CN103360146A - High potassium washing fertilizer containing amino acid chelated medium and trace elements - Google Patents
High potassium washing fertilizer containing amino acid chelated medium and trace elements Download PDFInfo
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- CN103360146A CN103360146A CN2013103217608A CN201310321760A CN103360146A CN 103360146 A CN103360146 A CN 103360146A CN 2013103217608 A CN2013103217608 A CN 2013103217608A CN 201310321760 A CN201310321760 A CN 201310321760A CN 103360146 A CN103360146 A CN 103360146A
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Abstract
The invention discloses a production method of high potassium washing fertilizer containing amino acid chelated medium and trace elements, and the production method belongs to the field of compound fertilizer production. The production method takes amino acid mother liquid, which contains a plurality of amino acids and other organic materials, medium and trace elements, which includes calcium, magnesium, copper, iron, manganese, zinc, boron and molybdenum, monoammonium phosphate, potassium sulfate and potassium nitrate as the raw materials. The production method comprises following steps: chelating amino acid mother liquid with medium and trace elements, atomizing the chelation, drying, pulverizing monoammonium phosphate, potassium sulfate and potassium nitrate, and mixing all raw materials to obtain the product. The high potassium washing fertilizer containing amino acid chelated medium and trace elements is especially suitable for cash crops such as fruits and vegetables, can fully satisfy the needs of potassium and other nutrients in the fruit setting period for fruits and vegetables, and has the advantages of improvement on fertilizer utilization rate, prominent yield-increasing effect and simple application process. The fertilizer can be mixed with the irrigation water and applied in ways of sprinkling, drip irrigating and pouring.
Description
Technical field
Product of the present invention belongs to field of compound fertilizer production, relates in particular to a kind of production method that contains the high potassium punching fertilising of trace element in the chelating amino acids.
Background technology
Liquid fertilizer is again in the punching fertilising, it is soluble in water the readily avaiable fertilizer of solid and applies fertilizer in the mode of water band fertilizer, the characteristics of punching fertilising be a kind of can be fully water-soluble, and promptly be dissolved in the water, very easily absorbed by farm crop, and its absorption rate is relatively high, more crucial is it can be applied to spray, drip, the agricultural facility such as filling, realize water-fertilizer integral, reach water-saving, economize usefulness fertile, the saving of labor.The main component of punching fertilising is nitrogenous fertilizer and potash fertilizer, nitrogenous fertilizer and potash fertilizer water-soluble strong, by the rich water combination, allow the nitrogen potassium nutrition of solubility infiltrate in the soil, be that again crop root absorbs, have several fertilizer not communications centre execute: one does not rush and executes phosphorus, two and do not rush and execute particulate state Chemical Mixed Fertilizer, three and do not rush solid organic fertilizer, four and do not rush microbial preparation.Along with the development of science and technology, single nitrogenous fertilizer and potash fertilizer can not satisfy the needs of farm crop, and is micro-in adding, and especially will add the middle trace element of chelating state.Generally speaking, the punching fertilising can contain the needed whole nutritive elements of plant growth and trace element, so, people can come component design according to the Different Crop needed nutritional needs characteristics of growing fully, the prescription of science can be so that its utilization rate of fertilizer improves 2-3 doubly, and can make adjustment to fertilizer formula according to the different growing ways of crop at any time.Rush fertilization type various, can be divided into by its composition: 1. macroelement class comprises nitrogenous fertilizer, potash fertilizer; 2. macroelement adds microelement kind; 3. microelement kind; 4. macroelement adds the aminoacid chelating microelement class, generally is applied to acid not too strong soil; 5. macroelement adds the humic acid chelating microelement kind; 6. other classes, such as bacterial manure etc., bacterial manure not only has good effect of increasing production, also can improve some crops quality, strengthen resistance.The present invention is exactly that a kind of macroelement adds aminoacid chelating microelement class punching fertilising, because Xinyi Hanling Bio-Engineering Co., Ltd. of parent firm of our company is the amino acids production producer of Jiangsu Province's maximum, annual by-product span amino acid mother liquor is more than 10000 ton when producing amino acid, now use it to produce aminoacid chelating microelement punching fertilising, will produce larger economic benefit.Product