CN106564998B - Regenerated plastics high concentration alkali water zero discharge treatment process - Google Patents

Regenerated plastics high concentration alkali water zero discharge treatment process Download PDF

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Publication number
CN106564998B
CN106564998B CN201610934992.4A CN201610934992A CN106564998B CN 106564998 B CN106564998 B CN 106564998B CN 201610934992 A CN201610934992 A CN 201610934992A CN 106564998 B CN106564998 B CN 106564998B
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Prior art keywords
sludge
clear water
water
plastic grain
added
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CN201610934992.4A
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CN106564998A (en
Inventor
杨传荣
宋现涛
姜永俊
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ANHUI HUANJIA TIANYI REGENERATION RESOURCE CO LTD
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ANHUI HUANJIA TIANYI REGENERATION RESOURCE CO LTD
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5263Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using natural chemical compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5272Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using specific organic precipitants
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • C02F11/122Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering using filter presses
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/34Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
    • C02F2103/36Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
    • C02F2103/38Polymers

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The invention discloses a kind of regenerated plastics high concentration alkali water zero discharge treatment process, it is related to regenerated plastics processing technique field, by obtaining clear water using filter press filters pressing after the sedimentation separation of settling tank, and the sludge in sedimentation bottom of pond portion is overstock with clear water backwash, so that sludge pumps out.Sewage water treatment method of the present invention is suitable for the processing of recycled plastic granules cleaning sullage, easy to operate, by the way that obtained clear water is re-used for down batch particle cleaning after separation suspension plastic grain and sludge, to save cleaning water consumption;And by the use of agglomerator, the rate of recovery of suspension plastic grain is improved, while secondary pollution will not be caused to sewage;It is backwashed additionally by clear water, prevents from being difficult to pump out due to sludge is serious because depositing.

