CN102057908B - 一种含二氰蒽醌与甲氧基丙烯酸酯类的杀菌组合物 - Google Patents
一种含二氰蒽醌与甲氧基丙烯酸酯类的杀菌组合物 Download PDFInfo
- Publication number
- CN102057908B CN102057908B CN 201010597452 CN201010597452A CN102057908B CN 102057908 B CN102057908 B CN 102057908B CN 201010597452 CN201010597452 CN 201010597452 CN 201010597452 A CN201010597452 A CN 201010597452A CN 102057908 B CN102057908 B CN 102057908B
- Authority
- CN
- China
- Prior art keywords
- dithianon
- kresoxim
- enestroburin
- methyl
- pyraclostrobin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000005764 Dithianon Substances 0.000 title claims abstract description 153
- PYZSVQVRHDXQSL-UHFFFAOYSA-N dithianon Chemical compound S1C(C#N)=C(C#N)SC2=C1C(=O)C1=CC=CC=C1C2=O PYZSVQVRHDXQSL-UHFFFAOYSA-N 0.000 title claims abstract description 153
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 21
- 239000002131 composite material Substances 0.000 title abstract description 35
- 239000005800 Kresoxim-methyl Substances 0.000 claims abstract description 35
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 claims abstract description 35
- 201000010099 disease Diseases 0.000 claims abstract description 17
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 17
- 240000007594 Oryza sativa Species 0.000 claims abstract description 3
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 3
- 235000009566 rice Nutrition 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 47
- 239000000843 powder Substances 0.000 claims description 32
- 238000009736 wetting Methods 0.000 claims description 27
- 239000000375 suspending agent Substances 0.000 claims description 23
- 239000004562 water dispersible granule Substances 0.000 claims description 16
- 239000000839 emulsion Substances 0.000 claims description 8
- 239000000725 suspension Substances 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 4
- 239000000306 component Substances 0.000 claims description 2
- 235000013399 edible fruits Nutrition 0.000 claims description 2
- SINFYWWJOCXYFD-UHFFFAOYSA-N methoxymethyl prop-2-enoate Chemical class COCOC(=O)C=C SINFYWWJOCXYFD-UHFFFAOYSA-N 0.000 claims 4
- 235000013311 vegetables Nutrition 0.000 claims 1
- VMNULHCTRPXWFJ-UJSVPXBISA-N enoxastrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)\C=C\C1=CC=C(Cl)C=C1 VMNULHCTRPXWFJ-UJSVPXBISA-N 0.000 abstract description 44
- 239000005869 Pyraclostrobin Substances 0.000 abstract description 38
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 abstract description 38
- -1 methoxy acrylic ester compounds Chemical class 0.000 abstract description 36
- 230000002195 synergetic effect Effects 0.000 abstract description 18
- 239000000575 pesticide Substances 0.000 abstract description 11
- 241000233679 Peronosporaceae Species 0.000 abstract description 10
- 241000221785 Erysiphales Species 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 5
- 206010039509 Scab Diseases 0.000 abstract description 3
- 239000003899 bactericide agent Substances 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 238000001228 spectrum Methods 0.000 abstract description 2
- 230000001954 sterilising effect Effects 0.000 abstract 2
- 241000412366 Alternaria mali Species 0.000 abstract 1
- 241000233614 Phytophthora Species 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 32
- 238000012360 testing method Methods 0.000 description 20
- 239000003795 chemical substances by application Substances 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 239000002270 dispersing agent Substances 0.000 description 11
