CN102077829A - Efficient insecticidal bactericide containing R-diniconazole and chlorantraniliprole - Google Patents
Efficient insecticidal bactericide containing R-diniconazole and chlorantraniliprole Download PDFInfo
- Publication number
- CN102077829A CN102077829A CN2011100508797A CN201110050879A CN102077829A CN 102077829 A CN102077829 A CN 102077829A CN 2011100508797 A CN2011100508797 A CN 2011100508797A CN 201110050879 A CN201110050879 A CN 201110050879A CN 102077829 A CN102077829 A CN 102077829A
- Authority
- CN
- China
- Prior art keywords
- agent
- rynaxypyr
- alkene azoles
- mild
- pure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 17
- 239000003899 bactericide agent Substances 0.000 title claims abstract description 17
- 230000000749 insecticidal effect Effects 0.000 title claims abstract description 8
- FBOUIAKEJMZPQG-BLXFFLACSA-N diniconazole-M Chemical compound C1=NC=NN1/C([C@H](O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1Cl FBOUIAKEJMZPQG-BLXFFLACSA-N 0.000 title abstract description 9
- 239000005886 Chlorantraniliprole Substances 0.000 title abstract 4
- 201000010099 disease Diseases 0.000 claims abstract description 22
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 22
- 241000238631 Hexapoda Species 0.000 claims abstract description 16
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 239000007900 aqueous suspension Substances 0.000 claims abstract 2
- 239000007938 effervescent tablet Substances 0.000 claims abstract 2
- 239000003094 microcapsule Substances 0.000 claims abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 17
- 150000003851 azoles Chemical class 0.000 claims description 17
- 239000002917 insecticide Substances 0.000 claims description 16
- 239000002270 dispersing agent Substances 0.000 claims description 13
- 229910019142 PO4 Inorganic materials 0.000 claims description 12
- 239000010452 phosphate Substances 0.000 claims description 12
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 12
- 239000013530 defoamer Substances 0.000 claims description 10
- 239000000375 suspending agent Substances 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 8
- 238000009736 wetting Methods 0.000 claims description 8
- 239000000080 wetting agent Substances 0.000 claims description 8
- 229920001285 xanthan gum Polymers 0.000 claims description 8
- 239000005995 Aluminium silicate Substances 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims description 6
- 229960000892 attapulgite Drugs 0.000 claims description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 6
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical group O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 229910052625 palygorskite Inorganic materials 0.000 claims description 6
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000000645 desinfectant Substances 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 239000004562 water dispersible granule Substances 0.000 claims description 5
- 239000011230 binding agent Substances 0.000 claims description 4
- 239000007884 disintegrant Substances 0.000 claims description 4
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 claims description 4
- 229940043264 dodecyl sulfate Drugs 0.000 claims description 4
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- -1 polyoxyethylene nonylphenol Polymers 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 239000002562 thickening agent Substances 0.000 claims description 4
- 238000009472 formulation Methods 0.000 claims description 3
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 2
- 239000004480 active ingredient Substances 0.000 claims description 2
- 239000002518 antifoaming agent Substances 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 2
- 241000209094 Oryza Species 0.000 abstract description 32
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 32
- 235000009566 rice Nutrition 0.000 abstract description 32
- 230000000694 effects Effects 0.000 abstract description 8
- 239000003814 drug Substances 0.000 abstract description 7
- 229940079593 drug Drugs 0.000 abstract 2
- 239000008187 granular material Substances 0.000 abstract 2
