiation visible ray or ultraviolet fixing is improved interim fixing glue The operation (hereinafter referred to as irradiation process) of the adhesive tension of stick, also includes the side or double from fixing component and processed component Side executes stressed operation (operation of hereinafter referred to as pressurizeing), wherein, this is executed stressed operation and this operation being irradiated At least while implement certain time.
(2) a kind of method of temporarily fixing, including: stick with glue, by temporarily fixing, the operation that agent is applied on processed component (hereinafter referred to as painting process), fixing component be mounted in the interim fixing operation sticking with glue in agent (hereinafter referred to as carry work Sequence) and this lift-launch after stick with glue agent and irradiate at least one in visible ray or ultraviolet to interim fixing and improve interim fixing Stick with glue the operation (hereinafter referred to as irradiation process) of the adhesive tension of agent, also include the side from fixing component and processed component Or both sides execute stressed operation (operation of hereinafter referred to as pressurizeing), wherein, this is executed stressed operation and this is irradiated Operation is at least while implemented certain time.
(3) method of temporarily fixing as described in above-mentioned (1) or (2), wherein, from fixing component and processed component The Stress control that side or both sides apply is at 1g/cm2Above and 1000kg/cm2Below.
(4) method of temporarily fixing as described in above-mentioned (1) or (3), wherein, by fixing component, interim fixing stick with glue agent, In processed component, any one above controls more than 0 DEG C and less than 150 DEG C.
(5) if above-mentioned (1) is to the method for temporarily fixing according to any one of (4), wherein, interim fixing sticks with glue agent for containing There are (A) multifunctional (methyl) acrylate, (B) simple function (methyl) acrylate and the compositions of (C) Photoepolymerizationinitiater initiater.
(6) method of temporarily fixing as described in above-mentioned (5), wherein, (A) and (B) is hydrophobicity.
(7) if above-mentioned (1) is to the method for temporarily fixing according to any one of (6), wherein, the interim fixing glass sticking with glue agent Glass transition temperature is more than-50 DEG C and less than 50 DEG C.
(8) if above-mentioned (5) are to the method for temporarily fixing according to any one of (7), wherein, interim fixing sticks with glue agent, (A) containing (A) 1～90 mass parts, (B) 10～99 mass parts and in total amount 100 mass parts of (B), and relative to (A) and (B) total amount 100 mass parts contains (C) 0.1～30 mass parts.
(9) if above-mentioned (5) are to the method for temporarily fixing according to any one of (8), wherein, interim fixing sticks with glue agent, phase Total amount 100 mass parts for (A) and (B) contains particulate matter (D) 0.1～20 mass parts insoluble in (A)～(C).
(10) method of temporarily fixing as described in above-mentioned (9), wherein, the shape of the particulate matter (D) insoluble in (A)～(C) Shape is spherical.
(11) method of temporarily fixing as described in above-mentioned (9) or (10), wherein, insoluble in (A)～the particulate matter of (C) (D) it is crosslinked polymethylmethacrylaparticles particle, crosslinked polystyrene particle and crosslinked polymethylmethacrylaparticles polystyrene The mixture of any one or they in copolymer particle.
(12) if above-mentioned (9) are to the method for temporarily fixing according to any one of (11), wherein, insoluble in (A)～the grain of (C) The mean diameter of shape material (D) is 5 μm～200 μm.
(13) if above-mentioned (9) are to the method for temporarily fixing according to any one of (12), wherein, will be insoluble in (A)～(C) The particle volume when particle diameter (μm) utilizing laser diffractometry to measure of particulate matter (D) represents with logarithm is distributed relative to particle diameter Standard deviation 0.0001～0.25 scope.
(14) the interim fixing/stripping means of a kind of component, wherein, including: to using above-mentioned (1) to any one of (13) After described method of temporarily fixing carries out interim fixing component processing, the component after this processing is immersed in less than 100 DEG C In warm water, remove the solidfied material of described compositions.
(15) the interim fixing/stripping means of a kind of component, wherein, including: to using above-mentioned (1) to any one of (13) After described method of temporarily fixing carries out the most fixing component processing, interim fixing is sticked with glue agent irradiation visible ray or ultraviolet Line, is immersed in the component after this processing in the warm water of less than 100 DEG C, removes the solidfied material of described compositions.
(16) as above-mentioned (1) is to the method for temporarily fixing according to any one of (13), wherein, it is seen that light or the photograph of ultraviolet The amount of penetrating is 1mJ/cm at wavelength 365nm2～4000mJ/cm2Scope.
(17) the interim fixing/stripping means as described in above-mentioned (15), it is characterised in that the component the most fixing to this adds Visible ray or the ultraviolet irradiation amount irradiated after work are 1000mJ/cm at wavelength 365nm2～40000mJ/cm2Scope.
(18) if above-mentioned (5) are to the method for temporarily fixing according to any one of (13), wherein, (A) multifunctional (methyl) third Olefin(e) acid ester contains multifunctional (methyl) acrylate oligomer/polymer and/or two senses (methyl) acrylate monomer.
(19) if above-mentioned (5) are to the method for temporarily fixing according to any one of (13), wherein, (A) multifunctional (methyl) third Olefin(e) acid ester contains multifunctional (methyl) acrylate oligomer/polymer and two senses (methyl) acrylate monomer.
(20) method of temporarily fixing as described in above-mentioned (18) or (19), wherein, multifunctional (methyl) acrylate oligomers Thing/polymer contains polyester-based polyurethane (methyl) acrylate and/or polyether polyurethane (methyl) acrylate.
(21) method of temporarily fixing as described in above-mentioned (18) or (19), wherein, two senses (methyl) acrylate monomer Containing 1,6-hexanediol two (methyl) acrylate and/or two (methyl) acrylic acid dicyclo pentyl ester.
(22) if above-mentioned (5) are to the method for temporarily fixing according to any one of (13), wherein, (B) simple function (methyl) third Olefin(e) acid ester contains phenolethylene oxide 2 mole (methyl) acrylate and/or 2-(1,2-ring six carboxyl acid imide) ethyl (methyl) acrylate.
(23) if above-mentioned (5) are to the method for temporarily fixing according to any one of (13), wherein, (B) simple function (methyl) third Olefin(e) acid ester contains phenolethylene oxide 2 mole (methyl) acrylate and 2-(1,2-ring six carboxyl acid imide) ethyl (first Base) acrylate.
(24) as above-mentioned (5) are to the method for temporarily fixing according to any one of (13), and wherein, (C) Photoepolymerizationinitiater initiater contains Have selected from benzyl dimethyl ketal, epoxide-phenyl-acetic acid 2-[2-oxo-2-phenyl-acetic acid base-ethyoxyl]-ethyl ester and oxygen One kind or two or more in base-phenyl-acetic acid 2-[2-Hydroxy-ethoxy]-ethyl ester.
In the method for temporarily fixing of the present invention, by pressurization operation and irradiation process are at least while implemented certain time, Significant effect is obtained in terms of the dimensional accuracy of processed component.
Detailed description of the invention
Painting process in the present invention, on fixing component or processed component, interim the fixing of coating sticks with glue agent.At this In painting process, as long as known painting process, then any means can be used the most not limit, but be preferably and carrying out admittedly The operation of appropriate coating binder on the fixing component of a fixed side or the gluing surface of processed component.The coating weight of adhesive is excellent Elect 0.00000001～0.1mg/mm as2, more preferably 0.000001～0.001mg/mm2.If the method being coated with in right amount Being that known method is just not particularly limited, such as, the method using coating machine is easy and accurate, preferred in terms of productivity ratio.
Lift-launch operation in the present invention, is to be mounted in be coated with by processed component or fixing component to face after painting process Time fix the interim fixing operation sticking with glue in agent sticked with glue on the fixing component of agent or on processed component.In this lift-launch work In sequence, as long as known method is just not particularly limited, such as, the operation of the automatic loading devices such as industrial robot is used Easy and accurate, preferred in terms of improving productivity ratio.
