CN101948671A - Adhesive for precision machining and environment-friendly cleaning method thereof - Google Patents
Adhesive for precision machining and environment-friendly cleaning method thereof Download PDFInfo
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- CN101948671A CN101948671A CN 201010288119 CN201010288119A CN101948671A CN 101948671 A CN101948671 A CN 101948671A CN 201010288119 CN201010288119 CN 201010288119 CN 201010288119 A CN201010288119 A CN 201010288119A CN 101948671 A CN101948671 A CN 101948671A
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Abstract
The invention discloses an adhesive for precision machining and a preparation method and an environment-friendly cleaning method thereof. The adhesive is prepared from the following raw materials by weight: 50-65 parts of rosins and derivatives thereof, 10-20 parts of fatty acids and derivatives thereof and 10-30 parts of wax. The preparation method comprises the following steps: placing the rosins and derivatives thereof, the fatty acids and derivatives thereof and the wax into a mixer, discharging the mixture after stirring the mixture at 60-80 DEG C for 15-30min and obtaining the solid adhesive for precision machining after cooling. The adhesive has good melt fluidity and high adhesive strength, is suitable for precision machining of fine parts and can be removed by being soaked in hot alkaline water with concentration of 3% by mass at 70-80 DEG C for 5-30min. The adhesive fully meets the requirements for the adhesive for precision machining, including fast sizing and high adhesive strength, and utilizes the environment-friendly cleaning method.
Description
Technical field
The invention belongs to adhesive area, relate to a kind of precision sizing and stick with glue agent and environmental protection purging method thereof, particularly a kind of tackiness agent and environmental protection purging method thereof that mainly in precision sizing such as cutting, correct grinding or polishing, is used for fixing electronic component or optical precision component.
Background technology
Precision component, for example contact lens and camera eyeglass etc., in the courses of processing such as cutting, correct grinding or polishing, usually need processed element or blank are fixed on the mechanical workout instrument, the general mechanical clamp that carries on the processing instrument that adopts carries out mechanical fixation to element or blank.Yet, because general precision component volume is less, course of processing complexity is meticulous, accuracy requirement to processed precision component finished product is also very high, mechanical clamp to element or blank fixedly the time owing to might cause unbalance stress or elasticity improper etc., can cause in the course of processing physical disturbance of element or blank is influenced the processing and the result of use of finished part.Therefore use tackiness agent that processed original paper or blank are fixed in and become the approach that addresses this problem on the mechanical workout instrument.The drawback of tradition tackiness agent be thermally melting relatively poor cause being bonded in after the completion of processing on part or the processing instrument be difficult for removing, remove after perhaps needing organic solvent to clean repeatedly, might cause corrosion and destruction to finished part, processing instrument or environment.
Summary of the invention
In order to solve the shortcoming and defect that above-mentioned prior art exists, primary and foremost purpose of the present invention is to provide a kind of precision sizing to stick with glue agent.
Another object of the present invention is to provide above-mentioned precision sizing to stick with glue the preparation method of agent.
The environmental protection purging method that provides above-mentioned precision sizing to stick with glue agent is provided a further object of the present invention.
Purpose of the present invention is achieved through the following technical solutions: a kind of precision sizing sticks with glue agent, and this tackiness agent is formed by the following feedstock production of meter by weight:
50～65 parts in rosin and derivative thereof
10～20 parts in lipid acid and derivative thereof
10～30 parts in wax.
Described rosin and derivative thereof are more than one in the modified product of modified product, polymerized rosin and polymerized rosin of modified product, staybelite, staybelite of rosin, rosiny modified product, nilox resin, nilox resin.
