CN101899365B - Adhesive remover and preparation method thereof - Google Patents
Adhesive remover and preparation method thereof Download PDFInfo
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- CN101899365B CN101899365B CN2009100992519A CN200910099251A CN101899365B CN 101899365 B CN101899365 B CN 101899365B CN 2009100992519 A CN2009100992519 A CN 2009100992519A CN 200910099251 A CN200910099251 A CN 200910099251A CN 101899365 B CN101899365 B CN 101899365B
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Abstract
The invention relates to an adhesive remover and a preparation method thereof. The basic composition of the adhesive remover formula is as follows in percentage by weight: 12-25% of fatty alcohol-polyoxyethylene ether sodium sulfate and fatty alcohol-polyoxyethylene ether silane, 20-30% of alkylphenol polyoxyethylene ether, 4-5% of ethylene oxide/propane segmented copolymer, 5-7.9% of sodium chloride, 10-12% of triethyl phosphate and dimethyl adipate, 5-10% of tricarboxyl triethylamine, triethylamine, diethanol amine, EDTA, urea, triethanolamine and hexamethylene tetramine, 2-10% of ethylene glycol, butyl cellosolve, propylene glycol methyl ether, ethanol, isopropanol, benzyl alcohol and methyl isoamyl ketone and 0.1-42% of deionized water. Compared with the prior art, the invention has the advantages that the adhesive remover is aqueous and low irritating, is wide in application range, can rapidly remove various trade mark adhesives, eliminate adhesiveness, degrease, remove adhesive and deliquate adhering oil stain in the aspect of removing advertising posters on the surfaces of glass, ceramics, marbles, stainless steel, etc. The invention also provides an environment-friendly and safe method for preparing the adhesive remover.
Description
Technical field
The present invention relates to a kind of adhesive remover and preparation method thereof.
Background technology
Existing a kind of application number discloses prescription for the Chinese invention patent that the CN200710158081.8 name is called " a kind of degumming agent and remove the method for bottom glue at plastic surface "; Its prescription is by alcohol (Fatty Alcohol(C12-C14 and C12-C18); 30.0～50.0w%), acid (linear saturated fatty acids of C9～C16,0.5～3.0w%), fused agent (Fatty Alcohol(C12-C14 and C12-C18) and monoether thereof, 3.0～9.0w%), tensio-active agent (negatively charged ion and nonionic; 4.0～9.0w%), (JFC-2,0～2.0w%) forms with water permeate agent.Utilizing above-mentioned degumming agent to remove the method for bottom glue at plastic surface and non-setting adhesive, is that above-mentioned degumming agent is heated to 40～60 ℃, and plastics to be come unstuck are stirred 10min in above-mentioned degumming agent, itself and degumming agent is contacted fully reach best degumming effect.The degumming agent of this invention has the higher ability of coming unstuck, and is with low cost, nontoxic to not damage of frosting, do not have flammable, free from environmental pollution, safe and convenient to use.Its shortcoming is: only be applicable to that plastic sheet surface comes unstuck, to surfaces such as glass, pottery, marble, stainless steel remove posters, subsides of carving characters, adhesive tape glue, fit up surplus glue, self-adhesive pad pasting, cuticula cull, ink paint, resin grease, pitch, machine oil, chewing gum, exhibition room sign and floor dirt be difficult suitable.So its prescription awaits to improve.
Summary of the invention
The present invention to solve first technical problem be a kind of adhesive remover to be provided to above-mentioned prior art present situation; It can be used to remove non-setting adhesive, self adhesive foil, double faced adhesive tape, adhesive tape and the sticking thing primer that is coated with and be detained glue stain or the glue dirt that the back forms; Can remove various trade mark adhesives fast; Elimination viscosity, degreasing remove glue, release to separate and adhere to oil stain, have wide range of applications.
The present invention will to solve second technical problem be the making method that a kind of above-mentioned adhesive remover is provided to above-mentioned prior art present situation, and safety and environmental protection.