In the method for temporarily fixing of the present invention, by fixing component, interim fixing are sticked with glue in agent, processed component Any one is above control more than 0 DEG C and less than 150 DEG C implement, can control to fix the mobility sticking with glue agent temporarily.When Fixing component, interim fixing stick with glue agent, processed component is when being more than 0 DEG C, mobility is excellent, when it is below 150 DEG C, Interim fixing sticking with glue agent and will not be polymerized because of heat cure, dimensional accuracy is excellent.From the viewpoint of mobility and dimensional accuracy, It is preferably more than 10 DEG C and less than 100 DEG C, more preferably more than 20 DEG C and less than 80 DEG C.And then, more preferably 20 DEG C with Go up and less than 60 DEG C.
The pressurization operation of the present invention, preferably one or both from fixing component and processed component execute stressed work Sequence, more preferably to make the evenly spaced mode of fixing component and processed component execute stressed operation from one or both. In this pressurization operation, as long as known method is just not particularly limited, for example, it is preferable to use vacuum press or pressuring machine The method carrying out pressurizeing.
What is called in the present invention uniformly, refers to that the maximum at the interval of fixing component and processed component deducts at minimum In difference scope below 40 μm.If in this scope, then obtain good dimensional accuracy when processing processed component.From chi From the viewpoint of very little precision, the maximum at the interval preferably fixing component and processed component deducts the difference at minimum in 20 μm In following scope, more preferably in the scope below 10 μm, further preferably in the scope below 5 μm.
It addition, in the pressurization operation of the present invention, preferably one or both from fixing component and processed component applies 1g/cm2Above and 1000kg/cm2Pressure below is implemented.As long as the interval of fixing component and processed component is uniform, it is then Make that fixing component and processed component partial are applied pressure the most no problem, but from fixing component and the interval of processed component From the viewpoint of, preferably overall applying pressure.The pressure applied is 1g/cm2In the case of above, it is possible to make fixing component and quilt The interval of tooling member is uniform, when it is 1000kg/cm2Time following, fixing component or processed component are not damaged.From From the viewpoint of the uniformity at the interval of fixing component and processed component and damage, preferably 3g/cm2Above and 800kg/cm2 Hereinafter, more preferably 5g/cm2Above and 500kg/cm2Hereinafter, more preferably 10g/cm2Above and 300kg/cm2Below.
It addition, in the present invention, need interim any one sticked with glue in agent irradiation visible ray or ultraviolet fixing is come Improve the irradiation process of the interim fixing adhesive tension sticking with glue agent.Use as in irradiation process or irradiation process more described later Lamp, as long as the lamp improving the interim fixing adhesive tension sticking with glue agent is just not particularly limited, be preferably able to illumination wavelength The black light lamp of the ultraviolet of 365nm, metal halide lamp, high-pressure mercury-vapor lamp, LED etc..The wavelength of ultraviolet be preferably 10～ 430nm, more preferably 200～420nm, most preferably 330～405nm.
In the irradiation process of the present invention, it is seen that light or ultraviolet irradiation amount are preferably 1mJ/cm at wavelength 365nm2 ～4000mJ/cm2Scope.As long as within the range, being achieved with good size when processed component is processed Precision.From the viewpoint of dimensional accuracy, preferably at 10mJ/cm2～3000mJ/cm2Scope, more preferably at 100mJ/cm2~ 2000mJ/cm2Scope, further preferably at 300mJ/cm2～1000mJ/cm2Scope.
In the present invention, preferably in pressurization operation, at least while implement irradiation process certain time.By in pressurization operation In at least while implement irradiation process certain time, the interval of fixing component and processed component can be made uniformly, processed The dimensional accuracy aspect adding man-hour of component obtains significant effect.At this so-called processing refer to such as to implement cutting, grinding, Polishing, perforate etc. make processed component become required shape.So-called certain time at this, if comprise carry out solidifying time Between be just not particularly limited.Set out at the uniform aspect in interval that can make fixing component and processed component, preferably real in advance After applying pressure operation, implement pressurization operation and irradiation process simultaneously.
In the present invention, the material of processed component and fixing component is not particularly limited, but is preferably by can be saturating Penetrate the component that the material of ultraviolet or visible ray is constituted.As this kind of material, crystal component, glass component, plastics structure can be enumerated Part etc..
As (A) used in the present invention multifunctional (methyl) acrylate, it is possible to use at oligomer/polymer end End or side chain more than 2 by multifunctional (methyl) acrylate oligomer/polymer after (methyl) polyacryl or have 2 The monomer of individual above (methyl) acryloyl group.
As multifunctional (methyl) acrylate oligomer/polymer, can enumerate: the polyurethane of 1,2-polybutadiene end-blocking (methyl) acrylate (" TE-2000 ", " TEA-1000 " that such as, Cao Da company of Japan manufactures), above-mentioned hydride (example As, Japan Cao Da company manufacture " TEAI-1000 "), 1，4-polybutadiene end-blocking polyurethane (methyl) acrylate (example " BAC-45 " manufactured such as, Osaka organic chemistry company), (methyl) acrylate of polyisoprene end-blocking, polyester birds of the same feather flock together ammonia Ester (methyl) acrylate is (such as, on " UV-2000B ", " UV-3000B ", " UV-7000B " of the manufacture of Synesis Company of Japan, root Industrial group manufacture " KHP-11 ", " KHP-17 "), polyether polyurethane (methyl) acrylate (such as, Japan Synesis Company " UV-3700B ", " UV-6100B " manufactured), double A type epoxy (methyl) acrylate etc..Wherein, at effective aspect, excellent Polyester-based polyurethane (methyl) acrylate and/or polyether polyurethane (methyl) acrylate, more preferably polyester is selected to birds of the same feather flock together ammonia Ester (methyl) acrylate.
The weight average molecular weight of multifunctional (methyl) acrylate oligomer/polymer is preferably 10000～60000, more excellent Elect 13000～40000 as.Weight average molecular weight uses GPC system (SC-8010 that Dong Cao company manufactures) etc., by commercially available standard Polystyrene is made standard curve and obtains.
As two senses (methyl) acrylate monomer, can enumerate: 1,3 butylene glycol two (methyl) acrylate, Isosorbide-5-Nitrae-fourth Glycol two (methyl) acrylate, 1,6-hexanediol two (methyl) acrylate, 1,9-nonanediol two (methyl) acrylate, new Pentanediol two (methyl) acrylate, two (methyl) acrylic acid dicyclo pentyl ester, 2-ethyl-2-butyl-propylene glycol (methyl) propylene Acid esters, neopentyl glycol modification trimethylolpropane two (methyl) acrylate, stearic acid modified pentaerythritol diacrylate, poly- Propylene glycol two (methyl) acrylate, 2, double (4-(methyl) acryloxy diethoxy phenyl) propane of 2-, 2, the double (4-of 2- (methyl) acryloxy propoxyphenyl) propane, 2,2-double (4-(methyl) acryloxy tetraethoxy phenyl) propane, 2- (1,2-ring six carboxyl acid imide) ethyl propylene acid esters, hexanediyl ester etc..Wherein, at effective aspect, preferably 1,6-hexanediol two (methyl) acrylate and/or two (methyl) acrylic acid dicyclo pentyl ester, more preferably two (methyl) acrylic acid is double Ring pentyl ester.
As trifunctional (methyl) acrylate monomer, can enumerate: trimethylolpropane tris (methyl) acrylate, three [(methyl) acryloyl-oxyethyl] isocyanuric acid ester etc..
As (methyl) acrylate monomers more than four senses, can enumerate: dihydroxy methylpropane four (methyl) acrylic acid Ester, tetramethylolmethane four (methyl) acrylate, tetramethylolmethane ethyoxyl four (methyl) acrylate, dipentaerythritol five (methyl) Acrylate, dipentaerythritol six (methyl) acrylate etc..
