CN102009037B - 光电化学保护金属的方法 - Google Patents
光电化学保护金属的方法 Download PDFInfo
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- CN102009037B CN102009037B CN2010105177086A CN201010517708A CN102009037B CN 102009037 B CN102009037 B CN 102009037B CN 2010105177086 A CN2010105177086 A CN 2010105177086A CN 201010517708 A CN201010517708 A CN 201010517708A CN 102009037 B CN102009037 B CN 102009037B
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- nano titanium
- titanium oxide
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- metal
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Abstract
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Priority Applications (4)
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CN2010105177086A CN102009037B (zh) | 2010-10-25 | 2010-10-25 | 光电化学保护金属的方法 |
PCT/CN2011/079936 WO2012055308A1 (zh) | 2010-10-25 | 2011-09-21 | 光电化学保护金属的方法 |
US13/881,660 US9371589B2 (en) | 2010-10-25 | 2011-09-21 | Surface modified nano-scaled titanium dioxide, preparation process thereof, coating containing the same, and photoelectrochemical method for metal preservation using the coating |
EP11835581.7A EP2633923B1 (en) | 2010-10-25 | 2011-09-21 | Photoelectrochemicalmethod on metal preservation |
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CN2010105177086A CN102009037B (zh) | 2010-10-25 | 2010-10-25 | 光电化学保护金属的方法 |
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CN102009037A CN102009037A (zh) | 2011-04-13 |
CN102009037B true CN102009037B (zh) | 2013-06-19 |
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US (1) | US9371589B2 (zh) |
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Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102009037B (zh) | 2010-10-25 | 2013-06-19 | 江苏考普乐新材料股份有限公司 | 光电化学保护金属的方法 |
US9849512B2 (en) | 2011-07-01 | 2017-12-26 | Attostat, Inc. | Method and apparatus for production of uniformly sized nanoparticles |
CN102653652B (zh) * | 2012-05-02 | 2014-07-09 | 常州大学 | 一种纳米复合氟碳涂料及其制备方法 |
CN103436112A (zh) * | 2013-09-13 | 2013-12-11 | 句容联众科技开发有限公司 | 一种耐候性涂料 |
CN104402347B (zh) * | 2014-10-20 | 2016-04-13 | 苏州市建筑科学研究院集团股份有限公司 | 一种用于净化甲醛的硅藻泥装饰材料及其制备方法 |
US9839652B2 (en) | 2015-04-01 | 2017-12-12 | Attostat, Inc. | Nanoparticle compositions and methods for treating or preventing tissue infections and diseases |
US10774429B2 (en) | 2015-04-13 | 2020-09-15 | Attostat, Inc. | Anti-corrosion nanoparticle compositions |
US11473202B2 (en) | 2015-04-13 | 2022-10-18 | Attostat, Inc. | Anti-corrosion nanoparticle compositions |
US10201571B2 (en) | 2016-01-25 | 2019-02-12 | Attostat, Inc. | Nanoparticle compositions and methods for treating onychomychosis |
WO2018013863A1 (en) * | 2016-07-14 | 2018-01-18 | Arcanum Alloys, Inc. | Methods for forming stainless steel parts |
CN107856156B (zh) * | 2017-11-21 | 2019-05-03 | 浙江省林业科学研究院 | 一种纳米二氧化钛基木材防腐剂的制备方法 |
US11018376B2 (en) | 2017-11-28 | 2021-05-25 | Attostat, Inc. | Nanoparticle compositions and methods for enhancing lead-acid batteries |
US11646453B2 (en) | 2017-11-28 | 2023-05-09 | Attostat, Inc. | Nanoparticle compositions and methods for enhancing lead-acid batteries |
CN110280461A (zh) * | 2019-06-11 | 2019-09-27 | 西安华捷奥海新材料有限公司 | 一种长效波纹板隧道防岩爆装置耐腐蚀复合膜及实施方法 |
CN113930130A (zh) * | 2021-11-04 | 2022-01-14 | 淮安凯佳粉末涂料有限公司 | 一种热固性粉末涂料 |
CN114231993B (zh) * | 2021-12-20 | 2022-08-23 | 上海集优张力控制螺栓有限公司 | 一种金属防腐材料 |
CN115521559B (zh) * | 2022-10-26 | 2023-05-09 | 金塑企业集团(上海)有限公司 | 一种高硬度的pvc-u电工套管及其加工工艺 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1287138A (zh) * | 1999-09-03 | 2001-03-14 | 中国科学院固体物理研究所泰兴纳米材料厂 | 纳米二氧化钛表面处理 |
CN1970662A (zh) * | 2006-11-09 | 2007-05-30 | 上海大学 | 高耐腐蚀性纳米复合环氧树脂涂料的制备方法 |
CN101323719A (zh) * | 2007-06-15 | 2008-12-17 | 上海金力泰化工股份有限公司 | 建筑幕墙烤瓷涂料 |
CN101440143A (zh) * | 2007-11-20 | 2009-05-27 | 山东东岳神舟新材料有限公司 | 一种增加聚全氟乙丙烯树脂端基稳定性的聚合工艺 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5853809A (en) * | 1996-09-30 | 1998-12-29 | Basf Corporation | Scratch resistant clearcoats containing suface reactive microparticles and method therefore |
US20020045010A1 (en) * | 2000-06-14 | 2002-04-18 | The Procter & Gamble Company | Coating compositions for modifying hard surfaces |
CN1189528C (zh) * | 2001-12-21 | 2005-02-16 | 中国科学院金属研究所 | 一种纳米光催化聚氨酯涂料及其制备方法 |
CN1181151C (zh) | 2002-04-17 | 2004-12-22 | 中国科学院金属研究所 | 一种纳米光催化氟碳树脂涂料及其制备方法 |
CN1927966A (zh) * | 2005-09-09 | 2007-03-14 | 鸿富锦精密工业(深圳)有限公司 | 纳米涂料及其制备方法 |
CN100587016C (zh) * | 2007-07-06 | 2010-02-03 | 北京化工大学 | 一种防雾自洁型抗菌防霉喷涂剂的制备方法 |
CA2707829A1 (en) | 2007-12-04 | 2009-06-11 | W.R. Grace & Co. -Conn | Anticorrosion material |
CN101440243B (zh) * | 2008-12-25 | 2012-01-04 | 上海交通大学 | 纳米二氧化钛氟碳涂料及其制备方法 |
CN101985541B (zh) * | 2010-10-25 | 2013-03-20 | 江苏考普乐新材料股份有限公司 | 聚氨酯涂料及其制备方法 |
CN102009037B (zh) | 2010-10-25 | 2013-06-19 | 江苏考普乐新材料股份有限公司 | 光电化学保护金属的方法 |
CN102010000B (zh) * | 2010-10-25 | 2014-07-16 | 江苏考普乐新材料有限公司 | 纳米二氧化钛及其制备方法 |
CN101985536B (zh) | 2010-10-25 | 2013-04-03 | 江苏考普乐新材料股份有限公司 | 氟碳涂料及其制备方法 |
-
2010
- 2010-10-25 CN CN2010105177086A patent/CN102009037B/zh active Active
-
2011
- 2011-09-21 US US13/881,660 patent/US9371589B2/en active Active
- 2011-09-21 EP EP11835581.7A patent/EP2633923B1/en active Active
- 2011-09-21 WO PCT/CN2011/079936 patent/WO2012055308A1/zh active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1287138A (zh) * | 1999-09-03 | 2001-03-14 | 中国科学院固体物理研究所泰兴纳米材料厂 | 纳米二氧化钛表面处理 |
CN1970662A (zh) * | 2006-11-09 | 2007-05-30 | 上海大学 | 高耐腐蚀性纳米复合环氧树脂涂料的制备方法 |
CN101323719A (zh) * | 2007-06-15 | 2008-12-17 | 上海金力泰化工股份有限公司 | 建筑幕墙烤瓷涂料 |
CN101440143A (zh) * | 2007-11-20 | 2009-05-27 | 山东东岳神舟新材料有限公司 | 一种增加聚全氟乙丙烯树脂端基稳定性的聚合工艺 |
Non-Patent Citations (2)
Title |
---|
杨景花等.纳米二氧化钛的分散及对氟碳涂料的改性.《化工进展》.2006,第25卷(第7期),803-806. |
纳米二氧化钛的分散及对氟碳涂料的改性;杨景花等;《化工进展》;20061231;第25卷(第7期);第803-806页 * |
Also Published As
Publication number | Publication date |
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EP2633923A4 (en) | 2015-07-15 |
WO2012055308A1 (zh) | 2012-05-03 |
US20130224477A1 (en) | 2013-08-29 |
EP2633923A1 (en) | 2013-09-04 |
CN102009037A (zh) | 2011-04-13 |
US9371589B2 (en) | 2016-06-21 |
EP2633923B1 (en) | 2017-04-19 |
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