CN101993279A - Gluconate water-soluble micronutrient fertilizer - Google Patents
Gluconate water-soluble micronutrient fertilizer Download PDFInfo
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- CN101993279A CN101993279A CN2009100659588A CN200910065958A CN101993279A CN 101993279 A CN101993279 A CN 101993279A CN 2009100659588 A CN2009100659588 A CN 2009100659588A CN 200910065958 A CN200910065958 A CN 200910065958A CN 101993279 A CN101993279 A CN 101993279A
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Abstract
The invention discloses a gluconate water-soluble micronutrient fertilizer. The fertilizer consists of the following substances in part by weight: 5 to 10 parts of ferrous gluconate, 5 to 10 parts of copper gluconate, 5 to 10 parts of zinc gluconate, 5 to 10 parts of manganese gluconate, 1 to 4 parts of complex boron gluconate, 0.05 to 0.1 part of ammonium molybdate and 60 to 70 parts of water. The invention also discloses a method for preparing the gluconate water-soluble micronutrient fertilizer. The fertilizer has the advantages of readily purchasable raw materials, simple process and stable performance and can be mixed with other acidic or neutral pesticides or bactericides to improve the pesticide effect.
Description
Technical field
The invention belongs to trace element fertilizer, be specifically related to a kind of gluconic acid water soluble trace elements fertilizer.
Background technology
Agriculture production is at present paid attention to nitrogen, phosphorus, using of potassium macroelement and has been ignored trace element, cause crop growth to show various trace element deficiencies, influence farm output and product quality, and some trace element fertilizer products all are the compositions of a kind of trace element or part trace element at present, the micro-element nutrition of full price can not be provided for farm crop, be difficult to satisfy the demand of farm crop various trace elements.
Summary of the invention
The purpose of this invention is to provide a kind of liquid fertilizer that comprises the various micro-full nutrition material of farm crop needs, satisfy the demand of farm crop various trace elements.
Technical scheme of the present invention is: a kind of gluconic acid water soluble trace elements fertilizer, it is made up of the material of following parts by weight: Ferrous Gluconate 5～10, copper gluconate 5～10, Zinc Gluconate 5～10, manganese gluconate 5～10, glucose complexing boron 1～4, ammonium molybdate 0.05～0.1, water 60～70.
The preferred weight umber that the material of described gluconic acid water soluble trace elements fertilizer is formed is: Ferrous Gluconate 7～9, copper gluconate 7～9, Zinc Gluconate 7～9, manganese gluconate 8～10, glucose complexing boron 1～2, ammonium molybdate 0.05～0.1, water 64～68.
The present invention is by following step preparation:
(1) glucose with 10～15 weight parts is dissolved in the water of 40～60 weight parts, be heated to 70～90 ℃, the ferrous sulfate that adds 0.05～0.1 weight part, under constantly stirring, the hydrogen peroxide that adds 10～20 weight parts when reaction solution is in boiling state, adds the borax of 2～5 weight parts, add the glucose of 10～20 weight parts and the hydrogen peroxide of 10～20 weight parts again, make gluconic acid solution;
(2) ferrous sulfate with 3～6 weight parts is dissolved in the water of 10～15 weight parts, under constantly stirring, adds the bicarbonate of ammonia of 1～2 weight part, filters then, and filter cake is iron protocarbonate; The copper sulfate of 3～6 weight parts is dissolved in the water of 10～15 weight parts, under constantly stirring, adds the bicarbonate of ammonia of 1～2 weight part, filter then, filter cake is copper carbonate; The zinc sulfate of 3～6 weight parts is dissolved in the water of 10～15 weight parts, under constantly stirring, adds the bicarbonate of ammonia of 1～2 weight part, filter then, filter cake is zinc carbonate; The manganous sulfate of 2～4 weight parts is dissolved in the water of 10～15 weight parts, under constantly stirring, adds the bicarbonate of ammonia of 1～2 weight part, filter then, filter cake is manganous carbonate;
(3) constantly stir down, iron protocarbonate, copper carbonate, zinc carbonate and manganous carbonate that step (2) is prepared join in the gluconic acid solution of step (1) preparation;
(4) constantly stir down, in the solution of step (3) preparation, add the ammonium molybdate of 0.05～0.1 weight part;
Promptly make gluconic acid water soluble trace elements fertilizer.
The present invention also can be prepared by following step:
The Ferrous Gluconate of 5～10 weight parts, the copper gluconate of 5～10 weight parts, the Zinc Gluconate of 5～10 weight parts, the manganese gluconate of 5～10 weight parts, the glucose complexing boron of 1～4 weight part, the ammonium molybdate of 0.05～0.1 weight part are dissolved in the water of 60～70 weight parts, promptly make gluconic acid water soluble trace elements fertilizer.