Description

Regenerated plastics high concentration alkali water zero discharge treatment process
Technical field:
The present invention relates to regenerated plastics processing technique fields, and in particular to regenerated plastics high concentration alkali water zero discharge handles work Skill.
Background technique:
Recycled plastic granules are belonged in this scope of plastic grain, and regenerated plastics are then exactly that recycling is used new The plastics that material or discarded plastics are produced by Luo bar machine, then a kind of granular plastics are cut by pelleter Grain.Due to containing dust and greasy dirt etc. in salvage material, it is therefore desirable to be cleaned to plastic grain.Common buck carries out clear It washes, but the sewage after cleaning, due to containing alkaline matter, environmental pollution is serious, therefore is unable to direct emission.And due to modeling Expect that particle cleaning hourly water consumption is larger, if will directly clean the sewage discharge of a plastic grain, it will increase cleaning With water cost.Current simplest sewage water treatment method be exactly the sludge for utilizing natural sedimentation, but being deposited in bottom be easy because It seriously overstocks and is difficult to pump out, Treatment of Sludge is given to increase difficulty.
Summary of the invention:
It is a kind of by being incited somebody to action after separation suspension plastic grain and sludge technical problem to be solved by the present invention lies in providing To clear water be re-used for down batch particle cleaning, save cleaning water consumption to play simultaneously and sewage neutral and alkali substance avoided to pollute The regenerated plastics high concentration alkali water zero discharge treatment process of environment.
The following technical solution is employed for the technical problems to be solved by the invention to realize:
A kind of regenerated plastics high concentration alkali water zero discharge treatment process, including following operating procedure:
(1) alkaline sewage after cleaning plastic grain is pumped into settling tank, and agglomerator is added, and is stood after being sufficiently stirred Layering, to form the three-decker of upper layer suspension plastic grain, middle layer clear water and lower layer's sludge, suspension plastic grain in upper layer is logical Filter screen is removed, and the related middle layer clear water of lower layer's sludge is discharged into sludge transporting pipeline by settling the mud mouth of bottom of pond portion;
(2) sludge water in sludge transporting pipeline is sent into filter press through sludge delivery pump, and the clear water after filters pressing flows into Clear water reserviors, sludge accumulation in filter press is to drawing off after a certain amount of;
(3) on the one hand in clear water reserviors clear water passes through clear water delivery pump and is pumped into clear water recovery channel to carry out down criticizing plastics On the other hand the cleaning of grain is pumped into sludge by clear water delivery pump and dilutes water pipeline, by the clear water import for settling bottom of pond portion It is pumped into settling tank to dilute the sludge for being difficult to pump out;
The agglomerator is made of the raw material of following parts by weight: 10 parts of microcrystalline cellulose, 3 parts of haloflex, hydrogenation 2 parts of rosin glycerides, 1 part of Brazil wax, 0.5 part of gelatin, 0.5 part of C5 Petropols, 0.5 part of lanonol, asbestos wool 0.5 Part, 0.3 part of petroleum coke micro mist, 0.3 part of double trifluoromethanesulfonimides, preparation method are as follows: add into hydrogenated rosin glyceride Enter Brazil wax and gelatin, after being sufficiently mixed under microwave frequency 2450MHz, power 700W microwave treatment 5min, add C5 Petropols and petroleum coke micro mist, continue microwave treatment 5min after mixing, and gained mixture is transferred to 0-5 DEG C of environment immediately Then haloflex and lanonol is added in middle sealing and standing 3h, and be heated to 120-130 DEG C of heat preservation mixing 10min, then certainly It so cools, microcrystalline cellulose, asbestos wool and double trifluoromethanesulfonimides, heat preservation is added after temperature is down to 70-80 DEG C 10min is mixed, gained mixture is placed in sealing and standing 3h in -5-0 DEG C of environment, powder finally is made using micronizer.
The dosage of the agglomerator is that every liter of cleaning sullage uses 0.05-0.1g.
By the way that agglomerator not soluble in water is added, is flocculating and is making the plastic grain to suspend aggregation agglomerating under suction-operated, In order to remove the lesser plastic grain of granularity by strainer;And agglomerator is removed together with plastic grain, to keep away Exempt from secondary pollution.
The gelatin passes through modification, processing method using preceding are as follows: 0.5 part of hydrogenated palm is added into 15 parts of gelatin Oil and 0.5 part of sulfurized lard, after being sufficiently mixed under microwave frequency 2450MHz, power 700W microwave treatment 5min, stand Then 0.5 part of silicone emulsion and 0.3 part of polyvinyl butyral is added, after mixing in microwave treatment 3min again after 30min Microwave treatment 5min again, gained mixture are placed in sealing and standing 3h in -5-0 DEG C of environment, are finally made using micronizer Powder.
It is hydrophobic while improving its absorption to suspension plastic grain to enhance its after above-mentioned modification for gelatin Property.
It is a further object to provide a kind of regenerated plastics high concentration alkali water zero discharge processing units, by settling Pond, sludge transporting pipeline, sludge delivery pump, filter press, clear water recovery channel, sludge dilution water pipeline and clear water convey pump group At the sedimentation bottom of pond portion is equipped with mud mouth and clear water import, and the upper layer suspension plastic grain in settling tank is carried out by strainer It removes, the related middle layer clear water of lower layer's sludge is discharged into sludge transporting pipeline by mud mouth, and is sent into filters pressing through sludge delivery pump In machine, the filters pressing motor spindle is equipped with clear water reserviors, and the clear water after filters pressing flows into clear water reserviors, the sludge accumulation in filter press to one It is drawn off after quantitative, on the one hand the clear water in clear water reserviors is pumped into clear water recovery channel to carry out down batch plastics by the clear water delivery pump On the other hand clear water is pumped into sludge dilution water pipeline, is pumped into settling tank by clear water import to dilute by the cleaning of particle It is difficult to the sludge pumped out.
Bottom side is transversely provided with spiral helicine stirring blade inside the settling tank.Stirring blade fits through sludge dilution and send The clear water rapid dilution sludge that waterpipe is sent into, to save the water consumption of dilution sludge.
The settling tank internal vertical is equipped with multiple mud rooms, the corresponding mud mouth of each mud room.Pass through multiple dirts The velocity of discharge of sludge water is accelerated in the setting of mud room and mud mouth, and sludge is prevented to be difficult to pump out because long-time is overstock.
The mud room is the structure that longitudinal section is in inverted trapezoidal.By the design of inverted trapezoidal, convenient for making by gravity Sludge is quickly discharged.
The arc-shaped structure of strainer, is fixed by the connecting rod in the shaft for being mounted on and rotation being driven by motor.Utilize electricity Machine band electric filter is rotated to remove upper layer suspension plastic grain automatically, reduces human input.
Valve is equipped on the sludge transporting pipeline, clear water recovery channel and sludge dilution water pipeline.
The beneficial effects of the present invention are: sewage water treatment method of the present invention is suitable for recycled plastic granules cleaning sullage Processing, it is easy to operate, by the way that obtained clear water is re-used for down batch particle cleaning after separation suspension plastic grain and sludge, with Save cleaning water consumption;And by the use of agglomerator, the rate of recovery of suspension plastic grain is improved, while sewage will not be made At secondary pollution;It is backwashed additionally by clear water, prevents from being difficult to pump out due to sludge is serious because depositing.
Detailed description of the invention:
Fig. 1 is apparatus of the present invention structure top view;
Fig. 2 is apparatus of the present invention structure rearview;
Wherein: 1- settling tank;2- sludge transporting pipeline;3- sludge delivery pump;4- filter press;5- clear water recovery channel;6- Sludge dilutes water pipeline;7- clear water delivery pump;8- mud mouth;9- clear water import;10- strainer;11- clear water reserviors;12- stirring slurry Leaf;13- mud room;14- connecting rod;15- motor;16- shaft;17- valve.
Specific embodiment:
In order to be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, tie below Conjunction is specifically illustrating and embodiment, and the present invention is further explained.
(1) alkaline sewage after cleaning plastic grain is pumped into settling tank 1, and agglomerator is added, and is sufficiently stirred rear quiet Layering is set, so that the three-decker of upper layer suspension plastic grain, middle layer clear water and lower layer's sludge is formed, upper layer suspension plastic grain It is removed by strainer 10, the related middle layer clear water of lower layer's sludge is discharged into sludge transporting pipeline 2 by the mud mouth 8 of sedimentation bottom of pond portion;
(2) sludge water in sludge transporting pipeline is sent into filter press 4 through sludge delivery pump 3, the clear water stream after filters pressing Enter clear water reserviors 11, the accumulation of sludge in filter press is to drawing off after a certain amount of;
(3) on the one hand in clear water reserviors clear water passes through clear water delivery pump 7 and is pumped into clear water recovery channel 5 to carry out down criticizing plastics The cleaning of particle, on the other hand by clear water delivery pump be pumped into sludge dilute water pipeline 6, by settle bottom of pond portion clear water into Mouth 9 is pumped into settling tank to dilute the sludge for being difficult to pump out.
Bottom side is transversely provided with spiral helicine stirring blade 12 inside settling tank, and settling tank internal vertical is equipped with multiple mud rooms 13, the corresponding mud mouth of each mud room, mud room is the structure that longitudinal section is in inverted trapezoidal.The arc-shaped structure of strainer, By connecting rod 14 be fixedly mounted on by motor 15 driving rotation shaft 16 on, sludge transporting pipeline, clear water recovery channel and It is equipped with valve 17 on sludge dilution water pipeline, as depicted in figs. 1 and 2.
Agglomerator is added into settling tank using the amount of 0.05g agglomerator according to every liter of cleaning sullage, upper layer is promoted to suspend Particle aggregation is agglomerating, in order to strainer removing.
Agglomerator the preparation method comprises the following steps: 1 part of Brazil wax and 0.5 part of gelatin are added into 2 parts of hydrogenated rosin glycerides, After being sufficiently mixed under microwave frequency 2450MHz, power 700W microwave treatment 5min, add 0.5 part of C5 Petropols and 0.3 Part petroleum coke micro mist, continues microwave treatment 5min after mixing, and gained mixture is transferred to sealing and standing in 0-5 DEG C of environment immediately Then 3 parts of haloflexes and 0.5 part of lanonol is added in 3h, and be heated to 120-130 DEG C of heat preservation mixing 10min, then nature It cools, 10 parts of microcrystalline celluloses, 0.5 part of asbestos wool and 0.3 part of double fluoroform sulphur is added after temperature is down to 70-80 DEG C Acid imide, heat preservation mixing 10min, gained mixture are placed in sealing and standing 3h in -5-0 DEG C of environment, finally utilize micronizer Powder is made.
The modification of gelatin: 0.5 part of hydrogenated palm oil and 0.5 part of sulfurized lard being added into 15 parts of gelatin, sufficiently mixed After conjunction under microwave frequency 2450MHz, power 700W microwave treatment 5min, stand microwave treatment 3min again after 30min, then 0.5 part of silicone emulsion and 0.3 part of polyvinyl butyral is added, after mixing microwave treatment 5min again, gained mixture It is placed in sealing and standing 3h in -5-0 DEG C of environment, powder finally is made using micronizer.
Processing result shows, after handling cleaning sullage using above-mentioned processing system, suspension plastic grain in sewage and outstanding The clearance rate of floating mud granule reaches 99% or more, and the clear water of acquisition can be re-used for down the cleaning of batch plastic grain.
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (3)

