CN106221820A - A kind of environment-friendly fuel and preparation method thereof - Google Patents

A kind of environment-friendly fuel and preparation method thereof Download PDF

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Publication number
CN106221820A
CN106221820A CN201610578090.1A CN201610578090A CN106221820A CN 106221820 A CN106221820 A CN 106221820A CN 201610578090 A CN201610578090 A CN 201610578090A CN 106221820 A CN106221820 A CN 106221820A
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parts
fuel
auxiliary agent
environment
oil
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马迎慧
范晓龙
薛奥运
马革兰
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Nanjing University of Information Science and Technology
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Nanjing University of Information Science and Technology
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/183—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
    • C10L1/1832—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C10L1/1985—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/23—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/02—Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
    • C10L2200/0204—Metals or alloys
    • C10L2200/024—Group VIII metals: Fe, Co, Ni, Ru, Rh, Pd, Os, Ir, Pt
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0407—Specifically defined hydrocarbon fractions as obtained from, e.g. a distillation column
    • C10L2200/0415—Light distillates, e.g. LPG, naphtha
    • C10L2200/0423—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0461—Fractions defined by their origin
    • C10L2200/0469—Renewables or materials of biological origin
    • C10L2200/0476—Biodiesel, i.e. defined lower alkyl esters of fatty acids first generation biodiesel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/24—Mixing, stirring of fuel components
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The invention discloses a kind of environment-friendly fuel, the raw material of following weight proportion prepare: 20 30 parts of gasoline, biodiesel 10 20 parts, Vegetable oil lipoprotein 20 30 parts, microbial grease 10 20 parts, biomass block fuel 30 40 parts, mask agent 13 parts, mutual solvent 13 parts, 0.1 0.3 parts of antioxidant, antidetonator 1 1.5 parts, enzyme auxiliary agent 12 parts and auxiliary agent 35 parts.The environment-friendly fuel environmental protection that the present invention prepares, and combustion heat value is high, it is possible to sufficiently achieve the ignition temperature requirement in use, can use as power fuel and boiler oil.