The present invention solves the technical scheme that above-mentioned first technical problem adopts: this adhesive remover is characterized in that: basic composition is of this adhesive remover prescription:
A, polyoxyethylenated alcohol sodium sulfate and AEO silane: 12-25%, the proportioning of polyoxyethylenated alcohol sodium sulfate and AEO silane is: 1: 2-3;
B, TX10: 20-30%;
C, oxyethane/propane segmented copolymer: 4-5%
D, sodium-chlor: 5-7.9%;
E, triethyl phosphate and hexanodioic acid dimethyl-fat: 10-12%, the proportioning of triethyl phosphate and hexanodioic acid dimethyl-fat is: 1: 0.9～1.1;
F, three carboxyl triethylamines, triethylamine, diethylolamine, EDTA, urea, trolamine and hexamethylenetetramine: 5-10%, the proportioning between them is followed successively by: 2: 10: 10: 2: 1: 1: 09～1.1;
G, ethylene glycol ethyl ether, butyl glycol ether, propylene glycol monomethyl ether, ethanol, Virahol, phenylcarbinol and methyl isoamyl ketone: 2-10%, the proportioning between them is followed successively by: 2: 3: 2: 5: 1: 2: 0.9～1.1;
H, deionized water: 0.1-42%;
Above-mentioned per-cent is weight percentage.
As improvement, in the adhesive remover prescription, also can add CTAB: 0.05-5%, this per-cent is weight percentage.
The present invention solves above-mentioned second technical scheme that technical problem adopted: the making method of above-mentioned adhesive remover is characterized in that: may further comprise the steps successively:
I, in reaction kettle, add the deionized water of regulation deal; Adding the sodium-chlor salt then dissolves; Add oxyethane/propane segmented copolymer, TX10, polyoxyethylenated alcohol sodium sulfate and AEO silane more while stirring; Churning time 5-10 minute, it is stirred;
II, add ethylene glycol ethyl ether, butyl glycol ether, propylene glycol monomethyl ether, ethanol, Virahol, phenylcarbinol, the methyl isoamyl ketone that proportioning is good in advance while stirring then; Churning time is 20-30 minute; Make the abundant wetting dissolving of pressed powder, the solid-liquid body mixes;
III, then be to feed steam while stirring, make mixed liquid be warming up to 60-80 ℃, react 25-35 minute, let the above-mentioned tensio-active agent equilibrium that has added;
IV, in temperature is 60-80 ℃ mixed liquid, add good triethyl phosphate of proportioning and hexanodioic acid dimethyl-fat while stirring again, it is fully dissolved, churning time is 5-10 minute, and it is stirred;
V, in temperature is 60-80 ℃ mixed liquid, add proportioning good three carboxyl triethylamines, triethylamine, diethylolamine, EDTA, urea, trolamine and hexamethylenetetramine while stirring then, churning time is 5-10 minute, and it is stirred;
VI, static froth breaking 8-10 hour, to glue be no bubble transparent liquid, the discharging can.
As improvement, between above-mentioned steps V and step VI, also can add while stirring: CTAB, and stir.
Improve, mixed liquid temp is 75 ℃ among the said step IV, slowly adds good triethyl phosphate of proportioning and hexanodioic acid dimethyl-fat equably while stirring, and it is fully dissolved again.
Improve again; The mixed liquid temp of said step V is 75 ℃; Slowly add proportioning good three carboxyl triethylamines, triethylamine, diethylolamine, EDTA, urea, trolamine and hexamethylenetetramine equably while stirring, churning time is 5-10 minute, and it is stirred.
Improve again; Tensio-active agent among the said Step II I is meant ethylene glycol ethyl ether, butyl glycol ether, propylene glycol monomethyl ether, ethanol, Virahol, phenylcarbinol, the methyl isoamyl ketone in the Step II; Described equilibrium is meant that these several kinds of tensio-active agents reach complementary.
Compared with prior art, the invention has the advantages that this adhesive remover is a kind of water-based low irritant adhesive remover, can add water by concentration and regulate to have the little characteristics of smell.Comprise that a certain proportion of AEO and multiple aqueous alcoholic and organic amine are separately or be composited; PH value is 7; Promptly be neutral, to most surfaces safety, effective especially to there not being hardened glue; Easy to use; Applied range is removed posters, subsides of carving characters, adhesive tape glue, is fitted up surplus glue, self-adhesive pad pasting, cuticula cull, ink paint, resin grease, pitch, machine oil, chewing gum, exhibition room sign and floor dirt on surfaces such as glass, pottery, marble, stainless steels, and removes non-setting adhesive, self adhesive foil, double faced adhesive tape, adhesive tape and sticking and be coated with the thing primer to be detained glue stain or glue that the back forms dirty; Can remove various trade mark adhesives fast, eliminate viscosity, degreasing and remove glue, release to separate and adhere to oil stain and can use.And the present invention also provides a kind of adhesive remover making method of Environmental Safety.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail, following per-cent is weight percentage.