(A) multifunctional (methyl) acrylate, the most hydrophobic multifunctional (methyl) acrylate.So-called at this Hydrophobicity refer to be difficult to be dissolved in the character of water or be difficult to the character mixed with water.As hydrophobic multifunctional (methyl) third Olefin(e) acid ester, can enumerate such as: 1,3 butylene glycol two (methyl) acrylate, BDO two (methyl) acrylate, 1,6- Hexanediol two (methyl) acrylate, 1,9-nonanediol two (methyl) acrylate, neopentyl glycol two (methyl) acrylate, two (methyl) acrylic acid dicyclo pentyl ester, 2-ethyl-2-butyl-propylene glycol (methyl) acrylate, neopentyl glycol modification trihydroxy methyl Propane two (methyl) acrylate, stearic acid modified pentaerythritol diacrylate, polypropylene glycol two (methyl) acrylate, 2, Double (4-(methyl) the acryloxy diethoxy phenyl) propane of 2-, 2,2-is double (4-(methyl) acryloxy propoxyphenyl) Propane, 2,2-double (4-(methyl) acryloxy tetraethoxy phenyl) propane, 2-(1,2-ring six carboxyl acid imide) ethyl third Olefin(e) acid ester, hexanediyl ester etc..As hydrophobic trifunctional (methyl) acrylate monomer, can enumerate: three hydroxyl first Base propane three (methyl) acrylate, three [(methyl) acryloyl-oxyethyl] isocyanuric acid ester etc..As hydrophobic four officials (methyl) acrylate monomer more than can, can enumerate: dihydroxy methylpropane four (methyl) acrylate, tetramethylolmethane four (first Base) acrylate, tetramethylolmethane ethyoxyl four (methyl) acrylate, dipentaerythritol five (methyl) acrylate, two seasons penta Tetrol six (methyl) acrylate etc..In the case of water miscible, may consolidating due to resin combination when machining Compound is swelling and occurs position to deviate, and adds the dimensional accuracy in man-hour and is deteriorated, the most preferred.Even if be hydrophilic, as long as its group The solidfied material of compound will not be the most swelling due to water or be partly dissolved, then can also use.
In multifunctional (methyl) acrylate, at effective aspect, preferably comprise multifunctional (methyl) acrylate Oligomer/polymer and/or two senses (methyl) acrylate monomer, more preferably and with multifunctional (methyl) acrylate oligomers Thing/polymer and two senses (methyl) acrylate monomer.
And by multifunctional (methyl) acrylate oligomer/polymer and the situation of two senses (methyl) acrylate monomer Under content ratio, at multifunctional (methyl) acrylate oligomer/polymer and two senses (methyl) acrylate monomer Add up in 100 mass parts, by quality ratio, the most multifunctional (methyl) acrylate oligomer/polymer: two senses (methyl) Acrylate monomer=30～95: 5～70, more preferably 40～90: 60～10, most preferably 60～80: 40～20.
(A) consumption of multifunctional (methyl) acrylate, in total amount 100 mass parts of (A) and (B), preferably 1～90 Mass parts, more preferably 30～85 mass parts.More than 1 mass parts, then can sufficiently promote the solidfied material of compositions From adherend, the character (hereinafter referred to as " fissility ") of this solidfied material is peeled off, it is ensured that consolidating of compositions when impregnated in warm water Compound is with membranaceous stripping.It addition, below if 90 mass parts, the most there is not the possibility that initial adhesivity declines.
As (B) simple function (methyl) acrylate, it is possible to use simple function (methyl) acrylate monomer.As single official Energy (methyl) acrylate monomer, can enumerate: (methyl) acrylic acid methyl ester., (methyl) ethyl acrylate, (methyl) acrylic acid third Ester, (methyl) butyl acrylate, (methyl) 2-EHA, (methyl) Isooctyl acrylate monomer, (methyl) acrylic acid are different The last of the ten Heavenly stems ester, (methyl) lauryl acrylate, (methyl) octadecyl acrylate, (methyl) phenyl acrylate, (methyl) acrylic acid Cyclohexyl, (methyl) acrylic acid dicyclo pentyl ester, (methyl) acrylic acid dicyclopentenyloxyethyl methacrylate, (methyl) acrylic acid dicyclopentenyl epoxide second Ester, (methyl) isobornyl acrylate, methoxylation ring triolefin in the last of the ten Heavenly stems (methyl) acrylate, (methyl) acrylic acid 2-hydroxyl second Ester, (methyl) acrylic acid 2-hydroxy propyl ester, (methyl) acrylic acid 3-hydroxy propyl ester, (methyl) acrylic acid 4-hydroxybutyl, (first Base) acrylic acid tetrahydro furfuryl ester, (methyl) acrylic acid 2-hydroxyl-3-phenoxy-propyl, (methyl) glycidyl acrylate, oneself Lactone-modified tetrahydrofurfuryl (methyl) acrylate, (methyl) acrylic acid 3-chlorine-2-hydroxyl propyl ester, (methyl) acrylic acid N, N-bis- Methylamino ethyl ester, (methyl) acrylic acid N, N-lignocaine ethyl ester, (methyl) acrylic acid tertiary fourth amino ethyl ester, ethoxycarbonylmethyl group (methyl) acrylate, phenolethylene oxide modification acrylate, phenol (oxirane 2 mole) acrylate, phenol (oxirane 4 mole) acrylate, the ethylene-oxide-modified acrylate of p-cumylphenol, nonyl phenol EO are modified Acrylate, nonyl phenol (oxirane 4 mole) acrylate, nonyl phenol (oxirane 8 mole) acrylate, Nonyl phenol (expoxy propane 2.5 mole) acrylate, 2-ethylhexyl carbitol acrylate, ethylene-oxide-modified neighbour Phthalic acid (methyl) acrylate, ethylene-oxide-modified succinic acid (methyl) acrylate, (methyl) acrylic acid trifluoro ethyl ester, Acrylic acid, methacrylic acid, maleic acid, fumaric acid, ω-carboxyl-polycaprolactone list (methyl) acrylate, phthalic acid list Ethoxy (methyl) acrylate, (methyl) acrylic acid dimer, mono succinate β-(methyl) acryloyloxyethyl isocyanate, N- (methyl) acryloxyalkyl hexahydrophthalic phthalimide, 2-(1,2-ring six carboxyl acid imide) ethyl propylene acid esters etc..
(B) simple function (methyl) acrylate, is more preferably similarly hydrophobic simple function (methyl) acrylic acid with (A) Ester.At this, so-called hydrophobicity refers to be difficult to be dissolved in the character of water or be difficult to the character mixed with water.So-called hydrophobic list Sense (methyl) acrylate, can enumerate: (methyl) acrylic acid methyl ester., (methyl) ethyl acrylate, (methyl) propyl acrylate, (methyl) butyl acrylate, (methyl) 2-EHA, (methyl) Isooctyl acrylate monomer, (methyl) Isodecyl Ester, (methyl) lauryl acrylate, (methyl) octadecyl acrylate, (methyl) phenyl acrylate, (methyl) acrylic acid ring Own ester, (methyl) acrylic acid dicyclo pentyl ester, (methyl) acrylic acid dicyclopentenyloxyethyl methacrylate, (methyl) acrylic acid dicyclo amylene epoxide second Ester, (methyl) isobornyl acrylate, methoxylation ring triolefin in the last of the ten Heavenly stems (methyl) acrylate, (methyl) acrylic acid tetrahydrofurfuryl Ester, (methyl) acrylic acid 2-hydroxyl-3-phenoxy-propyl, (methyl) glycidyl acrylate, caprolactone modification tetrahydrofurfuryl (methyl) acrylate, (methyl) acrylic acid 3-chlorine-2-hydroxyl propyl ester, (methyl) acrylic acid N, N-dimethylaminoethyl, (first Base) acrylic acid N, N-lignocaine ethyl ester, (methyl) acrylic acid tertiary fourth amino ethyl ester, ethoxycarbonylmethyl group (methyl) acrylic acid Ester, phenolethylene oxide modification acrylate, phenol (oxirane 2 mole) acrylate, (oxirane 4 rubs phenol You are modified) acrylate, the ethylene-oxide-modified acrylate of p-cumylphenol, nonyl phenol EO modification acrylate, nonyl Base phenol (oxirane 4 mole) acrylate, nonyl phenol (oxirane 8 mole) acrylate, nonyl phenol (epoxy Propane 2.5 mole) acrylate, 2-ethylhexyl carbitol acrylate, ethylene-oxide-modified phthalic acid (first Base) acrylate, ethylene-oxide-modified succinic acid (methyl) acrylate, (methyl) acrylic acid trifluoro ethyl ester, ω-carboxyl-poly- Caprolactone list (methyl) acrylate, phthalic acid list ethoxy (methyl) acrylate, (methyl) acrylic acid dimer, amber Amber acid list β-(methyl) acryloyloxyethyl isocyanate, N-(methyl) acryloxyalkyl hexahydrophthalic phthalimide, 2-(1, 2-ring six carboxyl acid imide) ethyl propylene acid esters etc..In the case of water miscible, may be due to resin group when machining The solidfied material of compound is swelling and occurs position to deviate, and machining accuracy is deteriorated, the most preferred.Even if it addition, be hydrophilic, only The solidfied material wanting its resin combination will not be swelling because of water or be partly dissolved, then can also use.
