CN101945897B - 具有双齿内部供体的自限制催化剂组合物 - Google Patents

具有双齿内部供体的自限制催化剂组合物 Download PDF

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Publication number
CN101945897B
CN101945897B CN200880127351.1A CN200880127351A CN101945897B CN 101945897 B CN101945897 B CN 101945897B CN 200880127351 A CN200880127351 A CN 200880127351A CN 101945897 B CN101945897 B CN 101945897B
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Prior art keywords
catalyst composition
agent
catalyst
electron donor
external electron
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Chinese (zh)
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CN101945897A (zh
Inventor
陈林枫
小理查德·E·坎贝尔
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WR Grace and Co
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Dow Global Technologies LLC
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Priority to CN201410344155.7A priority Critical patent/CN104193857B/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN200880127351.1A 2007-12-21 2008-12-12 具有双齿内部供体的自限制催化剂组合物 Active CN101945897B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410344155.7A CN104193857B (zh) 2007-12-21 2008-12-12 具有双齿内部供体的自限制催化剂组合物

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US1597807P 2007-12-21 2007-12-21
US61/015,978 2007-12-21
PCT/US2008/086551 WO2009085649A1 (en) 2007-12-21 2008-12-12 Self-limiting catalyst composition with bidentate internal donor

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201410344155.7A Division CN104193857B (zh) 2007-12-21 2008-12-12 具有双齿内部供体的自限制催化剂组合物

Publications (2)

Publication Number Publication Date
CN101945897A CN101945897A (zh) 2011-01-12
CN101945897B true CN101945897B (zh) 2014-08-20

Family

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Family Applications (2)

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CN200880127351.1A Active CN101945897B (zh) 2007-12-21 2008-12-12 具有双齿内部供体的自限制催化剂组合物
CN201410344155.7A Expired - Fee Related CN104193857B (zh) 2007-12-21 2008-12-12 具有双齿内部供体的自限制催化剂组合物

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Country Status (10)

