CN101967699B - 高性能碳纳米管纤维的制备方法 - Google Patents
高性能碳纳米管纤维的制备方法 Download PDFInfo
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- CN101967699B CN101967699B CN2010105055036A CN201010505503A CN101967699B CN 101967699 B CN101967699 B CN 101967699B CN 2010105055036 A CN2010105055036 A CN 2010105055036A CN 201010505503 A CN201010505503 A CN 201010505503A CN 101967699 B CN101967699 B CN 101967699B
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- carbon nanotube
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 103
- 239000000835 fiber Substances 0.000 title claims abstract description 102
- 239000002041 carbon nanotube Substances 0.000 title claims abstract description 87
- 229910021393 carbon nanotube Inorganic materials 0.000 title claims abstract description 87
- 238000002360 preparation method Methods 0.000 title claims description 13
- 239000002131 composite material Substances 0.000 claims abstract description 59
- 238000000034 method Methods 0.000 claims abstract description 42
- 229920005575 poly(amic acid) Polymers 0.000 claims abstract description 25
- 239000004642 Polyimide Substances 0.000 claims abstract description 15
- 229920001721 polyimide Polymers 0.000 claims abstract description 15
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002238 carbon nanotube film Substances 0.000 claims abstract description 14
- 229920001187 thermosetting polymer Polymers 0.000 claims abstract 2
- 238000009987 spinning Methods 0.000 claims description 23
- 229910052799 carbon Inorganic materials 0.000 claims description 16
- 239000002071 nanotube Substances 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000002998 adhesive polymer Substances 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 1
- 230000008595 infiltration Effects 0.000 claims 1
- 238000001764 infiltration Methods 0.000 claims 1
- 239000004634 thermosetting polymer Substances 0.000 claims 1
- 238000012545 processing Methods 0.000 abstract description 5
- 229920000049 Carbon (fiber) Polymers 0.000 abstract description 2
- 239000004917 carbon fiber Substances 0.000 abstract description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract description 2
- 238000009941 weaving Methods 0.000 abstract description 2
- 238000011031 large-scale manufacturing process Methods 0.000 abstract 1
- 229920002292 Nylon 6 Polymers 0.000 description 28
- 150000002466 imines Chemical class 0.000 description 18
- 150000001413 amino acids Chemical class 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000010008 shearing Methods 0.000 description 3
- 238000002166 wet spinning Methods 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 150000001721 carbon Chemical class 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000010036 direct spinning Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000000578 dry spinning Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000010041 electrostatic spinning Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 210000003746 feather Anatomy 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002048 multi walled nanotube Substances 0.000 description 1
- 229910021392 nanocarbon Inorganic materials 0.000 description 1
- 239000002121 nanofiber Substances 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 239000002109 single walled nanotube Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
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CN101967699A CN101967699A (zh) | 2011-02-09 |
CN101967699B true CN101967699B (zh) | 2012-08-08 |
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Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102220696B (zh) * | 2011-05-20 | 2013-06-12 | 复旦大学 | 一种取向碳纳米管/高分子复合纤维及其制备方法 |