Embodiment one
Basic composition is of its prescription of adhesive remover of present embodiment:
A, polyoxyethylenated alcohol sodium sulfate and AEO silane: 12%, the proportioning of polyoxyethylenated alcohol sodium sulfate and AEO silane is: 1: 2;
B, TX10: 20%;
C, oxyethane/propane segmented copolymer: 4%
D, sodium-chlor: 5%;
E, triethyl phosphate and hexanodioic acid dimethyl-fat: 10%, the proportioning of triethyl phosphate and hexanodioic acid dimethyl-fat is: 1: 1;
F, three carboxyl triethylamines, triethylamine, diethylolamine, EDTA, urea, trolamine and hexamethylenetetramine: 5%, the proportioning between them is followed successively by: 2: 10: 10: 2: 1: 1: 1;
G, ethylene glycol ethyl ether, butyl glycol ether, propylene glycol monomethyl ether, ethanol, Virahol, phenylcarbinol and methyl isoamyl ketone: 2%, the proportioning between them is followed successively by: 2: 3: 2: 5: 1: 2: 1;
H, deionized water: 42%.
The making method of above-mentioned adhesive remover may further comprise the steps successively:
I, in reaction kettle, add the deionized water of regulation deal; Adding the sodium-chlor salt then dissolves; Add oxyethane/propane segmented copolymer, TX10, polyoxyethylenated alcohol sodium sulfate and AEO silane more while stirring; Churning time 5 minutes stirs it;
II, add ethylene glycol ethyl ether, butyl glycol ether, propylene glycol monomethyl ether, ethanol, Virahol, phenylcarbinol, the methyl isoamyl ketone that proportioning is good in advance while stirring then; Churning time is 20 minutes; Make the abundant wetting dissolving of pressed powder, the solid-liquid body mixes;
III, then be to feed steam while stirring, make mixed liquid be warming up to 60 ℃, react 35 minutes, let the above-mentioned tensio-active agent equilibrium that has added;
IV, in temperature is 75 ℃ mixed liquid, add good triethyl phosphate of proportioning and hexanodioic acid dimethyl-fat while stirring again, it is fully dissolved, churning time is 5 minutes, and it is stirred;
V, in temperature is 75 ℃ mixed liquid, add proportioning good three carboxyl triethylamines, triethylamine, diethylolamine, EDTA, urea, trolamine and hexamethylenetetramine while stirring then, churning time is 6 minutes, and it is stirred;
VI, static froth breaking 8 hours, to glue be no bubble transparent liquid, the discharging can.
Tensio-active agent among the above-mentioned steps III is meant ethylene glycol ethyl ether, butyl glycol ether, propylene glycol monomethyl ether, ethanol, Virahol, phenylcarbinol, the methyl isoamyl ketone in the Step II, and described equilibrium is meant that these several kinds of tensio-active agents reach complementary.
Embodiment two
Basic composition is of its prescription of adhesive remover of present embodiment:
A, polyoxyethylenated alcohol sodium sulfate and AEO silane: 20%, the proportioning of polyoxyethylenated alcohol sodium sulfate and AEO silane is: 1: 2.5;
B, TX10: 25%;
C, oxyethane/propane segmented copolymer: 4%
D, sodium-chlor: 7.9%;
E, triethyl phosphate and hexanodioic acid dimethyl-fat: 11%, the proportioning of triethyl phosphate and hexanodioic acid dimethyl-fat is: 1: 1;
F, three carboxyl triethylamines, triethylamine, diethylolamine, EDTA, urea, trolamine and hexamethylenetetramine: 7%, the proportioning between them is followed successively by: 2: 10: 10: 2: 1: 1: 1;
G, ethylene glycol ethyl ether, butyl glycol ether, propylene glycol monomethyl ether, ethanol, Virahol, phenylcarbinol and methyl isoamyl ketone: 5%, the proportioning between them is followed successively by: 2: 3: 2: 5: 1: 2: 1;
H, deionized water: 19.1%;
And in the adhesive remover prescription, also can add CTAB: 1%.