- 241001530056 Athelia rolfsii Species 0.000 abstract 1
- 241000228982 Botyodes diniasalis Species 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000002552 dosage form Substances 0.000 abstract 1
- 239000012053 oil suspension Substances 0.000 abstract 1
- 239000000575 pesticide Substances 0.000 abstract 1
- 239000004548 suspo-emulsion Substances 0.000 abstract 1
- 239000004563 wettable powder Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 12
- 241000008892 Cnaphalocrocis patnalis Species 0.000 description 7
- 241000665051 Chilo sacchariphagus indicus Species 0.000 description 6
- 241000426497 Chilo suppressalis Species 0.000 description 6
- 241000894006 Bacteria Species 0.000 description 3
- 241000098289 Cnaphalocrocis medinalis Species 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 241000124008 Mammalia Species 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- OILXMJHPFNGGTO-UHFFFAOYSA-N (22E)-(24xi)-24-methylcholesta-5,22-dien-3beta-ol Natural products C1C=C2CC(O)CCC2(C)C2C1C1CCC(C(C)C=CC(C)C(C)C)C1(C)CC2 OILXMJHPFNGGTO-UHFFFAOYSA-N 0.000 description 1
- RQOCXCFLRBRBCS-UHFFFAOYSA-N (22E)-cholesta-5,7,22-trien-3beta-ol Natural products C1C(O)CCC2(C)C(CCC3(C(C(C)C=CCC(C)C)CCC33)C)C3=CC=C21 RQOCXCFLRBRBCS-UHFFFAOYSA-N 0.000 description 1
- OQMZNAMGEHIHNN-UHFFFAOYSA-N 7-Dehydrostigmasterol Natural products C1C(O)CCC2(C)C(CCC3(C(C(C)C=CC(CC)C(C)C)CCC33)C)C3=CC=C21 OQMZNAMGEHIHNN-UHFFFAOYSA-N 0.000 description 1
- 241000590412 Agromyzidae Species 0.000 description 1
- 241000254127 Bemisia tabaci Species 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241001124134 Chrysomelidae Species 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- DNVPQKQSNYMLRS-NXVQYWJNSA-N Ergosterol Natural products CC(C)[C@@H](C)C=C[C@H](C)[C@H]1CC[C@H]2C3=CC=C4C[C@@H](O)CC[C@]4(C)[C@@H]3CC[C@]12C DNVPQKQSNYMLRS-NXVQYWJNSA-N 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000256259 Noctuidae Species 0.000 description 1
- 206010033799 Paralysis Diseases 0.000 description 1
- 241000500437 Plutella xylostella Species 0.000 description 1
- 241000255893 Pyralidae Species 0.000 description 1
- 241001361634 Rhizoctonia Species 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- 241001558929 Sclerotium <basidiomycota> Species 0.000 description 1
- 241000251539 Vertebrata <Metazoa> Species 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010520 demethylation reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- DNVPQKQSNYMLRS-SOWFXMKYSA-N ergosterol Chemical compound C1[C@@H](O)CC[C@]2(C)[C@H](CC[C@]3([C@H]([C@H](C)/C=C/[C@@H](C)C(C)C)CC[C@H]33)C)C3=CC=C21 DNVPQKQSNYMLRS-SOWFXMKYSA-N 0.000 description 1
- 230000008686 ergosterol biosynthesis Effects 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 230000001617 migratory effect Effects 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 210000002460 smooth muscle Anatomy 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 210000002948 striated muscle cell Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an efficient insecticidal bactericide containing R-diniconazole and chlorantraniliprole, wherein the effective components comprise R-diniconazole and chlorantraniliprole; the mass percentage of the R-diniconazole is 10-30%; the mass percentage of the chlorantraniliprole is 10-30%; the dosage form of the insecticidal and bactericidal compound agent is water suspension agent, oil suspension agent, suspoemulsion, wettable powder, water dispersed granule, effervescent tablets, granule or micro-capsules. The insecticidal bactericide is used for preventing and treating diseases and insect pests of a plurality of crops such as rice banded sclerotial blight, rice vertical botyodes diniasalis walker and the like; the insecticidal bactericide has the effect of treating diseases and a plurality of insect pests by one medicine, reduces times for applying drug, reduces the drug application cost for preventing and treating the pests, reduces the selection difficulty of the farmers to the pesticides, facilitates ecological environment of farmlands, and protects excellent ecological environment of the farmlands.