CN103850114B (zh) * | 2012-12-04 | 2016-01-27 | 中国科学院苏州纳米技术与纳米仿生研究所 | 电致增强碳纳米管纤维的方法 |
EP3018242B1 (en) * | 2013-07-05 | 2019-10-23 | Murata Machinery, Ltd. | Yarn manufacturing apparatus |
CN105339537B (zh) * | 2013-07-22 | 2017-08-08 | 村田机械株式会社 | 纱线制造装置 |
JP5971421B2 (ja) * | 2013-07-22 | 2016-08-17 | 村田機械株式会社 | 糸製造装置 |
JP5962859B2 (ja) * | 2013-07-22 | 2016-08-03 | 村田機械株式会社 | 糸製造装置 |
CN104294434A (zh) * | 2014-07-31 | 2015-01-21 | 复旦大学 | 一种弹簧状碳纳米管纤维及其制备方法和用途 |
JP6462458B2 (ja) * | 2015-03-31 | 2019-01-30 | 日立造船株式会社 | カーボンナノチューブ集合体の製造方法 |
JP6879664B2 (ja) * | 2016-01-05 | 2021-06-02 | リンテック株式会社 | 引出装置 |
WO2017131061A1 (ja) * | 2016-01-29 | 2017-08-03 | 日立造船株式会社 | カーボンナノチューブ糸の製造方法 |
CN107337195B (zh) * | 2016-04-28 | 2019-09-03 | 清华大学 | 一种碳纳米管拉取装置 |
CN107337196B (zh) * | 2016-04-28 | 2019-09-03 | 清华大学 | 一种碳纳米管膜的制备方法 |
CN106337215A (zh) * | 2016-06-06 | 2017-01-18 | 中国科学院苏州纳米技术与纳米仿生研究所 | 碳纳米管复合纤维及其制备方法 |
CN106381592A (zh) * | 2016-09-07 | 2017-02-08 | 苏州捷迪纳米科技有限公司 | 碳纳米管扁丝及其制备方法和制备装置 |
KR102059237B1 (ko) | 2016-10-31 | 2019-12-30 | 주식회사 엘지화학 | 정렬도가 향상된 탄소나노튜브 섬유 집합체 제조 방법 |
CN106629669B (zh) * | 2016-12-08 | 2019-01-25 | 华侨大学 | 一种超细金刚石-碳纳米管纤维复合材料的制备方法 |
CN106939518A (zh) * | 2017-04-14 | 2017-07-11 | 哈尔滨理工大学 | 具有电磁屏蔽功能的聚酰亚胺三层复合薄膜的制备方法 |
CN109545574B (zh) * | 2017-09-22 | 2020-09-22 | 中国科学院物理研究所 | 碳纳米管/导电聚合物复合材料的制备方法及装置 |
CN109837627B (zh) * | 2019-02-15 | 2021-11-12 | 南通纺织丝绸产业技术研究院 | 一步法纳米纤维纱增强方法及一种亲水化纤织物 |
CN110028789A (zh) * | 2019-04-11 | 2019-07-19 | 东华大学 | 一种高强耐磨应变传感纤维的制备方法 |
CN110310765A (zh) * | 2019-06-04 | 2019-10-08 | 深圳烯湾科技有限公司 | 一种碳纳米管漆包线及其应用 |
JP7372092B2 (ja) * | 2019-09-18 | 2023-10-31 | 日立造船株式会社 | カーボンナノチューブ撚糸の製造方法 |
JP7311374B2 (ja) * | 2019-09-20 | 2023-07-19 | トクセン工業株式会社 | 絶縁被覆カーボンナノチューブ線 |
CN110734053B (zh) * | 2019-10-14 | 2020-10-13 | 深圳烯湾科技有限公司 | 碳纳米管的制备方法,碳纳米管纤维 |
CN111050433B (zh) * | 2019-12-03 | 2022-05-27 | 深圳烯湾科技有限公司 | 柔性发热片及其制备方法 |
CN111235888B (zh) * | 2020-02-03 | 2022-10-25 | 江苏大学 | 一种单极性高输出功率的电化学驱动器及制备方法 |
CN112865239A (zh) * | 2021-01-22 | 2021-05-28 | 苏州大学 | 一种可缝制于织物的无线充电器件的制备方法及器件 |
CN113089150B (zh) * | 2021-03-16 | 2022-08-23 | 南通纺织丝绸产业技术研究院 | 一种光驱致动的人工肌肉材料及其制备方法和应用 |
CN115127463B (zh) * | 2022-06-23 | 2023-08-29 | 中国科学技术大学 | 一种基于原位观测的碳纳米管阵列纺丝纤维的装置 |
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CN101187078B (zh) * | 2007-12-13 | 2010-06-23 | 东华大学 | 一种碳纳米管/聚酰亚胺复合纤维的制备方法 |
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Owner name: JIANGSU NANO-TECH BUSINESS DEVELOPMENT CO., LTD. Free format text: FORMER OWNER: SUZHOU INSTITUTE OF NANO-TECH. AND NANO-BIONICS, CHINESE ACADEMY OF SCIENCES Effective date: 20121026 Owner name: SUZHOU JIEDI NANO TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: JIANGSU NANO-TECH BUSINESS DEVELOPMENT CO., LTD. Effective date: 20121026 |
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Effective date of registration: 20121026 Address after: 215123, Jiangsu province Suzhou Industrial Park alone villa lake high Parish, if waterway 398, A103 Patentee after: SUZHOU CREATIVE-CARBON NANOTECHNOLOGY Co.,Ltd. Address before: 215123, Jiangsu province Suzhou Industrial Park alone villa lake high Parish, if waterway 398, C518 Patentee before: Suzhou Nafang Technology Development Co.,Ltd. Effective date of registration: 20121026 Address after: 215123, Jiangsu province Suzhou Industrial Park alone villa lake high Parish, if waterway 398, C518 Patentee after: SUZHOU NAFANG TECHNOLOGY DEVELOPMENT Co.,Ltd. Address before: 215123 Jiangsu city of Suzhou province Dushu Lake Industrial Park No. 398 waterway if higher education Patentee before: SUZHOU INSTITUTE OF NANO-TECH AND NANO-BIONICS (SINANO), CHINESE ACADEMY OF SCIENCES |