The making method of above-mentioned adhesive remover may further comprise the steps successively:
I, in reaction kettle, add the deionized water of regulation deal; Adding the sodium-chlor salt then dissolves; Add oxyethane/propane segmented copolymer, TX10, polyoxyethylenated alcohol sodium sulfate and AEO silane more while stirring; Churning time 8 minutes stirs it;
II, add ethylene glycol ethyl ether, butyl glycol ether, propylene glycol monomethyl ether, ethanol, Virahol, phenylcarbinol, the methyl isoamyl ketone that proportioning is good in advance while stirring then; Churning time is 25 minutes; Make the abundant wetting dissolving of pressed powder, the solid-liquid body mixes;
III, then be to feed steam while stirring, make mixed liquid be warming up to 75 ℃, react 30 minutes, let the above-mentioned tensio-active agent equilibrium that has added;
IV, in temperature is 60 ℃ mixed liquid, slowly add good triethyl phosphate of proportioning and hexanodioic acid dimethyl-fat equably while stirring again, it is fully dissolved, churning time is 8 minutes, and it is stirred;
V, in temperature is 75 ℃ mixed liquid, slowly add proportioning good three carboxyl triethylamines, triethylamine, diethylolamine, EDTA, urea, trolamine and hexamethylenetetramine equably while stirring then, churning time is 8 minutes, and it is stirred; And add while stirring: CTAB stirs it.
VI, static froth breaking 9 hours, to glue be no bubble transparent liquid, the discharging can.
Embodiment three
Basic composition is of its prescription of adhesive remover of present embodiment:
A, polyoxyethylenated alcohol sodium sulfate and AEO silane: 15%, the proportioning of polyoxyethylenated alcohol sodium sulfate and AEO silane is: 1: 3;
B, TX10: 28%;
C, oxyethane/propane segmented copolymer: 5%
D, sodium-chlor: 6%;
E, triethyl phosphate and hexanodioic acid dimethyl-fat: 12%, the proportioning of triethyl phosphate and hexanodioic acid dimethyl-fat is: 1: 1;
F, three carboxyl triethylamines, triethylamine, diethylolamine, EDTA, urea, trolamine and hexamethylenetetramine: 6%, the proportioning between them is followed successively by: 2: 10: 10: 2: 1: 1: 1;
G, ethylene glycol ethyl ether, butyl glycol ether, propylene glycol monomethyl ether, ethanol, Virahol, phenylcarbinol and methyl isoamyl ketone: 8%, the proportioning between them is followed successively by: 2: 3: 2: 5: 1: 2: 1;
H, deionized water: 19.95%;
In the adhesive remover prescription, also can add CTAB: 0.05%.
The making method of above-mentioned adhesive remover may further comprise the steps successively:
I, in reaction kettle, add the deionized water of regulation deal; Adding the sodium-chlor salt then dissolves; Add oxyethane/propane segmented copolymer, TX10, polyoxyethylenated alcohol sodium sulfate and AEO silane more while stirring; Churning time 10 minutes stirs it;
II, add ethylene glycol ethyl ether, butyl glycol ether, propylene glycol monomethyl ether, ethanol, Virahol, phenylcarbinol, the methyl isoamyl ketone that proportioning is good in advance while stirring then; Churning time is 30 minutes; Make the abundant wetting dissolving of pressed powder, the solid-liquid body mixes;
III, then be to feed steam while stirring, make mixed liquid be warming up to 80 ℃, react 35 minutes, let the above-mentioned tensio-active agent equilibrium that has added;
IV, in temperature is 75 ℃ mixed liquid, slowly add good triethyl phosphate of proportioning and hexanodioic acid dimethyl-fat equably while stirring again, it is fully dissolved, churning time is 10 minutes, and it is stirred;
V, in temperature is 75 ℃ mixed liquid, slowly add proportioning good three carboxyl triethylamines, triethylamine, diethylolamine, EDTA, urea, trolamine and hexamethylenetetramine equably while stirring then, churning time is 10 minutes, and it is stirred; And add while stirring: CTAB stirs it.
VI, static froth breaking 10 hours, to glue be no bubble transparent liquid, the discharging can.
Below performance of the present invention is described further,
Water-based low irritant adhesive remover: a kind of glue removing composition agent, product adopt water-soluble system, can add water by concentration and regulate, and have the little characteristics of smell.Comprise that a certain proportion of AEO and multiple aqueous alcoholic and organic amine are separately or be composited.Product, mixes and stirs through batching through requiring operation with related process in proportion, thermal treatment, and sterilization and anticorrosion, operations such as discharging filling formation are processed, and in the plastics or vial of can safety and environmental protection, and join an applying glue mouth.