Description

A kind of environment-friendly fuel and preparation method thereof
Technical field
The present invention relates to a kind of fuel, be specifically related to a kind of environment-friendly fuel and preparation method thereof.
Background technology
At present, existing situation is that energy crisis is on the rise and consumption of petroleum amount is continuously increased, the cost of high-grade fuel oil Escalating with price, people more wish to replace high-quality fuel oil with reduced fuel oil, and this makes various fuel oil all to weight Matter direction is developed.Domestic each province and city fuel oil equipment is in great demand, and because not having special oil, fuel made by major part diesel oil, both Waste national energy adds again user's spending, also results in environmental pollution, and flammability is poor, and row's black smoke amount is big, and not environmentally, cost is high High.Heavy oil, the advantage of super-viscous oil are low price, calorific value height.Its shortcoming is that viscosity is high, flash-point is low, be not easy to store, transport and Use, and discharge amount of exhaust gas is big, pollute environment serious.Due to its these features, for a long time only in large-scale industry combustion Applied on burning equipment, and be restricted on general medium and small combustion apparatus.Fuel oil equipment institute of China at present The burner used is mostly from imports such as Italy, Korea S, Germany, the U.S., and the performance indications using oil product are wanted by they Ask very strict, in order to solve these difficult problems, it is necessary to research and develop a kind of novel fuel oil.
Summary of the invention
The invention aims to solve defect present in prior art, it is provided that a kind of combustion heat value is high, and environmental protection Fuel oil.
In order to achieve the above object, the invention provides a kind of environment-friendly fuel, the raw material of following weight proportion be prepared into Arrive: gasoline 20-30 part, biodiesel 10-20 part, Vegetable oil lipoprotein 20-30 part, microbial grease 10-20 part, biomass block combustion Material 30-40 part, mask agent 1-3 part, mutual solvent 1-3 part, antioxidant 0.1-0.3 part, antidetonator 1-1.5 part, enzyme auxiliary agent 1-2 Part and auxiliary agent 3-5 part.
Wherein, the thick methyl ester that biodiesel blendes together with waste oil, hogwash fat and methanol as raw material, oxidized decolouring, deacidification, Go soap to refine to form；Vegetable oil lipoprotein uses useless Petiolus Trachycarpi oil；Biomass block Fuel Selection weeds, beanstalk, Caulis et Folium Oryzae, rice husk, Semen Maydis One or more mixing in straw, corn cob, sorghum stalks, cotton straw or wheat straw.
Mask agent uses one or more mixing in Flos Lilii viriduli essence, jasmine flower essence or Flos Rosae Rugosae essence；Mutual solvent The solvent mixed with butanol 1:1.5 in mass ratio for triethanolamine；Antioxidant is 2,6 di-t-butyl 4-methylphenols；Antiknock Agent is one or both mixing in ferrocene or tert-butyl group ferrocene；Enzyme auxiliary agent is catalase and biological lipase Mix with weight proportion 1:1.2；Auxiliary agent is fatty alcohol-polyoxyethylene ether.
The optimum feed stock weight proportion of environment-friendly fuel of the present invention is: 25 parts of gasoline, biodiesel 15 parts, Vegetable oil lipoprotein 25 Part, microbial grease 15 parts, biomass block fuel 35 parts, mask agent 2 parts, mutual solvent 2 parts, 0.2 part of antioxidant, antidetonator 1.2 parts, enzyme auxiliary agent 1.5 parts and auxiliary agent 4 parts.
Wherein, biodiesel is prepared by the following method:
(1) oxidative decoloration: with thick methyl ester as raw material, is warming up to 65-70 DEG C, add sulphuric acid-acetic acid mixture to pH be 5 ~ 6, after stirring；Add 35wt% hydrogen peroxide, keep oxidative decoloration 1h；Stand, remove oxidation residua and moisture；Described sulfur Acid-acetic acid mixture uses 96wt% sulphuric acid, industrial acetic 9:1 in mass ratio to mix；
(2) deacidification, soap is removed: add compound aqueous slkali, after stirring 15min, stratification, removes soap；Then through washing, vacuum 90-100 DEG C of distillation removing moisture, prepares biodiesel；Compound aqueous slkali uses the component configuration of following weight proportion to form: hydrogen Potassium oxide 1～3 parts, sodium hydroxide 2～4 parts, potassium sulfate 3～5 parts, sodium carbonate 2～6 parts, water 200～400 parts.
The preparation method of microbial grease is as follows:
(1) regulation aqueous slurry to the pH value containing oleaginous microorganism is 1-5；
(2) stirring under the hydrothermal condition that temperature is 160-260 DEG C, power of agitator is 0.15-1.5kw；Mixing time is 2- 250 minutes, make the oils and fats dissolution in oleaginous microorganism cell, obtain the molten slurry of the oleaginous microorganism containing oils and fats；
(3) centrifugation is used, under rotating speed 3000-8000rpm, the regulation of 2-10 minute time, from the molten slurry of oleaginous microorganism In isolate oils and fats.
Present invention also offers the preparation method of above-mentioned environment-friendly fuel, comprise the following steps:
(1) gasoline and biodiesel are placed in stirred tank, add mask agent, antidetonator and auxiliary agent, uniform stirring；
(2) biomass block fuel is pulverized, and by the biomass block fuel pulverized and Vegetable oil lipoprotein and microbial oil Fat mix homogeneously；
3) by step (1) and the material mixing in step (2), and pump in static mixer, add mutual solvent, antioxidant and life Thing enzyme auxiliary agent, room temperature, normal pressure lower seal mixed storage 24-36 hour, after filter, pumps into oil tank and stores,.
The present invention has the advantage that the present invention, with various waste oil as raw material, becomes after treatment compared to existing technology Fuel oil, has reached the recycling of refuse；In combination with the hyperoxic feature of biomass fuel so that each component is abundant Burning, fuel value is high, it is possible to sufficiently achieve the ignition temperature requirement in use, and the oil product prepared is environment-friendly products, will not Air is polluted；And the fuel price of preparation is less than ordinary petroleum fuel, can use as power fuel and boiler oil.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1