In simple function (methyl) acrylate, at effective aspect, preferably comprise phenolethylene oxide 2 mole (methyl) acrylate and/or 2-(1,2-ring six carboxyl acid imide) ethyl (methyl) acrylate, more preferably and use phenol ring Oxidative ethane 2 mole (methyl) acrylate and 2-(1,2-ring six carboxyl acid imide) ethyl (methyl) acrylate.And use Phenolethylene oxide 2 mole (methyl) acrylate and 2-(1,2-ring six carboxyl acid imide) ethyl (methyl) acrylate In the case of content ratio, at phenolethylene oxide 2 mole (methyl) acrylate and 2-, (1,2-ring six carboxyl acyl is sub- Amine) ethyl (methyl) acrylate total 100 mass parts in, by quality ratio, preferably phenolethylene oxide 2 mole (methyl) acrylate: 2-(1,2-ring six carboxyl acid imide) ethyl (methyl) acrylate=30～90: 10～70, more preferably It is 40～80: 20～60, most preferably 50～70: 30～50.
(B) consumption of simple function (methyl) acrylate, in total amount 100 mass parts of (A) and (B), preferably 10～ 99 mass parts, more preferably 15～70 mass parts.As long as more than 10 mass parts, it is then not possible to make initial adhesivity decline, only If below 99 mass parts, it is possible to guarantee fissility, the solidfied material of compositions is with membranaceous stripping.
It addition, by the blend compositions of aforementioned (A) and (B) and with (methyl) acryloyl-oxyethyl acid phosphate Ester, dibutyl 2-(methyl) acryloyl-oxyethyl phosphate ester acid, dioctyl 2-(methyl) acryloyl-oxyethyl phosphate ester, Diphenyl 2-(methyl) acryloyl-oxyethyl phosphate ester, (methyl) acryloyl-oxyethyl Polyethylene Glycol acid phosphate ester etc. have There are vinyl or the phosphate ester of (methyl) acryloyl group, the adaptation to metal covering can be improved further.
(C) Photoepolymerizationinitiater initiater is to utilize the active ray of visible ray or ultraviolet to make its sensitization to promote resin group The photocuring of compound and the material that coordinates, can use known various Photoepolymerizationinitiater initiaters.As Photoepolymerizationinitiater initiater, can lift Go out: benzophenone and derivant thereof；Benzil and derivant thereof；Anthraquinone and derivant, benzoin, benzoin methylether, benzene are occasionally The benzoin derivatives such as relation by marriage ether, benzoin propyl ether, benzoin isobutyl ether, benzyl dimethyl ketal；Diethoxy acetophenone, The acetophenone derivs such as 4-tert-butyl group trichloroacetophenone；2-dimethyl aminoethyl benzoate, to dimethyl aminoethyl benzene Formic acid esters, Diphenyl disulfide ether, thiaxanthone and derivant thereof；Camphorquinone, 7,7-dimethyl-2,3-dioxo-bicyclo [2.2.1] Heptane-1-carboxylic acid, 7,7-dimethyl-2,3-dioxo-bicyclo [2.2.1] heptane-1-carboxyl-2-bromine ethyl ester, 7,7-dimethyl- 2,3-dioxo-bicyclos [2.2.1] heptane-1-carboxyl-2-methyl ester, 7,7-dimethyl-2,3-dioxo-bicyclo [2.2.1] heptan The camphorquinone derivative such as alkane-1-carboxylic acid chloride；2-methyl isophthalic acid-[4-(methyl mercapto) phenyl]-2-morpholinyl-1-acetone, 2-benzyl The alpha-aminoalkyl benzophenone derivatives such as base-2-dimethylamino-1-(4-morpholinyl phenyl)-1-butanone；Benzoyl diphenyl oxygen Change phosphine, TMDPO, benzoyl diethoxy phosphine oxide, 2,4,6-trimethylbenzene first The acylphosphine oxides such as acyl group Dimethoxyphenyl phosphine oxide, 2,4,6-trimethylbenzoyl diethoxy phenyl phosphine oxides derive Thing；Epoxide-phenyl-acetic acid 2-[2-oxo-2-phenyl-acetic acid base-ethyoxyl]-ethyl ester and/or epoxide-phenyl-acetic acid 2-[2- Hydroxy-ethoxy]-ethyl ester etc..Photoepolymerizationinitiater initiater can use a kind or be applied in combination two or more.Cause in these photopolymerization In agent, at effective aspect, be preferably selected from 1-benzyl dimethyl ketal, epoxide-phenyl-acetic acid 2-[2-oxo-2-phenyl- Acetate-ethyoxyl] one kind or two or more in-ethyl ester and epoxide-phenyl-acetic acid 2-[2-Hydroxy-ethoxy]-ethyl ester.
(C) consumption of Photoepolymerizationinitiater initiater, total 100 mass parts relative to (A) and (B) is preferably 0.1～30 mass Part.More preferably 0.5～25 mass parts.As long as being more than 0.1 mass parts, thus it is ensured that obtain the effect that solidification promotes, in 25 matter Sufficient curing rate can be obtained below amount part.As preferred mode, by using more than (C) composition 1 mass parts, can To solidify in the case of being independent of light irradiation dose, and then the crosslink density of the solidfied material of compositions increases, during machining just Position deviation etc. will not occur, in terms of improving fissility more preferably.
In the present invention, it is preferred to sticked with glue the glass transition temperature of the solidfied material that agent obtains at-50 DEG C by interim fixing ～in the range of 50 DEG C.Interim fixing the glass transition temperature of the solidfied material that agent obtains is sticked with glue at this model by making by above-mentioned In enclosing, component is carried out gluing interim fixing and after this most fixing component is processed, the component that this is processed When being immersed in the warm water of less than 100 DEG C, the interim fixing solidfied material thermal expansion significantly sticking with glue agent itself.Its result, due to Gluing area realizes reducing, thus adhesive strength declines, and therefore, it can the most only reclaim component.When by interim fixing glue When the glass transition temperature of the solidfied material that stick obtains is for more than-50 DEG C, it is less likely to occur during the component that processing is fixed temporarily Deviation, excellent in terms of dimensional accuracy.When less than 50 DEG C, warm water fissility is excellent.In terms of fissility and dimensional accuracy Consider, be more preferably-25 DEG C～45 DEG C by the above-mentioned interim fixing glass transition temperature sticking with glue the solidfied material that agent obtains, entered One step is preferably-20 DEG C～42 DEG C, is further preferably 0 DEG C～40 DEG C.
It should be noted that by the interim fixing glass transition sticking with glue the solidfied material that agent obtains used in the present invention The assay method of temperature is not particularly limited, and known method such as available DSC or dynamic viscoelastic spectrum etc. measures.Preferably method is The method utilizing dynamic viscoelastic spectrum.
In the present invention, it is preferred to (D) particulate matter insoluble in (A)～(C) is used with (A), (B) simultaneously.Thus, hold Easily make the thickness that the holding of the compositions after solidification is certain, the dimensional accuracy more simply adding man-hour can be improved.And then, owing to facing Time to fix the solidfied material sticking with glue agent different from the linear expansion coefficient of the particulate matter insoluble in (A)～(C), therefore, make With above-mentioned adhesive compound component carried out gluing interim fixing and after this most fixing component is processed, should When component after processing is immersed in the warm water of less than 100 DEG C, at component and the interface of the interim fixing solidfied material sticking with glue agent Wriggle fluctuating shape or 3 D deformation, its result occur, and gluing area reduces, and fissility further improves.
