CN101948702B - Alcohol-based biological fuel oil for boiler and preparation method thereof - Google Patents
Alcohol-based biological fuel oil for boiler and preparation method thereof Download PDFInfo
- Publication number
- CN101948702B CN101948702B CN201010297495.0A CN201010297495A CN101948702B CN 101948702 B CN101948702 B CN 101948702B CN 201010297495 A CN201010297495 A CN 201010297495A CN 101948702 B CN101948702 B CN 101948702B
- Authority
- CN
- China
- Prior art keywords
- alcohol
- oil
- acid
- grease
- fuel oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Landscapes
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention provides a biodiesel-based alcoholic fuel oil, which consists of the following substances in percentage by mass: 20 to 50 percent of refined biodiesel, 40 to 80 percent of industrial methanol and 5 to 30 percent of additive, wherein the additive comprises 5 to 20 percent of solvent aid, 1 to 15 percent of cosurfactant, 0.2 to 2 percent of stabilizer and 0.1 to 1 percent of corrosion inhibitor. A preparation method comprises the following steps of: mixing the substances in percentage by mass, and stirring the mixture uniformly at normal temperature to obtain the fuel oil. The fuel oil has the advantages of low cost, high heat value and stable performance; the preparation method has the advantages of simple process, convenience and safety of use and good adaptability to the boiler; and compared with diesel oil, the fuel oil is economic and energy-saving, has low environmental pollution, is regenerative energy, and can be used as commercial oil for great popularization and use.
Description
Technical field
The invention belongs to oil fuel hybrid technology field, be specifically related to a kind of alcohol-group fuel oil based on biofuel and preparation method thereof.
Background technology
Along with global day by day serious energy shortage and environmental degradation, develop the fuel of alternative oil, the physical environment that to protect mankind is depended on for existence has become the Tough questions of current facing mankind.Biofuel has caused people's extensive concern with its good environment friendly and recyclability, and it is a kind of renewable energy source, environmentally friendly, uses, transports and store all safer.But the condensation point of biofuel is high, the easy temperature influence of character, viscosity is large compared with petrifaction diesel, and these are all unfavorable for that it applies.
Alcohol-based biological fuel oil has overcome above shortcoming, under solubility promoter effect, in biofuel, adds a certain amount of alcohols material to form microemulsion, has reduced the condensation point of oil fuel, has reduced its kinematic viscosity.But due to the microemulsion poor stability forming, standing easy layering.Head it off is mainly to find suitable additive to keep its stability.
The present invention has found several suitable additives, and the alcohol-based biological fuel oil calorific value of preparation is high, and cost is lower, and stability is fine, and preparation technology is simple.Evidence, oil fuel is not stratified standing half a year, and solution is clear still.
The fuel using on boiler is at present mainly petrifaction diesel, and along with the continuous minimizing of fossil fuel, its cost is constantly soaring, therefore find alternative pot furnace fuel significant, alcohol-based biological fuel oil prepared by the present invention has good adaptability to boiler, and its cost is low, and calorific value is high, stable in properties, preparation technology is simple, and environmental pollution is little, and raw material is renewable, can substitute boiler petrifaction diesel, therefore there are wide market outlook.
Summary of the invention
The present invention is directed to that boiler is low with fuel cost alcohol-group fuel calorific value high and current preparation, the feature of poor stability, a kind of alcohol-group fuel oil based on biofuel and preparation method thereof is provided, the alcohol-based biological fuel oil good stability of preparation, calorific value is high, and cost is low.
