CN101999388A - Weeding composite with nicosulfuron and quinclorac - Google Patents

Weeding composite with nicosulfuron and quinclorac Download PDF

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Publication number
CN101999388A
CN101999388A CN2010105734427A CN201010573442A CN101999388A CN 101999388 A CN101999388 A CN 101999388A CN 2010105734427 A CN2010105734427 A CN 2010105734427A CN 201010573442 A CN201010573442 A CN 201010573442A CN 101999388 A CN101999388 A CN 101999388A
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China
Prior art keywords
nicosulfuron
quinolinic acid
dichloro quinolinic
acid
dichloro
Prior art date
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Pending
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CN2010105734427A
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Chinese (zh)
Inventor
王强
刘跃群
范福玉
李刚
吴松兰
姚刚
丁海胜
王现全
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WEIFANG CYNDA CHEMICAL CO Ltd
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WEIFANG CYNDA CHEMICAL CO Ltd
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Priority to CN2010105734427A priority Critical patent/CN101999388A/en
Publication of CN101999388A publication Critical patent/CN101999388A/en
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Abstract

The invention relates to a herbicide and particularly discloses a weeding composite with nicosulfuron and quinclorac. The active ingredient of the weeding composite is the mixture of nicosulfuron and quinclorac, wherein the ratio of the weight percentage of nicosulfuron to the weight percentage of quinclorac is 1-20%:40-1%. The weeding composite has wide herbicidal spectrum, good herbicidal effect on elder gramineous weeds, remarkable synergistic effect, low combination dosage and lower cost and environmental pollution.