of the present invention is that to produce amino acid whose byproduct span amino acid mother liquor be carrier, first and quantitative moderate-element calcium, magnesium and trace copper, iron, manganese, zinc, boron, molybdenum are through chelatropic reaction, make middle trace element be converted into solubleness good, easily micro-in the chelating amino acids attitude absorbed by crops, then through atomizing, be dried to powder, the high potassium powdery punching fertilising of making through the post-treatment that is mixed with raw materials such as the monoammonium phosphate of formula ratio, vitriolate of tartar, saltpetre again, products characteristics are 100% entirely water-soluble.Product of the present invention is the molten fertilizer of a kind of high potassium full-effective water, be particularly suitable for the cash crop such as gourd, fruit and vegetable, can satisfy the crops such as gourd, fruit and vegetable in the phase of bearing fruit the demand to potassium and other nutrient, has the raising utilization rate of fertilizer, obvious effect of increasing production, the advantages such as application process is easy, it can along with irrigation water with the sprinkling irrigation, drip irrigation, the fertilising when modes such as pouring are irrigated, both saved water, saved again fertilizer, but also saved a large amount of labor forces, because the application process of water soluble fertilizer is application with irrigation water, institute is so that fertilising is very even, water soluble fertilizer impurity is few simultaneously, and specific conductivity is low, and working concentration is regulated very convenient, so even it also is safe to the tender seedling of children, do not worry causing the adverse consequencess such as burning seedling.
Summary of the invention
The problem that the present invention mainly solves provides a kind of production method that contains the high potassium punching fertilising of trace element in the chelating amino acids, the method is with span amino acid mother liquor (containing multiple amino acids and other organic matter), middle trace elements calcium, magnesium, copper, iron, manganese, zinc, boron, molybdenum, monoammonium phosphate, vitriolate of tartar, saltpetre is raw material, chelating by span amino acid mother liquor and middle trace element, the atomizing of inner complex, dry, monoammonium phosphate, vitriolate of tartar, the pulverizing of saltpetre, all obtain finished product after the blending of raw material, the raw material weight proportioning that the present invention uses is: span amino acid mother liquor wherein contains amino acid sterling 10% and other organic matter 10%, calcium 0.25%, magnesium 0.25%, copper 0.1%, iron 0.1%, manganese 0.1%, zinc 0.05%, boron 0.1%, molybdenum 0.05%, monoammonium phosphate 28-30%, vitriolate of tartar 25-27%, saltpetre 23%, xylogen 1%, aqueous sodium hydroxide solution is an amount of.
The present invention can be achieved through the following technical solutions:
A kind of production method that contains the high potassium punching fertilising of trace element in the chelating amino acids is characterized in that being made of following steps:
(1) span amino acid mother liquor of formula ratio is sent in the concentration tank, pass into steam, the control temperature concentrates between 90 ℃-95 ℃, concentration time is 6-8 hour, stop when being concentrated into 23-25 ° of B é, send into immediately filter and filter, the purpose of filtration is desalination, and the span amino acid mother liquor after then will filtering is sent into chemical reaction kettle.
(2) after being mixed, middle trace elements calcium, magnesium, copper, iron, manganese, zinc, boron, the molybdenum of formula ratio carry out the solid phase pulverization process.
(3) with microwave heating method the temperature of span amino acid mother liquor in the chemical reaction kettle is brought up to 75-85 ℃, start agitator, middle trace element after pulverizing is added chemical reaction kettle, chelatropic reaction begins, and will constantly monitor the pH value this moment, remains between the 5-7 with aqueous sodium hydroxide solution control pH value, chelatropic reaction finishes after 6-7 hour chelating time, add the stablizer xylogen of formula ratio this moment, stirring reaction stops after 0.2 hour stirring, and obtains trace element in the liquid chelating amino acids.
(4) send into drying machine after trace element in the chelating amino acids of above-mentioned liquid state being sent into spraying machine atomizing, drying temperature is 45-55 ℃, and be 1.2-1.5 hour time of drying, obtains trace element in the Powdered chelating amino acids after the drying.
(5) monoammonium phosphate, vitriolate of tartar, the saltpetre of formula ratio are sent into pulverizer and pulverized, micro-even blend namely gets product after pulverizing and in the Powdered chelating amino acids.
The thickening temperature of the span amino acid mother liquor described in the above-mentioned steps (1) is 92.5 ℃, and concentration time is 7 hours.