The present invention adopts following technical scheme, an alcohol-based biological fuel oil, is characterized in that being comprised of refining biodiesel, industrial methyl alcohol, additive, and described additive is comprised of solubility promoter, cosurfactant, stablizer, corrosion inhibitor, by percentage to the quality, ratio is as follows:
1) refining biodiesel 20-50%
2) industrial methyl alcohol 40-80%
3) additive 5-30%
Solubility promoter 5-20%;
Cosurfactant 1-15%;
Stablizer 0.2-2%;
Corrosion inhibitor 0.1-1%;
Described refining biodiesel be take vegetables oil or waste grease and industrial methanol and is prepared from as raw material;
The purity of described industrial methyl alcohol is 90%-99%;
Described solubility promoter comprises one or more in oleic acid, palmitinic acid, naphthenic acid, n-dodecanol, n-Octanol, isooctyl alcohol, n-Heptyl alcohol, propyl carbinol, isopropylcarbinol;
Cosurfactant comprises one or more in fatty alcohol-polyoxyethylene ether, polyoxyethylene 20 sorbitan monooleate, alkyl lactate ester, sorbitan monooleate, polyoxyethylene, Nonyl pheno (4) ether, dodecyl phenol polyethenoxy (10) ether, Triton X-100, methyl sodiosul foaliphatate;
Stablizer is: one or more in Xylo-Mucine, sodium oleate, polyacrylamide, polyoxyethylene glycol;
Corrosion inhibitor is: one or more in benzotriazole, linoleic acid dimer, dodecenylsuccinic acid, ditertbutylparacresol, organophosphate (tributyl phosphate, triphenylphosphate, dioctylphosphoric acid ester), dimeracid, maleic anhydride, succinyl oxide, fatty acid imidazoline quinoline boric acid ester.
Described alcohol-based biological fuel oil, energy perfect combustion, its thermal value range is 25.5KJ/g～37.6KJ/g;
Described refining biodiesel makes by chemical method soda acid two-step catalysis technique;
Described vegetables oil comprises plantation manioca, Chinese pistache, castor-oil plant, the seeds of a tung oil tree, walnut, the oil crops such as palm tree, tea oil tree and the oil that obtains;
Described waste grease refers to the grease that foodstuff production and leather processing produce or contains grease waste material, food and restaurant service industry and unit dining room fried food produce can not be edible again grease, the grease refining from swill, the grease that fume extracting system is collected, the grease that oil-containing waste water produces after water-and-oil separator or isolation tank separation, the grease that unedible livestock is smelt and expired rotten grease.
The preparation method of described alcohol-based biological fuel oil, contain following steps: by the solubility promoter in additive, cosurfactant joins in refining biodiesel or industrial methyl alcohol successively, after stirring with stirrer, industrial methyl alcohol or refining biodiesel are joined in prepared solution, stir until solution is transparent, add successively again stablizer and corrosion inhibitor, stirring makes it fully dissolve the alcohol-based biological fuel oil that can obtain clear, described solubility promoter comprises oleic acid, palmitinic acid, naphthenic acid, n-dodecanol, n-Octanol, isooctyl alcohol, n-Heptyl alcohol, propyl carbinol, one or more in isopropylcarbinol,
Cosurfactant comprises one or more in fatty alcohol-polyoxyethylene ether, polyoxyethylene 20 sorbitan monooleate, alkyl lactate ester, sorbitan monooleate, polyoxyethylene, Nonyl pheno (4) ether, dodecyl phenol polyethenoxy (10) ether, Triton X-100, methyl sodiosul foaliphatate;
Stablizer is: one or more in Xylo-Mucine, sodium oleate, polyacrylamide, polyoxyethylene glycol;
Corrosion inhibitor is: one or more in benzotriazole, linoleic acid dimer, dodecenylsuccinic acid, ditertbutylparacresol, organophosphate (tributyl phosphate, triphenylphosphate, dioctylphosphoric acid ester), dimeracid, maleic anhydride, succinyl oxide, fatty acid imidazoline quinoline boric acid ester.
Described solubility promoter, cosurfactant, stablizer, corrosion inhibitor are that a kind of material wherein adds, or select wherein any two kinds of materials to be not less than 20% with a kind of mass ratio ratio of material wherein, mix and add.
When adding additive in refining biodiesel or industrial methanol, at room temperature with stirrer, slowly add while stirring, mixing speed is 300-1000r/min, after additive adds completely, can stop after continuing to stir 1-5min.
The present invention is based on the oil fuel of biofuel, by following several materials, form (by weight percentage):
1) refining biodiesel 20-50%
2) industrial methyl alcohol 40-80%
3) additive 5-30%
Solubility promoter 5-20%;
Cosurfactant 1-15%;
Stablizer 0.2-2%;
Corrosion inhibitor 0.1-1%;
The feed purification biofuel of described alcohol-based biological fuel oil is to take vegetables oil or waste grease and industrial methanol as raw material, by chemical method soda acid two-step catalysis technique, is prepared from; Described its purity of industrial methyl alcohol is 90%-99%; Described additive is comprised of solubility promoter, cosurfactant, stablizer and corrosion inhibitor, every kind of additive is that a kind of material of wherein introducing adds, or selects wherein any two kinds of materials to mix and add with certain mass ratio (wherein a kind of ratio of material is not less than 20%).
