CN101953356A - Dimethomorph-containing thermal smoke agent for preventing and controlling downy mildew of vinyl house cucumbers - Google Patents

Dimethomorph-containing thermal smoke agent for preventing and controlling downy mildew of vinyl house cucumbers Download PDF

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Publication number
CN101953356A
CN101953356A CN2010105051938A CN201010505193A CN101953356A CN 101953356 A CN101953356 A CN 101953356A CN 2010105051938 A CN2010105051938 A CN 2010105051938A CN 201010505193 A CN201010505193 A CN 201010505193A CN 101953356 A CN101953356 A CN 101953356A
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China
Prior art keywords
dimethomorph
downy mildew
agent
thermal smoke
smoke agent
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Pending
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CN2010105051938A
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Chinese (zh)
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王开运
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Shandong Agricultural University
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Shandong Agricultural University
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Priority to CN2010105051938A priority Critical patent/CN101953356A/en
Publication of CN101953356A publication Critical patent/CN101953356A/en
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Abstract

The invention relates to a dimethomorph-containing thermal smoke agent for preventing and controlling downy mildew of vinyl house cucumbers. The thermal smoke agent comprises the following active ingredients: dimethomorph and azoxystrobin, dimethomorph and chlorothalonil, dimethomorph and cymoxanil, dimethomorph and metalaxyl, dimethomorph and hymexazol, or dimethomorph and enestroburin, and also comprises the following auxiliaries: an emulsifying agent, a dispersing agent, a solvent, a viscosity regulating agent, a defoaming agent and the like. The active ingredients and the auxiliaries are prepared into an oil-suspending thermal smoke agent, wherein the dimethomorph is mixed with other medicaments in a ratio of 1:3 to 3:1; and the medicaments comprise 20 to 40 percent of active ingredients. The dimethomorph-containing thermal smoke agent is specially used for thermal smoke sprayers and has special effects on the downy mildew of the vinyl house or facility-cultured cucumbers. The thermal smoke agent can also be widely used for preventing and controlling diseases such as the downy mildew, peronophythora and the like of watermelons, pumpkins, tomatoes, chillies, eggplants and the like cultured by facilities such as vinyl houses and the like, and has the advantages of high application value, and sufficiently obvious economic and social benefits.