Product cooperates rationally, contains a large amount of electrolytical salts, destroys the charge balance of system, can be with a part of organism cohesion, and the disengaging aqueous systems of saltouing plays destruction, cleaning easily for the tackiness agent of some organic molecule materials.And a large amount of amine materials makes that the infiltration wetting ability of this agent is fine, could be that the residual glue that need remove softens fast, and is loosening, comes off, and some sulfonamide derivativess have sequestering action simultaneously! Simultaneously organic amine has weakly alkaline, and good deoiling effect is arranged, and for some unsaturated polyester jointing materials two good destructions is arranged.Can ensure that again there is corrosion inhibition the metallic surface in the time of for the tackiness agent of process metal surfaces.For some carbohydrates and some organic binder bonds the good effect of peeling off is arranged,
Adopted polyoxyethylenated alcohol sodium sulfate and AEO silane at last,, the reasonable combination of TX10; Be main raw; Being equipped with the tensio-active agent of appropriate H LB value. this component tensio-active agent, HLB value preferably contain two nitrogen-atoms 1～7.9 in the molecule; And two primary amine of methylate Ethylene Oxide, oxyethane containing of getting or the organic amine of secondary amine group in order, carbonatoms is no more than 22.In prescription, the scope of the weight ratio of tensio-active agent and basic amine component is generally at 1: 26～1: 12.Being product all possesses good avidity for aqueous binder and the property said tackiness agent, can form the O/W oil-in-water system fast, goes out adhesive material.Fatty alcohol polyethenoxy ether class product pungency is low simultaneously, is not easy to cause discomfort! Product possesses dual washing decontamination simultaneously.Material can be directly goed deep in this agent, removes various residual stains rapidly.
Also have product of the present invention,
One, product cooperation aspect has been considered, soaks, and system is destroyed, gel, and the infiltration parcel such as peels off at a series of residual modes of removing, and has adopted inorganic salt, organic amine, and the proportioning that combines of multifunctional meter surface-active agent.Flexibility than traditional is strong, and specific aim is wide, organic to present employing, and inorganic combination adhesive could both adapt to!
Two, the water-based system of product employing is more stable than the oiliness system of traditional most of clean-out systems, safety, environmental protection! But system has adopted the organic amine with corrosion inhibition, is again that some traditional water-based adhesive removers are not available.
Three, the salt component and the tensio-active agent component that adopt, organic amine replaces ammoniacal liquor, reduces the bad smell that causes because of the ammoniacal liquor volatilization, and smell all reaches low, does not have pungency! From result of use, environmental requirement, personal feeling, the several aspects of Environmental Safety all are superior to conventional traditional glue cleaning material that removes just!
Other character: pH value is 7, is neutral, and is to most surfaces safety, effective especially, easy-to-use to there not being hardened glue.
Function: be used to remove other sticking thing primer that is coated with such as non-setting adhesive, self adhesive foil, double faced adhesive tape, adhesive tape and be detained glue stain or the glue dirt that the back forms, remove various trade mark adhesives fast.Elimination viscosity, degreasing remove glue, release to separate and adhere to oil stain.
Accommodation: suit to remove posters, subsides of carving characters, adhesive tape glue, fit up surplus glue, self-adhesive pad pasting, cuticula cull, ink paint, resin grease, pitch, machine oil, chewing gum, exhibition room identifies and floor dirt etc. can use on surfaces such as glass, pottery, marble, stainless steels.
Method of use: load onto the applying glue mouth, stoste spray or drip and be coated onto the surface.Treat after the several minutes dissolving deliquescing or let the adhesive remover infiltration, start bonding coat with hand then, peel off unnecessary obedient paper, can be at label, many a little solution below mark or the adhesive tape.At last with clean wet cloth scrub.For some unusual aged jellies, wiping or available brush are scrubbed once more.And product appearance had no to be influenced it and belongs to volatile matter.After the product appearance processing, have no smell, be difficult for the injury surface.