Description
Technical field
The invention belongs to rice pest chemical control field, be specifically related to the efficient insecticide built disinfectant of the pure and mild Rynaxypyr of a kind of R-of containing alkene azoles, be mainly used in the control of multiple rice disease and pest insects such as preventing and treating rice sheath blight disease, rice blast, false smut and rice leaf roller, striped rice borer, paddy stem borer, pink rice borer, also can be used for the control of multiple damage by disease and insect on cotton, wheat, the seeding corn and other crops.
Background technology
Rice sheath blight disease and rice blast are the important diseases in growth period duration of rice all the time, cause heavy losses throughout the year.In recent years, rice green smut in Anhui, the generation of paddy fields such as Hubei, Jiangsu is in rising trend, also caused serious production loss, has a strong impact on rice quality simultaneously.Rice leaf roller, striped rice borer, paddy stem borer, pink rice borer be the interim hazard ratio of paddy growth more serious several insects, wherein rice leaf roller [Cnaphalocrocis medinalis (Guenee)] is a kind of migratory pest, in each rice district of China generation is arranged all, it is sudden strong, hazard area is wide, be one of paddy rice primary pest, cause the underproduction of paddy rice throughout the year.For a long time, people are devoted to study the control of rice sheath blight disease, rice blast, rice leaf roller, striped rice borer, paddy stem borer and pink rice borer always, and the control of false smut also more and more becomes the focus of concern advancing year.
Rynaxypyr belongs to the O-formammidotiazol-benzamide insecticide, high-efficiency broad spectrum, lepidopterous Noctuidae, Pyralidae, moth fruit moth section, tortricid, miller section, diamond-back moth section, Gelechidae, Gracilariidae etc. all there is excellent control effect, can also control the coleoptera Culculionidae, Chrysomelidae, multiple non-lepidoptera pests such as diptera Agromyzidae and Bemisia tabaci, especially very good really, the control time is very long to lepidopterous insect effect.Its mechanism of action mainly is to activate blue Buddhist nun's alkali acceptor, discharges the calcium ion of storing in smooth muscle and the striated muscle cell, causes that the muscle adjusting is weak, and paralysis is until last insect death.Rynaxypyr shows mammal and the extremely significant selective difference of the blue Buddhist nun's alkali of insect acceptor simultaneously, has improved greatly mammal and other vertebrate safeties.
R-alkene azoles alcohol suppresses 14 α-demethylation effect for belonging to triazole bactericidal agent in the ergosterol biosynthesis of fungi, cause that ergosterol lacks, and causes fungal cell membrane undesired, final fungi death, and the lasting period is permanent.To people and animals, useful insect, Environmental security.It is broad-spectrum germicide with protection, treatment, eradicant action; For capsule bacterium, the microbial plurality of plant diseases of load such as powdery mildew, rust, smut, scab etc. special efficacy is arranged.In addition, the disease that causes of also mould to the tail spore, ball chamber bacterium, sclerotinite, sclerotium bacteria, rhizoctonia has good control efficiency.
Rynaxypyr and R-alkene azoles alcohol are composite, and emphasis is at the control of paddy rice middle and later periods main diseases worm.With insect such as rice leaf folder, paddy stem borer, striped rice borer with line is withered, rice is bent and disease such as rice blast is a controlling object, enlarged the control spectrum of crop pest.Accomplished-medicine is controlled more, damage by disease and insect is planted by double Zhiduo County, reduces spraying times, can effectively reduce the dispenser cost of crop PCO, reduces the selection difficulty of peasant household to agricultural chemicals.Rynaxypyr and R-alkene azoles alcohol are composite, to farmland beneficial organism and Environmental security, have improved the control evil effect of natural enemy biology, have protected the good ecotope in farmland.