As the material of (D) particulate matter insoluble in (A)～(C), normally used organic and inorganic particle is the most permissible. As organic filler, can enumerate: polyethylene particles, polypropylene particles, crosslinked polymethylmethacrylaparticles particle, crosslinking polyphenyl second Alkene particles etc., as inorganic particulate, can enumerate the ceramic particle of glass, silicon dioxide, aluminium oxide, titanium etc..
(D) insoluble in (A)～the particulate matter of (C), add the dimensional accuracy in man-hour from improvement, i.e. control the thickness of adhesive From the standpoint of, the most spherical.As organic filler, preferably: utilize methyl methacrylate monomer, styrene monomer and friendship Connection property monomer known emulsion polymerization method obtain with the form of monodisperse particle crosslinked polymethylmethacrylaparticles particle, friendship Polystyrene particle or crosslinked polymethylmethacrylaparticles polystyrene copolymer particle.As inorganic particulate, due to spherical The deformation of silicon dioxide granule is little, particle diameter deviation the deviation of the thickness of the compositions after the solidification caused reduces, the most excellent Choosing.Wherein, from the standpoint of the reactivity of the bin stability caused by precipitation of particle etc. and compositions, more preferably cross-link Polymethyl methacrylate particle, crosslinked polystyrene particle or crosslinked polymethylmethacrylaparticles polystyrene copolymer grain Son, crosslinked polymethylmethacrylaparticles particle, crosslinked polystyrene particle, crosslinked polymethylmethacrylaparticles polystyrene copolymerization The mixture of any one or they of thing particle.Further preferably crosslinked polymethylmethacrylaparticles particle, crosslinked polystyrene The mixture of any one or they of particle and crosslinked polymethylmethacrylaparticles polystyrene copolymer particle.
(D) particulate matter insoluble in (A)～(C) utilizes mean diameter that laser method measures preferably in 5 μm～200 μm Scope.When the mean diameter of above-mentioned particulate matter is more than 5 μm, fissility is excellent, and when it is below 200 μm, processing is faced Time fixing component time deviation is less likely to occur, excellent in terms of dimensional accuracy.From the viewpoint of fissility and dimensional accuracy, Preferred mean diameter is 8 μm～150 μm, more preferably 9 μm～120 μm.It should be noted that the grain in the present invention Footpath and the standard deviation of particle diameter distribution, utilize " the laser diffraction formula particle size distribution device SALD-that Shimadzu Seisakusho Ltd. manufactures 2200 " it is measured.Particle diameter is volume reference.
It addition, the particle diameter (μm) utilizing laser method to measure of (D) particulate matter insoluble in (A)～(C) is used table of logarithm When showing, particle volume distribution relative to particle diameter standard deviation preferably 0.0001～0.25 scope.Grain when particulate matter The standard deviation in footpath is when this scope, because the deviation of the thickness of the compositions after the solidification that the deviation of particle diameter causes diminishes, and processing Being less likely to occur deviation during the component temporarily fixed, not only excellent in terms of dimensional accuracy, fissility also significantly improves.From size From the viewpoint of precision and fissility, the standard deviation of the particle diameter of particulate matter is more preferably 0.0001～0.15, the most excellent Elect 0.0001～0.1, further preferably 0.0001～0.08, particularly preferably 0.0001～0.072 as.
(D) consumption of the particulate matter insoluble in (A)～(C), from the standpoint of adhesive strength, machining accuracy, fissility, Total amount 100 mass parts relative to (A) and (B), preferably 0.1～20 mass parts, more preferably 0.2～10 mass parts, enter one Step is preferably 0.2～6 mass parts.
Interim fixing for the present invention sticks with glue agent, in order to improve its bin stability, it is possible to use a small amount of inhibition Agent.As polymerization inhibitor, can enumerate: methyl hydroquinone, hydroquinone, 2,2-methylene-bis-(4-methyl-6-tert butyl benzene Phenol), catechol, hydroquinone monomethyl ether, single tert-butyl hydroquinone, 2,5-di-tert-butyl hydroquinone, 1,4-benzoquinone, 2, 5-diphenyl-1,4-benzoquinone, 2,5-di-t-butyl-1,4-benzoquinone, picric acid, citric acid, phenothiazine, tert-butyl catechol, 2-fourth Base-4-HA and 2,6-di-t-butyl-paracresol etc..
For the consumption of these polymerization inhibitors, total amount 100 mass parts relative to (A) and (B), preferably 0.001～3 matter Amount part, more preferably 0.01～2 mass parts.Time more than 0.001 mass parts, it can be ensured that bin stability, below 3 mass parts Time, it is thus achieved that good adhesivity, also do not result in uncured.
Interim fixing in the present invention sticks with glue in agent, it is also possible to use polar organic solvent simultaneously.
Interim fixing for the present invention sticks with glue agent, is not affecting in the range of the purpose of the present invention, it is also possible to use The various elastomers such as commonly used acrylic rubber, polyurethane rubber, acrylonitrile-butadiene-styrene (ABS) rubber, inorganic fill out Fill thing, solvent, compatibilizing material, reinforcement material, plasticizer, thickening agent, dyestuff, pigment, fire retardant, silane coupler and surface to live The additives such as property agent.
Interim fixing/stripping means of the component of the present invention is as follows: stick with glue agent by above-mentioned side to using interim fixing After the component that method is fixed temporarily is processed, be impregnated in by this component processed in the warm water of less than 100 DEG C, removing have cured Interim fixing stick with glue agent.Utilize the present invention, do not use organic solvent, adding of the various components such as optics component can be improved Work precision.
According to the preferred embodiment of the present invention, removing processed component on the solidfied material of agent from interim fixing sticking with glue Time, interim fixing is sticked with glue agent irradiation visible ray or ultraviolet, thus can shorten will the fixing solidification sticking with glue agent temporarily Thing is immersed in the interim fixing time sticking with glue agent after removing solidification in the warm water of less than 100 DEG C.
In the present invention, from interim fixing stick with glue remove processed component on the solidfied material of agent time, to interim fixing Stick with glue agent and irradiate visible ray or the visible ray of ultraviolet or ultraviolet irradiation amount at wavelength 365nm for 1000mJ/cm2With Go up and 40000mJ/cm2In the case of below, can shorten and the fixing solidfied material sticking with glue agent temporarily is immersed in less than 100 DEG C Warm water in and interim fixing time sticking with glue agent after removing solidification effective, therefore preferably (irradiation process again).According to The amount of penetrating is more preferably 2000mJ/cm2Above and 38000mJ/cm2Below, more preferably 4000mJ/cm2Above and 36000mJ/cm2Below.
In the present invention, when using the warm water after suitably heating, the warm water of such as less than 100 DEG C, can be at short notice Realizing the fissility in water, productivity ratio improves, the most preferably.Using preferably 30 DEG C～100 DEG C, more preferably 40～99 DEG C In the case of warm water, the thermal expansion at short notice of the solidfied material of adhesive, the remnants produced during the most releasable compositions solidification Distortional stress.And then, different from the linear expansion coefficient of particulate matter owing to fixing the solidfied material sticking with glue agent temporarily, therefore, Use above-mentioned adhesive compound that component is carried out gluing interim fixing and after this most fixing component is processed, will When this component processed is immersed in the warm water of less than 100 DEG C, on the boundary of component with the interim fixing solidfied material sticking with glue agent There is wriggle fluctuating shape or 3 D deformation in face.Its result, gluing area reduces, and adhesive strength declines, can be with membranaceous by interim The fixing solidfied material sticking with glue agent removes.It should be noted that the interim fixing solidfied material sticking with glue agent is contacted with water Method, owing to the method being immersed in water together with conjugant is easy, therefore recommends.
Below, enumerate embodiment and comparative example illustrates in greater detail the present invention.The present invention is not limited to these embodiments.