Among the present invention, gluconic acid can provide bio-energy for farm crop after crop absorption, and it has good water-solubility and to the good chelating of various nutritive elements, gluconic acid can with iron, copper, manganese, the good chelating of metallic cations such as zinc, and with nonmetallic borate ion chelating, be created on the sugared boric acid of quite stable in the aqueous solution, these and gluconic acid bonded associated products have mutual solubility, and has very strong stability, chemical reaction does not take place each other, this product can well be miscible in ammonium molybdate again, forms stable composite trace element nutritional liquid.
Among the present invention, borax be raw material also be catalyzer.
The invention has the beneficial effects as follows:
(1) raw material of the present invention is easily purchased, and technology is simple, need not be oily, electric, and save energy, scale is changeable, does not need substantial contribution, easily starts instant effect.
(2) lack micro-plain situation according to crop, use concentration of the present invention changeable, do not burn leaf, and stable performance of the present invention, can use with other acidity or neutral pesticides or sterilant, to improve drug effect.
(3) the present invention does not contain hormone, can use in the production of Organic farming and non-polluted farm product.
250ml of the present invention is dissolved in the 50kg water, sprays application in the following farm crop, effect of increasing production is as follows:
(1) sprays application on the tomato, divide in initial bloom stage, full-bloom stage, young fruit period and to spray for three times, after spraying, tomato leaf look dark green, plant not early ageing of later stage, big and the rounding of orchard worker, fruit face gloss is vivid, quality better, and output is 5025kg/ mu, the tomato output that does not spray fertilizer of the present invention is 4000kg/ mu, volume increase 26%.
(2) spray application on the cucumber, divide in initial bloom stage, full-bloom stage, young fruit period to spray for three times, after spraying, output is 5000kg/ mu, and the cucumber yield that does not spray fertilizer of the present invention is a 6250kg/ mu, volume increase 25%.
(3) spray application on the summer squash, divide in initial bloom stage, full-bloom stage, young fruit period to spray for three times, after spraying, leaf dark green, it is vigorous to grow, not early ageing of later stage, output is 4500kg/ mu, the summer squash output that does not spray fertilizer of the present invention is 5500kg/ mu, volume increase 33%.
(4) spray application on the wheat, divide in period of seedling establishment, boot stage, filling stage to spray for three times, after spraying, output is 550kg/ mu, and the wheat yield that does not spray fertilizer of the present invention is a 500kg/ mu, volume increase 10%.
(5) spray application on the cotton, divide in initial bloom stage, full-bloom stage, young bell phase to spray for three times, after spraying, the leaf look dark green, growing way is surely strong, and fruit abscission rate is few, and bell is big, and single bell heavily increases 0.6g, seed cotton yield is a 250kg/ mu, and the seed cotton yield that does not spray fertilizer of the present invention is a 200kg/ mu, volume increase 25%.
Embodiment
Embodiment 1
(1) glucose with 10kg is dissolved in the water of 40kg, be heated to 70 ℃, the ferrous sulfate that adds 50g, under constantly stirring, the hydrogen peroxide that adds 12.5kg when reaction solution is in boiling state, adds the borax of 3kg, add the glucose of 20kg and the hydrogen peroxide of 10kg again, make gluconic acid solution;
(2) ferrous sulfate with 4kg is dissolved in the water of 10kg, under constantly stirring, adds the bicarbonate of ammonia of 1.5kg, filters then, and filter cake is iron protocarbonate; The copper sulfate of 3kg is dissolved in the water of 10kg, under constantly stirring, adds the bicarbonate of ammonia of 1kg, filter then, filter cake is copper carbonate; The zinc sulfate of 3kg is dissolved in the water of 10kg, under constantly stirring, adds the bicarbonate of ammonia of 1kg, filter then, filter cake is zinc carbonate; The manganous sulfate of 3kg is dissolved in the water of 10kg, under constantly stirring, adds the bicarbonate of ammonia of 1.5kg, filter then, filter cake is manganous carbonate;
(3) constantly stir down, iron protocarbonate, copper carbonate, zinc carbonate and manganous carbonate that step (2) is prepared join in the gluconic acid solution of step (1) preparation;
(4) constantly stir down, in the solution of step (3) preparation, add the ammonium molybdate of 50g;
Promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 2
(1) glucose with 15kg is dissolved in the water of 60kg, be heated to 90 ℃, the ferrous sulfate that adds 100g, under constantly stirring, the hydrogen peroxide that adds 20kg when reaction solution is in boiling state, adds the borax of 5kg, add the glucose of 20kg and the hydrogen peroxide of 20kg again, make gluconic acid solution;