The drying temperature of the drying machine described in the above-mentioned steps (4) is 50 ℃, and be 1.35 hours time of drying.
The invention has the beneficial effects as follows:
A kind of production method that contains the high potassium punching fertilising of trace element in the chelating amino acids is provided, the method production technique is simple, need not to increase visual plant, easy to operate, be easy to promote, product is the molten fertilizer of a kind of high potassium full-effective water, be particularly suitable for the cash crop such as gourd, fruit and vegetable, can satisfy the crops such as gourd, fruit and vegetable in the phase of bearing fruit the demand to potassium and other nutrient, have the raising utilization rate of fertilizer, obvious effect of increasing production, the advantage such as application process is easy.
Embodiment
Embodiment 1
Span amino acid mother liquor is sent in the concentration tank, this span amino acid mother liquor contains amino acid sterling prescription total amount 10%, contain other organic matter accounts for prescription total amount 10%, pass into steam, the control temperature concentrates between 90 ℃, concentration time is 8 hours, stops when being concentrated into 23-25 ° of B é, sends into immediately filter and filters, the purpose of filtering is desalination, and the span amino acid mother liquor after then will filtering is sent into chemical reaction kettle.It is to carry out the solid phase pulverization process after 0.25% calcium, 0.25% magnesium, 0.1% copper, 0.1% iron, 0.1% manganese, 0.05% zinc, 0.1% boron, 0.05% molybdenum mix that middle trace element is accounted for total amount.With microwave heating method the temperature of span amino acid mother liquor in the chemical reaction kettle is brought up to 75 ℃, start agitator, middle trace element after pulverizing is added chemical reaction kettle, chelatropic reaction begins, and will constantly monitor the pH value this moment, remains between the 5-7 with aqueous sodium hydroxide solution control pH value, chelatropic reaction finishes after 7 hours chelating time, add that to account for total amount be 1% stablizer xylogen this moment, stirring reaction stops after 0.2 hour stirring, and obtains trace element in the liquid chelating amino acids.Send into drying machine after trace element in the chelating amino acids of above-mentioned liquid state sent into spraying machine atomizing, drying temperature is 45 ℃, and be 1.5 hours time of drying, obtains trace element in the Powdered chelating amino acids after the drying.Be 28% monoammonium phosphate with accounting for total amount, to account for total amount be 27% vitriolate of tartar, account for total amount is that 23% saltpetre is sent into pulverizer and pulverized, micro-even blend namely gets product after pulverizing and in the Powdered chelating amino acids.
Embodiment 2
Span amino acid mother liquor is sent in the concentration tank, this span amino acid mother liquor contains amino acid sterling prescription total amount 10%, contain other organic matter accounts for prescription total amount 10%, pass into steam, the control temperature concentrates between 92.5 ℃, concentration time is 7 hours, stops when being concentrated into 23-25 ° of B é, sends into immediately filter and filters, the purpose of filtering is desalination, and the span amino acid mother liquor after then will filtering is sent into chemical reaction kettle.It is to carry out the solid phase pulverization process after 0.25% calcium, 0.25% magnesium, 0.1% copper, 0.1% iron, 0.1% manganese, 0.05% zinc, 0.1% boron, 0.05% molybdenum mix that middle trace element is accounted for total amount.With microwave heating method the temperature of span amino acid mother liquor in the chemical reaction kettle is brought up to 80 ℃, start agitator, middle trace element after pulverizing is added chemical reaction kettle, chelatropic reaction begins, and will constantly monitor the pH value this moment, remains between the 5-7 with aqueous sodium hydroxide solution control pH value, chelatropic reaction finishes after 6.5 hours chelating time, add that to account for total amount be 1% stablizer xylogen this moment, stirring reaction stops after 0.2 hour stirring, and obtains trace element in the liquid chelating amino acids.Send into drying machine after trace element in the chelating amino acids of above-mentioned liquid state sent into spraying machine atomizing, drying temperature is 50 ℃, and be 1.35 hours time of drying, obtains trace element in the Powdered chelating amino acids after the drying.Be 29% monoammonium phosphate with accounting for total amount, to account for total amount be 26% vitriolate of tartar, account for total amount is that 23% saltpetre is sent into pulverizer and pulverized, micro-even blend namely gets product after pulverizing and in the Powdered chelating amino acids.