Description

A kind of thermal aerosol that contains control such as dimethomorph plastic tunnel cucumber downy mildew
(1) invention field:
A kind of thermal aerosol that contains control such as dimethomorph plastic tunnel cucumber downy mildew that the present invention relates to, contain (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine (to call dimethomorph (dimethomorph) in the following text) dimethomorph and Fluoxastrobin, or contain dimethomorph and tpn, dimethomorph and white urea cyanogen, dimethomorph and metalaxyl, dimethomorph and Wakil, dimethomorph and Enestroburin, emulsifier, dispersant, the oil suspension thermal aerosol that solvent, auxiliary agents such as viscosity-controlling agent and defoamer are made (hot fogging concen-trate) composition.
Simultaneously, the present invention relates to use a kind of thermal aerosol and using method thereof that contains control plastic tunnel cucumber downy mildews such as dimethomorph.This thermal aerosol also can be widely used in watermelon, custard squash, tomato, capsicum, eggplant of facility cultivations such as plastic tunnel etc. and prevent and treat diseases such as downy mildew, phytophthora root rot, and using value is big, and economic and social benefit is very remarkable.
(2) technical background:
Dimethomorph (dimethomorph) is the single-minded Oomycete fungi bactericide that kills, its effect characteristics are to destroy the formation of cell envelope, all there is effect in each stage to oomycetes history of life, and is particularly responsive in the formation stage of sporangiophore and egg spore, promptly is suppressed under extremely low concentration.This medicament is widely used in vegetables downy mildew, eqpidemic disease, seedling stage damping off, black shank etc. by the fungus-caused disease control of Mastigomycotina Oomycete, inhales bactericidal activity in the tool.
Cucumber downy mildew main harm blade, stem, inflorescence tendril, become strain phase blade to catch an illness by lower blade to vertical spread, blade back produces the water soaking mode spot during their early stage high humidity in early morning, the water soaking mode scab disappeared after the morning, humidity descended, after enlarging, leaf spot lesion is subjected to the vein restriction to be polygonal, leaf front scab moves back and greenly is faint yellow, and the scab back side is yellowish-brown, and blade back scab portion produced purplish grey to black downy mildew layer when the edge was obviously moist.As untimely control, greatly to the yield and quality influence.
Cucumber downy mildew is the disease, particularly winter warm type plastic tunnel cucumber that each cucumber producing region of China generally takes place, and because of low, the high humidity of temperature of shed in winter, especially is fit to the generation of cucumber downy mildew.Run into sleety weather especially, excessive because of humidity in the canopy, be difficult for adopting traditional spray-on process control.
(3) summary of the invention:
The purpose of this invention is to provide a kind of thermal aerosol that contains control such as dimethomorph plastic tunnel cucumber downy mildew, and adopt thermal aerosol generator to use, the method for control plastic tunnel cucumber downy mildew.
Dimethomorph (DMM) belongs to a kind of derivative of cinnamic acid compound, also is a kind of new efficient systemic fungicide of preventing and treating Peronospora (Peronosporales) disease fungus disease.
Fluoxastrobin, tpn, white urea cyanogen, metalaxyl, Wakil, Enestroburin all are the effective agents of preventing and treating cucumber downy mildew at present.
The present invention finds; dimethomorph and Fluoxastrobin, dimethomorph and tpn, dimethomorph and white urea cyanogen, dimethomorph and metalaxyl, dimethomorph and Wakil, dimethomorph and Enestroburin are used with, the plastic tunnel cucumber downy mildew is all had higher protection and result of treatment.The ratio range of dimethomorph and Fluoxastrobin, dimethomorph and tpn, dimethomorph and white urea cyanogen, dimethomorph and metalaxyl, dimethomorph and Wakil, dimethomorph and Enestroburin 1: 3~3: 1.Can contain dimethomorph 10~30% in a kind of thermal aerosol that contains control plastic tunnel cucumber downy mildews such as dimethomorph, Fluoxastrobin or tpn, white urea cyanogen, metalaxyl, Wakil, Enestroburin 10~30%, with dimethomorph and Fluoxastrobin or dimethomorph and tpn, dimethomorph and white urea cyanogen, dimethomorph and metalaxyl, dimethomorph and Wakil, dimethomorph and Enestroburin is active ingredient, adds auxiliary agents such as emulsifier, dispersant, solvent, viscosity-controlling agent and defoamer and makes oily suspension thermal aerosol composition.
The active ingredient that the present invention selects for use also can be and is used to prevent and treat downy mildew, phytophthora root rot, and at heating and gasifying or become performance in the cigarette process stable and to other mixed bactericide that contains dimethomorph of plant safety.
The emulsifier that the present invention selects for use can be OP-7, farming breast 0201, farming breast 601, farming breast 500 etc., and the compound emulsifying agent that mixes by proper proportion.
The dispersant that the present invention selects for use can be farming breast 1600, nekal (drawing back powder), the polyoxy ester sodium salt etc. that contracts, and the composite dispersing agent that mixes by proper proportion.
The solvent that the present invention selects for use can be diesel oil, machine oil, the senior aliphatic hydrocarbon wet goods of methyl naphthalene mineral oil, soybean oil, rapeseed oil, cottonseed wet goods vegetable oil, and biodiesel, dioctyl phthalate etc., and press the mixed solvent that proper proportion is mixed.
The viscosity-controlling agent that the present invention selects for use can be xanthans, carboxymethyl cellulose, polyvinyl alcohol, gum Arabic etc.