Embodiment
(embodiment 1)
(the interim fixing making sticking with glue agent)
Sequentially built as described below is temporarily fixing sticks with glue agent.As (A) multifunctional (methyl) acrylate, make (polyester-based polyurethane acrylate, hereinafter referred to as " UV-3000B " are thin to " UV-3000B " manufactured with Synesis Company of Japan (methyl) acrylate of aqueous, weight average molecular weight 15000) 30 mass parts, diacrylate dicyclo pentyl ester (chemical medicine company of Japan " the KAYARAD R-684 " manufactured, hereinafter referred to as " R-684 ", for hydrophobic (methyl) acrylate) 15 mass parts；Make For (B) simple function (methyl) acrylate, use 2-(1,2-ring six carboxyl acid imide) ethyl propylene acid esters (East Asia Synesis Company Manufacture " ARONIX M-140 ", hereinafter referred to as " M-140 ", for hydrophobic (methyl) acrylate) 20 mass parts, phenol (" the ARONIX M-101A " that East Asia Synesis Company manufactures, for hydrophobic (methyl) for oxirane 2 mole acrylate Acrylate) 35 mass parts；As (C) Photoepolymerizationinitiater initiater, (Ciba Specialty Chemicals manufactures to use benzyl dimethyl ketal " IRGACURE651 ", hereinafter referred to as " BDK ") 10 mass parts；As (D) insoluble in (A)～the particulate matter of (C), use flat All particle diameter 100 μm, particle volume distribution when being represented with logarithm by particle diameter (μm) are 0.063 relative to the standard deviation of particle diameter Spherical crosslinked polystyrene particle (GANZ is melted into " GS-100S " that company manufactures) 1 mass parts；As polymerization inhibitor, use 2,2- Methylene-bis-(4-methyl-6-tert-butylphenol) (" ス ミ ラ イ ザ mono-MDP-S " that Sumitomo Chemical Co. Ltd. manufactures, below Referred to as " MDP ") 0.1 mass parts, makes resin combination.
Use obtained resin combination, carry out glass transition temperature with evaluation methodology shown below, stretch and cut Cut adhesive strength, disbonded test.These results are shown in table 1.It addition, putting down (D) particulate matter insoluble in (A)～(C) All particle diameter and particle volume distributions when being represented with logarithm by particle diameter (μm) are also carried out measuring relative to the standard deviation of particle diameter.
(evaluation methodology)
Glass transition temperature: with silicon chip thick for 1mm as mould plate, resin combination is inserted PET film.Had by use The solidification equipment that the Off ユ mono-ジ ヨ Application company of electrodeless discharge lamp manufactures, the accumulated light at 365nm wavelength is 2000mJ/cm2 Under conditions of, make resin combination after overlying cured, then be 2000mJ/cm at the accumulated light of 365nm wavelength2Under conditions of Make it from following solidification, make the solidfied material of the resin combination of thickness 1mm.It is long by the solidfied material sickle severing of making 50mm width 5mm, as glass transition temperature mensuration solidfied material.Obtained solidfied material is utilized Seiko electronic industry company Manufacture Measurement of Dynamic Viscoelasticity device " DMS210 ", in blanket of nitrogen to described solidfied material apply 1Hz draw direction should Power and deformation, measure tan δ with the ratio arm intensification limit of 2 DEG C per minute of programming rate, using the temperature of the summit of this tan δ as Glass transition temperature.
Tensile shear adhesive strength (" adhesive strength " in table): be measured according to JIS K 6850.Specifically, make It is used as being glued the heat resistant glass of material (25mm × 25mm × thickness 2.0mm), gluing position is set as diameter 8mm, by system The resin combination made makes 2 heat resistant glasses paste, and has the Off ユ mono-ジ ヨ Application company of electrodeless discharge lamp to manufacture by use Solidification equipment, the accumulated light at 365nm wavelength is 2000mJ/cm2Under conditions of make it solidify, make tensile shear gluing by force Degree test film.To the test film made, use universal testing machine, in the environment of temperature 23 DEG C, humidity 50%, with draw speed Tensile shear adhesive strength is measured for 10mm/min.
Disbonded test (" 80 DEG C of warm water splitting times " " stripping state " in table): coating compositions on above-mentioned heat resistant glass Thing so that it is be pasted onto on the soda-lime glass (150mm × 150mm × thickness 1.7mm) as supporter, in addition, with on Make the resin composition of making under conditions of stating equally, make disbonded test thing.Obtained trier is immersed in temperature In water (80 DEG C), measure the time that heat resistant glass is peeled off, also stripping state is observed.
The mean diameter of particulate matter and particle volume when being represented with logarithm by particle diameter (μm) are distributed relative to particle diameter Standard deviation (" insoluble in (A), (B), the standard deviation of the particle diameter of the particulate matter of (C) " in table): utilize laser diffraction formula Particle size distribution device (" SALD-2200 " that Shimadzu Seisakusho Ltd. manufactures) is measured.
(interim fixing/stripping means)
Soda-lime glass (150mm × 150mm × thickness 1.7mm) as fixing component is heated to 80 on hot plate DEG C, interim the fixing that coating 1g makes sticks with glue agent (painting process).Thereafter, the sodium calcium as processed component is carried from top Glass (80mm × 80mm × thickness 1.1mm) (lift-launch operation).Then, by the quartz glass of thickness 50mm (80mm × 80mm × Thickness 5mm) it is mounted in the soda-lime glass as processed component from top, from above-mentioned quartz glass, apply load, apply 12.5g/cm is added up to the wt part of quartz glass2Pressure, place 5 minutes (pressurization operation).Fix component and added The interval of work component, maximum the difference deducting minimum is below 5 μm.
Then, limit applies 12.5g/cm2Pressure side use black light lamp from the soda-lime glass side as fixing component, shine Penetrate the UV light 300mJ/cm of 365nm wavelength2(implementing irradiation process (30 seconds) with pressurization operation) simultaneously.Use cutter sweep, only Using the square that soda-lime glass severing is length of side 10mm as processed component of obtained adhesive test thing.Severing process The middle soda-lime glass as processed component does not fall off, and demonstrates good processability.To only will be as processed structure Adhesive test thing after the soda-lime glass severing of part, uses the UV light 16000mJ/cm of metal halide light irradiation 365nm wavelength2 Afterwards (irradiation process (40 seconds) again), being immersed in the warm water of 80 DEG C, result was completely exfoliated (warm water splitting time) in 1 minute. It addition, arbitrarily take out the severing test film after 10 these strippings, with optical microscope, the back side of its severing test film (is used interim Fixing stick with glue the face that agent is fixed temporarily) each limit observe, measure glass and the Breadth Maximum of indentation, there occur, obtain it and put down Average and standard deviation.And then, in order to interim fixing the sticking with glue after peeling off is fixed on the severing test film of agent temporarily Stick with glue the solidfied material film of agent, arbitrarily take out the severing test film after 10 strippings, utilize thickness gauge (MICRO GAUGE) to measure The thickness of the film of described solidfied material, obtains its meansigma methods and standard deviation.The glass on each limit is occurred the Breadth Maximum of indentation, there Meansigma methods and the meansigma methods of thickness of film of standard deviation and the interim fixing solidfied material sticking with glue agent and the survey of standard deviation Determine result and be shown in table 1.
Table 1
*) membranaceous: the adhesive compound after solidification from glass surface when without generation of adhesive deposit with membranaceous stripping.
**) generation of adhesive deposit: glass is peeled off, but the adhesive compound after solidification remains in glass surface.
Table 2
*) membranaceous: the adhesive compound after solidification from glass surface when without generation of adhesive deposit with membranaceous stripping.
**) generation of adhesive deposit: glass is peeled off, but the adhesive compound after solidification remains in glass surface.
Table 3
*) membranaceous: the adhesive compound after solidification from glass surface when without generation of adhesive deposit with membranaceous stripping.
**) generation of adhesive deposit: glass is peeled off, but the adhesive compound after solidification remains in glass surface.
Table 4
*) membranaceous: the adhesive compound after solidification from glass surface when without generation of adhesive deposit with membranaceous stripping.
**) generation of adhesive deposit: glass is peeled off, but the adhesive compound after solidification remains in glass surface.
(embodiment 2～7, comparative example 1,2)
Under conditions of shown in table 1～2,4, implement interim fixing/stripping means, in addition, grasp similarly to Example 1 Make, measure the glass on each limit and the meansigma methods of Breadth Maximum of indentation, there and standard deviation occur and interim fixing sticks with glue consolidating of agent The meansigma methods of the thickness of compound film and standard deviation, be shown in table 1～2,4 by its measurement result.