Embodiment 3
Span amino acid mother liquor is sent in the concentration tank, this span amino acid mother liquor contains amino acid sterling prescription total amount 10%, contain other organic matter accounts for prescription total amount 10%, pass into steam, the control temperature concentrates between 95 ℃, concentration time is 6 hours, stops when being concentrated into 23-25 ° of B é, sends into immediately filter and filters, the purpose of filtering is desalination, and the span amino acid mother liquor after then will filtering is sent into chemical reaction kettle.It is to carry out the solid phase pulverization process after 0.25% calcium, 0.25% magnesium, 0.1% copper, 0.1% iron, 0.1% manganese, 0.05% zinc, 0.1% boron, 0.05% molybdenum mix that middle trace element is accounted for total amount.With microwave heating method the temperature of span amino acid mother liquor in the chemical reaction kettle is brought up to 85 ℃, start agitator, middle trace element after pulverizing is added chemical reaction kettle, chelatropic reaction begins, and will constantly monitor the pH value this moment, remains between the 5-7 with aqueous sodium hydroxide solution control pH value, chelatropic reaction finishes after 6 hours chelating time, add that to account for total amount be 1% stablizer xylogen this moment, stirring reaction stops after 0.2 hour stirring, and obtains trace element in the liquid chelating amino acids.Send into drying machine after trace element in the chelating amino acids of above-mentioned liquid state sent into spraying machine atomizing, drying temperature is 55 ℃, and be 1.2 hours time of drying, obtains trace element in the Powdered chelating amino acids after the drying.Be 30% monoammonium phosphate with accounting for total amount, to account for total amount be 25% vitriolate of tartar, account for total amount is that 23% saltpetre is sent into pulverizer and pulverized, micro-even blend namely gets product after pulverizing and in the Powdered chelating amino acids.
Claims (3)
1. one kind contains the production method that the high potassium punching of trace element is applied fertilizer in the chelating amino acids, the raw material of its use comprises: span amino acid mother liquor wherein contains amino acid sterling 10% and other organic matter 10%, calcium 0.25%, magnesium 0.25%, copper 0.1%, iron 0.1%, manganese 0.1%, zinc 0.05%, boron 0.1%, molybdenum 0.05%, monoammonium phosphate 28-30%, vitriolate of tartar 25-27%, saltpetre 23%, xylogen 1%, aqueous sodium hydroxide solution is an amount of, it is characterized in that:
Step (1) is sent into the span amino acid mother liquor of formula ratio in the concentration tank, pass into steam, the control temperature concentrates between 90 ℃-95 ℃, concentration time is 6-8 hour, stop when being concentrated into 23-25 ° of B é, send into immediately filter and filter, the purpose of filtration is desalination, and the span amino acid mother liquor after then will filtering is sent into chemical reaction kettle;
Step (2) is carried out the solid phase pulverization process after middle trace elements calcium, magnesium, copper, iron, manganese, zinc, boron, the molybdenum of formula ratio mixed;
Step (3) is brought up to 75-85 ℃ to the temperature of span amino acid mother liquor in the chemical reaction kettle with microwave heating method, start agitator, middle trace element after pulverizing is added chemical reaction kettle, chelatropic reaction begins, and will constantly monitor the pH value this moment, remains between the 5-7 with aqueous sodium hydroxide solution control pH value, chelatropic reaction finishes after 6-7 hour chelating time, add the stablizer xylogen of formula ratio this moment, stirring reaction stops after 0.2 hour stirring, and obtains trace element in the liquid chelating amino acids;
Step (4) is sent into drying machine after trace element in the chelating amino acids of above-mentioned liquid state is sent into the spraying machine atomizing, and drying temperature is 45-55 ℃, and be 1.2-1.5 hour time of drying, obtains trace element in the Powdered chelating amino acids after the drying;
Step (5) is sent monoammonium phosphate, vitriolate of tartar, the saltpetre of formula ratio into pulverizer and is pulverized, and micro-even blend namely gets product after pulverizing and in the Powdered chelating amino acids.
2. a kind of production method that contains in the chelating amino acids the high potassium punching fertilising of trace element according to claim 1, the feature of its step (1) is: the thickening temperature of described span amino acid mother liquor is 92.5 ℃, concentration time is 7 hours.
3. a kind of production method that contains in the chelating amino acids the high potassium punching fertilising of trace element according to claim 1, the feature of its step (4) is: the drying temperature of described drying machine is 50 ℃, be 1.35 hours time of drying.