- 239000006185 dispersion Substances 0.000 description 10
- 230000001018 virulence Effects 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- 239000000440 bentonite Substances 0.000 description 9
- 229910000278 bentonite Inorganic materials 0.000 description 9
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 9
- 239000008367 deionised water Substances 0.000 description 9
- 229910021641 deionized water Inorganic materials 0.000 description 9
- 239000008187 granular material Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 231100000419 toxicity Toxicity 0.000 description 9
- 230000001988 toxicity Effects 0.000 description 9
- 239000000080 wetting agent Substances 0.000 description 9
- 230000003449 preventive effect Effects 0.000 description 8
- 231100000820 toxicity test Toxicity 0.000 description 8
- 241000223600 Alternaria Species 0.000 description 7
- 240000008067 Cucumis sativus Species 0.000 description 7
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 7
- 229920001732 Lignosulfonate Polymers 0.000 description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- 240000003377 Shepherdia canadensis Species 0.000 description 7
- 235000018324 Shepherdia canadensis Nutrition 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 150000004996 alkyl benzenes Chemical class 0.000 description 7
- 239000011575 calcium Substances 0.000 description 7
- 229910052791 calcium Inorganic materials 0.000 description 7
- 239000007859 condensation product Substances 0.000 description 7
- 239000013530 defoamer Substances 0.000 description 7
- 230000000149 penetrating effect Effects 0.000 description 7
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 6
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 6
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 6
- 230000002528 anti-freeze Effects 0.000 description 6
- 229940077388 benzenesulfonate Drugs 0.000 description 6
- 238000009313 farming Methods 0.000 description 6
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 6
- 229920001296 polysiloxane Polymers 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 241000255789 Bombyx mori Species 0.000 description 5
- 239000003905 agrochemical Substances 0.000 description 5
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 5
- 235000011130 ammonium sulphate Nutrition 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- 239000000470 constituent Substances 0.000 description 5
- 230000005764 inhibitory process Effects 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 5
- LDFKFZLKFVECOU-UHFFFAOYSA-N 5,10-dioxobenzo[g][1,4]benzodithiine-2,3-dicarbonitrile hydrate Chemical compound O.O=c1c2ccccc2c(=O)c2sc(C#N)c(sc12)C#N LDFKFZLKFVECOU-UHFFFAOYSA-N 0.000 description 4
- 206010067482 No adverse event Diseases 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 150000007942 carboxylates Chemical class 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000007884 disintegrant Substances 0.000 description 4
- 229940079593 drug Drugs 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 238000011835 investigation Methods 0.000 description 4
- 229920005646 polycarboxylate Polymers 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 229920002545 silicone oil Polymers 0.000 description 4
- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 239000005995 Aluminium silicate Substances 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 230000008485 antagonism Effects 0.000 description 3