Prepare the raw material weight proportioning of environment-friendly fuel of the present invention: 20 parts of gasoline, biodiesel 10 parts, Vegetable oil lipoprotein 20 parts, micro-life Thing oils and fats 10 parts, biomass block fuel 30 parts, mask agent 1 part, mutual solvent 1 part, 0.1 part of antioxidant, antidetonator 1 part, biology Enzyme auxiliary agent 1 part and auxiliary agent 3 parts.
Wherein, gasoline is made up of the isobutyltrimethylmethane. of 90-97% and the normal heptane of 3-10%,
Biodiesel be waste oil, the thick methyl ester of hogwash fat and methanol-fueled CLC be raw material, oxidized decolouring, deacidification, go soap to refine Biodiesel.
The concrete preparation technology of biodiesel is as follows:
1) oxidative decoloration: with thick methyl ester as raw material, is warming up to 65-70 DEG C, and adding sulphuric acid-acetic acid mixture is 5 to pH ~ 6, after stirring；Add 35wt% hydrogen peroxide, keep oxidative decoloration 1h；Stand, remove oxidation residua and moisture；Described Sulphuric acid-acetic acid mixture be that 96wt% sulphuric acid, industrial acetic 9:1 in mass ratio mixes；2) deacidification, soap is removed: add Compound aqueous slkali, after stirring 15min, stratification, removes soap；Then through washing, vacuum 90-100 DEG C distillation removing moisture, system Obtain biodiesel.Compound aqueous slkali uses the component configuration of following weight proportion to form: potassium hydroxide 1～3 parts, sodium hydroxide 2～4 parts, potassium sulfate 3～5 parts, sodium carbonate 2～6 parts, water 200～400 parts.
Biomass block fuel uses weeds briquet.
Microbial grease is prepared by following steps:
(1) regulation aqueous slurry to the pH value containing oleaginous microorganism is 1-5；
(2) stirring under the hydrothermal condition that temperature is 160-260 DEG C, power of agitator is 0.15-1.5kw；Mixing time is 2- 250 minutes, make the oils and fats dissolution in oleaginous microorganism cell, obtain the molten slurry of the oleaginous microorganism containing oils and fats；
(3) centrifugation is used, under rotating speed 3000-8000rpm, the regulation of 2-10 minute time, from the molten slurry of oleaginous microorganism In isolate oils and fats.
Mask agent uses Flos Lilii viriduli essence.
Vegetable oil lipoprotein uses useless Petiolus Trachycarpi oil.
Mutual solvent is the solvent that triethanolamine mixes with butanol 1:1.5 in mass ratio.
Antioxidant is 2,6 di-t-butyl 4-methylphenols.
Antidetonator is ferrocene.
Enzyme auxiliary agent is that catalase mixes with weight proportion 1:1.2 with biological lipase, and auxiliary agent is fat Polyoxyethylenated alcohol.
The preparation method of this environment-friendly fuel is as follows:
1) gasoline and biodiesel are placed in stirred tank, add mask agent, antidetonator and auxiliary agent low speed uniform stirring；
2) biomass block fuel is pulverized, and by the biomass block fuel pulverized and Vegetable oil lipoprotein and microbial grease Mix homogeneously；
3) by step 1) and step 2) in material mixing, and pump in static mixer, add mutual solvent, antioxidant and biology Enzyme auxiliary agent, room temperature, normal pressure lower seal mixed storage 24 hours, after filter, circulation are filtered again, is pumped into oil tank storage Deposit,.
Embodiment 2
A kind of environment-friendly fuel, including the raw material of following weight portion: 30 parts of gasoline, biodiesel 20 parts, Vegetable oil lipoprotein 30 parts, micro-life Thing oils and fats 20 parts, biomass block fuel 40 parts, mask agent 3 parts, mutual solvent 3 parts, 0.3 part of antioxidant, antidetonator 1.5 parts, life Thing enzyme auxiliary agent 2 parts and auxiliary agent 5 parts.
Biomass block fuel uses rice husk briquet.
Mask agent is Flos Rosae Rugosae essence.
Antidetonator is tert-butyl group ferrocene.
Vegetable oil lipoprotein, antioxidant, mutual solvent, biodiesel, enzyme auxiliary agent and auxiliary agent are with embodiment 1.
Preparation method is with embodiment 1.
Embodiment 3
A kind of environment-friendly fuel, including the raw material of following weight portion: 25 parts of gasoline, biodiesel 15 parts, Vegetable oil lipoprotein 25 parts, micro-life Thing oils and fats 15 parts, biomass block fuel 35 parts, mask agent 2 parts, mutual solvent 2 parts, 0.2 part of antioxidant, antidetonator 1.2 parts, life Thing enzyme auxiliary agent 1.5 parts and auxiliary agent 4 parts.
Biomass block fuel uses sorghum stalks briquet.
Mask agent is jasmine flower essence.
Antidetonator is the mixture (mixed proportion 1:2) of ferrocene and tert-butyl group ferrocene.
Vegetable oil lipoprotein, antioxidant, mutual solvent, biodiesel, enzyme auxiliary agent and auxiliary agent are with embodiment 1.
Preparation method is with embodiment 1.
Effect example:
Experimental technique: according to national standard assay method, measure the combustion heat of the environment-friendly fuel of existing fuel and the application respectively Value, the combustion heat value of the environment-friendly fuel that the present invention prepares is all higher than 31000KJ/Kg.Wherein, embodiment 3 prepares Environment-friendly fuel combustion heat value is the highest, and measurement result see table 1.
The existing fuel of table 1 and the combustion heat value measurement result of environment-friendly fuel of the present invention.
As can be seen here, the environment-friendly fuel of the application is compared to existing fuel, and its calorific value is higher.
The above, the only detailed description of the invention of the present invention, but protection scope of the present invention is not limited thereto, and any The change expected without creative work or replacement, all should contain within protection scope of the present invention, therefore, and the present invention's Protection domain should be as the criterion with the protection domain that claims are limited.