Described rosiny modified product is preferably methyl esters of rosin, rosin ethyl ester, ester gum or pentalyn, is more preferably ester gum or pentalyn; The modified product of described nilox resin is preferably nilox resin methyl esters, nilox resin ethyl ester, nilox resin glyceryl ester or nilox resin pentaerythritol ester, is more preferably nilox resin glyceryl ester or nilox resin pentaerythritol ester; The modified product of the modified product of described staybelite is preferably hercolyn D, staybelite ethyl ester, hydrogenated rosin glyceride or staybelite pentaerythritol ester, is more preferably hydrogenated rosin glyceride or staybelite pentaerythritol ester; The modified product of described polymerized rosin is polymerized rosin methyl esters, polymerized rosin ethyl ester, polymerized rosin glyceryl ester or polymerized rosin pentaerythritol ester, is more preferably polymerized rosin glyceryl ester or polymerized rosin pentaerythritol ester.
Described lipid acid and derivative thereof are more than one in modified product, lauric acid and the lauric modified product of stearic acid, stearic modified product, palmitinic acid, palmitinic acid.
Described stearic modified product is preferably Zerol, the two stearates of glycerine or tristearin, is more preferably Zerol; The modified product of described palmitinic acid is glycerine monopalmitate, glycerine acid dipalmitate or glycerol tripalmitate, is more preferably the glycerine monopalmitate; Described lauric modified product is glyceryl monolaurate, glycerine bilaurate or trilaurin, is more preferably glyceryl monolaurate.
Described wax is more than one in petroleum wax, beeswax, palm wax and the haze tallow.
Above-mentioned a kind of precision sizing sticks with glue the preparation method of agent, comprise following operation steps: rosin and derivative, lipid acid and derivative thereof and wax are placed mixing tank, 60～80 ℃ of stirring dischargings after 15～30 minutes down, obtain solid-state precision sizing after the cooling and stick with glue agent.
Above-mentioned a kind of precision sizing sticks with glue the environmental protection purging method of agent, and by following operation steps: it is that thermokalite water logging bubble 5～30min of 3% cleans removal with 70～80 ℃ mass percent concentration that precision sizing is sticked with glue agent.
The relative prior art of the present invention has following advantage and beneficial effect:
Tackiness agent of the present invention time below 0～50 ℃ be solid-state and bond effect good; Can be molten into mobile and wettability better fluid in time more than 50～80 ℃, has very strong bounding force after the cooling, can under the high loading working conditions, provide stable operation, be fit to the precision sizing of meticulous parts, and can be dissolved in 70～80 ℃ the thermokalite water (mass percent concentration 3%).This tackiness agent can be filled the gap between workpiece and the dowel disc rapidly under molten state; Behind adhesive solidification, workpiece and dowel disc bond together, and become as a whole, so just workpiece have been played fixed action; In the course of processing, tackiness agent has stronger bounding force, can provide stable operation for high loading processing; After the completion of processing, the tackiness agent between workpiece and dowel disc is easily removed.Therefore satisfying precision sizing fully sticks with glue the agent requirement--and applying glue speed is fast, bonding strength is high, and uses the environmental protection purging method.
Embodiment
The present invention is described in further detail below in conjunction with embodiment, but embodiments of the present invention are not limited thereto.
Embodiment 1:
20 parts of staybelites, 30 parts of nilox resin pentaerythritol esters, 5 parts of stearic acid, 10 parts of laurins, 5 parts of beeswaxs, 10 parts of petroleum waxes are placed mixing tank, stir down at 70 ℃, stir discharging after 20 minutes, can get the water-soluble precision sizing of solid state heat after the cooling and stick with glue agent.
Gained tackiness agent fusing point is 44～46 ℃, and cohesive strength is 0.42MPa, and available 80 ℃ of thermokalite water (mass percent concentration 3%) soak 10min and remove.
Embodiment 2:
20 parts of ester gums, 35 parts of staybelites, 5 parts of lauric acid, 5 parts of hard ester acid, 10 parts of haze tallows, 5 parts of petroleum waxes are placed mixing tank, stir down, stir discharging after 20 minutes, can get the water-soluble precision sizing of solid state heat after the cooling and stick with glue agent at 70 ℃.
Gained tackiness agent fusing point is 46～48 ℃, and cohesive strength is 0.40MPa, and available 70 ℃ of thermokalite water (concentration 3%) soak 15min and remove.
