CN102040407B - Production method of amino acid complex microorganism fertilizer - Google Patents
Production method of amino acid complex microorganism fertilizer Download PDFInfo
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- CN102040407B CN102040407B CN 201010504078 CN201010504078A CN102040407B CN 102040407 B CN102040407 B CN 102040407B CN 201010504078 CN201010504078 CN 201010504078 CN 201010504078 A CN201010504078 A CN 201010504078A CN 102040407 B CN102040407 B CN 102040407B
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- amino acid
- fertilizer
- microbial inoculum
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 107
- 150000001413 amino acids Chemical class 0.000 title claims abstract description 75
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 57
- 244000005700 microbiome Species 0.000 title abstract description 33
- 238000000034 method Methods 0.000 claims abstract description 24
- 238000005469 granulation Methods 0.000 claims abstract description 21
- 230000003179 granulation Effects 0.000 claims abstract description 21
- 239000000463 material Substances 0.000 claims abstract description 16
- 239000007787 solid Substances 0.000 claims abstract description 15
- 230000008569 process Effects 0.000 claims abstract description 11
- 229940024606 amino acid Drugs 0.000 claims description 71
- 239000002131 composite material Substances 0.000 claims description 70
- 239000003795 chemical substances by application Substances 0.000 claims description 67
- 239000007788 liquid Substances 0.000 claims description 60
- 239000002068 microbial inoculum Substances 0.000 claims description 58
- 239000000047 product Substances 0.000 claims description 52
- 230000002906 microbiologic effect Effects 0.000 claims description 51
- 239000007921 spray Substances 0.000 claims description 44
- 239000002699 waste material Substances 0.000 claims description 39
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims description 36
- 241000894006 Bacteria Species 0.000 claims description 29
- 239000002245 particle Substances 0.000 claims description 29
- 241000194107 Bacillus megaterium Species 0.000 claims description 25
- 238000010521 absorption reaction Methods 0.000 claims description 22
- 230000001580 bacterial effect Effects 0.000 claims description 22
- 238000000855 fermentation Methods 0.000 claims description 18
- 230000004151 fermentation Effects 0.000 claims description 18
- 241000193830 Bacillus <bacterium> Species 0.000 claims description 17
- 230000000855 fungicidal effect Effects 0.000 claims description 17
- 239000000417 fungicide Substances 0.000 claims description 17
- 238000012262 fermentative production Methods 0.000 claims description 16
- 229940049906 glutamate Drugs 0.000 claims description 16
- 229930195712 glutamate Natural products 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 238000002360 preparation method Methods 0.000 claims description 15
- 241000881860 Paenibacillus mucilaginosus Species 0.000 claims description 14
- 239000007633 bacillus mucilaginosus Substances 0.000 claims description 14
- 244000063299 Bacillus subtilis Species 0.000 claims description 13
- 235000014469 Bacillus subtilis Nutrition 0.000 claims description 13
- 230000000813 microbial effect Effects 0.000 claims description 13
- 229960002989 glutamic acid Drugs 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 7
- 239000011573 trace mineral Substances 0.000 claims description 5
- 235000013619 trace mineral Nutrition 0.000 claims description 5
- 239000002609 medium Substances 0.000 claims description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 2
- 239000006227 byproduct Substances 0.000 claims description 2
- 239000000618 nitrogen fertilizer Substances 0.000 claims description 2
- 239000002686 phosphate fertilizer Substances 0.000 claims description 2
- 229940072033 potash Drugs 0.000 claims description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 2
- 235000015320 potassium carbonate Nutrition 0.000 claims description 2
- 238000001179 sorption measurement Methods 0.000 claims description 2
- 239000008187 granular material Substances 0.000 abstract description 8
- 238000002156 mixing Methods 0.000 abstract description 4
- 238000001035 drying Methods 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract 2
- 239000002054 inoculum Substances 0.000 abstract 2
- 239000000843 powder Substances 0.000 abstract 2
- 239000010808 liquid waste Substances 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 241000195940 Bryophyta Species 0.000 description 27
- 239000003415 peat Substances 0.000 description 27
- 239000004021 humic acid Substances 0.000 description 15
- 239000002994 raw material Substances 0.000 description 12
- 238000009736 wetting Methods 0.000 description 11
- 239000002689 soil Substances 0.000 description 9
- 235000015097 nutrients Nutrition 0.000 description 8
- 239000005416 organic matter Substances 0.000 description 8
- 208000006558 Dental Calculus Diseases 0.000 description 7
- 241000227653 Lycopersicon Species 0.000 description 7
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 7
- 238000007596 consolidation process Methods 0.000 description 7
- 238000000227 grinding Methods 0.000 description 7
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 5
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 235000019837 monoammonium phosphate Nutrition 0.000 description 5
- 239000006012 monoammonium phosphate Substances 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 4
- 235000011130 ammonium sulphate Nutrition 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 229910000365 copper sulfate Inorganic materials 0.000 description 4
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 235000013305 food Nutrition 0.000 description 4
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 description 4
- 239000004223 monosodium glutamate Substances 0.000 description 4
- 235000013923 monosodium glutamate Nutrition 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000005696 Diammonium phosphate Substances 0.000 description 3
- 241000209094 Oryza Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 3
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 3
- 235000019838 diammonium phosphate Nutrition 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000011790 ferrous sulphate Substances 0.000 description 3
- 235000003891 ferrous sulphate Nutrition 0.000 description 3
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 3
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 210000003608 fece Anatomy 0.000 description 2
- 230000004720 fertilization Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000011081 inoculation Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000010871 livestock manure Substances 0.000 description 2
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000012452 mother liquor Substances 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- 230000035764 nutrition Effects 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- -1 salt ions Chemical class 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
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- 239000007858 starting material Substances 0.000 description 2
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- 235000013311 vegetables Nutrition 0.000 description 2