Claims (6)
1. adhesive remover is characterized in that: basic composition is of this adhesive remover prescription:
A, polyoxyethylenated alcohol sodium sulfate and AEO silane: 12-25%, the proportioning of polyoxyethylenated alcohol sodium sulfate and AEO silane is: 1: 2-3;
B, TX10: 20-30%;
C, oxyethane/propane segmented copolymer: 4-5%
D, sodium-chlor: 5-7.9%;
E, triethyl phosphate and dimethyl adipate: 10-12%, the proportioning of triethyl phosphate and dimethyl adipate is: 1: 0.9～1.1;
F, three carboxyl triethylamines, triethylamine, diethylolamine, EDTA, urea, trolamine and hexamethylenetetramine: 5-10%, the proportioning between them is followed successively by: 2: 10: 10: 2: 1: 1: 0.9～1.1;
G, ethylene glycol ethyl ether, butyl glycol ether, propylene glycol monomethyl ether, ethanol, Virahol, phenylcarbinol and methyl isoamyl ketone: 2-10%, the proportioning between them is followed successively by: 2: 3: 2: 5: 1: 2: 0.9～1.1;
H, deionized water: 0.1-42%;
Above-mentioned per-cent is weight percentage.
2. require 1 described adhesive remover according to power, it is characterized in that: in the adhesive remover prescription, also can add CTAB: 0.05-5%, this per-cent is weight percentage, and each component concentration sum is 100%.
3. the making method of the adhesive remover of a claim 1 is characterized in that: may further comprise the steps successively:
I, in reaction kettle, add the deionized water of regulation deal; Adding the sodium-chlor salt then dissolves; Add oxyethane/propane segmented copolymer, TX10, polyoxyethylenated alcohol sodium sulfate and AEO silane more while stirring; Churning time 5-10 minute, it is stirred;
II, add ethylene glycol ethyl ether, butyl glycol ether, propylene glycol monomethyl ether, ethanol, Virahol, phenylcarbinol, the methyl isoamyl ketone that proportioning is good in advance while stirring then; Churning time is 20-30 minute; Make the abundant wetting dissolving of pressed powder, the solid-liquid body mixes;
III, then be to feed steam while stirring, make mixed liquid be warming up to 60-80 ℃, react 25-35 minute, let the above-mentioned tensio-active agent equilibrium that has added;
Tensio-active agent among the said Step II I is meant ethylene glycol ethyl ether, butyl glycol ether, propylene glycol monomethyl ether, ethanol, Virahol, phenylcarbinol, the methyl isoamyl ketone in the Step II, and described equilibrium is meant that these several kinds of tensio-active agents reach complementary;
IV, in temperature is 60-80 ℃ mixed liquid, add good triethyl phosphate of proportioning and dimethyl adipate while stirring again, it is fully dissolved, churning time is 5-10 minute, and it is stirred;
V, in temperature is 60-80 ℃ mixed liquid, add proportioning good three carboxyl triethylamines, triethylamine, diethylolamine, EDTA, urea, trolamine and hexamethylenetetramine while stirring then, churning time is 5-10 minute, and it is stirred;
VI, static froth breaking 8-10 hour, to glue be no bubble transparent liquid, the discharging can.
4. require 3 described making methods according to power, it is characterized in that: between above-mentioned steps V and step VI, also can add while stirring: CTAB, and stir.
5. require 3 or 4 described making methods according to power, it is characterized in that: mixed liquid temp is 75 ℃ among the said step IV, slowly adds good triethyl phosphate of proportioning and dimethyl adipate equably while stirring, and it is fully dissolved.
6. require 3 or 4 described making methods according to power; It is characterized in that: the mixed liquid temp of said step V is 75 ℃; Slowly add proportioning good three carboxyl triethylamines, triethylamine, diethylolamine, EDTA, urea, trolamine and hexamethylenetetramine while stirring equably; Churning time is 5-10 minute, and it is stirred.
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| CN2009100992519A CN101899365B (en) | 2009-05-27 | 2009-05-27 | Adhesive remover and preparation method thereof |
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| CN111167825A (en) * | 2019-10-18 | 2020-05-19 | 温州大学 | Recycling method of adhesive label facial tissue waste |
| CN110776872A (en) * | 2019-11-12 | 2020-02-11 | 佛山科学技术学院 | Dispergator |
| CN111851375A (en) * | 2020-07-30 | 2020-10-30 | 杨犄 | Road surface cleaning method for road and bridge construction |
Citations (1)
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|---|---|---|---|---|
| CN101186864A (en) * | 2007-11-09 | 2008-05-28 | 大连工业大学 | Degumming agent and method for removing bottom glue at plastic surface by using the same |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101186864A (en) * | 2007-11-09 | 2008-05-28 | 大连工业大学 | Degumming agent and method for removing bottom glue at plastic surface by using the same |
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