(2) ferrous sulfate with 6kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 2kg, filters then, and filter cake is iron protocarbonate; The copper sulfate of 6kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 2kg, filter then, filter cake is copper carbonate; The zinc sulfate of 6kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 2kg, filter then, filter cake is zinc carbonate; The manganous sulfate of 4kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 2kg, filter then, filter cake is manganous carbonate;
(3) constantly stir down, iron protocarbonate, copper carbonate, zinc carbonate and manganous carbonate that step (2) is prepared join in the gluconic acid solution of step (1) preparation;
(4) constantly stir down, in the solution of step (3) preparation, add the ammonium molybdate of 60g;
Promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 3
(1) glucose with 12kg is dissolved in the water of 50kg, is heated to 80 ℃, adds the ferrous sulfate of 60g, under constantly stirring, add the hydrogen peroxide of 15kg, when reaction solution is in boiling state, add the borax of 4kg, add the glucose of 15kg and the hydrogen peroxide of 15kg again, make gluconic acid solution;
(2) ferrous sulfate with 5kg is dissolved in the water of 13kg, under constantly stirring, adds the bicarbonate of ammonia of 1.5kg, filters then, and filter cake is iron protocarbonate; The copper sulfate of 5kg is dissolved in the water of 12kg, under constantly stirring, adds the bicarbonate of ammonia of 1.8kg, filter then, filter cake is copper carbonate; The zinc sulfate of 4kg is dissolved in the water of 12kg, under constantly stirring, adds the bicarbonate of ammonia of 1.4kg, filter then, filter cake is zinc carbonate; The manganous sulfate of 3kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 1.8kg, filter then, filter cake is manganous carbonate;
(3) constantly stir down, iron protocarbonate, copper carbonate, zinc carbonate and manganous carbonate that step (2) is prepared join in the gluconic acid solution of step (1) preparation;
(4) constantly stir down, in the solution of step (3) preparation, add the ammonium molybdate of 80g;
Promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 4
(1) glucose with 13kg is dissolved in the water of 55kg, is heated to 75 ℃, adds the ferrous sulfate of 60g, under constantly stirring, add the hydrogen peroxide of 18kg, when reaction solution is in boiling state, add the borax of 4kg, add the glucose of 16kg and the hydrogen peroxide of 12kg again, make gluconic acid solution;
(2) ferrous sulfate with 6kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 2kg, filters then, and filter cake is iron protocarbonate; The copper sulfate of 6kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 2kg, filter then, filter cake is copper carbonate; The zinc sulfate of 3kg is dissolved in the water of 10kg, under constantly stirring, adds the bicarbonate of ammonia of 1kg, filter then, filter cake is zinc carbonate; The manganous sulfate of 2kg is dissolved in the water of 10kg, under constantly stirring, adds the bicarbonate of ammonia of 1kg, filter then, filter cake is manganous carbonate;
(3) constantly stir down, iron protocarbonate, copper carbonate, zinc carbonate and manganous carbonate that step (2) is prepared join in the gluconic acid solution of step (1) preparation;
(4) constantly stir down, in the solution of step (3) preparation, add the ammonium molybdate of 70g;
Promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 5
(1) glucose with 13kg is dissolved in the water of 50kg, be heated to 85 ℃, the ferrous sulfate that adds 100g, under constantly stirring, the hydrogen peroxide that adds 15kg when reaction solution is in boiling state, adds the borax of 3kg, add the glucose of 12kg and the hydrogen peroxide of 14kg again, make gluconic acid solution;
(2) ferrous sulfate with 5kg is dissolved in the water of 14kg, under constantly stirring, adds the bicarbonate of ammonia of 2kg, filters then, and filter cake is iron protocarbonate; The copper sulfate of 4kg is dissolved in the water of 14kg, under constantly stirring, adds the bicarbonate of ammonia of 1.6kg, filter then, filter cake is copper carbonate; The zinc sulfate of 4.5kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 2kg, filter then, filter cake is zinc carbonate; The manganous sulfate of 2.5kg is dissolved in the water of 10kg, under constantly stirring, adds the bicarbonate of ammonia of 1.3kg, filter then, filter cake is manganous carbonate;
(3) constantly stir down, iron protocarbonate, copper carbonate, zinc carbonate and manganous carbonate that step (2) is prepared join in the gluconic acid solution of step (1) preparation;
(4) constantly stir down, in the solution of step (3) preparation, add the ammonium molybdate of 100g;
Promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 6