Country Link
US (1) US20100273641A1 (enExample)
EP (1) EP2225288B1 (enExample)
JP (1) JP5740159B2 (enExample)
KR (2) KR101716507B1 (enExample)
CN (2) CN101945897B (enExample)
BR (1) BRPI0819539B1 (enExample)
MX (1) MX2010006895A (enExample)
PL (1) PL2225288T3 (enExample)
RU (1) RU2489447C2 (enExample)
WO (1) WO2009085649A1 (enExample)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102325808B (zh) 2008-12-31 2014-03-12 陶氏环球技术有限责任公司 包含取代的1,2-亚苯基芳族二酯内给体的前催化剂组合物及方法
US8507717B2 (en) * 2008-12-31 2013-08-13 Dow Global Technologies Llc Production of substituted phenylene aromatic diesters
BRPI1014019B1 (pt) * 2009-06-19 2019-10-22 Basell Poliolefine Italia Srl processo para a preparação de composições de polímeros de propileno resistentes ao impacto
KR101784537B1 (ko) 2009-12-02 2017-10-11 더블유.알. 그레이스 앤드 캄파니-콘. 폴리프로필렌 제조를 위한 촉매 중 내부 공여체로서 2개의 원자로 브릿지된 디카르보네이트 화합물
MY158466A (en) 2009-12-02 2016-10-14 Grace W R & Co Three and four atom bridged dicarbonate compounds as internal donors in catalysts for polypropylene manufacture
MY156361A (en) * 2009-12-21 2016-02-15 Grace W R & Co Gas-phase polymerization process having multiple flow regimes
US8835578B2 (en) * 2010-03-04 2014-09-16 Basell Poliolefine Italia S.R.L. Catalyst components for the polymerization of olefins
WO2011107371A1 (en) * 2010-03-04 2011-09-09 Basell Poliolefine Italia Srl Catalyst components for the polymerization of olefins
CN102234337B (zh) 2010-04-22 2013-08-14 中国石油化工股份有限公司 用于烯烃聚合反应的催化剂组分及其催化剂
CN102958953B (zh) * 2010-06-24 2015-08-05 巴塞尔聚烯烃意大利有限责任公司 用于烯烃聚合的催化剂体系
BR112013008900A2 (pt) * 2010-10-19 2016-06-28 Basell Poliolefine Srl "sistema da catalisação para a polimerização de olefinas"
BR112013008507A2 (pt) 2010-10-19 2017-10-31 Basell Poliolefine Italia Srl processo para a polimerização de olefinas
JP2014500384A (ja) * 2010-12-21 2014-01-09 ダウ グローバル テクノロジーズ エルエルシー アルコキシアルキルエステル内部電子供与体を有するプロ触媒組成物の製造方法および製品
US20120157295A1 (en) 2010-12-21 2012-06-21 Linfeng Chen Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product
EP2610274A1 (en) * 2011-12-30 2013-07-03 Borealis AG Propylene random copolymer
US9587041B2 (en) * 2012-09-24 2017-03-07 Indian Oil Corporation Limited Organometallic compound in solid form, process for preparing the same and use thereof
KR102060849B1 (ko) 2013-02-27 2019-12-30 도호 티타늄 가부시키가이샤 올레핀류 중합용 고체 촉매 성분의 제조 방법, 올레핀류 중합용 촉매 및 올레핀류 중합체의 제조 방법
US9790291B2 (en) * 2013-03-14 2017-10-17 Formosa Plastics Corporation, Usa Non-phthalate compounds as electron donors for polyolefin catalysts
CZ2013676A3 (cs) * 2013-09-03 2015-03-11 Polymer Institute Brno, Spol. S R. O. Polyolefinový prášek, způsob jeho výroby a použití
CN104558282B (zh) * 2013-10-18 2017-02-15 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其制备方法和用于烯烃聚合的催化剂与应用
US9714302B2 (en) * 2014-10-10 2017-07-25 W. R. Grace & Co.—Conn. Process for preparing spherical polymerization catalyst components for use in olefin polymerizations
KR101699590B1 (ko) * 2014-11-28 2017-01-24 한화토탈 주식회사 프로필렌 중합용 고체촉매 및 이를 이용한 폴리프로필렌 제조 방법
US10392453B2 (en) * 2015-01-30 2019-08-27 Toho Titanium Co., Ltd. Production method for olefin-polymerization catalyst and production method for olefin polymer
JPWO2016121551A1 (ja) * 2015-01-30 2017-11-09 東邦チタニウム株式会社 オレフィン類重合用固体触媒成分、オレフィン類重合触媒の製造方法およびオレフィン類重合体の製造方法
CA3038093A1 (en) 2016-10-06 2018-04-12 W.R. Grace & Co.-Conn. Procatalyst composition made with a combination of internal electron donors
EP3309183A1 (en) * 2016-10-14 2018-04-18 SABIC Global Technologies B.V. Polypropylene for use in bopp applications
US10124324B1 (en) * 2017-05-09 2018-11-13 Formosa Plastics Corporation, Usa Olefin polymerization catalyst components and process for the production of olefin polymers therewith
KR102287922B1 (ko) 2017-11-03 2021-08-06 롯데케미칼 주식회사 고밀도 폴리올레핀의 중합용 촉매 조성물의 제조방법
KR102287924B1 (ko) 2017-11-09 2021-08-06 롯데케미칼 주식회사 고밀도 폴리에틸렌 중합용 촉매의 제조방법
CN109517099B (zh) * 2018-11-27 2021-07-30 山东鲁晶化工科技有限公司 一种外给电子体、烯烃聚合催化剂体系及其应用
CN110003367B (zh) * 2019-04-26 2020-07-17 营口市向阳催化剂有限责任公司 一种具有双功能的外给电子体的齐格勒-纳塔催化剂及其应用
JP7539785B2 (ja) * 2020-03-31 2024-08-26 住友化学株式会社 オレフィン重合用固体触媒成分
US20230235102A1 (en) * 2020-06-26 2023-07-27 Reliance Industries Limited A ziegler-natta catalyst system and a process of polymerisation therefrom
CN118591567A (zh) 2022-01-27 2024-09-03 英尼奥斯欧洲股份公司 催化剂组合物
US20250154299A1 (en) 2022-02-09 2025-05-15 Ineos Europe Ag Catalyst component
CN120303311A (zh) 2022-12-09 2025-07-11 英尼奥斯欧洲股份公司 催化剂组分

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6399837B1 (en) * 1997-12-10 2002-06-04 Union Carbide Chemicals & Plastics Technology Corporation Electron donors
CN1681853A (zh) * 2002-09-16 2005-10-12 巴塞尔聚烯烃意大利有限公司 烯烃聚合用组分和催化剂
CN1240729C (zh) * 1999-04-15 2006-02-08 巴塞尔聚烯烃意大利有限公司 用于烯烃聚合的组分和催化剂