The preparation method of described alcohol-based biological fuel oil is as follows: the solubility promoter in additive, cosurfactant are joined in refining biodiesel or industrial methanol successively, after stirring with stirrer, industrial methanol or refining biodiesel are joined in prepared solution, fully stir until mixed solution is transparent.Add successively again stablizer and corrosion inhibitor, stir and make it fully dissolve the alcohol-based biological fuel oil that can obtain clear.
Owing to adopting technique scheme, compared with prior art, tool has the following advantages and beneficial effect in the present invention:
(1) the present invention's raw material used is cheap and easy to get, and the alcohol-based biological fuel oil cost of preparation is low, and the character of itself makes it have energy-saving and cost-reducing advantage.
(2) the alcohol-based biological fuel oil calorific value of preparing is high, energy perfect combustion, and good stability, standing not stratified for a long time, can be used as boiler oil fuel large-scale popularization.
(3) preparation technology of the present invention is simple, without complex apparatus, and convenient operation, practical.
Embodiment
Alcohol-based biological fuel oil of the present invention is comprised of refining biodiesel, industrial methyl alcohol, additive, and described additive is comprised of solubility promoter, cosurfactant, stablizer, corrosion inhibitor, and by percentage to the quality, ratio is as follows:
1) refining biodiesel 20-50%
2) industrial methyl alcohol 40-80%
3) additive 5-30%
Solubility promoter 5-20%;
Cosurfactant 1-15%;
Stablizer 0.2-2%;
Corrosion inhibitor 0.1-1%;
Described refining biodiesel be take vegetables oil or waste grease and industrial methanol and is prepared from as raw material; The purity of industrial methyl alcohol is 90%-99%; Solubility promoter comprises one or more in oleic acid, palmitinic acid, naphthenic acid, n-dodecanol, n-Octanol, isooctyl alcohol, n-Heptyl alcohol, propyl carbinol, isopropylcarbinol; Cosurfactant comprises one or more in fatty alcohol-polyoxyethylene ether, polyoxyethylene 20 sorbitan monooleate, alkyl lactate ester, sorbitan monooleate, polyoxyethylene, Nonyl pheno (4) ether, dodecyl phenol polyethenoxy (10) ether, Triton X-100, methyl sodiosul foaliphatate; Stablizer is: one or more in Xylo-Mucine, sodium oleate, polyacrylamide, polyoxyethylene glycol; Corrosion inhibitor is: one or more in benzotriazole, linoleic acid dimer, dodecenylsuccinic acid, ditertbutylparacresol, organophosphate (tributyl phosphate, triphenylphosphate, dioctylphosphoric acid ester), dimeracid, maleic anhydride, succinyl oxide, fatty acid imidazoline quinoline boric acid ester.
For a better understanding of the present invention, below by example, the present invention is further elaborated, but content of the present invention is not limited to this.
Embodiment 1: a kind of alcohol-based biological fuel oil for boiler, and various raw material add-ons (by weight percentage) are as follows:
Refining biodiesel 20%
Industrial methyl alcohol 68%
Oleic acid 8%;
Tween80+Span60(7+3) 3.4％；
Xylo-Mucine 0.5%
Benzotriazole 0.1%
The present embodiment step is: oleic acid, Tween80+Span60 by weight getting are joined in industrial alcohol, and rotating speed 400r/min, stirs, again refining biodiesel is slowly joined in the mixed solution of firm preparation, rotating speed 400r/min, stirs while adding, until solution clarification.Again stablizing agent carboxymethyl sodium cellulosate and corrosion inhibitor benzotriazole joins in mixed solution, be stirred to solution clear and can obtain alcohol-based biological fuel oil of the present invention, record its calorific value and be about 28.1KJ/g, product is placed and within six months, is still kept clear state.