Description

The Herbicidal combinations that contains nicosulfuron and dichloro quinolinic acid
(1) technical field
The present invention relates to a kind of weed killer herbicide, particularly a kind of Herbicidal combinations that contains nicosulfuron and dichloro quinolinic acid.
(2) background technology
Weeds are formidable enemies that crops produce, if it is not controlled, it is striven water and strives fertile characteristic and can bring heavy losses to crop.Corn is the staple food crop of China, nicosulfuron is one of main weed killer herbicide of corn field, can behind bud, effectively prevent and kill off multiple annual gramineae, broad leaved weed and sedge weed, it is by the leaf of plant and root absorbs and conduction rapidly, by suppressing the activity of acetolactate synthestase in the plant corpus, stop the synthetic of branched-chain amino acid and the prevention cell division.Use handle 4~5 days blades in back fade, downright bad and expand to whole plant very soon.The nicosulfuron high-efficiency broad spectrum, but a lot of shortcomings are also arranged,, not good such as low temperature to above the average age for marriage grassy weed to the grassy weed poor effect, to the responsive easily generation of a lot of serial corn varieties poisoning.
Dichloro quinolinic acid is interior absorption hormone herbicide, mainly absorbs by the weeds root, also can be absorbed by seeds germinated, and conduction makes weeds death in the weeds body, is mainly used to prevent and treat grassy weed.
(3) summary of the invention
The present invention provides the Herbicidal combinations that contains nicosulfuron and dichloro quinolinic acid that a kind of control efficiency is good, enlarge careless extremely spectrum in order to remedy the deficiencies in the prior art.
The present invention is achieved through the following technical solutions:
A kind of Herbicidal combinations that contains nicosulfuron and dichloro quinolinic acid, it is characterized in that: its active component is the mixture of nicosulfuron and dichloro quinolinic acid, the weight fraction ratio of nicosulfuron and dichloro quinolinic acid is 1~20%: 40~1%, preferred proportioning is 3~8%: 20~2%, and best proportioning is 3~6%: 20~10%.
Described dichloro quinolinic acid comprises dichloro quinolinic acid, dichloroquinoline acid sodium-salt, dichloro quinolinic acid methylamine salt, dichloro quinolinic acid ethylamine salt, dichloro quinolinic acid ethanolamine salt and dichloro quinolinic acid isopropyl amine salt.
Its active component accounts for 0.5~90% of composition weight, and preferred weight fraction is 0.5~50%.
Described composition is missible oil, wetting powder, granula, water dispersible granules, aqueous suspension agent, aqueous emulsion, dry suspending agent, microemulsion or oil-suspending agent.
Method of application of the present invention depends on specific application, in all cases, must guarantee that their dispersion is trickle as much as possible and even.
These preparations can prepare in a known manner, for example by active compound is mixed with solvent and carrier; If desired, can fill with emulsifier and dispersant; If water is cooked thinner, also can make cosolvent with other solvents.
The cosolvent that is fit to this purpose mainly is:
Solvent such as aromatic compound (as dimethylbenzene), chlorinated aromatic hydrocarbons compound (as chlorobenzene), paraffin (as petroleum distillate), alcohols (as methyl alcohol, ethanol), ketone (as cyclohexanone), amine (as monoethanolamine, dimethyl formamide) and water.
Carrier has the natural mineral matter (as kaolin, diatomite, calcite, talcum etc.) of grinding and the synthetic mineral matter (for example white carbon) that grinds.
Emulsifier has nonionic and anion emulsifier as (polyoxyethylene aliphatic alcohol ether, alkylsulfonate and arylsulphonate).
Dispersant has lignin sulfite waste liquor or methylcellulose.
Being fit to surface-active material is that aryl sulfonic acid is (as lignin sulfonic acid, phenolsulfonic acid, naphthalene sulfonic acids and dibutyl naphthalene sulfonic acids) and the alkali metal of fatty acid, alkaline earth metal and ammonium salt, alkylsulfonate and alkylaryl sulfonates, alkyl sulfate, lauryl ether sulfuric acid and aliphatic alcohol sulfate, and Sulfated 16-, 17-and the salt of octadecanol and fatty alcohol ether, the condensation product of gentle its derivative of sulfonated naphthalene and formaldehyde, the condensation product of naphthalene or naphthalene sulfonic acids and phenol and formaldehyde, dioxygen ethene octylphenol ether, the iso-octyl of ethoxylation-, octyl group or nonyl phenol, alkylphenol or tributyl phenyl polyglycol ether, different three decyl alcohol, the fatty alcohol ethylene oxide condensate, ethoxylated castor oil.Polyoxyethylene or polyoxypropylene alkyl ether, laruyl alcohol polyglycol ether acetic acid esters, sorbitan ester, lignin sulfite waste liquor or methylcellulose.