Embodiment 3:
25 parts of rosin, 35 parts of staybelite pentaerythritol esters, 10 parts of lauric acid, 10 parts of palmitins, 15 parts of palm waxs, 15 parts of petroleum waxes are placed mixing tank, stir down at 70 ℃, stir discharging after 20 minutes, can get the water-soluble precision sizing of solid state heat after the cooling and stick with glue agent.
Gained tackiness agent fusing point is 44～47 ℃, and cohesive strength is 0.43MPa, and available 80 ℃ of thermokalite water (concentration 3%) soak to be removed.
Embodiment 4:
20 parts of methyl esters of rosin, 45 parts of staybelites, 20 parts of nilox resin glyceryl ester, 5 parts of Zerols, 10 parts of laurins, 5 parts of beeswaxs, 5 parts of petroleum waxes are placed mixing tank, stir down at 60 ℃, stir discharging after 15 minutes, can get the water-soluble precision sizing of solid state heat after the cooling and stick with glue agent.
Gained tackiness agent fusing point is 44～46 ℃, and cohesive strength is 0.41MPa, and available 80 ℃ of thermokalite water (mass percent concentration 3%) soak 5min and remove.
Embodiment 5:
40 parts of hydrogenated rosin glycerides, 25 parts of polymerized rosin pentaerythritol esters, 8 parts of glycerine monopalmitates, 10 parts of glyceryl monolaurate esters, 5 parts of palm waxs, 10 parts of petroleum waxes are placed mixing tank, stir down at 80 ℃, stir discharging after 30 minutes, can get the water-soluble precision sizing of solid state heat after the cooling and stick with glue agent.
Gained tackiness agent fusing point is 45～46 ℃, and cohesive strength is 0.42MPa, and available 80 ℃ of thermokalite water (mass percent concentration 3%) soak 30min and remove.
Embodiment 6:
30 parts of polymerized rosin glyceryl ester, 35 parts of nilox resin pentaerythritol esters, 5 parts of glycerine monopalmitates, 10 parts of laurins, 2 parts of haze tallows, 10 parts of petroleum waxes are placed mixing tank, stir down at 65 ℃, stir discharging after 18 minutes, can get the water-soluble precision sizing of solid state heat after the cooling and stick with glue agent.
Gained tackiness agent fusing point is 45～47 ℃, and cohesive strength is 0.43MPa, and available 75 ℃ of thermokalite water (mass percent concentration 3%) soak 25min and remove.
Embodiment 7:
30 parts of rosin ethyl esters, 25 parts of nilox resin pentaerythritol esters, 20 parts of pentalyns, 5 parts of stearic acid, 5 parts of glycerine monopalmitates, 5 parts of glycerine bilaurates, 15 parts of palm waxs, 10 parts of haze tallows are placed mixing tank, stir down at 75 ℃, stir discharging after 25 minutes, can get the water-soluble precision sizing of solid state heat after the cooling and stick with glue agent.
Gained tackiness agent fusing point is 44～46 ℃, and cohesive strength is 0.42MPa, and available 80 ℃ of thermokalite water (mass percent concentration 3%) soak 18min and remove.
Embodiment 8:
20 parts of staybelites, 30 parts of nilox resin ethyl esters, 15 parts of nilox resin pentaerythritol esters, 15 parts, 5 parts stearic acid, 10 parts of laurins, 5 parts of beeswaxs, 10 parts of petroleum waxes are placed mixing tank, stir down at 70 ℃, stir discharging after 20 minutes, can get the water-soluble precision sizing of solid state heat after the cooling and stick with glue agent.
Gained tackiness agent fusing point is 44～47 ℃, and cohesive strength is 0.43MPa, and available 75 ℃ of thermokalite water (mass percent concentration 3%) soak 10min and remove.
Embodiment 9:
15 parts of polymerized rosin ethyl esters, 50 parts of nilox resin pentaerythritol esters, 5 parts of glycerol tripalmitate, 5 parts of laurins, 5 parts of trilaurins, 5 parts of beeswaxs, 10 parts of petroleum waxes are placed mixing tank, stir down at 80 ℃, stir discharging after 30 minutes, can get the water-soluble precision sizing of solid state heat after the cooling and stick with glue agent.