Claims (7)

1. an environment-friendly fuel, it is characterised in that prepared by the raw material of following weight proportion: gasoline 20-30 part, biological bavin Oil 10-20 part, Vegetable oil lipoprotein 20-30 part, microbial grease 10-20 part, biomass block fuel 30-40 part, mask agent 1-3 Part, mutual solvent 1-3 part, antioxidant 0.1-0.3 part, antidetonator 1-1.5 part, enzyme auxiliary agent 1-2 part and auxiliary agent 3-5 part.
Environment-friendly fuel the most according to claim 1, it is characterised in that described biodiesel is with waste oil, hogwash fat and first The thick methyl ester that alcohol blendes together is raw material, oxidized decolouring, deacidification, goes that soap is refined to be formed；Described Vegetable oil lipoprotein uses useless Petiolus Trachycarpi oil；Institute State in biomass block Fuel Selection weeds, beanstalk, Caulis et Folium Oryzae, rice husk, corn stalk, corn cob, sorghum stalks, cotton straw or wheat straw Plant or multiple mixing.
Environment-friendly fuel the most according to claim 2, it is characterised in that: described mask agent uses Flos Lilii viriduli essence, Flos Jasmini Sambac One or more mixing in essence or Flos Rosae Rugosae essence；Described mutual solvent is that triethanolamine mixes with butanol 1:1.5 in mass ratio The solvent closed；Described antioxidant is 2,6 di-t-butyl 4-methylphenols；Described antidetonator is ferrocene or the tert-butyl group two cyclopentadienyl One or both mixing in ferrum；Described enzyme auxiliary agent is that catalase mixes with weight proportion 1:1.2 with biological lipase Conjunction forms；Described auxiliary agent is fatty alcohol-polyoxyethylene ether.
Environment-friendly fuel the most according to claim 3, it is characterised in that prepared by the raw material of following weight proportion: vapour Oil 25 parts, biodiesel 15 parts, Vegetable oil lipoprotein 25 parts, microbial grease 15 parts, biomass block fuel 35 parts, mask agent 2 parts, Mutual solvent 2 parts, 0.2 part of antioxidant, antidetonator 1.2 parts, enzyme auxiliary agent 1.5 parts and auxiliary agent 4 parts.
Environment-friendly fuel the most according to claim 4, it is characterised in that described biodiesel is prepared by the following method:
(1) oxidative decoloration: with thick methyl ester as raw material, is warming up to 65-70 DEG C, add sulphuric acid-acetic acid mixture to pH be 5 ~ 6, after stirring；Add 35wt% hydrogen peroxide, keep oxidative decoloration 1h；Stand, remove oxidation residua and moisture；Described sulfur Acid-acetic acid mixture uses 96wt% sulphuric acid, industrial acetic 9:1 in mass ratio to mix；
(2) deacidification, soap is removed: add compound aqueous slkali, after stirring 15min, stratification, removes soap；Then through washing, vacuum 90-100 DEG C of distillation removing moisture, prepares biodiesel；Described compound aqueous slkali use following weight proportion component configuration and Become: potassium hydroxide 1～3 parts, sodium hydroxide 2～4 parts, potassium sulfate 3～5 parts, sodium carbonate 2～6 parts, water 200～400 parts.
Environment-friendly fuel the most according to claim 4, it is characterised in that described microbial grease is prepared by the following method:
(1) regulation aqueous slurry to the pH value containing oleaginous microorganism is 1-5；
(2) stirring under the hydrothermal condition that temperature is 160-260 DEG C, power of agitator is 0.15-1.5kw；Mixing time is 2- 250 minutes, make the oils and fats dissolution in oleaginous microorganism cell, obtain the molten slurry of the oleaginous microorganism containing oils and fats；
(3) centrifugation is used, under rotating speed 3000-8000rpm, the regulation of 2-10 minute time, from the molten slurry of oleaginous microorganism In isolate oils and fats.
7. the preparation method of the arbitrary described environment-friendly fuel of claim 1 to 6, it is characterised in that comprise the following steps:
(1) gasoline and biodiesel are placed in stirred tank, add mask agent, antidetonator and auxiliary agent, uniform stirring；
(2) biomass block fuel is pulverized, and by the biomass block fuel pulverized and Vegetable oil lipoprotein and microbial oil Fat mix homogeneously；
(3) by the material mixing in step (1) and step (2), and pump in static mixer, add mutual solvent, antioxidant and Enzyme auxiliary agent, room temperature, normal pressure lower seal mixed storage 24-36 hour, after filter, pumps into oil tank and stores,.
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CN108179042A (en) * 2018-02-07 2018-06-19 合肥嘉仕诚能源科技有限公司 A kind of New Alcohol Based liquid fuel and preparation method thereof
CN108384586A (en) * 2018-03-01 2018-08-10 合肥嘉仕诚能源科技有限公司 A kind of preparation method of novel environment friendly fuel
CN113549476A (en) * 2021-07-21 2021-10-26 四川新源素科技有限公司 Civil life fuel and preparation method thereof
CN114075462A (en) * 2020-08-12 2022-02-22 湖南荣海新能源科技有限公司 Preparation method of environment-friendly fuel oil
US11807824B1 (en) 2022-10-03 2023-11-07 Clifton Ray Taylor Fuel additive composition