Summary of the invention
The efficient insecticide built disinfectant that the purpose of this invention is to provide the pure and mild Rynaxypyr of a kind of R-of containing alkene azoles is used to prevent and treat the disease and the insect pest of various crop such as rice pests such as rice sheath blight disease, rice blast, false smut, rice leaf roller, striped rice borer, paddy stem borer, pink rice borer and wheat, cotton, corn.
Technical scheme of the present invention is as follows:
The efficient insecticide bactericide that contains the pure and mild Rynaxypyr of R-alkene azoles, it is characterized in that: its active ingredient is two kinds of components of the pure and mild Rynaxypyr of R-alkene azoles, wherein, R-alkene azoles alcohol mass percent is 10%～30%, and the mass percent of Rynaxypyr is 10%～30%.
The described efficient insecticide built disinfectant that contains the pure and mild Rynaxypyr of R-alkene azoles, its formulation can the process water suspending agents, wetting powder, water-dispersible granules.
The described efficient insecticide bactericide that contains the pure and mild Rynaxypyr of R-alkene azoles, the consisting of of auxiliary agent when making suspending agent: surfactant 1～15%, thickener 0.1～2%, antifreezing agent 0.5～5%, defoamer 0.1～2%; Wherein surfactant is selected one or more mixing in castor oil polyoxyethylene ether (BY140 etc.), polyoxyethylene nonylphenol ether (NP-10 etc.), the sodium lignin sulfonate for use, thickener is selected in xanthans, the polyvinyl alcohol one or both for use, antifreezing agent selects in ethylene glycol or the propane diols one or both for use, defoamer is selected phosphoric acid ester defoamer or silicone defoaming agent for use, and water is surplus;
The described efficient insecticide built disinfectant that contains the pure and mild Rynaxypyr of R-alkene azoles, the consisting of of auxiliary agent when making wetting powder: wetting agent 1～15%, dispersant 1%～10%, filler are surplus; Wherein wetting agent is selected among neopelex, sldium lauryl sulfate octyl group phosphate or the JFC one or more for use, and dispersant is selected one or more in PVP, dispersing agent MF, the alkylphenol-polyethenoxy base phosphate for use; Filler is kaolin, attapulgite;
The described efficient insecticide bactericide that contains the pure and mild Rynaxypyr of R-alkene azoles, the consisting of of auxiliary agent when making water dispersible granules: wetting agent 1～15%, dispersant 1%～15%, disintegrant 0.5～4%, binding agent 0.5～8%; Wherein wetting agent is selected among neopelex, sldium lauryl sulfate octyl group phosphate or the JFC one or more for use, dispersant is selected one or more in PVP, dispersing agent MF, the alkylphenol-polyethenoxy base phosphate for use, disintegrant is selected among bentonite, white carbon, the PEG one or more for use, binding agent is selected one or more in xanthans, polyvinyl alcohol, the Sodium Polyacrylate for use, and filler is kaolin, attapulgite.
Advantage of the present invention composite dose:
Composite dose of Rynaxypyr of the present invention and R-alkene azoles alcohol, emphasis is at the control of paddy rice middle and later periods main diseases worm.With insect such as rice leaf folder, paddy stem borer, striped rice borer with line is withered, rice is bent and disease such as rice blast is a controlling object, enlarged the control spectrum of crop pest.Accomplished-medicine is controlled more, damage by disease and insect is planted by double Zhiduo County, reduces spraying times, can effectively reduce the dispenser cost of crop PCO, reduces the selection difficulty of peasant household to agricultural chemicals.Rynaxypyr and R-alkene azoles alcohol are composite, to farmland beneficial organism and Environmental security, have improved the control evil effect of natural enemy biology, have protected the good ecotope in farmland.
Embodiment
The invention will be further described below in conjunction with specific embodiment, but do not limit so.