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103708892A (en) * | 2013-12-27 | 2014-04-09 | 四川通丰科技有限公司 | Production method of amino acid secondary element fertilizer |
| CN104058844A (en) * | 2014-06-09 | 2014-09-24 | 李学春 | Method for preparing multielement chelate fertilizer by use of threonine mother liquor |
| CN104402611A (en) * | 2014-11-21 | 2015-03-11 | 新疆慧尔农业科技股份有限公司 | Special amino acid drip irrigation fertilizer and preparation method thereof |
| CN104529646A (en) * | 2015-01-06 | 2015-04-22 | 上海红辉化工有限公司 | Chelated trace element fertilizer and preparation method thereof |
| CN104788167A (en) * | 2014-01-16 | 2015-07-22 | 江苏汉菱肥业有限责任公司 | Organic and inorganic composite fertilizer containing amino acid chelate and humic acid |
| CN104973916A (en) * | 2014-04-10 | 2015-10-14 | 江苏汉菱肥业有限责任公司 | Production method of water flush fertilizer containing amino acid chelated microelement |
| CN105646099A (en) * | 2016-04-13 | 2016-06-08 | 赵洪军 | Preparation method of special fertilizer for cucumbers |
| CN105950166A (en) * | 2016-05-12 | 2016-09-21 | 四川施利旺农业科技开发有限公司 | Ecological soil conditioner capable of improving acid soil and preparation method |
| CN107286032A (en) * | 2017-06-20 | 2017-10-24 | 峨眉山市龙腾生物科技有限公司 | The method that poultry feather prepares amino-acid chelate |
| CN115594545A (en) * | 2022-11-15 | 2023-01-13 | 石家庄上争信息科技有限公司（Cn） | Method for producing Gly-containing water-soluble fertilizer |
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| CN102260107A (en) * | 2010-05-25 | 2011-11-30 | 陈士安 | Production method of amino acid organic secondary and micro-element fertilizer |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102260107A (en) * | 2010-05-25 | 2011-11-30 | 陈士安 | Production method of amino acid organic secondary and micro-element fertilizer |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103708892A (en) * | 2013-12-27 | 2014-04-09 | 四川通丰科技有限公司 | Production method of amino acid secondary element fertilizer |
| CN103708892B (en) * | 2013-12-27 | 2015-12-09 | 四川通丰科技有限公司 | A kind of method of producing amino acid secondary element fertilizer |
| CN104788167A (en) * | 2014-01-16 | 2015-07-22 | 江苏汉菱肥业有限责任公司 | Organic and inorganic composite fertilizer containing amino acid chelate and humic acid |
| CN104973916A (en) * | 2014-04-10 | 2015-10-14 | 江苏汉菱肥业有限责任公司 | Production method of water flush fertilizer containing amino acid chelated microelement |
| CN104058844A (en) * | 2014-06-09 | 2014-09-24 | 李学春 | Method for preparing multielement chelate fertilizer by use of threonine mother liquor |
| CN104058844B (en) * | 2014-06-09 | 2016-04-20 | 李学春 | Threonine mother liquor is utilized to prepare the method for multicomponent chelate thing fertilizer |
| CN104402611A (en) * | 2014-11-21 | 2015-03-11 | 新疆慧尔农业科技股份有限公司 | Special amino acid drip irrigation fertilizer and preparation method thereof |
| CN104529646A (en) * | 2015-01-06 | 2015-04-22 | 上海红辉化工有限公司 | Chelated trace element fertilizer and preparation method thereof |
| CN105646099A (en) * | 2016-04-13 | 2016-06-08 | 赵洪军 | Preparation method of special fertilizer for cucumbers |
| CN105950166A (en) * | 2016-05-12 | 2016-09-21 | 四川施利旺农业科技开发有限公司 | Ecological soil conditioner capable of improving acid soil and preparation method |
| CN107286032A (en) * | 2017-06-20 | 2017-10-24 | 峨眉山市龙腾生物科技有限公司 | The method that poultry feather prepares amino-acid chelate |
| CN115594545A (en) * | 2022-11-15 | 2023-01-13 | 石家庄上争信息科技有限公司（Cn） | Method for producing Gly-containing water-soluble fertilizer |
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Application publication date: 20131023 |