Gained tackiness agent fusing point is 44～46 ℃, and cohesive strength is 0.41MPa, and available 80 ℃ of thermokalite water (mass percent concentration 3%) soak 8min and remove.
Embodiment 10:
10 parts of nilox resin ethyl esters, 40 parts of nilox resin methyl esters, 25 parts of nilox resin pentaerythritol esters, 5 parts of stearic acid, 9 parts of laurins, 5 parts of beeswaxs, 5 parts of petroleum waxes and 5 parts of haze tallows are placed mixing tank, stir down at 60 ℃, stir discharging after 15 minutes, can get the water-soluble precision sizing of solid state heat after the cooling and stick with glue agent.
Gained tackiness agent fusing point is 44～45 ℃, and cohesive strength is 0.42MPa, and available 80 ℃ of thermokalite water (mass percent concentration 3%) soak 15min and remove.
The foregoing description is a preferred implementation of the present invention; but embodiments of the present invention are not restricted to the described embodiments; other any do not deviate from change, the modification done under spirit of the present invention and the principle, substitutes, combination, simplify; all should be the substitute mode of equivalence, be included within protection scope of the present invention.
Claims (10)
1. a precision sizing sticks with glue agent, it is characterized in that: this tackiness agent is formed by the following feedstock production of meter by weight:
50～65 parts in rosin and derivative thereof
10～20 parts in lipid acid and derivative thereof
10～30 parts in wax.
2. a kind of precision sizing according to claim 1 sticks with glue agent, it is characterized in that: described rosin and derivative thereof are more than one in the modified product of modified product, polymerized rosin and polymerized rosin of modified product, staybelite, staybelite of rosin, rosiny modified product, nilox resin, nilox resin.
3. a kind of precision sizing according to claim 2 sticks with glue agent, it is characterized in that: described rosiny modified product is methyl esters of rosin, rosin ethyl ester, ester gum or pentalyn; The modified product of described nilox resin is nilox resin methyl esters, nilox resin ethyl ester, nilox resin glyceryl ester or nilox resin pentaerythritol ester; The modified product of described staybelite is hercolyn D, staybelite ethyl ester, hydrogenated rosin glyceride or staybelite pentaerythritol ester; The modified product of described polymerized rosin is polymerized rosin methyl esters, polymerized rosin ethyl ester, polymerized rosin glyceryl ester or polymerized rosin pentaerythritol ester.
4. a kind of precision sizing according to claim 2 sticks with glue agent, it is characterized in that: described rosiny modified product is ester gum or pentalyn; The modified product of described nilox resin is nilox resin glyceryl ester or nilox resin pentaerythritol ester; The modified product of described staybelite is hydrogenated rosin glyceride or staybelite pentaerythritol ester; The modified product of described polymerized rosin is polymerized rosin glyceryl ester or polymerized rosin pentaerythritol ester.
5. a kind of precision sizing according to claim 1 sticks with glue agent, it is characterized in that: described lipid acid and derivative thereof are more than one in modified product, lauric acid and the lauric modified product of stearic acid, stearic modified product, palmitinic acid, palmitinic acid.
6. a kind of precision sizing according to claim 5 sticks with glue agent, it is characterized in that: described stearic modified product is the two stearates of Zerol, glycerine, tristearin; The modified product of described palmitinic acid is glycerine monopalmitate, glycerine acid dipalmitate or glycerol tripalmitate; Described lauric modified product is glyceryl monolaurate, glycerine bilaurate or trilaurin.
7. a kind of precision sizing according to claim 5 sticks with glue agent, it is characterized in that: described stearic modified product is a Zerol; The modified product of described palmitinic acid is the glycerine monopalmitate; Described lauric modified product is the glyceryl monolaurate ester.
8. a kind of precision sizing according to claim 1 sticks with glue agent, it is characterized in that: described wax is more than one in petroleum wax, beeswax, palm wax and the haze tallow.