- 229960000892 attapulgite Drugs 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052625 palygorskite Inorganic materials 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- 239000001488 sodium phosphate Substances 0.000 description 3
- 229910000162 sodium phosphate Inorganic materials 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 239000013638 trimer Substances 0.000 description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 2
- 244000215068 Acacia senegal Species 0.000 description 2
- 229920000084 Gum arabic Polymers 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 235000010489 acacia gum Nutrition 0.000 description 2
- 239000000205 acacia gum Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 230000009036 growth inhibition Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 229920000136 polysorbate Polymers 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- LYCAIKOWRPUZTN-NMQOAUCRSA-N 1,2-dideuteriooxyethane Chemical compound [2H]OCCO[2H] LYCAIKOWRPUZTN-NMQOAUCRSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 1
- YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical compound CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 description 1
- CUFXMPWHOWYNSO-UHFFFAOYSA-N 2-[(4-methylphenoxy)methyl]oxirane Chemical compound C1=CC(C)=CC=C1OCC1OC1 CUFXMPWHOWYNSO-UHFFFAOYSA-N 0.000 description 1
- AOBIOSPNXBMOAT-UHFFFAOYSA-N 2-[2-(oxiran-2-ylmethoxy)ethoxymethyl]oxirane Chemical compound C1OC1COCCOCC1CO1 AOBIOSPNXBMOAT-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- JCUDAMKYTWVICI-UHFFFAOYSA-N 4-benzyl-2,3-dimethylphenol Chemical compound C1=C(O)C(C)=C(C)C(CC=2C=CC=CC=2)=C1 JCUDAMKYTWVICI-UHFFFAOYSA-N 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229920005682 EO-PO block copolymer Polymers 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- KWYHKXQDUHJSGC-UHFFFAOYSA-N S1C(C#N)=C(C#N)SC2=C1C(=O)C1=CC=CC=C1C2=O.S1C(C#N)=C(C#N)SC2=C1C(=O)C1=CC=CC=C1C2=O Chemical compound S1C(C#N)=C(C#N)SC2=C1C(=O)C1=CC=CC=C1C2=O.S1C(C#N)=C(C#N)SC2=C1C(=O)C1=CC=CC=C1C2=O KWYHKXQDUHJSGC-UHFFFAOYSA-N 0.000 description 1
- 239000004283 Sodium sorbate Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004166 bioassay Methods 0.000 description 1
- ZCILODAAHLISPY-UHFFFAOYSA-N biphenyl ether Natural products C1=C(CC=C)C(O)=CC(OC=2C(=CC(CC=C)=CC=2)O)=C1 ZCILODAAHLISPY-UHFFFAOYSA-N 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000035613 defoliation Effects 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- CDZSUWIIEXAAET-UHFFFAOYSA-N dithiane 1-oxide Chemical compound O=S1CCCCS1 CDZSUWIIEXAAET-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- KFSLWBXXFJQRDL-UHFFFAOYSA-N peroxyacetic acid Substances CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 235000021003 saturated fats Nutrition 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- LROWVYNUWKVTCU-STWYSWDKSA-M sodium sorbate Chemical compound [Na+].C\C=C\C=C\C([O-])=O LROWVYNUWKVTCU-STWYSWDKSA-M 0.000 description 1
- 235000019250 sodium sorbate Nutrition 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201010597452 CN102057908B (zh) | 2010-12-26 | 2010-12-26 | 一种含二氰蒽醌与甲氧基丙烯酸酯类的杀菌组合物 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201010597452 CN102057908B (zh) | 2010-12-26 | 2010-12-26 | 一种含二氰蒽醌与甲氧基丙烯酸酯类的杀菌组合物 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102057908A CN102057908A (zh) | 2011-05-18 |
CN102057908B true CN102057908B (zh) | 2013-08-14 |
Family
ID=43993585