(embodiment 8～11)
Composition as shown in table 2,3 uses the raw material of the kind shown in table 2,3, in addition, grasps similarly to Example 1 Make, measure the glass on each limit and the meansigma methods of Breadth Maximum of indentation, there and standard deviation occur and interim fixing sticks with glue consolidating of agent The meansigma methods of the thickness of compound film and standard deviation, be shown in table 2,3 by its measurement result.
(embodiment 12)
As (D) insoluble in (A)～the particulate matter of (C), mean diameter is used to be 140 μm, particle diameter (μm) is used logarithm Particle volume during expression is distributed relative to the spherical crosslinked polymethylmethacrylaparticles particle that the standard deviation of particle diameter is 0.086 (" GM-5003 " that the company that is melted into by GANZ the manufactures sieve of the sieve that screen size is 150 μm and 125 μm carries out sieving making Make), the composition as shown in table 3 uses the raw material of the kind shown in table 3, in addition, operates similarly to Example 1, and making is faced Time fixing stick with glue agent.Interim fixing stick with glue agent for obtained, implement similarly to Example 1 glass transition temperature, Tensile shear adhesive strength, disbonded test.It addition, to the mean diameter of (D) particulate matter insoluble in (A)～(C) and by grain Particle volume distribution when footpath (μm) represents with logarithm is also carried out measuring relative to the standard deviation of particle diameter.These results are shown in Table 3.
Use this temporarily fixing to stick with glue agent, implement interim fixing/stripping means under the conditions shown in Table 3, except this it Outward, operate similarly to Example 1, measure the glass on each limit occur the meansigma methods of Breadth Maximum of indentation, there and standard deviation and The meansigma methods of the thickness of the interim fixing solidfied material film sticking with glue agent and standard deviation.Its measurement result is shown in table 3.
(embodiment 13)
As (D) insoluble in (A)～the particulate matter of (C), mean diameter is used to be 40 μm, particle diameter (μm) is used table of logarithm (hydrops chemistry is public for the spherical crosslinked polystyrene particle that standard deviation is 0.062 of particle volume distribution relative grain size when showing " GS-240 " that department manufactures), the composition as shown in table 3 uses the raw material of the kind shown in table 3, in addition, same with embodiment 1 Sample operates, and makes interim fixing and sticks with glue agent.Agent is sticked with glue for obtained interim fixing, implements glass similarly to Example 1 Glass transition temperature, tensile shear adhesive strength, disbonded test.It addition, putting down (D) particulate matter insoluble in (A)～(C) All particle diameter and particle volume distributions when being represented with logarithm by particle diameter (μm) are also carried out measuring relative to the standard deviation of particle diameter.Will These results are shown in table 3.
Use this temporarily fixing to stick with glue agent, implement interim fixing/stripping means under the conditions shown in Table 3, except this it Outward, operate similarly to Example 1, measure the glass on each limit and meansigma methods and the standard deviation of Breadth Maximum of indentation, there occurs and faces Time fix the meansigma methods of thickness and the standard deviation of the solidfied material film sticking with glue agent.Its measurement result is shown in table 3.
(embodiment 14)
As (D) insoluble in (A)～the particulate matter of (C), mean diameter is used to be 20 μm, particle diameter (μm) is used table of logarithm (hydrops chemistry is public for the spherical crosslinked polystyrene particle that standard deviation is 0.061 of particle volume distribution relative grain size when showing " GS-220 " that department manufactures), the composition as shown in table 3 uses the raw material of the kind shown in table 3, in addition, same with embodiment 1 Sample operates, and makes interim fixing and sticks with glue agent.Agent is sticked with glue for obtained interim fixing, implements glass similarly to Example 1 Glass transition temperature, tensile shear adhesive strength, disbonded test.It addition, putting down (D) particulate matter insoluble in (A)～(C) All particle diameter and particle volume distributions when being represented with logarithm by particle diameter (μm) are also carried out measuring relative to the standard deviation of particle diameter.Will These results are shown in table 3.
Use this temporarily fixing to stick with glue agent, implement interim fixing/stripping means under the conditions shown in Table 3, except this it Outward, operate similarly to Example 1, measure the glass on each limit occur the meansigma methods of Breadth Maximum of indentation, there and standard deviation and The meansigma methods of the thickness of the interim fixing solidfied material film sticking with glue agent and standard deviation.Its measurement result is shown in table 3.
(embodiment 15)
As (D) insoluble in (A)～the particulate matter of (C), mean diameter is used to be 10 μm, particle diameter (μm) is used table of logarithm Particle volume distribution when showing is relative to spherical crosslinked polystyrene particle (the hydrops chemistry that the standard deviation of particle diameter is 0.058 " SP-210 " that company manufactures), the composition as shown in table 3 uses the raw material of the kind shown in table 3, in addition, with embodiment 1 Same operation, makes interim fixing and sticks with glue agent.Agent is sticked with glue for obtained interim fixing, implements similarly to Example 1 Glass transition temperature, tensile shear adhesive strength, disbonded test.It addition, to (D) particulate matter insoluble in (A)～(C) Mean diameter and the distribution of particle volume when being represented with logarithm by particle diameter (μm) are also carried out measuring relative to the standard deviation of particle diameter. These results are shown in table 3.
Use this temporarily fixing to stick with glue agent, implement interim fixing/stripping means under the conditions shown in Table 3, except this it Outward, operate similarly to Example 1, measure the glass on each limit and meansigma methods and the standard deviation of Breadth Maximum of indentation, there occurs and faces Time fix the meansigma methods of thickness and the standard deviation of the solidfied material film sticking with glue agent.Its measurement result is shown in table 3.
(use material)
UV-3700B: polyether polyurethane acrylate (Japan synthesis chemical company manufacture " UV-3700B "), hydrophobic (methyl) acrylate of property, weight average molecular weight 38000
1.6-X-A: hexanediyl ester (" the ラ イ ト ア Network リ レ mono-ト 1.6-HX-that chemical company of common prosperity society manufactures A "), hydrophobic (methyl) acrylate
I-754: epoxide-phenyl-acetic acid 2-[2-oxo-2-phenyl-acetic acid base-ethyoxyl]-ethyl ester and epoxide-phenyl- The mixture (" IRGACURE754 " that Qi Ba Japanese firm manufactures) of acetic acid 2-[2-Hydroxy-ethoxy]-ethyl ester
The present invention has to make the interval of fixing component and processed component uniformly be applied 1g/ by one or both cm2Above and 1000kg/cm2The pressurization operation of pressure below, and implement pressurization operation and irradiation process simultaneously, thus adding The dimensional accuracy of excellence can be obtained man-hour.
The present invention by with specific hydrophobicity (methyl) acrylic monomers, uses the specific composition that is combined Interim fixing sticks with glue agent, its solidfied material can be made not affected by cutting water etc., manifest high adhesive strength, and therefore, component adds man-hour Deviation is less likely to occur, is readily available processed component more excellent in terms of dimensional accuracy.By the present invention in that fixing component It is immersed in after processing in warm water with processed component, adhesive strength can be made to decline, fixing component and processed component gluing Power declines, and can easily reclaim processed component.
The present invention fixes according to it temporarily and sticks with glue the composition of agent and have light solidity, utilizes visible ray or ultraviolet to carry out Solidification.Therefore, compared with existing hot melt system adhesive, laborsaving, energy-conservation, shorten operation in terms of obtain significant effect.
The present invention, by implementing irradiation process in pressurization operation, obtains notable in terms of the dimensional accuracy of processed component Effect.That is, by implementing irradiation process in pressurization operation, the interim fixing thickness sticking with glue agent can easily be controlled.
By the present invention in that the interim fixing of the particulate matter little with the standard deviation being distributed containing particle volume sticks with glue Agent, it is thus achieved that preferred dimensional accuracy.
According to the present invention, interim fixing solidfied material, by the warm water of contact particularly less than 100 DEG C, makes under adhesive strength Fall, makes between component or the adhesive tension of component and fixture declines, therefore, it is thus achieved that can easily reclaim the such effect of component.Cause This, compared with the existing interim fixing interim fixing situation sticking with glue agent, can obtain and be required for costliness, ignitability By force or produce the such significant effect of organic solvent of harmful gas.