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 description 1
- FRXSZNDVFUDTIR-UHFFFAOYSA-N 6-methoxy-1,2,3,4-tetrahydroquinoline Chemical compound N1CCCC2=CC(OC)=CC=C21 FRXSZNDVFUDTIR-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- VEMHQNXVHVAHDN-UHFFFAOYSA-J [Cu+2].[Cu+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O Chemical compound [Cu+2].[Cu+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O VEMHQNXVHVAHDN-UHFFFAOYSA-J 0.000 description 1
- YMKIRWHSXOBLCF-UHFFFAOYSA-N [Mg].[P].[Ca] Chemical compound [Mg].[P].[Ca] YMKIRWHSXOBLCF-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- RBUOVFCQLHVYOQ-UHFFFAOYSA-J dizinc disulfate Chemical compound [Zn+2].[Zn+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RBUOVFCQLHVYOQ-UHFFFAOYSA-J 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
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- 244000037666 field crops Species 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000009332 manuring Methods 0.000 description 1
- 235000019691 monocalcium phosphate Nutrition 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 235000021049 nutrient content Nutrition 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
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- 150000003384 small molecules Chemical class 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
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- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
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Abstract
The invention provides a production method of an amino acid complex microorganism fertilizer, in particular to a method for producing an amino acid complex microorganism fertilizer by using amino acid organic granules. The method comprises the following steps: preparing solid inoculant; pelleting amino acida liquid waste into organic granules; compounding the organic granules with solid powders; when compounding, adding powdery inoculant which accounts for 5-15% of the finished product complex microorganism fertilizer at weight ratio; and mixing, pelleting and drying, wherein the material temperature in a drying cylinder is not higher than 80 DEG C. The production method provided by the invention breaks the normal procedure and is divided into two steps of pelleting of the organic granules and the package of the organic granules, as well as ensures viable count in the complex microorganism fertilizer. The production method of the complex microorganism fertilizer provides a new process which realizes the breakthrough of the process from powder pelleting by a disc and a roller to spraying granulation, thus improving commodity and effectiveness of the complex microorganism fertilizer and laying a foundation for popularization.
Description
Technical field
The present invention relates to a kind of production method of novel particle composite microbiological fertilizer, specifically, relate to a kind of production method and application that utilizes the span amino acid mother liquor that produces in L-glutamic acid or monosodium glutamate (L-glutamic acid is the main raw material(s) of the producing monosodium glutamate) production process to produce high-efficiency environment friendly particle composite microbe fertilizer by the amino acid organic granular agent behind the spray granulating.
Background technology
Since using of a large amount of chemical fertilizer, soil compaction, deteriorating water quality, the agricultural-food severe contamination, whole farmland ecological environment and people's living environment is affected, and Sustainable development how to keep China's agricultural has caused the great attention of governments at all levels.Particularly after the China joined WTO; China's agricultural is subject to severe challenge; develop the outlet agriculture oriented for export and foreign exchange earnings; must carry forward vigorously the development of green food and pollution-free food; and under the impact of international financial crisis, traditional Fertilizer Industry is got deeply stuck in quagmire, and new-type fertilizer has but had good development space; tracing it to its cause is because " newly " in the new-type fertilizer, new science and technology, new fertilising theory and new product advantage.As the new-type fertilizer microbial fertilizer of production pollution-free food production data, become Ministry of Agriculture's emphasis and promoted product.But because microbial fertilizer is with high content of technology, production difficulty is large, and work of high quality also seldom on China market.The tool authoritative department is estimated: in 5 years of future, the annual requirement of microbial fertilizer will reach 30% of fertilizer amount, market capacity will reach the forty-two million ton, and 3,000,000 tons of present year output less thaies of China's microbial fertilizer, needs that far away can not satisfying the market.
Composite microbiological fertilizer is according to rhizosphere soil microecology and the plant principle of science of earning a living, take the active bacterium of multifunctional microbial (vinelandii, phosphate solubilizing bacteria, potassium bacterium) as core, take fertilizer type organic matter as carrier, having of being equipped with again that a small amount of inorganic nutrients and trace element process is pollution-free, nuisanceless, is suitable for producing the new-type fertilizer of green food.This new-type fertilizer can be to the farm crop fertilizer, can draw to crop rhizosphere soils again to be implanted with the beneficial microorganism dominant group, reaches the purpose of the strong sprout of fertilizing the soil, short biological and ecological methods to prevent plant disease, pests, and erosion disease and good quality and high output.According to the requirement of the composite microbiological fertilizer industry standard NY/T798-2004 of the Ministry of Agriculture, living bacteria count is the key technical indexes of this product, and the living bacteria count amount must be greater than 2,000 ten thousand/gram, total nutrient (N+P
2O
5+ K
2O) must be greater than 6%.But guarantee high number of viable, the support material that accounts for formula for a product ratio 70%-80% is the principal element that affects number of viable.Produce in the market the composite microbiological fertilizer product and mainly contain following technical problem:
1, mainly utilize the peat composed of rotten mosses or humic acids as organic carrier.Contain a large amount of organic matters in the peat composed of rotten mosses and the humic acids, C/N can guarantee the number of viable of microorganism than the life condition that meets microorganism.But the peat composed of rotten mosses and humic acids belong to mineral substance, be subjected to the restriction of national resources, a large amount of exploitations can destroy ecological, and execute in soil and to be difficult to dissolving, organic matter wherein and humic acids are difficult to by crop utilization, affect fertilizer efficiency, the price of the peat composed of rotten mosses and humic acids also goes up year by year simultaneously, and the production cost of product is also improving year by year.