The defoamer that the present invention selects for use can be n-octyl alcohol, bubble enemy, silicic acid class etc.
The present invention also provides a kind of thermal aerosol that contains control such as dimethomorph plastic tunnel cucumber downy mildew, and the method for preventing and treating the plastic tunnel cucumber downy mildew with thermal aerosol generator aerosol spraying mist.
The present invention uses emulsifier, the oil suspension thermal aerosol composition that dispersant, solvent, auxiliary agents such as viscosity-controlling agent and defoamer are made.
The present invention is processed into oily suspension thermal aerosol and can further be illustrated by following " example ", but is not limited thereto.Below all umbers all refer to weight.
(4) description of drawings:
Fig. 1: a kind of processing process figure that contains the thermal aerosol of control such as dimethomorph plastic tunnel cucumber downy mildew
1 is dimethomorph among Fig. 1, the 2nd, and other active ingredient, the 3rd, emulsifier, the 4th, dispersant, the 5th, solvent, the 6th, defoamer, the 7th, viscosity-controlling agent, the 8th, ground and mixed, the 9th, finished product packing.
(5) invention embodiment:
A kind of prescription that contains the thermal aerosol of control plastic tunnel cucumber downy mildews such as dimethomorph that the present invention relates to can be specifically described by example 1, example 2, example 3, example 4, example 5, example 6 and example 7, but is not limited thereto.
Example 1:
The present invention relates to the dimethomorph 20% (1) in a kind of thermal aerosol that contains control such as dimethomorph plastic tunnel cucumber downy mildew, Fluoxastrobin 10% (2), polyoxyethylene nonylphenol ether-7 2%+ farming breast 500 2% (3), dispersant farming breast 1,600 1% (4), solvent diesel oil 64% (5), defoamer n-octyl alcohol 0.1% (6), viscosity-controlling agent xanthans 0.5%+ polyvinyl alcohol 0.4% (7), above composition is all weighed by weight, ground and mixed (8) is prepared into oil-suspending agent formulation (9).Above raw material is commercially available qualified products.
Example 2:
The present invention relates to the dimethomorph 15% (1) in a kind of thermal aerosol that contains control such as dimethomorph plastic tunnel cucumber downy mildew, tpn 20% (2), polyoxyethylene nonylphenol ether-7 2%+ farming breast 500 2% (3), dispersant farming breast 1,600 1% (4), solvent diesel oil 59% (5), defoamer n-octyl alcohol 0.1% (6), viscosity-controlling agent xanthans 0.5%+ polyvinyl alcohol 0.4% (7), above composition is all weighed by weight, ground and mixed (8) is prepared into oil-suspending agent formulation (9).Above raw material is commercially available qualified products.
Example 3:
The present invention relates to the dimethomorph 15% (1) in a kind of thermal aerosol that contains control such as dimethomorph plastic tunnel cucumber downy mildew, frost urea cyanogen 15% (2), polyoxyethylene nonylphenol ether-7 2%+ farming breast 500 2% (3), dispersant farming breast 1,600 1% (4), solvent diesel oil 64% (5), defoamer n-octyl alcohol 0.1% (6), viscosity-controlling agent xanthans 0.5%+ polyvinyl alcohol 0.4% (7), above composition is all weighed by weight, ground and mixed (8) is prepared into oil-suspending agent formulation (9).Above raw material is commercially available qualified products.
Example 4:
The present invention relates to the dimethomorph 15% (1) in a kind of thermal aerosol that contains control such as dimethomorph plastic tunnel cucumber downy mildew, metalaxyl 15% (2), polyoxyethylene nonylphenol ether-7 2%+ farming breast 500 2% (3), dispersant farming breast 1,600 1% (4), solvent diesel oil 64% (5), defoamer n-octyl alcohol 0.1% (6), viscosity-controlling agent xanthans 0.5%+ polyvinyl alcohol 0.4% (7), above composition is all weighed by weight, ground and mixed (8) is prepared into oil-suspending agent formulation (9).Above raw material is commercially available qualified products.
Example 5:
The present invention relates to the dimethomorph 15% (1) in a kind of thermal aerosol that contains control such as dimethomorph plastic tunnel cucumber downy mildew, Wakil 15% (2), polyoxyethylene nonylphenol ether-7 2%+ farming breast 500 2% (3), dispersant farming breast 1,600 1% (4), solvent diesel oil 64% (5), defoamer n-octyl alcohol 0.1% (6), viscosity-controlling agent xanthans 0.5%+ polyvinyl alcohol 0.4% (7), above composition is all weighed by weight, ground and mixed (8) is prepared into oil-suspending agent formulation (9).Above raw material is commercially available qualified products.
Example 6:
The present invention relates to the dimethomorph 20% (1) in a kind of thermal aerosol that contains control such as dimethomorph plastic tunnel cucumber downy mildew, Enestroburin 10% (2), polyoxyethylene nonylphenol ether-7 2%+ farming breast 500 2% (3), dispersant farming breast 1600 farming breasts 1,600 1% (4), solvent diesel oil 64% (5), defoamer n-octyl alcohol 0.1% (6), viscosity-controlling agent xanthans 0.5%+ polyvinyl alcohol 0.4% (7), above composition is all weighed by weight, ground and mixed (8) is prepared into oil-suspending agent formulation (9).Above raw material is commercially available qualified products.
Use above-mentioned a kind of method that contains the thermal aerosol of control plastic tunnel cucumber downy mildews such as dimethomorph to be: in the cucumber downy mildew emergence period, aerosol spraying mist in this thermal aerosol adding thermal aerosol generator is used, the cucumber downy mildew of facility cultivations such as control booth, watermelon, custard squash, tomato, capsicum, eggplant that also can be widely used in facility cultivations such as plastic tunnel etc. prevented and treated diseases such as downy mildew, phytophthora root rot, using value is big, and economic and social benefit is very remarkable.