9. a kind of precision sizing according to claim 1 sticks with glue the preparation method of agent, it is characterized in that comprising following operation steps: rosin and derivative, lipid acid and derivative thereof and wax are placed mixing tank, 60～80 ℃ of stirring dischargings after 15～30 minutes down, obtain solid-state precision sizing after the cooling and stick with glue agent.
10. a kind of precision sizing according to claim 1 sticks with glue the environmental protection purging method of agent, it is characterized in that by following operation steps: it is that thermokalite water logging bubble 5～30min of 3% cleans removal with 70～80 ℃ mass percent concentration that precision sizing is sticked with glue agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010288119 CN101948671B (en) | 2010-09-17 | 2010-09-17 | Adhesive for precision machining and environment-friendly cleaning method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010288119 CN101948671B (en) | 2010-09-17 | 2010-09-17 | Adhesive for precision machining and environment-friendly cleaning method thereof |
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| CN101948671A true CN101948671A (en) | 2011-01-19 |
| CN101948671B CN101948671B (en) | 2012-05-30 |
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| CN 201010288119 Expired - Fee Related CN101948671B (en) | 2010-09-17 | 2010-09-17 | Adhesive for precision machining and environment-friendly cleaning method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103232833A (en) * | 2013-05-02 | 2013-08-07 | 衢州飞瑞特种陶瓷有限公司 | Formula of paraffin adhesive for bonding special ceramics and iron plate |
| CN104004494A (en) * | 2014-06-09 | 2014-08-27 | 成都泰美克晶体技术有限公司 | Quartz wafer and crystal lump adhesive for surface mounted device (SMD) and preparation technology thereof |
| CN106564998A (en) * | 2016-11-01 | 2017-04-19 | 安徽环嘉天再生资源有限公司 | Zero-discharge treatment process of recycled plastic high-concentration alkaline water |
| CN106833512A (en) * | 2015-12-04 | 2017-06-13 | 中国石油化工股份有限公司 | It is a kind of for silicon steel sheet process in bond containing Wax composition |
| CN106905920A (en) * | 2017-03-02 | 2017-06-30 | 成都新源汇博光电科技有限公司 | A kind of preparation method of optics bonded adhesives |
| CN113429932A (en) * | 2021-07-08 | 2021-09-24 | 浙江英赛德数码科技有限公司 | Adhesive, adhesive coating method and foam cover with adhesive |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103232833A (en) * | 2013-05-02 | 2013-08-07 | 衢州飞瑞特种陶瓷有限公司 | Formula of paraffin adhesive for bonding special ceramics and iron plate |
| CN103232833B (en) * | 2013-05-02 | 2016-06-29 | 衢州飞瑞特种陶瓷有限公司 | The Formula of paraffin adhesive that a kind of special cermacis is bonding with iron plate |
| CN104004494A (en) * | 2014-06-09 | 2014-08-27 | 成都泰美克晶体技术有限公司 | Quartz wafer and crystal lump adhesive for surface mounted device (SMD) and preparation technology thereof |
| CN106833512A (en) * | 2015-12-04 | 2017-06-13 | 中国石油化工股份有限公司 | It is a kind of for silicon steel sheet process in bond containing Wax composition |
| CN106833512B (en) * | 2015-12-04 | 2019-01-25 | 中国石油化工股份有限公司 | It is a kind of to contain Wax composition for what is bonded in silicon steel sheet processing |
| CN106564998A (en) * | 2016-11-01 | 2017-04-19 | 安徽环嘉天再生资源有限公司 | Zero-discharge treatment process of recycled plastic high-concentration alkaline water |
| CN106564998B (en) * | 2016-11-01 | 2019-05-14 | 安徽环嘉天一再生资源有限公司 | Regenerated plastics high concentration alkali water zero discharge treatment process |
| CN106905920A (en) * | 2017-03-02 | 2017-06-30 | 成都新源汇博光电科技有限公司 | A kind of preparation method of optics bonded adhesives |
| CN113429932A (en) * | 2021-07-08 | 2021-09-24 | 浙江英赛德数码科技有限公司 | Adhesive, adhesive coating method and foam cover with adhesive |
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