2, product forms is mainly take powdery as main.Because contain viable bacteria in the composite microbiological fertilizer, the oven dry in the granulation process has a great impact number of viable, and because the peat composed of rotten mosses and humic acids belong to mineral attitude organic raw material, indissoluble solution more after the granulation, grain affects quality and the effect of product.But a lot of local arable land the in the north belongs to machine sowing, and powder-like product can't use, so granulating not directly has influence on using in a large number and promoting of product.
3, low with disk and drum granulating balling ratio, particle is irregular, and is rough, affected the visual appearance of product.
Summary of the invention
Therefore, the technical problem to be solved in the present invention provides production method a kind of cheapness, particle composite microbiological fertilizer that biological activity is high, solubility, and the method while resource utilization is high, Environmental Safety.
Technical scheme of the present invention is, the production method of a seed amino acid composite microbiological fertilizer comprises the preparation of microbial inoculum, and the method may further comprise the steps:
(1) preparation of solid fungicide: will utilize for the microbial bacteria of fertilizer field the fermentation equipment fermentative production, and after adsorption medium absorption, microbial inoculum be pulverized, the effective total viable count of bacterial classification reaches 3 * 10
8Individual/more than the gram;
(2) granulation: with the agent of amino acid waste liquid process spray granulating granulation amino acid organic granular;
(3) microbial inoculum dressing: the agent of amino acid organic granular is added in the tablets press, the microbial inoculum that when tablets press rotates step (1) is obtained adds according to the part by weight that accounts for finished product composite microbiological fertilizer 5-15%, and it is surperficial that microbial inoculum evenly is sprinkling upon the organic granular agent, spray form adds water or the amino acid waste liquid makes microbial inoculum stick to organic granular agent surface, forms the microbial inoculum dressing; With the particle composite microbiological fertilizer cold wind oven dry of even microbial inoculum dressing, the bake out temperature inlet temperature is at 120-150 ℃, and temperature of charge is not higher than 80 ℃ in dram.
This bake out temperature is oven drying at low temperature, can guarantee the activity of microbial inoculum.
The basic proterties of amino acid organic granular agent sees Table 1, and Fig. 1 is seen in concrete Production Flow Chart.
Table 1: amino acid organic granular agent proterties
As can be seen from Table 1, the total nutrient content (N+P of amino acid organic granular agent
2O
5+ K
2O) % has reached the requirement of " composite microbiological fertilizer " agricultural industry criteria (NY/T798-2004) total nutrient greater than 6%.
Bacterial classification in the step (1) can be single culture, also can be mixed strains, can determine concrete bacterial classification according to the character of different soil, crop.The effective total viable count of bacterial classification reaches 3-8 * 10 after the absorption
8Individual/more than the gram, the highest effective total viable count can reach 8 * 10
8Individual/gram, moisture remains in 30%.The medium of absorption can be the peat composed of rotten mosses, also can be other media such as powdered rice hulls, adopts the routine operation of this area to get final product.
Preferably, described microbial bacteria for fertilizer field is selected from subtilis (Bacillus subtilis), one or more in bacillus megaterium (Bacillus megaterium) and the Bacillus mucilaginosus (Bacillus mucilagimosus krassilm).These three kinds of bacterial classifications are in 80 ℃ of lower low temperature drying courses, and viability is higher.The microbial bacteria that is used for fertilizer field involved in the present invention is not limited to above three kinds, can select different microbe species according to different soil and the demand of crop, as adopting vinelandii etc.The kind of selected microbial bacteria and ratio should make its total living bacteria count after fermentation, absorption reach 3 * 10
8Individual/as more than the gram, then when solid fungicide dressing amino acid organic granular agent step, to determine the weight ratio that microbial inoculum adds according to the viable count of microbial inoculum, make the finished product meet the requirement of " composite microbiological fertilizer " agriculture standard (NY/T798-2004).
For example, when using separately subtilis (Bacillus subtilis), the fermentation of bacillus subtilis liquid of adding accounts for the 5%-8% of finished product composite microbiological fertilizer gross weight; During separately with bacillus megaterium (Bacillus megaterium), the bacillus megaterium fermented liquid of adding accounts for the 6%-10% of finished product composite microbiological fertilizer gross weight; During separately with Bacillus mucilaginosus (Bacillus mucilagimosus krassilm), the Bacillus mucilaginosus fermented liquid of adding accounts for the 8%-15% of finished product composite microbiological fertilizer gross weight; With subtilis (Bacillus subtilis) and bacillus megaterium (Bacillus megaterium) two bacterial classifications difference fermentative production, two kinds of fermented liquids were mixed by weight 1: 1, and the mixed fermentation liquid of adding accounts for the 5%-9% of finished product composite microbiological fertilizer gross weight; With subtilis (Bacillus subtilis) and Bacillus mucilaginosus (Bacillus mucilagimosus krassilm) two bacterial classifications difference fermentative production, two kinds of fermented liquids were mixed by weight 2: 1, and the mixed fermentation liquid of adding accounts for the 6%-10% of finished product composite microbiological fertilizer gross weight; With bacillus megaterium (Bacillus megaterium) and Bacillus mucilaginosus (Bacillus mucilagimosus krassilm) two bacterial classifications difference fermentative production, two kinds of fermented liquids were mixed by weight 2: 1, and the mixed fermentation liquid of adding accounts for the 8%-12% of finished product composite microbiological fertilizer gross weight.Subtilis (Bacillus subtilis), bacillus megaterium (Bacillus megaterium) and Bacillus mucilaginosus (Bacillus mucilagimosus krassilm) be fermentative production respectively, three kinds of fermented liquids are mixed by weight 1-3: 0.5-2: 0.5-2, and the mixed fermentation liquid of adding accounts for the 6%-15% of finished product composite microbiological fertilizer gross weight.