Embodiment 2: a kind of alcohol-based biological fuel oil for boiler, and various raw material add-ons (by weight percentage) are as follows:
Refining biodiesel 25%
Industrial methyl alcohol 61%
N-dodecanol 10%;
Hexadecyl lactate 3%;
Sodium oleate 0.9%
Benzotriazole+linoleic acid dimer (2+1) 0.1%;
The present embodiment step is: solubility promoter n-dodecanol, cosurfactant hexadecyl lactate by weight getting are joined in refining biodiesel, rotating speed 500r/min, stir, again mixed solution is slowly joined in industrial alcohol, rotating speed 450r/min, stir while adding, until solution clarification.Again the mixture of stablizer sodium oleate, corrosion inhibitor benzotriazole and linoleic acid dimer is joined in mixed solution, be stirred to solution clear and can obtain alcohol-based biological fuel oil of the present invention, record its calorific value and be about 30.2.2KJ/g, product is placed and within six months, is still kept clear state.
Embodiment 3: a kind of alcohol-based biological fuel oil for boiler, and various raw material add-ons (by weight percentage) are as follows:
Refining biodiesel 30%
Industrial methyl alcohol 55%
Oleic acid+n-Octanol (8+2) 12%;
Aliphatic alcohol polyethenoxy (4) ether 2%;
Polyoxyethylene glycol 0.8%;
Benzotriazole+dodecenylsuccinic acid (1+1) 0.2%
The present embodiment step is: solubility promoter oleic acid and n-Octanol, cosurfactant fatty alcohol-polyoxyethylene ether by weight getting are joined in industrial methanol, rotating speed 600r/min stirs, again refining biodiesel is slowly joined in the mixed solution of firm preparation, rotating speed 400r/min, stir while adding, until solution clarification.Again stablizer polyoxyethylene glycol, corrosion inhibitor benzotriazole and dodecenylsuccinic acid mixture are joined in mixed solution, be stirred to solution clear and can obtain alcohol-based biological fuel oil of the present invention, record its calorific value and be about 31.3KJ/g, product is placed and within six months, is still kept clear state.
Embodiment 4: a kind of alcohol-based biological fuel oil for boiler, and various raw material add-ons (by weight percentage) are as follows:
Refining biodiesel 35%
Industrial methyl alcohol 51%
Palmitinic acid+isopropylcarbinol (8+2) 10%;
Methyl sodiosul foaliphatate 3.5%;
Polyacrylamide 0.3%;
Dodecenylsuccinic acid+linoleic acid dimer (1+1) 0.2%;
The present embodiment step is: solubility promoter palmitinic acid and isopropylcarbinol, cosurfactant methyl sodiosul foaliphatate by weight getting are joined in refining biodiesel, stir, again methyl alcohol is slowly joined in the mixed solution of firm preparation, stir while adding, until solution clarification.Again stablizer polyacrylamide, corrosion inhibitor dodecenylsuccinic acid and linoleic acid dimer are joined in mixed solution, be stirred to solution clear and can obtain alcohol-based biological fuel oil of the present invention, record its calorific value and be about 34.6KJ/g, product is placed and within six months, is still kept clear state.
Embodiment 5: a kind of alcohol-based biological fuel oil for boiler, and various raw material add-ons (by weight percentage) are as follows:
Refining biodiesel 40%
Industrial methyl alcohol 47%
Oleic acid+n-dodecanol (6+4) 10%;
Polyoxyethylene 2%;
Sodium oleate 0.8%;
Benzotriazole+succinyl oxide (2+1) 0.2%;
The present embodiment step is: solubility promoter oleic acid and n-dodecanol, cosurfactant polyoxyethylene by weight getting are joined in refining biodiesel, rotating speed 800r/min, stir, again methyl alcohol is slowly joined in the mixed solution of firm preparation, rotating speed 500r/min, stir while adding, until solution clarification.Again stablizer sodium oleate, corrosion inhibitor benzotriazole and mixture of succinic anhydride are joined in mixed solution, be stirred to solution clear and can obtain alcohol-based biological fuel oil of the present invention, record its calorific value and be about 37.2KJ/g, product is placed and within six months, is still kept clear state.