(1) glucose with 14kg is dissolved in the water of 56kg, be heated to 75 ℃, the ferrous sulfate that adds 100g, under constantly stirring, the hydrogen peroxide that adds 18kg when reaction solution is in boiling state, adds the borax of 4kg, add the glucose of 10kg and the hydrogen peroxide of 12kg again, make gluconic acid solution;
(2) ferrous sulfate with 5kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 2kg, filters then, and filter cake is iron protocarbonate; The copper sulfate of 6kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 2kg, filter then, filter cake is copper carbonate; The zinc sulfate of 5kg is dissolved in the water of 12kg, under constantly stirring, adds the bicarbonate of ammonia of 2kg, filter then, filter cake is zinc carbonate; The manganous sulfate of 4kg is dissolved in the water of 12kg, under constantly stirring, adds the bicarbonate of ammonia of 1.5kg, filter then, filter cake is manganous carbonate;
(3) constantly stir down, iron protocarbonate, copper carbonate, zinc carbonate and manganous carbonate that step (2) is prepared join in the gluconic acid solution of step (1) preparation;
(4) constantly stir down, in the solution of step (3) preparation, add the ammonium molybdate of 90g;
Promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 7
(1) glucose with 14kg is dissolved in the water of 60kg, is heated to 75 ℃, adds the ferrous sulfate of 50g, under constantly stirring, add the hydrogen peroxide of 16kg, when reaction solution is in boiling state, add the borax of 2kg, add the glucose of 15kg and the hydrogen peroxide of 16kg again, make gluconic acid solution;
(2) ferrous sulfate with 3kg is dissolved in the water of 10kg, under constantly stirring, adds the bicarbonate of ammonia of 1kg, filters then, and filter cake is iron protocarbonate; The copper sulfate of 3kg is dissolved in the water of 10kg, under constantly stirring, adds the bicarbonate of ammonia of 1kg, filter then, filter cake is copper carbonate; The zinc sulfate of 6kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 2kg, filter then, filter cake is zinc carbonate; The manganous sulfate of 2kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 1kg, filter then, filter cake is manganous carbonate;
(3) constantly stir down, iron protocarbonate, copper carbonate, zinc carbonate and manganous carbonate that step (2) is prepared join in the gluconic acid solution of step (1) preparation;
(4) constantly stir down, in the solution of step (3) preparation, add the ammonium molybdate of 50g;
Promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 8
(1) glucose with 11kg is dissolved in the water of 40kg, is heated to 78 ℃, adds the ferrous sulfate of 82g, under constantly stirring, add the hydrogen peroxide of 15kg, when reaction solution is in boiling state, add the borax of 4kg, add the glucose of 20kg and the hydrogen peroxide of 18kg again, make gluconic acid solution;
(2) ferrous sulfate with 4kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 2kg, filters then, and filter cake is iron protocarbonate; The copper sulfate of 3kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 1.5kg, filter then, filter cake is copper carbonate; The zinc sulfate of 4kg is dissolved in the water of 10kg, under constantly stirring, adds the bicarbonate of ammonia of 1.5kg, filter then, filter cake is zinc carbonate; The manganous sulfate of 3kg is dissolved in the water of 10kg, under constantly stirring, adds the bicarbonate of ammonia of 1.5kg, filter then, filter cake is manganous carbonate;
(3) constantly stir down, iron protocarbonate, copper carbonate, zinc carbonate and manganous carbonate that step (2) is prepared join in the gluconic acid solution of step (1) preparation;
(4) constantly stir down, in the solution of step (3) preparation, add the ammonium molybdate of 70g;
Promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 9
(1) glucose with 10kg is dissolved in the water of 40kg, is heated to 70 ℃, adds the ferrous sulfate of 50g, under constantly stirring, add the hydrogen peroxide of 10kg, when reaction solution is in boiling state, add the borax of 5kg, add the glucose of 20kg and the hydrogen peroxide of 20kg again, make gluconic acid solution;
(2) ferrous sulfate with 6kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 2kg, filters then, and filter cake is iron protocarbonate; The copper sulfate of 6kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 2kg, filter then, filter cake is copper carbonate; The zinc sulfate of 6kg is dissolved in the water of 10kg, under constantly stirring, adds the bicarbonate of ammonia of 2kg, filter then, filter cake is zinc carbonate; The manganous sulfate of 3kg is dissolved in the water of 10kg, under constantly stirring, adds the bicarbonate of ammonia of 1.5kg, filter then, filter cake is manganous carbonate;
(3) constantly stir down, iron protocarbonate, copper carbonate, zinc carbonate and manganous carbonate that step (2) is prepared join in the gluconic acid solution of step (1) preparation;
