CN101921355B - 液态有机玻璃 - Google Patents
液态有机玻璃 Download PDFInfo
- Publication number
- CN101921355B CN101921355B CN2009100332877A CN200910033287A CN101921355B CN 101921355 B CN101921355 B CN 101921355B CN 2009100332877 A CN2009100332877 A CN 2009100332877A CN 200910033287 A CN200910033287 A CN 200910033287A CN 101921355 B CN101921355 B CN 101921355B
- Authority
- CN
- China
- Prior art keywords
- liquid
- organic glass
- liquid organic
- retort
- teb
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 25
- 239000011521 glass Substances 0.000 title claims abstract description 7
- 239000011347 resin Substances 0.000 claims abstract description 8
- 229920005989 resin Polymers 0.000 claims abstract description 8
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 7
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims abstract description 7
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000003960 organic solvent Substances 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 230000000379 polymerizing effect Effects 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 3
- 239000004902 Softening Agent Substances 0.000 claims description 2
- 239000012615 aggregate Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000243 solution Substances 0.000 claims 2
- 238000010438 heat treatment Methods 0.000 claims 1
- 238000002347 injection Methods 0.000 claims 1
- 239000007924 injection Substances 0.000 claims 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 229920000915 polyvinyl chloride Polymers 0.000 description 7
- 239000004800 polyvinyl chloride Substances 0.000 description 7
- 210000000795 conjunctiva Anatomy 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 210000004276 hyalin Anatomy 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 229920003217 poly(methylsilsesquioxane) Polymers 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
一种液态有机玻璃，把邻笨二甲酸二丁酯，环己酮，甲基丙烯酸甲酯按比例配成混合液态，加入过氧化二笨甲酰，让甲基丙烯酸甲酯在增塑剂和有机溶剂的混合液体里聚合成液态树脂。
Description
所属技术领域：
一种液态有机玻璃，具体指将有机玻璃单体-甲基丙烯酸甲酯聚合在特定的液体里，使之成为液态。
背景技术：
有一种聚氯乙烯-即PVC鞋材涂料，由于其特定的涂覆对象，受PVC树脂粉可溶度和PVC树脂粉非涂料树脂的制约，涂层结膜后的光泽度较差，手感也不好。因此，便需要有一种与PVC涂料和PVC基材相容性好、结膜光泽度高的材料来添加，以提高涂装效果。
发明内容：
本发明公开一种聚合液态有机玻璃的配方和方法，即把有机玻璃单体-甲基丙烯酸甲酯聚合在液体里，使之成为液态状的树脂膏，然后添加到PVC涂料，尤其是浸涂涂料里，改善涂料结膜后的光泽度和手感。
本发明所采用的技术方案是：把邻苯二甲酸二丁酯，环己酮，甲基丙烯酸甲酯按比例配成混合液态，加入过氧化二苯甲酰，让甲基丙烯酸甲酯在增塑剂和有机溶剂的混合液体里聚合成液态树脂。
本发明的有益效果是：将有机玻璃单体聚合成的液体树脂，作为增亮剂添加到PVC涂料里，可极大提高结膜后的光泽度和手感。
具体实施方式：
具体做法是：按重量百分比，取邻苯二甲酸二丁酯25％，环己酮40％，甲基丙烯酸甲酯35％投入到敞开式反应罐，水浴加温，开动搅拌机低速搅拌。取过氧化二苯甲酰0.5％溶解在环己酮里成聚合剂溶液，当罐内液体温度到60～70度时，开始滴加聚合剂溶液。
当罐内的单体开始聚合时，会有强烈的化学反应，其表现是：产生大量气泡，液态成沸腾状，产生大量热量。此时应停止加温并放空罐外热水，加速搅拌。如果反应过于强烈，还应暂停滴加聚合剂溶液，等反应稍缓再继续滴加，直到聚合剂溶液滴完，聚合反应结束为止即成液态有机玻璃树脂。
Claims (2)
1.一种液态有机玻璃，其特征是：按重量百分比，取邻苯二甲酸二丁酯25％，环己酮40％，甲基丙烯酸甲酯35％投入到敞开式反应罐，水浴加温，开动搅拌机低速搅拌；取过氧化二苯甲酰0.5％溶解在环己酮里成聚合剂溶液，当罐内液体温度到60～70度时，开始滴加聚合剂溶液，让甲基丙烯酸甲酯在增塑剂和有机溶剂的混合液体里聚合成液态树脂。
2.根据权利要求1所述的液态有机玻璃，其特征在于：所述的反应罐为敞开式水浴加温反应罐，并配有可变速搅拌机，传导温度的水可以根据需要排空或注入。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100332877A CN101921355B (zh) | 2009-06-17 | 2009-06-17 | 液态有机玻璃 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100332877A CN101921355B (zh) | 2009-06-17 | 2009-06-17 | 液态有机玻璃 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101921355A CN101921355A (zh) | 2010-12-22 |
| CN101921355B true CN101921355B (zh) | 2012-08-15 |
Family
ID=43336587
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009100332877A Active CN101921355B (zh) | 2009-06-17 | 2009-06-17 | 液态有机玻璃 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101921355B (zh) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103030915B (zh) * | 2012-12-05 | 2015-04-22 | 常州大学 | 一种增塑共聚改性有机玻璃的制备方法 |