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CN104099141A (en) * 2014-08-01 2014-10-15 东莞市向阳世纪能源有限公司 Energy-saving environment-friendly fuel oil and preparation method thereof
CN104164251A (en) * 2014-08-28 2014-11-26 刘五连 Environment-friendly fuel oil for special car
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CN104293473A (en) * 2013-07-19 2015-01-21 中国石油化工股份有限公司 Method for extracting oil from oil production microbes
CN103773541A (en) * 2014-01-20 2014-05-07 江苏集贤绿色化学科技研究院有限公司 Environment-friendly and energy-saving biological fuel
CN104099141A (en) * 2014-08-01 2014-10-15 东莞市向阳世纪能源有限公司 Energy-saving environment-friendly fuel oil and preparation method thereof
CN104164251A (en) * 2014-08-28 2014-11-26 刘五连 Environment-friendly fuel oil for special car

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108179042A (en) * 2018-02-07 2018-06-19 合肥嘉仕诚能源科技有限公司 A kind of New Alcohol Based liquid fuel and preparation method thereof
CN108384586A (en) * 2018-03-01 2018-08-10 合肥嘉仕诚能源科技有限公司 A kind of preparation method of novel environment friendly fuel
CN114075462A (en) * 2020-08-12 2022-02-22 湖南荣海新能源科技有限公司 Preparation method of environment-friendly fuel oil
CN113549476A (en) * 2021-07-21 2021-10-26 四川新源素科技有限公司 Civil life fuel and preparation method thereof
US11807824B1 (en) 2022-10-03 2023-11-07 Clifton Ray Taylor Fuel additive composition

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