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 201010597452 Expired - Fee Related CN102057908B (zh) | 2010-12-26 | 2010-12-26 | 一种含二氰蒽醌与甲氧基丙烯酸酯类的杀菌组合物 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN102057908B (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102239866A (zh) * | 2011-04-19 | 2011-11-16 | 山东省烟台市农业科学研究院 | 含有二氰蒽醌和吡唑醚菌酯的复配杀菌剂及其应用 |
CN103704214B (zh) * | 2013-12-25 | 2015-09-09 | 江苏龙灯化学有限公司 | 一种杀菌剂组合物及其用途 |
CN105076161B (zh) * | 2014-05-08 | 2018-05-25 | 江苏龙灯化学有限公司 | 一种杀菌组合物 |
CN106614587A (zh) * | 2016-12-16 | 2017-05-10 | 海南正业中农高科股份有限公司 | 含有肟菌酯与二氰蒽醌的杀菌组合物及应用 |
CN107467028A (zh) * | 2017-08-23 | 2017-12-15 | 山东省果树研究所 | 一种含丁香菌酯和二氰蒽醌的杀菌组合物及其应用 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101755759A (zh) * | 2009-10-26 | 2010-06-30 | 陕西汤普森生物科技有限公司 | 一种含二氰蒽醌与嘧菌酯的杀菌组合物 |
-
2010
- 2010-12-26 CN CN 201010597452 patent/CN102057908B/zh not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101755759A (zh) * | 2009-10-26 | 2010-06-30 | 陕西汤普森生物科技有限公司 | 一种含二氰蒽醌与嘧菌酯的杀菌组合物 |
Non-Patent Citations (2)
Title |
---|
A.Brunelli等.Experimental trials on the activity of new fungicides against apple scab.《Pflanzenschutz-Nachrichten Bayer》.2003,第259-280页. |
Experimental trials on the activity of new fungicides against apple scab;A.Brunelli等;《Pflanzenschutz-Nachrichten Bayer》;20031231;第259-280页 * |
Also Published As
Publication number | Publication date |
---|---|
CN102057908A (zh) | 2011-05-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102017955B (zh) | 一种含叶菌唑与甲氧基丙烯酸酯类的杀菌组合物 | |
CN102067851B (zh) | 一种含多抗霉素与甲氧基丙烯酸酯类的杀菌组合物 | |
CN102057908B (zh) | 一种含二氰蒽醌与甲氧基丙烯酸酯类的杀菌组合物 | |
CN102113487A (zh) | 一种含氰霜唑与甲氧基丙烯酸酯类化合物的杀菌组合物 | |
CN102204536A (zh) | 一种含有啶氧菌酯与抗生素类化合物的杀菌组合物 | |
CN102239863B (zh) | 一种含有啶氧菌酯与硫代氨基甲酸酯类的杀菌组合物 | |
CN103238608A (zh) | 一种含氟嘧菌酯与抗生素类的杀菌组合物 | |
CN102057913B (zh) | 一种含有氟菌唑与三唑类化合物的杀菌组合物 | |
CN102027957A (zh) | 一种含有氰霜唑的杀菌组合物 | |
CN102197820A (zh) | 一种含有啶氧菌酯与苯并咪唑类的杀菌组合物 | |
CN102007914A (zh) | 一种含有氟菌唑的增效杀菌组合物 | |
CN102204552A (zh) | 一种含烯肟菌酯与抗生素类化合物的杀菌组合物 | |
CN102057909B (zh) | 一种含有氟菌唑与抗生素类化合物的杀菌组合物 | |
CN102037974B (zh) | 一种含灭菌唑与甲氧基丙烯酸酯类的杀菌组合物 | |
CN102007934B (zh) | 一种含有三乙膦酸铝与抗生素类化合物的杀菌组合物 | |
CN102057916A (zh) | 一种含有腈苯唑与甲氧基丙烯酸酯类化合物的杀菌组合物 | |
CN102204544A (zh) | 一种含有啶氧菌酯的增效杀菌组合物 | |
CN102217618B (zh) | 一种含肟菌酯与抗生素类化合物的杀菌组合物 | |
CN102027938B (zh) | 一种含有联苯三唑醇与甲氧基丙烯酸酯类的杀菌组合物 | |
CN102067859A (zh) | 一种含有种菌唑与硫代氨基甲酸酯类化合物的杀菌组合物 | |
CN102027935B (zh) | 一种含有二氰蒽醌与三唑类化合物的杀菌组合物 | |
CN102037969B (zh) | 一种含有亚胺唑与甲氧基丙烯酸酯类化合物的杀菌组合物 | |
CN103392719B (zh) | 一种含有亚胺唑与甲氧基丙烯酸酯类化合物的杀菌组合物 | |
CN103749459A (zh) | 一种含氰霜唑与甲氧基丙烯酸酯类化合物的杀菌组合物 | |
CN101999398A (zh) | 含三乙膦酸铝与甲氧基丙烯酸酯类化合物的杀菌组合物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee | ||
CP02 | Change in the address of a patent holder |
Address after: 715500 Pucheng County of Shaanxi Province agricultural base industrial park Patentee after: Shaanxi Welch Crop Protection Co.,Ltd. Address before: 710077, C, 15 floor, Jinqiao International Plaza, science and technology road, hi tech Zone, Shaanxi, Xi'an Patentee before: Shaanxi Welch Crop Protection Co.,Ltd. |
|
CP01 | Change in the name or title of a patent holder | ||
CP01 | Change in the name or title of a patent holder |
Address after: Industrial Park of agricultural chemical base in Pucheng County, Shaanxi Province Patentee after: Shaanxi yitianfeng crop Technology Co.,Ltd. Address before: Industrial Park of agricultural chemical base in Pucheng County, Shaanxi Province Patentee before: Shaanxi Welch Crop Protection Co.,Ltd. |
|
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130814 |