| CN104262527B (zh) * | 2014-10-08 | 2016-01-27 | 天津儒创新材料科技有限公司 | 一种防辐射液态有机玻璃 |
| CN105821667A (zh) * | 2016-03-22 | 2016-08-03 | 李晨露 | 一种提高纺织品防电磁辐射的涂料及其制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB731634A (en) * | 1952-04-04 | 1955-06-08 | John Milton Proprietary Ltd | Improved plastic material and process of manufacture |
| CN1580170A (zh) * | 2003-08-01 | 2005-02-16 | 沈阳黎明航空发动机(集团)有限责任公司 | 制作粘带钎料用粘结剂 |
| CN101386662A (zh) * | 2008-10-23 | 2009-03-18 | 湖北大学 | 用于医疗x光机房门窗的低能辐射防护有机玻璃 |
-
2009
- 2009-06-17 CN CN2009100332877A patent/CN101921355B/zh active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB731634A (en) * | 1952-04-04 | 1955-06-08 | John Milton Proprietary Ltd | Improved plastic material and process of manufacture |
| CN1580170A (zh) * | 2003-08-01 | 2005-02-16 | 沈阳黎明航空发动机(集团)有限责任公司 | 制作粘带钎料用粘结剂 |
| CN101386662A (zh) * | 2008-10-23 | 2009-03-18 | 湖北大学 | 用于医疗x光机房门窗的低能辐射防护有机玻璃 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101921355A (zh) | 2010-12-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104073116B (zh) | 一种超双疏涂层的制备方法 | |
| CN101831230A (zh) | 反应性乳化剂制备聚丙烯酸酯/纳米SiO2复合涂饰剂的方法 | |
| CN105131866A (zh) | 一种铁皮面板复合贴面用水性胶粘剂及其制备方法 | |
| CN106752606B (zh) | 一种水性氟硅丙烯酸涂料及其制备方法 | |
| CN104761994A (zh) | 一种光固化有机硅改性环氧树脂漆膜的制备方法 | |
| CN101921355B (zh) | 液态有机玻璃 | |
| CN104892817B (zh) | 一种有机硅苯丙细乳液的制备方法 | |
| CN103965676A (zh) | 一种环氧粉末涂料专用反应型高活性流平剂及其制备方法和应用 | |
| CN105315400B (zh) | 一种硅氟改性丙烯酸酯乳液及其制备方法 | |
| CN106366985A (zh) | 水性封口胶胶黏剂乳液及其制备方法 | |
| CN104497332A (zh) | 一种离型膜及其制备方法 | |
| CN105255411A (zh) | 有机硅氧烷改性氯化聚丙烯胶粘剂的制备方法 | |
| CN103232566B (zh) | 密封胶用高固含量低粘度丙烯酸酯乳液的制备方法 | |
| CN107722882A (zh) | 一种丙烯酸酯乳液压敏胶及其制备方法 | |
| CN104530996A (zh) | 一种lcd离型膜及其制备方法 | |
| CN101186771B (zh) | 改性丙烯酸树脂涂饰剂的制备方法 | |
| CN104693371A (zh) | 一种新型水性双组份聚氨酯涂料用丙烯酸改性树脂 | |
| CN103665277A (zh) | 一种耐水建筑乳液的制备方法 | |
| CN102329573A (zh) | 一种不干胶生产配方及其制备方法 | |
| CN103755865B (zh) | 无皂聚合丙烯酸乳液及其制备方法 | |
| CN104592848A (zh) | 一种bopet离型膜及其制备方法 | |
| CN108794682A (zh) | 一种常温酮肼自交联丙烯酸树脂乳液及其制备方法和应用 | |
| CN102702446B (zh) | 水性油墨用低固含量酪素基乳液及其制备方法 | |
| CN104725554A (zh) | 一种高固含量氟改性丙烯酸酯阳离子树脂及其制备方法 | |
| CN104449018A (zh) | 有机涂料增光剂 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee | ||
| CP02 | Change in the address of a patent holder |
Address after: 362216, Fujian, Quanzhou, Jinjiang province Xintang Street sunny sunny area 79 Patentee after: Zhang Qinying Patentee after: Wang Wenting Address before: 210029, room 73, No. 19, exposed garden, Nanjing District, Jianye, Jiangsu province 303 Patentee before: Zhang Qinying Patentee before: Wang Wenting |
|
| ASS | Succession or assignment of patent right |
Owner name: QIDONG TIANFEN ELECTRIC TOOL TECHNOLOGY INNOVATION Free format text: FORMER OWNER: ZHANG QINYING Effective date: 20141120 Free format text: FORMER OWNER: WANG WENTING Effective date: 20141120 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 362216 QUANZHOU, FUJIAN PROVINCE TO: 226241 NANTONG, JIANGSU PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20141120 Address after: Qidong City, Jiangsu province 226241 Nantong lvsigang Tianfen electric tools trade city comprehensive building Patentee after: Qidong Tianfen Electric Tool Technology Innovation Center Address before: 362216, Fujian, Quanzhou, Jinjiang province Xintang Street sunny sunny area 79 Patentee before: Zhang Qinying Patentee before: Wang Wenting |