Claims (3)

1. thermal aerosol that contains control such as dimethomorph plastic tunnel cucumber downy mildew, it is characterized in that containing dimethomorph 10~30%, Fluoxastrobin or tpn, white urea cyanogen, metalaxyl, Wakil, Enestroburin 10~30%, emulsifier, dispersant, the oil suspension thermal aerosol composition that solvent, auxiliary agents such as viscosity-controlling agent and defoamer are made.
2. a kind of thermal aerosol that contains control such as dimethomorph plastic tunnel cucumber downy mildew according to claim 1 is characterized in that containing proportioning and is 1: 3~3: 1 dimethomorphs and Fluoxastrobin or tpn, white urea cyanogen, metalaxyl, Wakil, Enestroburin.
3. a kind of thermal aerosol that contains control such as dimethomorph plastic tunnel cucumber downy mildew according to claim 1 is characterized in that specializing in thermal aerosol generator and uses.
CN2010105051938A 2010-10-13 2010-10-13 Dimethomorph-containing thermal smoke agent for preventing and controlling downy mildew of vinyl house cucumbers Pending CN101953356A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102578127A (en) * 2012-02-06 2012-07-18 山东禾宜生物科技有限公司 Bactericide for controlling cucumber downy mildew
WO2012070961A3 (en) * 2010-11-26 2012-08-02 Sapec-Agro, Sa Fungicidal mixture
CN104222110A (en) * 2014-09-12 2014-12-24 江苏七洲绿色化工股份有限公司 Benzothiostrobin-containing and dimethomorph-containing bactericidal composition and application of bactericidal composition
CN105340916A (en) * 2015-12-19 2016-02-24 青岛奥迪斯生物科技有限公司 Bactericidal composition containing efficient metalaxyl-M and dimethomorph
CN106489922A (en) * 2016-08-31 2017-03-15 利民化工股份有限公司 Aqueous suspension agent that dimethomorph is compounded with cymoxanil and preparation method thereof
WO2020253212A1 (en) * 2019-06-21 2020-12-24 Jiangsu Rotam Chemistry Co., Ltd A synergistic fungicidal composition
WO2024184842A1 (en) * 2023-03-07 2024-09-12 Upl Mauritius Limited Fungicidal products, methods, and applications thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012070961A3 (en) * 2010-11-26 2012-08-02 Sapec-Agro, Sa Fungicidal mixture
CN102578127A (en) * 2012-02-06 2012-07-18 山东禾宜生物科技有限公司 Bactericide for controlling cucumber downy mildew
CN104222110A (en) * 2014-09-12 2014-12-24 江苏七洲绿色化工股份有限公司 Benzothiostrobin-containing and dimethomorph-containing bactericidal composition and application of bactericidal composition
CN104222110B (en) * 2014-09-12 2016-03-23 江苏七洲绿色化工股份有限公司 A kind of bactericidal composition and application thereof containing benzene thiophene bacterium ester and dimethomorph
CN105340916A (en) * 2015-12-19 2016-02-24 青岛奥迪斯生物科技有限公司 Bactericidal composition containing efficient metalaxyl-M and dimethomorph
CN106489922A (en) * 2016-08-31 2017-03-15 利民化工股份有限公司 Aqueous suspension agent that dimethomorph is compounded with cymoxanil and preparation method thereof
WO2020253212A1 (en) * 2019-06-21 2020-12-24 Jiangsu Rotam Chemistry Co., Ltd A synergistic fungicidal composition
CN112423588A (en) * 2019-06-21 2021-02-26 江苏龙灯化学有限公司 Synergistic fungicidal compositions
WO2024184842A1 (en) * 2023-03-07 2024-09-12 Upl Mauritius Limited Fungicidal products, methods, and applications thereof

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Application publication date: 20110126