For the scope that specifically preferably constitutes interim fixing of the present invention sticks with glue agent, due to solidfied material and 100 DEG C Following warm water contact, can reclaim from component with membranaceous, therefore obtain the effect that operability is excellent.
The present invention in detail and is illustrated with reference to specific embodiment, but can be the ancestor without departing from the present invention Carry out various change in the case of purport and scope or revision will be apparent to those skilled in the art.
The application is based on Japanese patent application (Japanese Patent Application 2008-188295) filed in 22 days July in 2008, its content As reference in this.
Industrial applicability
For the method for temporarily fixing of the present invention, as optical lens, prism, array, silicon wafer, quasiconductor, structure is installed The interim fixing of part etc. sticks with glue agent, the most useful.

Claims (19)

1. a method of temporarily fixing, including: stick with glue agent be applied to the operation on fixing component, by processed by temporarily fixing Component sticks with glue agent irradiation visible ray or purple to interim fixing after being mounted in the interim fixing operation sticking with glue in agent and this lift-launch At least one in outside line improves the operation of the interim fixing adhesive tension sticking with glue agent, also includes from fixing component and processed One or both in component executes stressed operation, wherein, this is executed stressed operation with this operation being irradiated extremely Implementing certain time less, the Stress control that one or both from fixing component and processed component applies is at 1g/cm simultaneously2 Above and 1000kg/cm2Hereinafter, interim fixing sticks with glue agent for containing (A) multifunctional (methyl) acrylate, (B) simple function (methyl) acrylate and the compositions of (C) Photoepolymerizationinitiater initiater, in total amount 100 mass parts of (A) and (B) containing (A) 1～ 90 mass parts, (B) 10～99 mass parts, and total amount 100 mass parts relative to (A) and (B) contains (C) 0.1～30 mass Part, total amount 100 mass parts relative to (A) and (B) contains particulate matter (D) 0.1～20 mass parts insoluble in (A)～(C), Visible ray or ultraviolet irradiation amount are 1mJ/cm at wavelength 365nm2～4000mJ/cm2Scope.
2. a method of temporarily fixing, including: by temporarily fixing stick with glue agent be applied to the operation on processed component, will be fixing Component sticks with glue agent irradiation visible ray or purple to interim fixing after being mounted in the interim fixing operation sticking with glue in agent and this lift-launch At least one in outside line improves the operation of the interim fixing adhesive tension sticking with glue agent, also includes from fixing component and processed One or both in component executes stressed operation, wherein, this is executed stressed operation with this operation being irradiated extremely Implementing certain time less, the Stress control that one or both from fixing component and processed component applies is at 1g/cm simultaneously2 Above and 1000kg/cm2Hereinafter, interim fixing sticks with glue agent for containing (A) multifunctional (methyl) acrylate, (B) simple function (methyl) acrylate and the compositions of (C) Photoepolymerizationinitiater initiater, in total amount 100 mass parts of (A) and (B) containing (A) 1～ 90 mass parts, (B) 10～99 mass parts, and total amount 100 mass parts relative to (A) and (B) contains (C) 0.1～30 mass Part, total amount 100 mass parts relative to (A) and (B) contains particulate matter (D) 0.1～20 mass parts insoluble in (A)～(C), Visible ray or ultraviolet irradiation amount are 1mJ/cm at wavelength 365nm2～4000mJ/cm2Scope.
3. method of temporarily fixing as claimed in claim 1 or 2, wherein, by fixing component, interim fixing sticks with glue agent, is added In work component, any one above controls more than 0 DEG C and less than 150 DEG C.
4. method of temporarily fixing as claimed in claim 1 or 2, wherein, (A) and (B) is hydrophobicity.
5. method of temporarily fixing as claimed in claim 1 or 2, wherein, the interim fixing glass transition temperature sticking with glue agent For more than-50 DEG C and less than 50 DEG C.
6. method of temporarily fixing as claimed in claim 1 or 2, wherein, the shape of the particulate matter (D) insoluble in (A)～(C) For spherical.
7. method of temporarily fixing as claimed in claim 1 or 2, wherein, the particulate matter (D) insoluble in (A)～(C) is crosslinking Polymethyl methacrylate particle, crosslinked polystyrene particle and crosslinked polymethylmethacrylaparticles polystyrene copolymer particle In the mixture of any one or they.
8. method of temporarily fixing as claimed in claim 1 or 2, wherein, the particulate matter (D) insoluble in (A)～(C) average Particle diameter is 5 μm～200 μm.
9. method of temporarily fixing as claimed in claim 1 or 2, wherein, by the profit of the particulate matter (D) insoluble in (A)～(C) Particle volume distribution when the particle diameter logarithm that unit is μm measured with laser diffractometry represents is relative to the standard deviation of particle diameter Differ from the scope 0.0001～0.25.
10. interim fixing/stripping means of component, wherein, including: to using according to any one of claim 1 to 9 After method of temporarily fixing carries out interim fixing component processing, the component after this processing is immersed in the warm water of less than 100 DEG C, Remove the solidfied material of described compositions.
Interim fixing/the stripping means of 11. 1 kinds of components, wherein, including: to using according to any one of claim 1 to 9 After method of temporarily fixing carries out the most fixing component processing, interim fixing is sticked with glue agent irradiation visible ray or ultraviolet, will Component after this processing is immersed in the warm water of less than 100 DEG C, removes the solidfied material of described compositions.
12. interim fixing/stripping means as claimed in claim 11, it is characterised in that the component processing the most fixing to this The visible ray of rear irradiation or ultraviolet irradiation amount are 1000mJ/cm at wavelength 365nm2～40000mJ/cm2Scope.
13. method of temporarily fixing as claimed in claim 1 or 2, wherein, (A) multifunctional (methyl) acrylate contains many officials Can (methyl) acrylate oligomer/polymer and/or two senses (methyl) acrylate monomer.
14. method of temporarily fixing as claimed in claim 1 or 2, wherein, (A) multifunctional (methyl) acrylate contains many officials Can (methyl) acrylate oligomer/polymer and two senses (methyl) acrylate monomer.
15. method of temporarily fixing as claimed in claim 13, wherein, multifunctional (methyl) acrylate oligomer/polymer Containing polyester-based polyurethane (methyl) acrylate and/or polyether polyurethane (methyl) acrylate, and/or, two sense (first Base) acrylate monomer contains 1,6-HD two (methyl) acrylate and/or two (methyl) acrylic acid dicyclo pentyl ester.
16. method of temporarily fixing as claimed in claim 14, wherein, multifunctional (methyl) acrylate oligomer/polymer Containing polyester-based polyurethane (methyl) acrylate and/or polyether polyurethane (methyl) acrylate, and/or, two sense (first Base) acrylate monomer contains 1,6-HD two (methyl) acrylate and/or two (methyl) acrylic acid dicyclo pentyl ester.
17. method of temporarily fixing as claimed in claim 1 or 2, wherein, (B) simple function (methyl) acrylate contains phenol Oxirane 2 mole (methyl) acrylate and/or 2-(1,2-ring six carboxyl acid imide) ethyl (methyl) acrylate.
18. method of temporarily fixing as claimed in claim 1 or 2, wherein, (B) simple function (methyl) acrylate contains phenol Oxirane 2 mole (methyl) acrylate and 2-(1,2-ring six carboxyl acid imide) ethyl (methyl) acrylate.
19. method of temporarily fixing as claimed in claim 1 or 2, wherein, (C) Photoepolymerizationinitiater initiater contains selected from benzyl diformazan Base ketal, epoxide-phenyl-acetic acid 2-[2-oxo-2-phenyl-acetic acid base-ethyoxyl]-ethyl ester and epoxide-phenyl-acetic acid 2- One kind or two or more in [2-Hydroxy-ethoxy]-ethyl ester.
CN200980128706.3A 2008-07-22 2009-07-22 Interim fixing/stripping means of component and be suitable to the interim fixing of its and stick with glue agent Active CN102105546B (en)

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