1. regenerated plastics high concentration alkali water zero discharge treatment process, which comprises the steps of:
(1) alkaline sewage after cleaning plastic grain is pumped into settling tank, and agglomerator is added, and is stood and is divided after being sufficiently stirred Layer, to form the three-decker of upper layer suspension plastic grain, middle layer clear water and lower layer's sludge, upper layer suspension plastic grain passes through Strainer is removed, and the related middle layer clear water of lower layer's sludge is discharged into sludge transporting pipeline by settling the mud mouth of bottom of pond portion;
(2) sludge water in sludge transporting pipeline is sent into filter press through sludge delivery pump, and the clear water after filters pressing flows into clear water Pond, sludge accumulation in filter press is to drawing off after a certain amount of;
(3) on the one hand in clear water reserviors clear water passes through clear water delivery pump and is pumped into clear water recovery channel to carry out down criticizing plastic grain On the other hand cleaning is pumped into sludge by clear water delivery pump and dilutes water pipeline, the clear water import by settling bottom of pond portion is pumped into To dilute the sludge for being difficult to pump out in settling tank;
The agglomerator is made of the raw material of following parts by weight: 10 parts of microcrystalline cellulose, 3 parts of haloflex, hydrogenated rosin 2 parts of glyceride, 1 part of Brazil wax, 0.5 part of gelatin, 0.5 part of C5 Petropols, 0.5 part of lanonol, 0.5 part of asbestos wool, stone 0.3 part of oil coke micro mist, 0.3 part of double trifluoromethanesulfonimides, preparation method are as follows: Brazil is added into hydrogenated rosin glyceride Palm wax and gelatin, after being sufficiently mixed under microwave frequency 2450MHz, power 700W microwave treatment 5min, add C5 petroleum Resin and petroleum coke micro mist, continue microwave treatment 5min after mixing, and gained mixture is transferred in 0-5 DEG C of environment immediately and seals 3h is stood, haloflex and lanonol is then added, and is heated to 120-130 DEG C of heat preservation mixing 10min, subsequent natural cooling Microcrystalline cellulose, asbestos wool and double trifluoromethanesulfonimides, heat preservation mixing is added in cooling after temperature is down to 70-80 DEG C 10min, gained mixture are placed in sealing and standing 3h in -5-0 DEG C of environment, powder finally are made using micronizer.
2. regenerated plastics high concentration alkali water zero discharge treatment process according to claim 1, it is characterised in that: the reunion The dosage of agent is that the alkaline sewage after every liter of plastic grain cleaning uses 0.05-0.1g.
3. regenerated plastics high concentration alkali water zero discharge treatment process according to claim 1, it is characterised in that: the gelatin Pass through modification, processing method using preceding are as follows: 0.5 part of hydrogenated palm oil and 0.5 part of vulcanization pig are added into 15 parts of gelatin Oil, after being sufficiently mixed under microwave frequency 2450MHz, power 700W microwave treatment 5min, stand microwave treatment again after 30min Then 0.5 part of silicone emulsion and 0.3 part of polyvinyl butyral is added in 3min, after mixing microwave treatment 5min again, institute It obtains mixture and is placed in sealing and standing 3h in -5-0 DEG C of environment, powder finally is made using micronizer.
CN201610934992.4A 2016-11-01 2016-11-01 Regenerated plastics high concentration alkali water zero discharge treatment process Active CN106564998B (en)