Claims (3)
1. an alcohol-based biological fuel oil, is characterized in that being comprised of refining biodiesel, industrial methyl alcohol, additive, and described additive is comprised of solubility promoter, cosurfactant, stablizer, corrosion inhibitor, and by percentage to the quality, ratio is as follows:
The content sum of each component is 100% above;
Described refining biodiesel be take vegetables oil or waste grease and industrial methanol and is prepared from as raw material;
The purity of described industrial methyl alcohol is 90%-99%;
Described solubility promoter comprises one or more in oleic acid, palmitinic acid, naphthenic acid, n-dodecanol, n-Octanol, isooctyl alcohol, n-Heptyl alcohol, propyl carbinol;
Cosurfactant comprises one or more in fatty alcohol-polyoxyethylene ether, alkyl lactate ester, sorbitan monooleate, polyoxyethylene, Nonyl pheno (4) ether, dodecyl phenol polyethenoxy (10) ether, Triton X-100, methyl sodiosul foaliphatate;
Stablizer is: one or more in Xylo-Mucine, sodium oleate, polyacrylamide, polyoxyethylene glycol;
Corrosion inhibitor is: one or more in benzotriazole, linoleic acid dimer, dodecenylsuccinic acid, ditertbutylparacresol, organophosphate, maleic anhydride, succinyl oxide, fatty acid imidazoline quinoline boric acid ester;
Described vegetables oil is by the oil of planting manioca, Chinese pistache, castor-oil plant, the seeds of a tung oil tree, walnut, palm tree, tea oil tree oil crops and obtaining;
Described waste grease refers to the grease that foodstuff production and leather processing produce or contains grease waste material, food and restaurant service industry and unit dining room fried food produce can not be edible again grease, the grease refining from swill, the grease that fume extracting system is collected, the grease that oil-containing waste water produces after water-and-oil separator or isolation tank separation, the grease that unedible livestock is smelt and expired rotten grease;
Described alcohol-based biological fuel oil, energy perfect combustion, its thermal value range is 25.5KJ/g～37.6KJ/g; Described organophosphate is tributyl phosphate, triphenylphosphate, dioctylphosphoric acid ester;
Described refining biodiesel makes by chemical method soda acid two-step catalysis technique.
2. the preparation method of alcohol-based biological fuel oil according to claim 1, is characterized in that containing following steps:
Solubility promoter in additive, cosurfactant are joined in refining biodiesel or industrial methyl alcohol successively, after stirring with stirrer, industrial methyl alcohol or refining biodiesel are joined in prepared solution, stir until solution is transparent, add successively again stablizer and corrosion inhibitor, stirring makes it fully dissolve the alcohol-based biological fuel oil that can obtain clear
Described solubility promoter comprises one or more in oleic acid, palmitinic acid, naphthenic acid, n-dodecanol, n-Octanol, isooctyl alcohol, n-Heptyl alcohol, propyl carbinol;
Cosurfactant comprises one or more in fatty alcohol-polyoxyethylene ether, alkyl lactate ester, sorbitan monooleate, polyoxyethylene, Nonyl pheno (4) ether, dodecyl phenol polyethenoxy (10) ether, Triton X-100, methyl sodiosul foaliphatate;
Stablizer is: one or more in Xylo-Mucine, sodium oleate, polyacrylamide, polyoxyethylene glycol;
Corrosion inhibitor is: one or more in benzotriazole, linoleic acid dimer, dodecenylsuccinic acid, ditertbutylparacresol, organophosphate, dimeracid, maleic anhydride, succinyl oxide, fatty acid imidazoline quinoline boric acid ester;
Described when adding additive in refining biodiesel or industrial methanol, at room temperature with stirrer, slowly add while stirring, mixing speed is 300-1000r/min, after additive adds completely, can stop after continuing to stir 1-5min;
Described organophosphate is tributyl phosphate, triphenylphosphate, dioctylphosphoric acid ester.