Described amino acid waste liquid is the by product in L-glutamic acid and the glutamate production process.
Produce the method for composite microbiological fertilizer according to amino acid organic granular agent of the present invention, be preferably, cool off behind the described baking operation, the cooling cylinder temperature out is lower than 35 ℃.
Further, described tablets press is granulating disc or roller pelletizer.The particle diameter of described finished product composite microbiological fertilizer is controlled at 1.0-4.0mm.This particle diameter can make the microbial inoculum dressing even, and the specific surface area of appropriate particle size also makes the living bacteria count in the microbial inoculum of parcel reach quality standards.
In a preferred embodiment, described step (2) can be added one or more of following material in the spray granulating operation: nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, trace element fertilizer.If the composite microbiological fertilizer of production Different Nutrients content can add nitrogen, phosphorus, potassium inorganic nutrients raw material in the spray granulating process, to improve total nutrient (N+P in the product
2O
5+ K
2O) content, its concrete prescription obtains according to the content of different material and the technical indicator cubage of product.Wherein the main raw material of N has: urea, ammonium sulfate; P
2O
5Main raw material have: monoammonium phosphate, diammonium phosphate, calcium superphosphate and calcium magnesium phosphorus; K
2The main raw material of O has: Repone K and vitriolate of tartar; Trace element in also can adding: magnesium sal epsom; Calcium nitrocalcite; The manganese manganous sulfate; Zinc zinc sulfate; The boron borax; Copper copper sulfate, iron is with ferrous sulfate etc.
Further, described step (2) can be added organic matter material in the spray granulating operation.If the composite microbiological fertilizer of production different organic matter contents, can in the spray granulating process, add organic matter material, to improve content organic in the product, concrete prescription obtains according to the content of organic matter material and the technical indicator cubage of product, and organic raw material has: the peat composed of rotten mosses, humic acids etc.
A large amount of high pollution discharging of waste liquid is a difficult problem that perplexs for a long time monosodium glutamate (L-glutamic acid is the main raw material of monosodium glutamate) manufacturing enterprise in the L-glutamic acid production process, the waste liquid of medium-sized manufacturing enterprise generation every day reaches kiloton, these waste liquid acidity are very strong, if do not deal carefully with the severe acidification that can cause soil and water after the discharging, pollution to environment will seriously restrict the development of glutamate production enterprise, the compulsory execution of the pollution treatment cost of great number and the national industrial policies of low-carbon economy and energy-saving and emission-reduction, a lot of enterprises stop production and close down.Owing to containing a large amount of soluble nitrogens, phosphorus, potassium nutrition, organic matter, amino acid, humic acids and various trace elements in the waste liquid, in order properly to dispose these waste liquids, a lot of glutamate production enterprises are through technological improvement, waste liquid is produced the agent of amino acid organic granular through concentrated whitewashing, turning waste into wealth has both solved the pollution problem of waste liquid, has produced again organic granular agent material product.But because the agent of amino acid organic granular is with low content of technology, added value is not high, has affected the popularization of product, but L-glutamic acid and glutamate production enterprise cause large-tonnage product to overstock in order to dispose waste liquid and can not to stop to produce, and cause heavy burden to enterprise.
The present invention utilizes in L-glutamic acid and the glutamate production process and to produce the amino acid waste liquid and make the agent of amino acid organic granular through spray granulating, then microbiobacterial agent is inoculated into the way of amino acid organic granular agent to reach the purpose of producing composite microbiological fertilizer.The invention solves balling-up problem and the dissolution problems of composite microbiological fertilizer, enlarge the product use range, not only can be used for the cash crop such as Southern Fruit Trees, vegetables and do the base fertilizer use, the mechanical fertilization that also can be used for the north, make things convenient for the peasant to use, and because cost of material cheaply is easy to get, and product price is also relatively cheap, make the result of use of product fast and obvious.Total nutrient (N+P in the composite microbiological fertilizer that the present invention produces
2O
5+ K
2O) can reach 6%-25%, meet " composite microbe fertilizer " agriculture standard (NY/T798-2004) fully, effectively solve the technical problem that composite microbiological fertilizer faces at present, remedy deficiency of the prior art, the production method of soluble composite microorganism fertilizer a kind of cheapness, high, the environmental protection of resource utilization is provided, makes simultaneously and produce amino acid waste liquid that L-glutamic acid produces and reach disposal of resources and effectively utilize.
From having disclosed data now: the material that has is also reported the production method of granulated fertilizer dressing bacteria agent, but see it is at inorganic composite fertilizer (or composite fertilizer) surface coatings microbial inoculum from example, because compound manure belongs to the chemical fertilizer of high-content, in the combination of surface coatings microbial inoculum owing to inorganic nutrients and microorganism, a large amount of salt ions infiltrates thalline can cause the microorganism mortality, can't play the purpose of effective inoculation, science not at chemical fertilizer or inorganic composite fertilizer surface coatings microbial inoculum, irrational.The simple declaration that is reported in organic granular agent surface coatings microbial inoculum is also arranged, but composition and the content of organic granular agent are not described, because the microorganism that contains in the microbiobacterial agent is living microorganism, different organic raw material has a great impact its vital movement, composition and the content of concrete organic granular agent are not described, also can't realize the possibility of dressing bacterial classification success, so the data granulated fertilizer dressing bacterial classification of above report does not have feasibility, and these data do not illustrate the technological standard that obtains product after the dressing microbial inoculum yet, can't obtain the license of country and realize producing and promoting.
Compared with prior art, the present invention has following beneficial effect:
1, a kind of new starting material are provided for composite microbe fertilizer production; broken the traditional mode of producing composite microbiological fertilizer with humic acids or the peat composed of rotten mosses; for a kind of new starting material have been found in the production of bio-feritlizer; and solved the production technique problem of utilizing this raw material; granulating and the solubility problem of composite microbiological fertilizer have also been solved; in the production cost that reduces bio-feritlizer, quality product is improved.
2, solved the technical barrier that utilizes spray granulating to produce bio-feritlizer: spray granulating uniform particles, smooth surface, granule strength are high, commodity is good, be easy to dissolve and be subject to user's welcome, but because the high temperature (above 1000 ℃) of spray granulating technique is dried and can't be carried out the production of microorganism particle fertilizer, spray can be fallen granulation and access the way that bacterial classification separately carries out by this Technology, realize production and the application of composite microbiological fertilizer whitewashing particle.
3, safety, environmental protection; present technique directly changes into the agent of amino acid organic granular and composite microbiological fertilizer with the waste liquid that produces in the L-glutamic acid production process; eliminated exhaust emission and because obtaining product good economic benefit has been arranged again; improvement is thorough, blowdown is zero; effluent resource; ecotope has been protected in the fully reuse and not effluxing of engineering non-wastewater discharge, the water of condensation that is produced by secondary steam.
4, solubilized, fertilizer efficiency is fast: produce composite microbiological fertilizer with the agent of amino acid organic granular, wherein contain a large amount of amino acid, solubility small molecules organic matter, micro-, amino acid can directly absorb for all parts of a plant, beneficial microorganism in the product can obtain a lot of nutrition from the agent of amino acid organic granular, Fast-propagation in soil namely can be observed positive effect in a short time after product is used.
5, can be directly in the dressing process come granulation with the amino acid waste liquid is wetting, not only obtained than the better adhesiving effect of water, and further increased the approach of recycling amino acid waste liquid.
6, enlarged the use range of product: with the composite microbiological fertilizer granulating, not only can be used for the vegetables fruit tree and make base fertilizer and use, also can be used for the land for growing field crops and carry out machine sowing, also use can be mixed with granular composite fertilizer, improved the market competitiveness of product.
7, raw material is easy to get, and technique is simple, can produce in enormous quantities, is not subjected to resource limit.
Description of drawings
Fig. 1 is amino acid organic granular agent output schema.
Fig. 2 is the agent of amino acid organic granular and powdery complex micro organism fungicide combined producing tech schema.
Embodiment
Embodiment 1
Amino acid waste liquid in the glutamate production process is a granulated into the organic granular agent, and the proterties of described organic granular agent sees Table 2.
Table 2: the basic proterties of amino acid organic granular agent
1, the preparation of powdery solid microbial inoculum: with subtilis (Bacillus subtilis), bacillus megaterium (Bacillus megaterium) and Bacillus mucilaginosus (Bacillus mucilagimosus krassilm) utilize the independent fermentative production of fermentation equipment, then with the peat composed of rotten mosses in bacterium liquid: the ratio absorption of the peat composed of rotten mosses=1: 4, with the ratio co-grinding of the single microbial inoculum after three kinds of absorption according to 2: 1: 1, make the total viable count that mixes rear three bacterial classifications reach 4.8 * 10
8Individual/gram, moisture remains on 28.3%.
2, dressing: open granulating disc, just the organic granular agent evenly adds disk, then sprays water or sprays into the amino acid waste liquid, at the wetting rear adding powdery complex micro organism fungicide of particle surface, makes the surface that sticks to the organic granular agent of the even consolidation of microbial inoculum.
Table 3: the production formula of amino acid composite microbe fertilizer
3, oven dry: the composite microbiological fertilizer particle behind the dressing is dried, and the oven dry of low temperature Wind Volume cold wind is taked in oven dry; The bake out temperature inlet temperature is at 120-150 ℃, and temperature of charge is not higher than 80 ℃ in dram;
4, cooling: material cools off in cooling cylinder, makes the cooling cylinder temperature out be lower than 35 ℃;
5, screening: with sieve apparatus particle is sieved, particle diameter is controlled at 3-4mm;
6, finished product: particle diameter is that finished product is packed at the microbial inoculum particle of 2-4mm.
Embodiment 2
Amino acid waste liquid spray granulating in the glutamate production process is become the organic granular agent, add urea and monoammonium phosphate, zinc sulfate during granulation.
The preparation of powdery solid microbial inoculum: with subtilis (Bacillus subtilis), bacillus megaterium (Bacillus megaterium) and Bacillus mucilaginosus (Bacillus mucilagimosus krassilm) utilize the independent fermentative production of fermentation equipment, then with the peat composed of rotten mosses in bacterium liquid: the ratio absorption of the peat composed of rotten mosses=1: 3, with the ratio co-grinding of the single microbial inoculum after three kinds of absorption according to 2.5: 1.2: 1.5, make the total viable count that mixes rear three bacterial classifications reach 4.3 * 10
8Individual/gram, moisture remains on 27.5%.
Dressing: open granulating disc, just the organic granular agent evenly adds disk, then sprays water or sprays into a small amount of amino acid waste liquid, at the wetting rear adding powdery complex micro organism fungicide of particle surface, makes the surface that sticks to the organic granular agent of the even consolidation of microbial inoculum.Microbial inoculum adds 7% by weight, and the organic granular agent adds 93%.
Other are with embodiment 1.
Embodiment 3
Amino acid waste liquid spray granulating in the glutamate production process is become the organic granular agent, add Repone K and monoammonium phosphate, sal epsom during granulation.
The preparation of powdery solid microbial inoculum: with subtilis (Bacillus subtilis), bacillus megaterium (Bacillus megaterium) and Bacillus mucilaginosus (Bacillus mucilagimosus krassilm) utilize the independent fermentative production of fermentation equipment, then with the peat composed of rotten mosses in bacterium liquid: the ratio absorption of powdered rice hulls=1: 2, with the ratio co-grinding of the single microbial inoculum after three kinds of absorption according to 3: 2: 1, make the total viable count that mixes rear three bacterial classifications reach 4.3 * 10
8Individual/gram, moisture remains on 27.5%.
Dressing: open granulating disc, just the organic granular agent evenly adds disk, then sprays water or sprays into a small amount of span amino acid mother liquor, at the wetting rear adding powdery complex micro organism fungicide of particle surface, makes the surface that sticks to the organic granular agent of the even consolidation of microbial inoculum.Microbial inoculum adds 10% by weight, and the organic granular agent adds 90%.
Other are with embodiment 1.
Embodiment 4
Amino acid waste liquid spray granulating in the glutamate production process is become the organic granular agent, add monoammonium phosphate and vitriolate of tartar, ferrous sulfate during granulation.
The preparation of powdery solid microbial inoculum: with subtilis (Bacillus subtilis), bacillus megaterium (Bacillus megaterium) and Bacillus mucilaginosus (Bacillus mucilagimosus krassilm) utilize the independent fermentative production of fermentation equipment, then with the peat composed of rotten mosses in bacterium liquid: the ratio absorption of the peat composed of rotten mosses=1: 4, with the ratio co-grinding of the single microbial inoculum after three kinds of absorption according to 4: 2: 0.8, make the total viable count that mixes rear three bacterial classifications reach 4.16 * 10
8Individual/gram, moisture remains on 27.5%.
Dressing: open granulating disc, just the organic granular agent evenly adds disk, then sprays water or sprays into a small amount of amino acid waste liquid, at the wetting rear adding powdery complex micro organism fungicide of particle surface, makes the surface that sticks to the organic granular agent of the even consolidation of microbial inoculum.Microbial inoculum adds 12% by weight, and the organic granular agent adds 88%.
Other are with embodiment 1.
Embodiment 5
Amino acid waste liquid spray granulating in the glutamate production process is become the organic granular agent, add monoammonium phosphate and vitriolate of tartar, ferrous sulfate during granulation.
The preparation of powdery solid microbial inoculum: subtilis (Bacillus subtilis) and bacillus megaterium (Bacillus megaterium) are utilized the independent fermentative production of fermentation equipment, then with the peat composed of rotten mosses in bacterium liquid: the ratio absorption of powdered rice hulls=1: 4, with the ratio co-grinding of the single microbial inoculum after two kinds of absorption according to 1: 1, the total viable count of two bacterial classifications reaches 4.5 * 10 after mixing
8Individual/gram, moisture remains on 26.5%.
Dressing: open roller pelletizer, evenly add the organic granular agent, then spray water or spray into a small amount of amino acid waste liquid, at the wetting rear adding powdery complex micro organism fungicide of particle surface, make the surface that sticks to the organic granular agent of the even consolidation of microbial inoculum.The microbial inoculum add-on is 6% of finished product composite microbiological fertilizer gross weight.
Other are with embodiment 1.
Embodiment 6
Amino acid waste liquid spray granulating in the glutamate production process is become the organic granular agent, add diammonium phosphate and vitriolate of tartar, copper sulfate during granulation.
The preparation of powdery solid microbial inoculum: subtilis (Bacillus subtilis) and Bacillus mucilaginosus (Bacillus mucilagimosus krassilm) are utilized the independent fermentative production of fermentation equipment, then with the peat composed of rotten mosses in bacterium liquid: the ratio absorption of the peat composed of rotten mosses=1: 4, with the ratio co-grinding of the single microbial inoculum after two kinds of absorption according to 2: 1, the total viable count of two bacterial classifications reaches 4.3 * 10 after mixing
8Individual/gram, moisture remains on 26.8%.
Dressing: open roller pelletizer, evenly add the organic granular agent, then spray water or spray into a small amount of amino acid waste liquid, at the wetting rear adding powdery complex micro organism fungicide of particle surface, make the surface that sticks to the organic granular agent of the even consolidation of microbial inoculum.The microbial inoculum add-on is 9% of finished product composite microbiological fertilizer gross weight.
Other are with embodiment 1.
Embodiment 7
Amino acid waste liquid spray granulating in the glutamate production process is become the organic granular agent, add diammonium phosphate and vitriolate of tartar, copper sulfate during granulation.
The preparation of powdery solid microbial inoculum: bacillus megaterium (Bacillus megaterium) and Bacillus mucilaginosus (Bacillus mucilagimosus krassilm) are utilized the independent fermentative production of fermentation equipment, then with the peat composed of rotten mosses in bacterium liquid: the ratio absorption of the peat composed of rotten mosses=1: 4, with the ratio co-grinding of the single microbial inoculum after two kinds of absorption according to 2: 1, the total viable count of two bacterial classifications reaches 4.16 * 10 after mixing
8Individual/gram, moisture remains on 27.5%.
Dressing: open roller pelletizer, evenly add the organic granular agent, then spray water or spray into a small amount of amino acid waste liquid, at the wetting rear adding powdery complex micro organism fungicide of particle surface, make the surface that sticks to the organic granular agent of the even consolidation of microbial inoculum.The microbial inoculum add-on is 8% of finished product composite microbiological fertilizer gross weight.
Other are with embodiment 1.
Embodiment 8
Amino acid waste liquid spray granulating in the glutamate production process is become the organic granular agent, add ammonium sulfate, vitriolate of tartar and copper sulfate during granulation.
The preparation of powdery solid microbial inoculum: Bacillus mucilaginosus (Bacillus mucilagimosus krassilm) utilizes the independent fermentative production of fermentation equipment, then with the peat composed of rotten mosses in bacterium liquid: the ratio absorption of the peat composed of rotten mosses=1: 4, the total viable count of bacterial classification reaches 2.3 * 10
8Individual/gram, moisture remains on 28.7%.
Dressing: open roller pelletizer, evenly add the organic granular agent, then spray water or spray into a small amount of amino acid waste liquid, at the wetting rear adding powdery complex micro organism fungicide 14% of particle surface.
Other are with embodiment 1.
Embodiment 9
Amino acid waste liquid spray granulating in the glutamate production process is become the organic granular agent, add ammonium sulfate, vitriolate of tartar and copper sulfate during granulation.
The preparation of powdery solid microbial inoculum: huge sample genus bacillus (Bacillus mucilagimosus krassilm) utilizes the independent fermentative production of fermentation equipment, then with the peat composed of rotten mosses in bacterium liquid: the ratio absorption of the peat composed of rotten mosses=1: 4, the total viable count of bacterial classification reaches 4.1 * 10
8Individual/gram, moisture remains on 27.9%.
Dressing: open roller pelletizer, evenly add the organic granular agent, then spray water or spray into a small amount of amino acid waste liquid, at the wetting rear adding powdery complex micro organism fungicide 9% of particle surface.
Other are with embodiment 1.
Embodiment 10
Amino acid waste liquid spray granulating in the glutamate production process is become the organic granular agent, add ammonium sulfate, Repone K and manganous sulfate during granulation.
The preparation of powdery solid microbial inoculum: huge sample genus bacillus (Bacillus mucilagimosus krassilm) utilizes the independent fermentative production of fermentation equipment, then with the peat composed of rotten mosses in bacterium liquid: the ratio absorption of the peat composed of rotten mosses=1: 4, the total viable count of bacterial classification reaches 5.1 * 10
8Individual/gram, moisture remains on 26.5%.
Dressing: open roller pelletizer, evenly add the organic granular agent, then spray water or spray into a small amount of amino acid waste liquid, at the wetting rear adding powdery complex micro organism fungicide 6% of particle surface.
Other are with embodiment 1.
Comparative example 1
Three, produce composite microbiological fertilizer with humic acids as organic materials
1, humic acid sampling.Come from Linfen, Shanxi, basic proterties sees Table 4
Table 4: the basic proterties of humic acids
| Project | Organic (%) | pH | Fineness (order) | Humic acids (%) | Moisture (%) | Miscellaneous bacteria rate (%) |
| Content | 51.6 | 5.7 | 100 | 40.3 | 20.6 | 16.4 |
The concrete preparation of complex micro organism fungicide and content's index are with embodiment 1.
2, batching: the formula table of pressing table 5 adds various materials in the stirrer, then stirs.
Table 5: the production formula of composite microbiological fertilizer
3, granulation: with carrying out granulation in the material adding granulating disc that stirs, make the diameter of most of grain at 2-4cm.
4, oven dry: adopt the oven dry of cylinder low-temperature cold wind, temperature can not surpass 120 ℃, makes the interior temperature of charge of dram be no more than 80 ℃.
5, cooling: material enters further lost moisture of cooling cylinder after the oven dry, makes pellet moisture less than 15%.
6, screening: by vibration separation screen, make finished product grain size at 1-4cm.
7, packing, metering, warehouse-in.
Product quality inspection
The examination and test of products is carried out according to the method for Ministry of Agriculture's industry standard (NY/T798-2004), with the agent of amino acid organic granular as organic raw material, produce particle composite microbial material product with powdery and liquid composite microbial microbial inoculum, and humic acids produces composite microbiological fertilizer as organic materials and preserves simultaneously and detect after 10 days, the results are shown in Table 6:
Table 6: the composite microbe fertilizer quality product detected result that different production methods are produced
Can find out from detected result: all reach more than 2,000 ten thousand/gram N+P in its living bacteria count quantity of the composite microbiological fertilizer product of producing behind the Mixed inoculation microbiobacterial agent in the agent of amino acid organic granular
2O
5+ K
2O is higher than 6%, granule strength is greater than 7N, granularity is all more than 90%, miscellaneous bacteria is no more than 9.5%, and moisture is lower than 8.5%, and indices is all considerably beyond the requirement of Ministry of Agriculture's industry standard, and the composite microbiological fertilizer moisture of producing with humic acids is high, the miscellaneous bacteria rate is high, and granule strength and granularity are low, and the commodity performance is starkly lower than the product that the agent of amino acid organic granular is produced.
Test effect:
Test is established three and is processed as follows respectively:
A: 100 kg/acres of amino acid composite microbe fertilizers (agent of amino acid organic granular and powdery complex micro organism fungicide are compound);
B: 100 kg/acres of composite microbe fertilizers (peat composed of rotten mosses and the granulation of pulvis complex micro organism fungicide complex disc).
Residential quarter area 20m
2, establish 3 repetitions, random district group is arranged.The trial crops tomato is tested fertile sample technical indicator mensuration and sees Table 5, and all tests are processed and all made base manure, and manuring late and management are identical with habits fertilization.Data statistical approach: yield data is checked significance with duncan's new multiple range method.
Table 7: different treatment on tomato trunk blade, highly, the impact of climing transverse diameter
Table 8: different treatment is on the impact of tomato yield
Table 7 can be found out: the number of blade, the plant height that three different treatment are processed tomato growth A all is significantly higher than B and processes the highlyest, illustrates that the amino acid composite microbe fertilizer will get well the common composite bio-fertilizer of the growth fraction of tomato.Table 8 can obviously be found out: the output that A processes than B processing tomato improves far away, illustrate and use this amino acid micro organism composite fertilizer more to be conducive to improve tomato growth and output than with common micro-organisms, amino acid composite biological fertilizer all more common composite microbe fertilizer effect of increasing production reaches utmost point conspicuous level.
Claims (6)
1. the production method of a seed amino acid composite microbiological fertilizer comprises the preparation of microbial inoculum, and it is characterized in that: the method may further comprise the steps:
(1) preparation of solid fungicide: will utilize for the microbial bacteria of fertilizer field the fermentation equipment fermentative production, and after adsorption medium absorption, microbial inoculum be pulverized, the effective total viable count of bacterial classification reaches 3 * 10
8Individual/more than the gram;
(2) granulation: with the agent of amino acid waste liquid process spray granulating granulation amino acid organic granular;
(3) microbial inoculum dressing: the agent of amino acid organic granular is added in the tablets press, the microbial inoculum that when tablets press rotates step (1) is obtained adds according to the part by weight that accounts for finished product composite microbiological fertilizer 5-15%, and it is surperficial that microbial inoculum evenly is sprinkling upon the organic granular agent, spray form adds water or the amino acid waste liquid makes microbial inoculum stick to organic granular agent surface, forms the microbial inoculum dressing; With the particle composite microbiological fertilizer cold wind oven dry of even microbial inoculum dressing, the bake out temperature inlet temperature is at 120-150 ℃, and temperature of charge is not higher than 80 ℃ in dram; Cool off behind the described baking operation, the cooling cylinder temperature out is lower than 35 ℃.
2. the production method of amino acid composite microbiological fertilizer according to claim 1, it is characterized in that: described microbial bacteria for fertilizer field is selected from subtilis (Bacillus subtilis), one or more in bacillus megaterium (Bacillus megaterium) and the Bacillus mucilaginosus (Bacillus mucilagimosus krassilm).
3. the production method of amino acid composite microbiological fertilizer according to claim 1, it is characterized in that: described amino acid waste liquid is the by product in L-glutamic acid and the glutamate production process.
4. the production method of amino acid composite microbiological fertilizer according to claim 1, it is characterized in that: described tablets press is granulating disc or roller pelletizer.
5. the production method of amino acid composite microbiological fertilizer according to claim 1, it is characterized in that: the particle diameter of described finished product composite microbiological fertilizer is controlled at 1.0-4.0mm.
6. the production method of amino acid composite microbiological fertilizer according to claim 1, it is characterized in that: described step (2) is added one or more of following material in the spray granulating operation: nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, trace element fertilizer.
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| CN102765983A (en) * | 2012-07-16 | 2012-11-07 | 江阴市联业生物科技有限公司 | Organic and inorganic compound fertilizer |
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| CN103964938B (en) * | 2014-03-21 | 2016-03-23 | 湖北吾尔利生物工程有限责任公司 | A kind of composite microbiological fertilizer |
| CN104725147A (en) * | 2015-02-12 | 2015-06-24 | 新疆阜丰生物科技有限公司 | Process for preparing organic-inorganic compound fertilizer from bio-fermented amino acid wastewater |
| CN105036974B (en) * | 2015-08-07 | 2018-06-29 | 沃达农业科技股份有限公司 | Amino acid microbial ecological fertilizer and its preparation and application |
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| CN106116834A (en) * | 2016-06-23 | 2016-11-16 | 深圳市芭田生态工程股份有限公司 | A kind of micro organism composite fertilizer improving quality of agricultural product |
| CN106116854A (en) * | 2016-06-25 | 2016-11-16 | 深圳市芭田生态工程股份有限公司 | A kind of fertilizer containing high functionality coated fertilizer |
| CN106116969A (en) * | 2016-06-29 | 2016-11-16 | 深圳市芭田生态工程股份有限公司 | A kind of micro organism composite fertilizer improving cropper resistance |
| CN108101707B (en) * | 2017-12-31 | 2021-04-06 | 三门峡龙飞生物工程有限公司 | Total nutrient microbial amino acid water-soluble fertilizer and preparation method thereof |
| CN111747785A (en) * | 2020-06-05 | 2020-10-09 | 中化农业生态科技(湖北)有限公司 | Microbial fertilizer and production method thereof |
| CN112209785B (en) * | 2020-10-10 | 2023-09-29 | 秦皇岛禾苗生物技术有限公司 | Columnar granular microbial fertilizer with double-layer structure |
| CN113336592A (en) * | 2021-05-13 | 2021-09-03 | 山东百沃生物科技有限公司 | Preparation process of granular microbial inoculum |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101468927A (en) * | 2007-12-27 | 2009-07-01 | 袁洋 | Biological organic inorganic compound fertilizer product and production method thereof |
| CN101544514A (en) * | 2008-10-29 | 2009-09-30 | 上海绿乐生物科技有限公司 | Production method of amino acid bio-organic fertilization fertilizer |
| CN101700986A (en) * | 2009-11-18 | 2010-05-05 | 陕西科技大学 | A kind of preparation technology of humic acid organic-inorganic multi-element fertilizer with core-shell structure |
-
2010
- 2010-10-12 CN CN 201010504078 patent/CN102040407B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101468927A (en) * | 2007-12-27 | 2009-07-01 | 袁洋 | Biological organic inorganic compound fertilizer product and production method thereof |
| CN101544514A (en) * | 2008-10-29 | 2009-09-30 | 上海绿乐生物科技有限公司 | Production method of amino acid bio-organic fertilization fertilizer |
| CN101700986A (en) * | 2009-11-18 | 2010-05-05 | 陕西科技大学 | A kind of preparation technology of humic acid organic-inorganic multi-element fertilizer with core-shell structure |
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