(4) constantly stir down, in the solution of step (3) preparation, add the ammonium molybdate of 80g;
Promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 10
(1) glucose with 15kg is dissolved in the water of 60kg, is heated to 90 ℃, adds the ferrous sulfate of 70g, under constantly stirring, add the hydrogen peroxide of 10kg, when reaction solution is in boiling state, add the borax of 2kg, add the glucose of 16kg and the hydrogen peroxide of 16kg again, make gluconic acid solution;
(2) ferrous sulfate with 5kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 1.8kg, filters then, and filter cake is iron protocarbonate; The copper sulfate of 3kg is dissolved in the water of 10kg, under constantly stirring, adds the bicarbonate of ammonia of 1kg, filter then, filter cake is copper carbonate; The zinc sulfate of 3kg is dissolved in the water of 10kg, under constantly stirring, adds the bicarbonate of ammonia of 1kg, filter then, filter cake is zinc carbonate; The manganous sulfate of 3kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 1.8kg, filter then, filter cake is manganous carbonate;
(3) constantly stir down, iron protocarbonate, copper carbonate, zinc carbonate and manganous carbonate that step (2) is prepared join in the gluconic acid solution of step (1) preparation;
(4) constantly stir down, in the solution of step (3) preparation, add the ammonium molybdate of 90g;
Promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 11
(1) glucose with 12kg is dissolved in the water of 50kg, is heated to 80 ℃, adds the ferrous sulfate of 80g, under constantly stirring, add the hydrogen peroxide of 12kg, when reaction solution is in boiling state, add the borax of 2kg, add the glucose of 10kg and the hydrogen peroxide of 10kg again, make gluconic acid solution;
(2) ferrous sulfate with 4kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 1.8kg, filters then, and filter cake is iron protocarbonate; The copper sulfate of 4kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 1.6kg, filter then, filter cake is copper carbonate; The zinc sulfate of 6kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 2kg, filter then, filter cake is zinc carbonate; The manganous sulfate of 4kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 2kg, filter then, filter cake is manganous carbonate;
(3) constantly stir down, iron protocarbonate, copper carbonate, zinc carbonate and manganous carbonate that step (2) is prepared join in the gluconic acid solution of step (1) preparation;
(4) constantly stir down, in the solution of step (3) preparation, add the ammonium molybdate of 100g;
Promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 12
(1) glucose with 15kg is dissolved in the water of 60kg, be heated to 70 ℃, the ferrous sulfate that adds 100g, under constantly stirring, the hydrogen peroxide that adds 15kg when reaction solution is in boiling state, adds the borax of 5kg, add the glucose of 12kg and the hydrogen peroxide of 16kg again, make gluconic acid solution;
(2) ferrous sulfate with 6kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 2kg, filters then, and filter cake is iron protocarbonate; The copper sulfate of 4kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 1.8kg, filter then, filter cake is copper carbonate; The zinc sulfate of 5kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 2kg, filter then, filter cake is zinc carbonate; The manganous sulfate of 5kg is dissolved in the water of 15kg, under constantly stirring, adds the bicarbonate of ammonia of 2kg, filter then, filter cake is manganous carbonate;
(3) constantly stir down, iron protocarbonate, copper carbonate, zinc carbonate and manganous carbonate that step (2) is prepared join in the gluconic acid solution of step (1) preparation;
(4) constantly stir down, in the solution of step (3) preparation, add the ammonium molybdate of 50g;
Promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 13
The Ferrous Gluconate of 5kg, the copper gluconate of 5kg, the Zinc Gluconate of 5kg, the manganese gluconate of 5kg, the glucose complexing boron of 1kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 14
The Ferrous Gluconate of 6kg, the copper gluconate of 5kg, the Zinc Gluconate of 5kg, the manganese gluconate of 5kg, the glucose complexing boron of 1kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 15
The Ferrous Gluconate of 7kg, the copper gluconate of 5kg, the Zinc Gluconate of 5kg, the manganese gluconate of 5kg, the glucose complexing boron of 1kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 16
The Ferrous Gluconate of 8kg, the copper gluconate of 5kg, the Zinc Gluconate of 5kg, the manganese gluconate of 5kg, the glucose complexing boron of 1kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 17
The Ferrous Gluconate of 9kg, the copper gluconate of 5kg, the Zinc Gluconate of 5kg, the manganese gluconate of 5kg, the glucose complexing boron of 1kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 18