3. the preparation method of alcohol-based biological fuel oil according to claim 2, it is characterized in that: described solubility promoter, cosurfactant, stablizer, corrosion inhibitor are a kind of material interpolation wherein, or select wherein any two kinds of materials to be not less than 20% with a kind of mass ratio of material wherein, mix and add.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010297495.0A CN101948702B (en) | 2010-09-30 | 2010-09-30 | Alcohol-based biological fuel oil for boiler and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010297495.0A CN101948702B (en) | 2010-09-30 | 2010-09-30 | Alcohol-based biological fuel oil for boiler and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101948702A CN101948702A (en) | 2011-01-19 |
| CN101948702B true CN101948702B (en) | 2014-10-01 |
Family
ID=43452334
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010297495.0A Expired - Fee Related CN101948702B (en) | 2010-09-30 | 2010-09-30 | Alcohol-based biological fuel oil for boiler and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101948702B (en) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102295966A (en) * | 2011-07-25 | 2011-12-28 | 青岛福瑞斯生物能源科技开发有限公司 | Micro-emulsified biodiesel and preparation method thereof |
| CN103087792A (en) * | 2011-10-31 | 2013-05-08 | 薛成才 | Micro-emulsified composite diesel oil fuel additive |
| CN102504887A (en) * | 2011-11-02 | 2012-06-20 | 平凉市中力新能源科技研究院 | Special methanol compound fuel for cooking range |
| CN102517101B (en) * | 2011-12-23 | 2014-05-14 | 江苏玖尚燃油发展有限公司 | Automobile methanol diesel fuel and preparation method thereof |
| CN103509611B (en) * | 2012-06-14 | 2015-08-05 | 刘粤荣 | A kind of biofuel and preparation method thereof |
| CN102899106B (en) * | 2012-11-12 | 2014-12-10 | 陕西宝姜新能源技术研发有限公司 | Novel low carbon methanol diesel and additive and preparation method thereof |
| CN103911190B (en) * | 2013-01-09 | 2015-12-02 | 刘粤荣 | Bio-fuel-oil of a kind of polynary formula combination and preparation method thereof |
| CN103184082A (en) * | 2013-04-12 | 2013-07-03 | 厦门鑫烨盛能源科技有限公司 | Methanol liquid fuel and preparation method thereof |
| CN103232868B (en) * | 2013-05-28 | 2014-01-01 | 宋贵中 | Novel environment-friendly high-energy alcohol-based industrial fuel and preparation method thereof |
| CN103351892B (en) * | 2013-08-06 | 2015-09-30 | 杨宝伟 | A kind of Environmentally-friebiofuel biofuel for boiler and preparation method thereof |
| CN103695048A (en) * | 2013-12-30 | 2014-04-02 | 湖南亿通新能源开发有限公司 | Biomass methanol diesel oil and preparation method thereof |
| US20160340599A1 (en) * | 2014-05-10 | 2016-11-24 | Gui-zhong Song | Novel Environmentally-Friendly High-Energy Alcohol-based Industrial Fuel and Preparation Method Thereof |
| CN104357101B (en) * | 2014-11-06 | 2016-10-26 | 金景达(北京)环保动力科技有限公司 | A kind of efficient stable biodiesel hybrid fuel |
| CN104479765B (en) * | 2014-11-14 | 2016-09-14 | 山东永泰化工有限公司 | A kind of biodiesel and preparation method thereof |
| CN104745242A (en) * | 2015-03-13 | 2015-07-01 | 张东宁 | Alcohol-hydrocarbon composite liquid fuel |
| CN108350372B (en) * | 2015-06-30 | 2021-05-25 | 拉弗朗特拉大学 | Bioadditive for heavy oils comprising rapeseed oil methyl ester, surfactant, diluent and metal oxide |
| CN107312578A (en) * | 2016-04-27 | 2017-11-03 | 广东博大新能源科技有限公司 | A kind of preparation method of gutter oil methanol cleaning fuel |
| CN107353941A (en) * | 2016-05-10 | 2017-11-17 | 郭小勇 | A kind of synthesized-power oil and preparation method thereof |
| CN106381178A (en) * | 2016-11-30 | 2017-02-08 | 广西东奇能源技术有限公司 | Biological fuel with high calorific value |
| CN108300521A (en) * | 2017-01-11 | 2018-07-20 | 舒高岭 | A kind of high heating value alcohol hydrocarbon bio-fuel |
| CN106833765A (en) * | 2017-03-14 | 2017-06-13 | 湖南云平环保科技有限公司 | The method that waste oil prepares microemulsion fuel |
| CN107164002B (en) * | 2017-06-07 | 2019-03-01 | 河南经特生物科技有限公司 | A kind of Methanol gasoline cosolvent |
| CN108034460A (en) * | 2017-12-27 | 2018-05-15 | 福建中源新能源股份有限公司 | Environment-friendly clean methanol biofuel |
| CN108410495B (en) * | 2018-02-09 | 2020-06-09 | 台州市莱恩克警报器有限公司 | Biofuel prepared from waste oil and fat and preparation method thereof |