Embodiment 1 (preparation method of 35% Rynaxypyr R-diniconazole suspending agent)
Composition of raw materials: by mass percentage
R-alkene azoles alcohol 10%
Rynaxypyr 25%
Sodium lignin sulfonate 5%
，BY140 3％
Xanthans 0.2%
Propane diols 1%
Phosphate defoamer 0.1%
Water surplus,
The preparation method is as follows:
According to prescription,, added the ball mill ball milling 30 minutes with the weighing in proportion of individual component, filter, suction dispersion tank high speed shear 3 minutes is after sand mill fully grinds, and control solid constituent particle diameter is in 2 microns, stir after grinding end, promptly get the suspending agent product.
Embodiment 2 (preparation method of 35% Rynaxypyr R-diniconazole suspending agent)
R-alkene azoles alcohol 15%
Rynaxypyr 20%
Sodium lignin sulfonate 5%
NP-10 4％
Xanthans 0.2%
Propane diols 1%
Phosphate defoamer 0.1%
Water surplus,
Preparation method: identical with embodiment 1.
Embodiment 3 (preparation method of 35% Rynaxypyr R-diniconazole suspending agent)
R-alkene azoles alcohol 20%
Rynaxypyr 15%
Sodium lignin sulfonate 5%
BY140 3％
Xanthans 0.2%
Propane diols 1%
Phosphate defoamer 0.1%
Water surplus,
Preparation method: identical with embodiment 1.
Embodiment 4 (preparation method of 35% Rynaxypyr R-diniconazole suspending agent)
R-alkene azoles alcohol 25%
Rynaxypyr 10%
Sodium lignin sulfonate 5%
BY140 3％
Xanthans 0.2%
Propane diols 1%
Phosphate defoamer 0.1%
Water surplus,
Preparation method: identical with embodiment 1.
Embodiment 5 (preparation method of 35% Rynaxypyr R-alkene azoles alcohol wetting powder)
Composition of raw materials: by mass percentage
R-alkene azoles alcohol 20%
Rynaxypyr 15%
Neopelex 7%
Dispersing agent MF 5%
White carbon 10%
Kaolin surplus/2
Attapulgite surplus/2,
The preparation method:
Above component is added mixer by formula rate mixes laggard promoting the circulation of qi stream and pulverize, pulverize and stir after finishing, get final product the wetting powder product.
Embodiment 6 (preparation method of 35% Rynaxypyr R-diniconazole water dispersible granule)
Composition of raw materials: by mass percentage
R-alkene azoles alcohol 20%
Rynaxypyr 15%
Neopelex 7%
Calcium lignosulfonate 5%
Polyvinyl alcohol 2.5%
White carbon 10%
Kaolin surplus/2
Attapulgite surplus/2,
The preparation method:
Above component is added mixer by formula rate mixes laggard promoting the circulation of qi stream and pulverize, pulverize and finish the back a small amount of purified water of adding and stir, extruder grain, get final product after the oven dry the wetting powder product.
Control efficiency:
The insecticidal bactericide of chloride worm benzamide and R-alkene azoles alcohol is used in the field and can effectively be prevented and treated rice sheath blight disease and rice leaf roller, sees Table one.From table one as seen, this insecticidal bactericide is suitable with contrast medicament 12.5%R-alkene azoles alcohol wetting powder, 20% Rynaxypyr suspending agent respectively to rice sheath blight disease and rice leaf roller preventive effect, it is double that to control effect obvious, the peasant is once sprayed medicine can prevent and treat rice disease and insect pest, has significantly improved and has prevented and treated efficient.
Field control effect after the dispenser of table one R-alkene azoles alcohol Rynaxypyr sterilizing insecticide secondary
Claims (3)
1. the efficient insecticide bactericide that contains the pure and mild Rynaxypyr of R-alkene azoles, it is characterized in that: its active ingredient is two kinds of components of the pure and mild Rynaxypyr of R-alkene azoles, wherein, R-alkene azoles alcohol mass percent is 10%～30%, and the mass percent of Rynaxypyr is 10%～30%.
2. according to the described efficient insecticide bactericide that contains the pure and mild Rynaxypyr of R-alkene azoles of claim 1, it is characterized in that: described composite dose of formulation is aqueous suspension agent, wetting powder, water-dispersible granules, effervescent tablet, granula or microcapsule formulations.
The described efficient insecticide bactericide that contains the pure and mild Rynaxypyr of R-alkene azoles, the consisting of of auxiliary agent when making suspending agent: surfactant 1～15%, thickener 0.1～2%, antifreezing agent 0.5～5%, defoamer 0.1～2%; Wherein surfactant is selected one or more mixing in castor oil polyoxyethylene ether (BY140 etc.), polyoxyethylene nonylphenol ether (NP-10 etc.), the sodium lignin sulfonate for use, thickener is selected in xanthans, the polyvinyl alcohol one or both for use, antifreezing agent selects in ethylene glycol or the propane diols one or both for use, defoamer is selected phosphoric acid ester defoamer or silicone defoaming agent for use, and water is surplus;
The described efficient insecticide built disinfectant that contains the pure and mild Rynaxypyr of R-alkene azoles, the consisting of of auxiliary agent when making wetting powder: wetting agent 1～15%, dispersant 1%～10%, filler are surplus; Wherein wetting agent is selected among neopelex, sldium lauryl sulfate octyl group phosphate or the JFC one or more for use, and dispersant is selected one or more in PVP, dispersing agent MF, the alkylphenol-polyethenoxy base phosphate for use; Filler is kaolin, attapulgite;
The described efficient insecticide bactericide that contains the pure and mild Rynaxypyr of R-alkene azoles, the consisting of of auxiliary agent when making water dispersible granules: wetting agent 1～15%, dispersant 1%～15%, disintegrant 0.5～4%, binding agent 0.5～8%; Wherein wetting agent is selected among neopelex, sldium lauryl sulfate octyl group phosphate or the JFC one or more for use, dispersant is selected one or more in PVP, dispersing agent MF, the alkylphenol-polyethenoxy base phosphate for use, disintegrant is selected among bentonite, white carbon, the PEG one or more for use, binding agent is selected one or more in xanthans, polyvinyl alcohol, the Sodium Polyacrylate for use, and filler is kaolin, attapulgite.
3. the efficient insecticide bactericide that contains the pure and mild Rynaxypyr of R-alkene azoles according to claim 1 and 2, it is characterized in that: described insecticidal bactericide is used for controlling crop diseases and insect pests.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102379290A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Ultralow volume liquid containing chlorantraniliprole |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1228256A (en) * | 1998-03-11 | 1999-09-15 | 赤国彤 | Seed coating agent series products |
| CN1231122A (en) * | 1998-04-09 | 1999-10-13 | 湖南省植物保护研究所 | Compound pesticide for comprehensively preventing and eliminating middle and later period plant diseases and insect pests of hybrid paddy rice |
| CN101117301A (en) * | 2007-07-17 | 2008-02-06 | 浙江省林业科学研究院 | Forestry nursery stock special-purposed compound preparation |
| CN101785455A (en) * | 2010-02-05 | 2010-07-28 | 深圳诺普信农化股份有限公司 | Pesticide oil suspension agent and preparation method thereof |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1228256A (en) * | 1998-03-11 | 1999-09-15 | 赤国彤 | Seed coating agent series products |
| CN1231122A (en) * | 1998-04-09 | 1999-10-13 | 湖南省植物保护研究所 | Compound pesticide for comprehensively preventing and eliminating middle and later period plant diseases and insect pests of hybrid paddy rice |
| CN101117301A (en) * | 2007-07-17 | 2008-02-06 | 浙江省林业科学研究院 | Forestry nursery stock special-purposed compound preparation |
| CN101785455A (en) * | 2010-02-05 | 2010-07-28 | 深圳诺普信农化股份有限公司 | Pesticide oil suspension agent and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102379290A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Ultralow volume liquid containing chlorantraniliprole |
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