The Ferrous Gluconate of 10kg, the copper gluconate of 5kg, the Zinc Gluconate of 5kg, the manganese gluconate of 5kg, the glucose complexing boron of 1kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 19
The Ferrous Gluconate of 5kg, the copper gluconate of 6kg, the Zinc Gluconate of 5kg, the manganese gluconate of 5kg, the glucose complexing boron of 1kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 20
The Ferrous Gluconate of 5kg, the copper gluconate of 7kg, the Zinc Gluconate of 5kg, the manganese gluconate of 5kg, the glucose complexing boron of 1kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 21
The Ferrous Gluconate of 5kg, the copper gluconate of 8kg, the Zinc Gluconate of 5kg, the manganese gluconate of 5kg, the glucose complexing boron of 1kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 22
The Ferrous Gluconate of 5kg, the copper gluconate of 9kg, the Zinc Gluconate of 5kg, the manganese gluconate of 5kg, the glucose complexing boron of 1kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 23
The Ferrous Gluconate of 5kg, the copper gluconate of 10kg, the Zinc Gluconate of 5kg, the manganese gluconate of 5kg, the glucose complexing boron of 1kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 24
The Ferrous Gluconate of 5kg, the copper gluconate of 5kg, the Zinc Gluconate of 6kg, the manganese gluconate of 5kg, the glucose complexing boron of 1kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 25
The Ferrous Gluconate of 5kg, the copper gluconate of 5kg, the Zinc Gluconate of 7kg, the manganese gluconate of 5kg, the glucose complexing boron of 1kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 26
The Ferrous Gluconate of 5kg, the copper gluconate of 5kg, the Zinc Gluconate of 8kg, the manganese gluconate of 5kg, the glucose complexing boron of 1kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 27
The Ferrous Gluconate of 5kg, the copper gluconate of 5kg, the Zinc Gluconate of 9kg, the manganese gluconate of 5kg, the glucose complexing boron of 1kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 28
The Ferrous Gluconate of 5kg, the copper gluconate of 5kg, the Zinc Gluconate of 10kg, the manganese gluconate of 5kg, the glucose complexing boron of 1kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 29
The Ferrous Gluconate of 5kg, the copper gluconate of 5kg, the Zinc Gluconate of 10kg, the manganese gluconate of 6kg, the glucose complexing boron of 1kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 30
The Ferrous Gluconate of 5kg, the copper gluconate of 5kg, the Zinc Gluconate of 10kg, the manganese gluconate of 7kg, the glucose complexing boron of 1kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 31
The Ferrous Gluconate of 5kg, the copper gluconate of 5kg, the Zinc Gluconate of 10kg, the manganese gluconate of 8kg, the glucose complexing boron of 1kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 32
The Ferrous Gluconate of 5kg, the copper gluconate of 5kg, the Zinc Gluconate of 10kg, the manganese gluconate of 9kg, the glucose complexing boron of 1kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 33
The Ferrous Gluconate of 5kg, the copper gluconate of 5kg, the Zinc Gluconate of 10kg, the manganese gluconate of 10kg, the glucose complexing boron of 1kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 34
The Ferrous Gluconate of 10kg, the copper gluconate of 10kg, the Zinc Gluconate of 10kg, the manganese gluconate of 10kg, the glucose complexing boron of 4kg, the ammonium molybdate of 0.05kg are dissolved in the water of 70kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 35
The Ferrous Gluconate of 8kg, the copper gluconate of 8kg, the Zinc Gluconate of 8kg, the manganese gluconate of 7kg, the glucose complexing boron of 2kg, the ammonium molybdate of 0.1kg are dissolved in the water of 65kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 36
The Ferrous Gluconate of 9kg, the copper gluconate of 5kg, the Zinc Gluconate of 8kg, the manganese gluconate of 7kg, the glucose complexing boron of 4kg, the ammonium molybdate of 0.06kg are dissolved in the water of 65kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 37
The Ferrous Gluconate of 6kg, the copper gluconate of 10kg, the Zinc Gluconate of 9kg, the manganese gluconate of 9kg, the glucose complexing boron of 3.5kg, the ammonium molybdate of 0.8kg are dissolved in the water of 68kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 38
The Ferrous Gluconate of 6kg, the copper gluconate of 8kg, the Zinc Gluconate of 10kg, the manganese gluconate of 9kg, the glucose complexing boron of 4kg, the ammonium molybdate of 0.09kg are dissolved in the water of 70kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 39
The Ferrous Gluconate of 9kg, the copper gluconate of 5kg, the Zinc Gluconate of 10kg, the manganese gluconate of 6kg, the glucose complexing boron of 2kg, the ammonium molybdate of 0.05kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 40
The Ferrous Gluconate of 6kg, the copper gluconate of 5kg, the Zinc Gluconate of 9kg, the manganese gluconate of 7kg, the glucose complexing boron of 2kg, the ammonium molybdate of 0.05kg are dissolved in the water of 70kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 41
The Ferrous Gluconate of 5kg, the copper gluconate of 6kg, the Zinc Gluconate of 10kg, the manganese gluconate of 8kg, the glucose complexing boron of 3kg, the ammonium molybdate of 0.07kg are dissolved in the water of 68kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 42
The Ferrous Gluconate of 8kg, the copper gluconate of 8kg, the Zinc Gluconate of 10kg, the manganese gluconate of 5kg, the glucose complexing boron of 4kg, the ammonium molybdate of 0.07kg are dissolved in the water of 64kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 43
The Ferrous Gluconate of 5kg, the copper gluconate of 7kg, the Zinc Gluconate of 9kg, the manganese gluconate of 8kg, the glucose complexing boron of 3kg, the ammonium molybdate of 0.06kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 44
The Ferrous Gluconate of 8kg, the copper gluconate of 8kg, the Zinc Gluconate of 10kg, the manganese gluconate of 5kg, the glucose complexing boron of 4kg, the ammonium molybdate of 0.07kg are dissolved in the water of 64kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 45
The Ferrous Gluconate of 9kg, the copper gluconate of 7kg, the Zinc Gluconate of 9kg, the manganese gluconate of 8kg, the glucose complexing boron of 3kg, the ammonium molybdate of 0.1kg are dissolved in the water of 60kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 46
The Ferrous Gluconate of 6kg, the copper gluconate of 7kg, the Zinc Gluconate of 8kg, the manganese gluconate of 6kg, the glucose complexing boron of 3kg, the ammonium molybdate of 0.06kg are dissolved in the water of 70kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 47
The Ferrous Gluconate of 10kg, the copper gluconate of 5kg, the Zinc Gluconate of 9kg, the manganese gluconate of 7kg, the glucose complexing boron of 4kg, the ammonium molybdate of 0.08kg are dissolved in the water of 62kg, promptly make gluconic acid water soluble trace elements fertilizer.
Embodiment 48
The Ferrous Gluconate of 6kg, the copper gluconate of 9kg, the Zinc Gluconate of 8kg, the manganese gluconate of 6kg, the glucose complexing boron of 2kg, the ammonium molybdate of 0.08kg are dissolved in the water of 70kg, promptly make gluconic acid water soluble trace elements fertilizer.
Claims (4)
1. gluconic acid water soluble trace elements fertilizer is characterized in that it is made up of the material of following parts by weight: Ferrous Gluconate 5～10, copper gluconate 5～10, Zinc Gluconate 5～10, manganese gluconate 5～10, glucose complexing boron 1～4, ammonium molybdate 0.05～0.1, water 60～70.
2. gluconic acid water soluble trace elements fertilizer according to claim 1 is characterized in that it is made up of the material of following parts by weight: Ferrous Gluconate 7～9, copper gluconate 7～9, Zinc Gluconate 7～9, manganese gluconate 8～10, glucose complexing boron 1～2, ammonium molybdate 0.05～0.1, water 64～68.
3. the preparation method of gluconic acid water soluble trace elements fertilizer as claimed in claim 1 or 2 is characterized in that it is by following step preparation:
(1) glucose with 10～15 weight parts is dissolved in the water of 40～60 weight parts, be heated to 70～90 ℃, the ferrous sulfate that adds 0.05～0.1 weight part, under constantly stirring, the hydrogen peroxide that adds 10～20 weight parts when reaction solution is in boiling state, adds the borax of 2～5 weight parts, add the glucose of 10～20 weight parts and the hydrogen peroxide of 10～20 weight parts again, make gluconic acid solution;
(2) ferrous sulfate with 3～6 weight parts is dissolved in the water of 10～15 weight parts, under constantly stirring, adds the bicarbonate of ammonia of 1～2 weight part, filters then, and filter cake is iron protocarbonate; The copper sulfate of 3～6 weight parts is dissolved in the water of 10～15 weight parts, under constantly stirring, adds the bicarbonate of ammonia of 1～2 weight part, filter then, filter cake is copper carbonate; The zinc sulfate of 3～6 weight parts is dissolved in the water of 10～15 weight parts, under constantly stirring, adds the bicarbonate of ammonia of 1～2 weight part, filter then, filter cake is zinc carbonate; The manganous sulfate of 2～4 weight parts is dissolved in the water of 10～15 weight parts, under constantly stirring, adds the bicarbonate of ammonia of 1～2 weight part, filter then, filter cake is manganous carbonate;
(3) constantly stir down, iron protocarbonate, copper carbonate, zinc carbonate and manganous carbonate that step (2) is prepared join in the gluconic acid solution of step (1) preparation;
(4) constantly stir down, in the solution of step (3) preparation, add the ammonium molybdate of 0.05～0.1 weight part;
Promptly make gluconic acid water soluble trace elements fertilizer.
4. the preparation method of gluconic acid water soluble trace elements fertilizer as claimed in claim 1 or 2, it is characterized in that it is by following step preparation: the Ferrous Gluconate of 5～10 weight parts, the copper gluconate of 5～10 weight parts, the Zinc Gluconate of 5～10 weight parts, the manganese gluconate of 5～10 weight parts, the glucose complexing boron of 1～4 weight part, the ammonium molybdate of 0.05～0.1 weight part are dissolved in the water of 60～70 weight parts, promptly make gluconic acid water soluble trace elements fertilizer.
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| CN 200910065958 CN101993279B (en) | 2009-08-27 | 2009-08-27 | Gluconate water-soluble micronutrient fertilizer |
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| CN102267829A (en) * | 2011-06-24 | 2011-12-07 | 金星 | Total-effect trace element water-soluble fertilizer and preparation method thereof |
| CN103011908A (en) * | 2012-12-24 | 2013-04-03 | 王树良 | Medicine for plant leaf surfaces |
| CN105084977A (en) * | 2015-07-29 | 2015-11-25 | 句容市茅山镇恒泰家庭农场 | Full-effect water fertilizer special for Kyoho grapes and preparation method and application thereof |
| WO2016061059A1 (en) * | 2014-10-13 | 2016-04-21 | University Of Central Florida Research Foundation, Inc. | Agrichemical compositions and methods of making and using same |
| CN106889062A (en) * | 2017-02-21 | 2017-06-27 | 金广彦 | A kind of soybean herbicides and safeners and preparation method thereof |
| CN107793262A (en) * | 2017-10-20 | 2018-03-13 | 日正九安科技（北京）有限公司 | A kind of water soluble fertilizer and preparation method thereof |
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| CN1562910A (en) * | 2004-03-26 | 2005-01-12 | 江萍 | Technique for producing compound fertilizers |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102267829A (en) * | 2011-06-24 | 2011-12-07 | 金星 | Total-effect trace element water-soluble fertilizer and preparation method thereof |
| CN103011908A (en) * | 2012-12-24 | 2013-04-03 | 王树良 | Medicine for plant leaf surfaces |
| US20170303543A1 (en) * | 2014-10-13 | 2017-10-26 | University Of Central Florida Research Foundation, Inc. | Agrichemical compositions and methods of making and using same |
| WO2016061059A1 (en) * | 2014-10-13 | 2016-04-21 | University Of Central Florida Research Foundation, Inc. | Agrichemical compositions and methods of making and using same |
| CN107249333A (en) * | 2014-10-13 | 2017-10-13 | 中佛罗里达大学研究基金会有限公司 | Agricultural chemical composition and its preparation and application |
| CN107249333B (en) * | 2014-10-13 | 2021-06-11 | 中佛罗里达大学研究基金会有限公司 | Agrochemical compositions and methods of making and using same |
| US11083201B2 (en) | 2014-10-13 | 2021-08-10 | University Of Central Florida Research Foundation, Inc. | Agrichemical compositions and methods of making and using same |
| CN105084977A (en) * | 2015-07-29 | 2015-11-25 | 句容市茅山镇恒泰家庭农场 | Full-effect water fertilizer special for Kyoho grapes and preparation method and application thereof |
| CN106889062A (en) * | 2017-02-21 | 2017-06-27 | 金广彦 | A kind of soybean herbicides and safeners and preparation method thereof |
| CN107793262A (en) * | 2017-10-20 | 2018-03-13 | 日正九安科技（北京）有限公司 | A kind of water soluble fertilizer and preparation method thereof |
| WO2019075971A1 (en) * | 2017-10-20 | 2019-04-25 | 日正九安科技（北京）有限公司 | Water-soluble fertilizer and preparation method therefor |
| CN108085013A (en) * | 2017-12-22 | 2018-05-29 | 山西农业大学 | A kind of soda salinization soil modifying agent |
| CN110642648A (en) * | 2019-11-08 | 2020-01-03 | 上海永通生态工程股份有限公司 | Preparation method of micronutrient zinc-manganese chelate |
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