| CN108359501A (en) * | 2018-02-09 | 2018-08-03 | 山东联星能源集团有限公司 | A kind of novel automobile coal alcohol compound bio fuel and preparation method thereof |
| CN108531228B (en) * | 2018-05-08 | 2020-07-28 | 桂林市淦隆环保科技有限公司 | Environment-friendly alcohol-based fuel for boiler |
| CN108587700B (en) * | 2018-05-08 | 2020-10-27 | 桂林市淦隆环保科技有限公司 | Alcohol-based fuel for boiler |
| CN108559554B (en) * | 2018-05-08 | 2020-10-27 | 桂林市淦隆环保科技有限公司 | Good-stability alcohol-based fuel for boiler |
| CN108753384B (en) * | 2018-06-20 | 2020-05-19 | 中国科学院兰州化学物理研究所苏州研究院 | Clean diesel additive, preparation method thereof and clean diesel composition |
| CN108906012A (en) * | 2018-07-06 | 2018-11-30 | 云南驰宝节能科技有限公司 | A kind of highly enriched gasoline, diesel oil special-purpose catalyst |
| CN111763541A (en) * | 2020-03-12 | 2020-10-13 | 榆林碳氢研究院股份有限公司 | High-calorific-value clean fuel for industrial boiler and preparation method thereof |
| CN112175680A (en) * | 2020-09-11 | 2021-01-05 | 江苏大学 | Methanol emulsification hydrogenation catalytic biodiesel and preparation method thereof |
| CN114317044A (en) * | 2022-01-26 | 2022-04-12 | 陕西延长石油能源科技有限公司 | Clean boiler fuel and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080184616A1 (en) * | 2007-01-09 | 2008-08-07 | The Board Of Regents Of The Nevada System Of Higher Education | Biofuel production methods |
| CN101497828A (en) * | 2009-01-13 | 2009-08-05 | 中国林业科学研究院林产化学工业研究所 | Biodiesel based fuel oil and preparation thereof |
| CN101643673A (en) * | 2009-09-08 | 2010-02-10 | 郭振山 | Methanol gasoline |
| CN101831327A (en) * | 2010-05-18 | 2010-09-15 | 杭州绿洲能源科技有限公司 | Novel alcohol-based fuel with high heat value |
-
2010
- 2010-09-30 CN CN201010297495.0A patent/CN101948702B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN101948702A (en) | 2011-01-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101948702B (en) | Alcohol-based biological fuel oil for boiler and preparation method thereof | |
| Mishra et al. | A review of production, properties and advantages of biodiesel | |
| Sivakumar et al. | Bio-diesel production by alkali catalyzed transesterification of dairy waste scum | |
| Rashid et al. | Production of sunflower oil methyl esters by optimized alkali-catalyzed methanolysis | |
| Ahmad et al. | Microalgae as a sustainable energy source for biodiesel production: a review | |
| CN103265981B (en) | Alcohol-based fuel combustion improver and alcohol-based fuel | |
| CN101688150A (en) | Biodiesel production | |
| Cvengroš et al. | Properties of alkyl esters base on castor oil | |
| Shields-Menard et al. | Lipid accumulation by Rhodococcus rhodochrous grown on glucose | |
| CN102311883A (en) | Method for preparing high-purity biodiesel | |
| CN101538490A (en) | Micro-emulsified biomass fuel and preparation method thereof | |
| CN103160336A (en) | Catering industry waste oil-based biological alcohol oil and preparation method thereof | |
| Pinzi | Feedstocks for advanced biodiesel production | |
| Sharmin et al. | Growth, fatty acid, and lipid composition of marine microalgae Skeletonema costatum available in Bangladesh coast: consideration as biodiesel feedstock | |
| CN101260416A (en) | Technique for preparing 1,3-diglyceride by enzyme method | |
| CN103060032B (en) | Temperature-resistant microemulsified methanol diesel oil and preparation method thereof | |
| CN106221820A (en) | A kind of environment-friendly fuel and preparation method thereof | |
| CN102559300A (en) | Alcohol ether diesel fuel for vehicles and preparation method thereof | |
| CN105001922B (en) | The preparation method of biodiesel | |
| Aderibigbe et al. | Waste cooking oil conversion to biodiesel using solid bifunctional catalysts | |
| CN101812331A (en) | Low-sulfur ester-based composite fuel oil | |
| CN104762121A (en) | Method using plant oil after-cut fraction for production of green lubricating oil | |
| Kalbande et al. | Jatropha and Karanj bio-fuel: an alternate fuel for diesel engine | |
| CN103045311B (en) | Micro-emulsified diesel oil and preparation method thereof | |
| CN101531913A (en) | Method for preparing biodiesel |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20141001 Termination date: 20160930 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |