CN104099140A - Industrial environment-friendly fuel oil and preparation method thereof - Google Patents
Industrial environment-friendly fuel oil and preparation method thereof Download PDFInfo
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- CN104099140A CN104099140A CN201410373840.2A CN201410373840A CN104099140A CN 104099140 A CN104099140 A CN 104099140A CN 201410373840 A CN201410373840 A CN 201410373840A CN 104099140 A CN104099140 A CN 104099140A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
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Abstract
The invention discloses an industrial environment-friendly fuel oil and a preparation method thereof. The industrial environment-friendly fuel oil comprises the following ingredients in parts by weight: 10-20 parts of biodiesel, 20-40 parts of vegetable fat, 3-6 parts of vegetable oil acid or ethanolamine, 10-25 parts of methanol and 10-40 parts of steamed oil, wherein steamed oil is obtained by distilling used oil and/or diesel oil and/or gutter oil. The industrial environment-friendly fuel oil is high in heating value, stable in properties, clean to discharge, has low possibility of volatilizing, nontoxic, smokeless and flavorless, can fully meet the requirement on the ignition temperature in use, can reasonably dispose waste oil, and saves the conventional energy sources.
Description
Technical field
The present invention relates to a kind of industry environmental protection oil fuel and preparation method thereof, industry environmental protection oil fuel is applicable to all kinds of diesel combustion machines, be applied to ceramics furnace, limestone kiln, drying oven, steam boiler, incinerator, smelting furnace, smelting furnace, sintering oven, process furnace and various degree type metallurgy industry kiln and generating set etc., equipment is without any transformation.
Background technology
At present, existing situation is that energy dilemma is on the rise and consumption of petroleum amount constantly increases, and cost and the price of high-grade fuel oil escalate, and people more wish with reduced fuel oil replacement high-quality fuel oil, and this makes various oil fuel all to heaviness future development.Domestic each province and city oil-burning apparatus is in great demand, and because there is no special oil, major part is made fuel with diesel oil, not only wastes national energy but also increased user's spending, also causes environmental pollution, and incendivity is poor, and row's black smoke amount is large, and not environmental protection is with high costs.The advantage of heavy oil, super viscous crude is that low price, calorific value are high.Its shortcoming is that viscosity is high, flash-point is low, be not easy to store, transport and use, and discharge amount of exhaust gas is large, and contaminate environment is serious.Due to its these features, only on large-scale industrial combustion equipment, obtained application for a long time, and be restricted on general medium and small combustion equipment.The burner that China's oil-burning apparatus is used is at present mostly from imports such as Italy, Korea S, Germany, the U.S., and they are very strict to using the performance index of oil product to require, and in order to solve these difficult problems, are necessary to research and develop a kind of novel oil fuel.
Summary of the invention
Technical problem to be solved by this invention is the defect that overcomes prior art, a kind of industry environmental protection oil fuel is provided, its oil fuel calorific value is high, stable performance, discharge clean, not volatile, nontoxic smoke-free and tasteless, can fully reach the ignition temperature requirement in use, can rationally dispose discarded oil product, save again the existing energy.
In order to solve the problems of the technologies described above, technical scheme of the present invention is: a kind of industry environmental protection oil fuel, and the mass parts of its component and each component is as follows:
Biofuel: 10 parts ~ 20 parts;
Vegetable oil lipoprotein: 20 parts-40 parts;
Vegetable oil acid or thanomin: 3 parts-6 parts;
Methyl alcohol: 10 parts-25 parts;
Steam oil: 10 parts-40 parts; Wherein, steam oil is the oil being drawn through distillation by used oil and/or diesel oil and/or sewer oil.
Further, described Vegetable oil lipoprotein is useless plam oil.
The mass parts of each component that a kind of industry environmental protection oil fuel of optimum is further provided, the mass parts of its component and each component is as follows:
Biofuel: 20 parts;
Vegetable oil lipoprotein: 20 parts;
Vegetable oil acid or thanomin: 5 parts;
Methyl alcohol: 15 parts;
Steam oil: 40 parts.
The present invention also provides a kind of preparation method of industry environmental protection oil fuel, and the step of the method is as follows:
(1) first biofuel, Vegetable oil lipoprotein and steam oil are put together and stirred;
(2) and then by methyl alcohol and vegetable oil acid or methyl alcohol and thanomin put into again and stir for some time simultaneously, can be made into industry environmental protection fuel oil product.
Adopted after technique scheme, its oil fuel calorific value is high, stable performance, discharge clean, not volatile, and nontoxic smoke-free and tasteless, can fully reach the ignition temperature requirement in use, can rationally dispose discarded oil product, has saved again the existing energy.
Embodiment
For content of the present invention is more easily expressly understood, below according to specific embodiment, the present invention is further detailed explanation.
Embodiment mono-
An industry environmental protection oil fuel, the mass parts of its component and each component is as follows:
Biofuel: 20 parts;
Vegetable oil lipoprotein: 20 parts;
Vegetable oil acid or thanomin: 5 parts;
Methyl alcohol: 15 parts;
Steam oil: 40 parts; Wherein, steam oil is the oil being drawn through distillation by used oil and/or diesel oil and/or sewer oil.
Vegetable oil lipoprotein can adopt useless plam oil.
The preparation method's of this industry environmental protection oil fuel step is as follows:
(1) first biofuel, Vegetable oil lipoprotein and steam oil are put together and stirred;
(2) and then by methyl alcohol and vegetable oil acid or methyl alcohol and thanomin put into again and stir for some time simultaneously, can be made into industry environmental protection fuel oil product.
Embodiment bis-
An industry environmental protection oil fuel, the mass parts of its component and each component is as follows:
Biofuel: 10 parts;
Vegetable oil lipoprotein: 20 parts;
Vegetable oil acid or thanomin: 3 parts;
Methyl alcohol: 10 parts;
Steam oil: 10 parts; Wherein, steam oil is the oil being drawn through distillation by used oil and/or diesel oil and/or sewer oil.
Vegetable oil lipoprotein can adopt useless plam oil.
The preparation method's of this industry environmental protection oil fuel step is as follows:
(1) first biofuel, Vegetable oil lipoprotein and steam oil are put together and stirred;
(2) and then by methyl alcohol and vegetable oil acid or methyl alcohol and thanomin put into again and stir for some time simultaneously, can be made into industry environmental protection fuel oil product.
Embodiment tri-
An industry environmental protection oil fuel, the mass parts of its component and each component is as follows:
Biofuel: 20 parts;
Vegetable oil lipoprotein: 40 parts;
Vegetable oil acid or thanomin: 6 parts;
Methyl alcohol: 25 parts;
Steam oil: 40 parts; Wherein, steam oil is the oil being drawn through distillation by used oil and/or diesel oil and/or sewer oil.
Vegetable oil lipoprotein can adopt useless plam oil.
The preparation method's of this industry environmental protection oil fuel step is as follows:
(1) first biofuel, Vegetable oil lipoprotein and steam oil are put together and stirred;
(2) and then by methyl alcohol and vegetable oil acid or methyl alcohol and thanomin put into again and stir for some time simultaneously, can be made into industry environmental protection fuel oil product.
Biofuel: in order to improve diesel production efficiency, adopt enzyme immobilization technology, and methyl alcohol is added in segmentation in reaction process, be more conducive to improve the production efficiency of diesel oil.This immobilized enzyme (lipase) is from a kind of candiyeast, is made reaction column for diesel production by it together with carrier, controls 30 ℃ of temperature, and transformation efficiency reaches 95%.This lipase is used continuously 100 days still non-inactivations, and reaction solution is through after reaction column several times, and reactant is standing, and glycerine is separated, can be directly used as biofuel.
Vegetable oil lipoprotein: the plant general designation oil plant of energy storing plant grease, Vegetable oil lipoprotein focuses mostly in the seed of plant, maximum with kind of benevolence content, Vegetable oil lipoprotein is the complex compound of higher fatty acid glyceride, water insoluble, be difficult to be dissolved in alcohol (except Viscotrol C), and be dissolved in fat, ether, sherwood oil, benzene equal solvent.Vegetable oil lipoprotein is oil plant and industrial raw material indispensable during people live, and except edible, is widely used in soap system, paint, lubricated wet goods aspect, and what have also has special purpose in national defense industry, is also the industrial important source material such as chemistry, medicine, light textile.
Vegetable oil acid: under normal temperature, be light yellow or red transparent oily liquid, 13.4 ℃ of fusing points, proportion 0.8905, water insoluble, dissolve in the organic solvents such as ethanol, gasoline, during hydrogenation, change stearic acid into, there is the general chemical property of organic carboxyl acid and the chemical property of unsaturated double-bond.Certainly there are a lot of purposes, as synthon.
Thanomin: thanomin can be made by ammonia and reacting ethylene oxide.Oxyethane, ammonia soln enter the reactor that stainless steel is made together with circulation ammonia, inside establish refrigerating unit, 30～40 ℃ of temperature of reaction, reaction pressure 0.7～3MPa.Reaction product enters deammoniation tower, and the ammonia removing returns to ammonia absorber and prepares ammonia soln, and bottom product obtains coarse ethanol amine through evaporation concentration and drying and dehydrating.Adopt underpressure distillation that Monoethanolamine MEA BASF, diethanolamine and trolamine are steamed respectively, purity to 98%～99%, the transformation efficiency of oxyethane approaches 100%, and the yield of thanomin is 95% left and right.In addition, still there is a small amount of by product polyethers to generate, in raw material, allocate the generation that a small amount of carbonic acid gas can reduce by product into.
Through detecting, the performance of industry environmental protection oil fuel prepared by above three kinds of embodiment is as shown in the table:
From upper table, can learn, the fuel value of industry environmental protection oil fuel of the present invention is high, stable performance, discharge are clean, not volatile, and nontoxic smoke-free and tasteless, can fully reach the ignition temperature requirement in use, can rationally dispose discarded oil product, save again the existing energy.
Above-described specific embodiment; technical problem, technical scheme and beneficial effect that the present invention is solved further describe; institute is understood that; the foregoing is only specific embodiments of the invention; be not limited to the present invention; within the spirit and principles in the present invention all, any modification of making, be equal to replacement, improvement etc., within all should being included in protection scope of the present invention.
Claims (4)
1. an industry environmental protection oil fuel, is characterized in that: the mass parts of its component and each component is as follows:
Biofuel: 10 parts ~ 20 parts;
Vegetable oil lipoprotein: 20 parts-40 parts;
Vegetable oil acid or thanomin: 3 parts-6 parts;
Methyl alcohol: 10 parts-25 parts;
Steam oil: 10 parts-40 parts; Wherein, steam oil is the oil being drawn through distillation by used oil and/or diesel oil and/or sewer oil.
2. industry environmental protection oil fuel according to claim 1, is characterized in that: described Vegetable oil lipoprotein is useless plam oil.
3. industry environmental protection oil fuel according to claim 1, is characterized in that: the mass parts of its component and each component is as follows:
Biofuel: 20 parts;
Vegetable oil lipoprotein: 20 parts;
Vegetable oil acid or thanomin: 5 parts;
Methyl alcohol: 15 parts;
Steam oil: 40 parts.
4. a preparation method for industry environmental protection oil fuel as claimed any one in claims 1 to 3, is characterized in that: the step of the method is as follows:
(1) first biofuel, Vegetable oil lipoprotein and steam oil are put together and stirred;
(2) and then by methyl alcohol and vegetable oil acid or methyl alcohol and thanomin put into again and stir for some time simultaneously, can be made into industry environmental protection fuel oil product.
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| CN201410373840.2A CN104099140A (en) | 2014-08-01 | 2014-08-01 | Industrial environment-friendly fuel oil and preparation method thereof |
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| CN201410373840.2A CN104099140A (en) | 2014-08-01 | 2014-08-01 | Industrial environment-friendly fuel oil and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105950230A (en) * | 2016-04-25 | 2016-09-21 | 杨宝伟 | Green and environment-friendly diesel oil for vehicles and preparation method thereof |
| CN109705927A (en) * | 2017-10-25 | 2019-05-03 | 台湾中油股份有限公司 | Low-carbon biomass fuel and its manufacturing method |
| CN111575067A (en) * | 2020-05-19 | 2020-08-25 | 张晋忠 | Energy-saving clean environment-friendly fuel oil and preparation method thereof |
| CN113122343A (en) * | 2021-04-25 | 2021-07-16 | 任新付 | Synthetic diesel oil and preparation method thereof |
| CN117363385A (en) * | 2023-11-24 | 2024-01-09 | 上海新泊地化工技术服务有限公司 | Environment-friendly smokeless diesel oil and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101475855A (en) * | 2009-01-13 | 2009-07-08 | 中国林业科学研究院林产化学工业研究所 | Fuel oil based on petrifaction diesel and coarse biodiesel and preparation thereof |
| CN101838562A (en) * | 2009-12-04 | 2010-09-22 | 郑州侨联生物能源有限公司 | Proportional bio-diesel and preparation method thereof |
-
2014
- 2014-08-01 CN CN201410373840.2A patent/CN104099140A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101475855A (en) * | 2009-01-13 | 2009-07-08 | 中国林业科学研究院林产化学工业研究所 | Fuel oil based on petrifaction diesel and coarse biodiesel and preparation thereof |
| CN101838562A (en) * | 2009-12-04 | 2010-09-22 | 郑州侨联生物能源有限公司 | Proportional bio-diesel and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105950230A (en) * | 2016-04-25 | 2016-09-21 | 杨宝伟 | Green and environment-friendly diesel oil for vehicles and preparation method thereof |
| CN105950230B (en) * | 2016-04-25 | 2018-07-17 | 杨宝伟 | A kind of vehicle environmentally protective diesel oil and preparation method thereof |
| CN109705927A (en) * | 2017-10-25 | 2019-05-03 | 台湾中油股份有限公司 | Low-carbon biomass fuel and its manufacturing method |
| CN111575067A (en) * | 2020-05-19 | 2020-08-25 | 张晋忠 | Energy-saving clean environment-friendly fuel oil and preparation method thereof |
| CN113122343A (en) * | 2021-04-25 | 2021-07-16 | 任新付 | Synthetic diesel oil and preparation method thereof |
| CN117363385A (en) * | 2023-11-24 | 2024-01-09 | 上海新泊地化工技术服务有限公司 | Environment-friendly smokeless diesel oil and preparation method thereof |
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Application publication date: 20141015 |