Moisture method of application can be by adding water, for example by missible oil, dispersion liquid, paste, wetting powder, effervescent tablet or water dispersion granule preparation.When preparation emulsion, paste, oily dispersion liquid or liquid water surface leafing agent, by adding the concentrate that wetting agent, adhesive, dispersant or emulsifier and possible solvent or oil are formed, this concentrate is fit to dilute with water.
Pulvis, spreading fertilizer over the fields pulvis, effervescent tablet, solid-state floater can be by mixing active substance or grinding and produce with solid matter.
Granule can prepare by reactive compound is adhered on the solid carrier.
Solid carrier is synthetic material such as white carbon, ammonium sulfate, ammonium phosphate, ammonium nitrate, urea and plant product such as flour, plant powder, sawdust, cellulose powder and other the solid powder carrier of ore soil as silica gel, silicic acid, silicate, talcum, kaolin, calcite, precipitated calcium carbonate, lime stone, diatomite, chalk, calcium sulphate, magnesium sulfate and grinding.
Application dosage of the present invention is generally 20~1000g a.i./ha according to different time, place, potential difference selectivity, weather conditions, preferred 50~300a.i./ha.Generally be foliage application, for example foliar spray is handled.
The present invention is applicable to annual gramineae hodgepodge and perennial broadleaf weeds such as directed spraying control barnyard grass grass, Ma Tang, lamb's-quarters, Amaranthus retroflexus, black nightshade, elscholtiza, piemarker, Commelina communis, bur beggar-ticks, eleusine indica, pale persicaria between corn full field spraying and other crop rows.
Broad weed-killing spectrum of the present invention, effective to above the average age for marriage grassy weed, synergistic effect is remarkable, and composite consumption is few, has reduced cost, has reduced environmental pollution.
(4) embodiment
Embodiment 1:18% missible oil
Raw material consumption (weight portion)
Nicosulfuron 8
Dichloro quinolinic acid 10
DMF 40
The newborn 500# 5 of farming
The newborn 600# 7 of farming
Dimethylbenzene 30
Nicosulfuron and dichloro quinolinic acid added be dissolved in the middle of DMF and the dimethylbenzene, add agricultural newborn 500# and agricultural newborn 600#, stir, promptly make described missible oil.
Embodiment 2:30% missible oil
Raw material consumption (weight portion)
Nicosulfuron 10
Dichloro quinolinic acid 20
DMF 45
The newborn 500# 5 of farming
The newborn 600# 7 of farming
Dimethylbenzene 13
Nicosulfuron and dichloro quinolinic acid added be dissolved in the middle of DMF and the dimethylbenzene, add agricultural newborn 500# and agricultural newborn 600#, stir, promptly make described missible oil.
Embodiment 3:30% oil-suspending agent
Raw material consumption (weight portion)
Nicosulfuron 4
Dichloro quinolinic acid 26
Soybean oil 45
The newborn 500# 7 of farming
NP-10 8
Dimethylbenzene 10
Nicosulfuron, dichloro quinolinic acid, soybean oil, 500#, NP-10, dimethylbenzene adding are sheared in the still and sheared, enter sand mill and be ground to required fineness, promptly make described suspending agent.
Embodiment 4:30% oil-suspending agent
Raw material consumption (weight portion)
Nicosulfuron 4
Dichloroquinoline acid sodium-salt 26
Soybean oil 45
The newborn 500# 7 of farming
NP-10 8
Dimethylbenzene 10
Nicosulfuron, dichloroquinoline acid sodium-salt, soybean oil, 500#, NP-10, dimethylbenzene adding are sheared in the still and sheared, enter sand mill and be ground to required fineness, promptly make described suspending agent.
Embodiment 5:30% aqueous suspension agent
Raw material consumption (weight portion)
Nicosulfuron 20
Dichloro quinolinic acid 10
Calcium lignosulfonate 8
NNO 3
NP-10 3
White carbon 2
Water 54
Nicosulfuron, dichloro quinolinic acid, calcium lignosulfonate, NNO, NP-10, white carbon, water adding are sheared in the still and sheared, enter sand mill and be ground to required fineness, promptly make described suspending agent.
Embodiment 6:50% wetting powder
Raw material consumption (weight portion)
Nicosulfuron 20
Dichloro quinolinic acid 30
Calcium lignosulfonate 6
NNO 3
K12 3
White carbon 5
Precipitated calcium carbonate 33
Nicosulfuron, dichloro quinolinic acid, calcium lignosulfonate, NNO, K12, white carbon, precipitated calcium carbonate are mixed at mixing kettle, enter comminution by gas stream, promptly make described wetting powder to required fineness.
Embodiment 7:50% dry suspending agent
Raw material consumption (weight portion)
Nicosulfuron 20
Dichloroquinoline acid sodium-salt 30
Calcium lignosulfonate 6
Draw back powder 3
White carbon 5
Ammonium sulfate 36
With nicosulfuron, dichloroquinoline acid sodium-salt, calcium lignosulfonate, draw back powder, white carbon, ammonium sulfate and mix at mixing kettle, enter comminution by gas stream to required fineness, extrusion modling promptly makes described dry suspending agent.
Embodiment 8:70% water dispersible granules
Raw material consumption (weight portion)
Nicosulfuron 10
Dichloroquinoline acid sodium-salt 60
Calcium lignosulfonate 6
NNO 3
Draw back powder 3
White carbon 5
Urea 13
With nicosulfuron, dichloroquinoline acid sodium-salt, calcium lignosulfonate, NNO, draw back powder, white carbon, urea and mix at mixing kettle, enter comminution by gas stream to required fineness, extruder grain promptly makes described water dispersible granules.
The biologicall test example:
For trying weed killer herbicide: 4% nicosulfuron oil-suspending agent, 5 proportionings of these two medicaments of 25% Dichloroquinolinic acid suspending agent
Reagent 1 2 3 4 5
Nicosulfuron 8 7 6 5 4
Dichloro quinolinic acid 2 3 4 5 6
Annotate: be the active ingredient W/W in the table.
Examination material: barnyard grass grass, eleusine indica, Commelina communis, kitchen garden
Effective dose:
Nicosulfuron oil-suspending agent 2.0,1.0,0.5,0.25,0.125 gram/mu
Dichloroquinolinic acid suspending agent 12,6,3,1.5,0.75 gram/mu
Mixed agent 1~No. 5 2.0,1.0,0.5,0.25,0.125 gram/mu
Assay method: indoor pot method, in barnyard grass grass, two leaf phases of eleusine indica, Commelina communis and kitchen garden rough leaf phase carry out cauline leaf and handle; 30 liters/mu of spray amount, measurement result was the fresh weight inhibiting rate, calculates ED90 value, co-toxicity coefficient in 15 days, relatively nicosulfuron, dichloro quinolinic acid and their composite back activity of weeding are determined best proportioning.
The activity of weeding of table 1 pair barnyard grass grass relatively
Reagent Y=a+bX Correlation coefficient r ED90 value (g/ mu) Co-toxicity coefficient
Nicosulfuron Y=5.23+1.21X ?0.9845 7.24 -
Dichloro quinolinic acid Y=4.25+1.92X 0.9900 11.49 -
No. 1, mixture Y=6.02+2.07X 0.9974 1.34 334.45
No. 2, mixture Y=5.83+1.92X 0.9907 1.72 204.22
No. 3, mixture Y=5.76+1.77X 0.9969 1.97 157.82
No. 4, mixture Y=5.93+1.97X 0.9941 1.51 118.09
No. 5, mixture Y=5.43+1.73X 0.9886 3.09 84.97
The activity of weeding of table 2 pair eleusine indica relatively
Reagent Y=a+bX Correlation coefficient r ED90 value (g/ mu) Co-toxicity coefficient
Nicosulfuron Y=5.16+1.87X 0.9841 8.79
Dichloro quinolinic acid Y=3.64+0.94X 0.9964 649.21
No. 1, mixture Y=5.18+1.76X 0.9975 1.85 223.50
No. 2, mixture Y=5.68+1.56X 0.9910 2.42 207.12
No. 3, mixture Y=5.56+1.38X 0.9818 3.36 113.22
No. 4, mixture Y=5.23+1.41X 0.9821 5.53 108.33
No. 5, mixture Y=5.23+1.21X 0.9845 7.24 102.86
Table 3 pair dayflower activity of weeding relatively
Reagent Y=a+bX Correlation coefficient r ED90 value (g/ mu) Co-toxicity coefficient
Nicosulfuron Y=5.02+1.04X 0.9847 15.85
Dichloro quinolinic acid Y=3.65+0.90X 0.9923 828.68
No. 1, mixture Y=5.56+1.38X 0.9818 3.36 203.22
No. 2, mixture Y=5.35+1.20X 0.9977 5.90 164.34
No. 3, mixture Y=5.23+1.21X 0.9845 7.24 142.86
No. 4, mixture Y=5.14+1.22X 0.9834 8.46 119.43
No. 5, mixture Y=5.11+1.17X 0.9826 10.09 102.38
Table 4 pair kitchen garden activity of weeding relatively
Reagent Y=a+bX Correlation coefficient r ED90 value (g/ mu) Co-toxicity coefficient
Nicosulfuron Y=5.02+0.84X 0.9972 30.96
Dichloro quinolinic acid Y=3.65+0.90X 0.9923 828.68
No. 1, mixture Y=5.23+1.41X 0.9821 5.53 128.33
No. 2, mixture Y=5.35+1.20X 0.9977 5.90 124.34
No. 3, mixture Y=5.23+1.34X 0.9890 6.09 109.69
No. 4, mixture Y=5.23+1.21X 0.9845 7.24 102.86
No. 5, mixture Y=5.11+1.17X 0.9826 10.09 102.38
From table 1 to table 4 as can be seen, the ratio of nicosulfuron is big more, and synergy is big more relatively.
As can be seen from Table 1, (nicosulfuron: dichloro quinolinic acid=8~5: 2~5), calculate with ED90 to barnyard grass grass synergy and summation action the back that is mixed, and the co-toxicity coefficient is 118-334 in measuring 4 mixed ratios of two kinds of weed killer herbicides.Table 2 pair eleusine indica, table 3 pair dayflower, table 4 pair kitchen garden be 5 interior (nicosulfurons: dichloro quinolinic acid=4~8: 2~6) synergy and summation action are arranged all of mixed ratio as can be seen.
As can be seen, calculate with ED90, nicosulfuron and dichloro quinolinic acid ratio are 6~8: synergistic effect in 2~4 o'clock is obvious.
Comprehensive virulence coefficient and cost factor, optimal proportion be nicosulfuron and dichloro quinolinic acid ratio 7~8: 2~3.

Claims (7)

1. Herbicidal combinations that contains nicosulfuron and dichloro quinolinic acid, it is characterized in that: its active component is the mixture of nicosulfuron and dichloro quinolinic acid, the weight fraction ratio of nicosulfuron and dichloro quinolinic acid is 1~20%: 40~1%.
2. the Herbicidal combinations that contains nicosulfuron and dichloro quinolinic acid according to claim 1 is characterized in that: described dichloro quinolinic acid comprises dichloro quinolinic acid, dichloroquinoline acid sodium-salt, dichloro quinolinic acid methylamine salt, dichloro quinolinic acid ethylamine salt, dichloro quinolinic acid ethanolamine salt and dichloro quinolinic acid isopropyl amine salt.
3. the Herbicidal mixture that contains nicosulfuron and dichloro quinolinic acid according to claim 1 is characterized in that: described active component accounts for 0.5~90% of composition weight.
4. the Herbicidal combinations that contains nicosulfuron and dichloro quinolinic acid according to claim 1 and 2 is characterized in that: the weight fraction ratio of nicosulfuron and dichloro quinolinic acid is 3~8%: 20~2%.
5. according to claim 1 and 2ly contain the Herbicidal combinations that nicosulfuron and dichloro lose phosphoric acid, it is characterized in that: described active component accounts for 0.5~50% of composition weight.
6. the Herbicidal combinations that contains nicosulfuron and dichloro quinolinic acid according to claim 3 is characterized in that: the weight fraction ratio of described nicosulfuron and dichloro quinolinic acid is 3~6%: 20~10%.
7. according to claim 1 and 2ly contain the Herbicidal combinations that nicosulfuron and dichloro lose phosphoric acid, it is characterized in that: described composition is missible oil, wetting powder, granula, water dispersible granules, aqueous suspension agent, aqueous emulsion, dry suspending agent, microemulsion or oil-suspending agent.
CN2010105734427A 2010-12-06 2010-12-06 Weeding composite with nicosulfuron and quinclorac Pending CN101999388A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107318872A (en) * 2016-04-28 2017-11-07 江苏龙灯化学有限公司 A kind of Herbicidal combinations
CN108605967A (en) * 2018-06-09 2018-10-02 合肥喜田生物科技有限公司 A kind of mixed herbicide and its application containing nicosulfuron, atrazine and dichloro quinolinic acid
CN111248216A (en) * 2020-03-17 2020-06-09 安徽美程化工有限公司 Weeding composition containing quinclorac, nicosulfuron and terbuthylazine

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1296744A (en) * 2000-11-29 2001-05-30 江苏省新沂中凯农用化工有限公司 Herbicidal composition containing quinclorac, its preparing process and its application in wheat field
CN101507439A (en) * 2009-03-30 2009-08-19 北京颖泰嘉和科技股份有限公司 Herbicide combination and use thereof
CN101790988A (en) * 2010-03-04 2010-08-04 张志高 Novel quinclorac weeding composition

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1296744A (en) * 2000-11-29 2001-05-30 江苏省新沂中凯农用化工有限公司 Herbicidal composition containing quinclorac, its preparing process and its application in wheat field
CN101507439A (en) * 2009-03-30 2009-08-19 北京颖泰嘉和科技股份有限公司 Herbicide combination and use thereof
CN101790988A (en) * 2010-03-04 2010-08-04 张志高 Novel quinclorac weeding composition

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107318872A (en) * 2016-04-28 2017-11-07 江苏龙灯化学有限公司 A kind of Herbicidal combinations
CN107318872B (en) * 2016-04-28 2021-07-06 江苏龙灯化学有限公司 Weeding composition
CN108605967A (en) * 2018-06-09 2018-10-02 合肥喜田生物科技有限公司 A kind of mixed herbicide and its application containing nicosulfuron, atrazine and dichloro quinolinic acid
CN111248216A (en) * 2020-03-17 2020-06-09 安徽美程化工有限公司 Weeding composition containing quinclorac, nicosulfuron and terbuthylazine

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Application publication date: 20110406