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5077357A (en) * 1990-10-22 1991-12-31 Shell Oil Company Olefin polymerization catalyst
US4866022A (en) 1984-03-23 1989-09-12 Amoco Corporation Olefin polymerization catalyst
IT1227260B (it) * 1988-09-30 1991-03-28 Himont Inc Dieteri utilizzabili nella preparazione di catalizzatori ziegler-natta
IT1227258B (it) * 1988-09-30 1991-03-28 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
DE3936856A1 (de) 1989-11-06 1991-05-08 Basf Ag Katalysatorsysteme vom typ der ziegler-natta-katalysatoren
US4983562A (en) 1989-11-17 1991-01-08 Union Carbide Chemicals And Plastics Company Inc. High activity catalyst system for the production of propylene polymers
US5432244A (en) 1990-12-12 1995-07-11 Union Carbide Chemicals & Plastics Technology Corporation Process for the production of polypropylene
US5218052A (en) 1991-02-04 1993-06-08 Amoco Corporation Olefin polymerization and copolymerization process
IT1252205B (it) * 1991-12-13 1995-06-05 Himont Inc Processo per la preparazione di poliolefine stabilizzate e prodotti cosi` ottenuti.
IT1262933B (it) 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Processo per la polimerizzazione in fase gas di alfa-olefine
CN1115988A (zh) 1993-09-16 1996-01-31 壳牌石油公司 聚合物的制备
US7049377B1 (en) * 1995-02-21 2006-05-23 Basell Poliolefine Italia S.R.L. 1,3-diethers and components and catalysts for the polymerization of olefins, containing said diethers
KR100218048B1 (ko) 1996-04-25 1999-09-01 유현식 α-올레핀 중합용 촉매 및 이를 이용하는 α-올레핀 중합방법
CN1115349C (zh) * 1998-04-03 2003-07-23 中国石油化工集团公司 一种制备稳定聚烯烃的方法
ES2267504T3 (es) * 1999-03-15 2007-03-16 Basell Poliolefine Italia S.R.L. Componentes y catalizadores para la polimerizacion de olefinas.
CN1137155C (zh) * 1999-12-06 2004-02-04 中国石油化工集团公司 用于烯烃聚合或共聚合的催化剂体系
FR2812642B1 (fr) * 2000-08-03 2003-08-01 Atofina Procede de preparation d'un support de catalyseur pour la poymerisation de l'ethylene et des alpha-olefines, le support ainsi obtenu et le catalyseur correspondant
US6825146B2 (en) * 2001-05-29 2004-11-30 Union Carbide Chemicals & Plastics Technology Corporation Olefin polymerization catalyst compositions and method of preparation
CN1169845C (zh) * 2002-02-07 2004-10-06 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用
US7220696B2 (en) 2002-04-04 2007-05-22 Mitsui Chemicals, Inc. Solid titanium catalyst component for olefin polymerization, catalyst for olefin polymerization, and process for olefin polymerization
US7202314B2 (en) 2002-09-16 2007-04-10 Basell Poliolefine Italia S.P.A. Components and catalysts for the polymerization of olefins
KR101114748B1 (ko) * 2003-09-23 2012-03-05 다우 글로벌 테크놀로지스 엘엘씨 자가 제한 촉매 조성물 및 프로필렌 중합 방법
RU2361885C2 (ru) * 2003-09-23 2009-07-20 Дау Глобал Текнолоджиз Инк. Каталитическая композиция, содержащая эфир монокарбоновой кислоты в качестве внутреннего донора, и способ полимеризации пропилена
RU2345094C2 (ru) * 2003-09-23 2009-01-27 Дау Глобал Текнолоджиз Инк. Композиция катализатора с самоограничением реакции, включающая внутренний донор в виде сложного эфира дикарбоновой кислоты, и способ полимеризации пропилена
US7351778B2 (en) * 2004-04-30 2008-04-01 China Petroleum & Chemical Corporation Catalyst component for olefin polymerization and catalyst comprising the same
JP4688135B2 (ja) * 2005-01-18 2011-05-25 東邦チタニウム株式会社 オレフィン類重合用固体触媒成分および触媒
TWI315318B (en) 2005-01-19 2009-10-01 Mitsui Chemicals Inc Process for producing olefin polymer and solid titanium catalyst component
US7491781B2 (en) 2005-03-08 2009-02-17 Ineos Usa Llc Propylene polymer catalyst donor component
BRPI0815246A2 (pt) 2007-08-24 2015-03-31 Dow Global Technologies Inc Composição de catalisador

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6399837B1 (en) * 1997-12-10 2002-06-04 Union Carbide Chemicals & Plastics Technology Corporation Electron donors
CN1240729C (zh) * 1999-04-15 2006-02-08 巴塞尔聚烯烃意大利有限公司 用于烯烃聚合的组分和催化剂
CN1681853A (zh) * 2002-09-16 2005-10-12 巴塞尔聚烯烃意大利有限公司 烯烃聚合用组分和催化剂

Also Published As

Publication number Publication date
CN101945897A (zh) 2011-01-12
KR101787927B1 (ko) 2017-10-18
JP5740159B2 (ja) 2015-06-24
CN104193857B (zh) 2017-05-24
KR20160049050A (ko) 2016-05-04
BRPI0819539B1 (pt) 2019-09-10
EP2225288A1 (en) 2010-09-08
RU2010130415A (ru) 2012-01-27
BRPI0819539A2 (pt) 2015-05-26
WO2009085649A1 (en) 2009-07-09
JP2011508013A (ja) 2011-03-10
US20100273641A1 (en) 2010-10-28
EP2225288B1 (en) 2018-08-29
KR101716507B1 (ko) 2017-03-14
MX2010006895A (es) 2010-09-30
PL2225288T3 (pl) 2019-01-31
KR20100105857A (ko) 2010-09-30
CN104193857A (zh) 2014-12-10
RU2489447C2 (ru) 2013-08-10

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