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CN106564998B true CN106564998B (en) 2019-05-14

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101948671A (en) * 2010-09-17 2011-01-19 中科院广州化学有限公司 Adhesive for precision machining and environment-friendly cleaning method thereof
CN201769295U (en) * 2010-07-07 2011-03-23 甘肃大禹节水股份有限公司 Waste plastic water floating device
CN105290312A (en) * 2015-10-21 2016-02-03 和县科嘉阀门铸造有限公司 Foamed plastic binder for lost foam casting of valve
CN105368383A (en) * 2015-10-21 2016-03-02 安徽埃斯克制泵有限公司 Foamed plastic binder for centrifugal pump lost foam casting

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201769295U (en) * 2010-07-07 2011-03-23 甘肃大禹节水股份有限公司 Waste plastic water floating device
CN101948671A (en) * 2010-09-17 2011-01-19 中科院广州化学有限公司 Adhesive for precision machining and environment-friendly cleaning method thereof
CN105290312A (en) * 2015-10-21 2016-02-03 和县科嘉阀门铸造有限公司 Foamed plastic binder for lost foam casting of valve
CN105368383A (en) * 2015-10-21 2016-03-02 安徽埃斯克制泵有限公司 Foamed plastic binder for centrifugal pump lost foam casting

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Denomination of invention: Zero-discharge treatment process of recycled plastic high-concentration alkaline water

Effective date of registration: 20191225

Granted publication date: 20190514

Pledgee: The development of small and medium-sized enterprises financing Company Limited by Guarantee Jieshou City

Pledgor: Anhui Huanjia Tianyi Regeneration Resource Co.,Ltd.

Registration number: Y2019980001282