CN103849496A - Adhesive residue detergent of adhesive sticker and production process of adhesive residue detergent - Google Patents
Adhesive residue detergent of adhesive sticker and production process of adhesive residue detergent Download PDFInfo
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- CN103849496A CN103849496A CN201410103073.3A CN201410103073A CN103849496A CN 103849496 A CN103849496 A CN 103849496A CN 201410103073 A CN201410103073 A CN 201410103073A CN 103849496 A CN103849496 A CN 103849496A
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- setting adhesive
- removing residual
- residual glue
- glue stain
- adhesive removing
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Abstract
The invention discloses an adhesive residue detergent of an adhesive sticker and a production process of the adhesive residue detergent, and aims to provide the detergent which is environment-friendly, good in formula and simple in production process and can effectively eliminate adhesive residues of the adhesive sticker on various apparatuses as well as the production process of the detergent. The residual adhesive residue detergent of the adhesive sticker is technically characterized by being prepared from the following components in percentage by mass: 0.001-0.1% of gummy substance control enzyme, 50-90% of deionized water, 5-40% of sulphobetaine surfactant, 0.5-20% of cocamidopropyl dimethylamine oxide, 0.1-0.5% of preservative and 0.1-1% of essence, totaling 100%. The invention belongs to the technical field of detergents.
Description
Technical field
The present invention discloses a kind of sanitising agent and production technique thereof, specifically, is a kind of non-setting adhesive removing residual glue stain cleanser and production technique thereof, belongs to sanitising agent technical field.
Background technology
In our daily life, in work, often need to use scotch tape, double sticky tape, foam tape, non-setting adhesive cartoon paster, all things pastes, trade mark ... these non-setting adhesive goods are in bringing convenience to people, also some worries have been brought, steep and wipe not fall with glue residual after crossing, clip and where where bond to, more wipe more black, wiping is spent a sheet of ... with methyl alcohol, ethanol, benzene homologues, acetone, although turpentine wet goods organic solvent and the detergent product that contains organic solvent can be removed residual glue stain fast, but these organic solvents and the detergent product that contains organic solvent can produce problems, such as:
1, evaporate into immediately in air, after being sucked by people, can stimulate respiratory tract, even stimulate optic nerve, then cause healthy hidden danger.Particularly in family, office, automobile etc. to health requirements in enclosed environment higher and that often need to close the doors and windows.
2, directly contact can damage human body skin.
3, dissolve the paint of cleaned object surface, also can dissolve conventional plastic cement product surface, cleaned article are damaged.
4, easily to environment.
These problems have caused inconvenience to people's life, how to develop a kind of non-corrosiveness environmental friendliness, the toxic substances such as not leaded, arsenic, mercury, not containing methyl alcohol, ethanol, benzene homologues, acetone, turpentine wet goods organic solvent, do not hinder hand, do not hinder clothing, non-volatility peculiar smell, smell delicate fragrance, to human body skin, optic nerve, respiratory system nonirritant; Can not cause secondary to destroy to object material itself, lacquer painting; Major ingredient can be by Soil Microorganism natural degradation, can not cause environmental pollution, and tool decontamination, sterilization, press down mould, anti-static function, can effectively clean household electrical appliance, family property woodenware, glass-ceramic container, plastifying material, vehicle body lacquer painting, metal, leather surface because using the cleaning product of the residual non-setting adhesive glue stain such as scotch tape, double sticky tape, foam tape, cartoon paster, all things subsides, trade mark, become the focus of some hobby person researchs.
Summary of the invention
For above-mentioned deficiency, the object of the present invention is to provide a kind of environmental friendliness formula, can effectively remove the non-setting adhesive removing residual glue stain cleanser on various utensils, the present invention also provides the production technique of this sanitising agent.
For addressing the above problem, last technical scheme provided by the invention is such: this non-setting adhesive removing residual glue stain cleanser, component by following mass percent is made: stickies control enzyme 0.001%～0.1%, deionized water 50%～90%, sultaine type tensio-active agent 5%～40%, cocamidopropyl propyl amide amine oxide 0.5%～20%, sanitas 0.1%～0.5%, essence 0.1%～1%, component sum is 100%.
Above-mentioned non-setting adhesive removing residual glue stain cleanser, described stickies control enzyme is to be formed by esterase, lipase mixed preparing.
Further, above-mentioned non-setting adhesive removing residual glue stain cleanser, described stickies control enzyme is one of them of Bark graceful stickies control enzyme Optimyze525 or Optimyze530 or Optimyze540 series or French import stickies control enzyme SupfineZ160 or SupfineZ272 or imported from America biological enzyme stickies control agent AM-201.
Further, above-mentioned non-setting adhesive removing residual glue stain cleanser, described sultaine type tensio-active agent is one of them or arbitrary combination of dodecyl oxyethyl group sultaine or dodecyl hydroxypropyl sultaine or dodecyl azochlorosulfonate propyl lycine or myristamide propyl group hydroxypropyl sultaine or decyl hydroxypropyl sultaine.
Further, above-mentioned non-setting adhesive removing residual glue stain cleanser, described sanitas is isothiazolinone.
Further, above-mentioned non-setting adhesive removing residual glue stain cleanser, described essence is the conventional essence of washing composition.
After of the present invention, a technical scheme is to provide the production technique of this sanitising agent, and the production technique of this non-setting adhesive removing residual glue stain cleanser, comprises the steps: successively
1) take each component;
2) deionized water, sanitas and sultaine type tensio-active agent are added in agitation vat, stir at normal temperatures 20 minutes to being mixed to get mixed liquor A completely;
3) determination step 2) temperature of mixed solution, add essence in temperature during lower than 40 ℃, stir at normal temperatures 10 minutes to being mixed to get mixed liquid B completely;
4) mixed liquid B leaves standstill and tests pH value after 30 minutes, adds acid or alkali to adjust pH value to 5～12, carries out homogeneous stirring;
5) by stirrer adjustment of rotational speed to 800-1000 rev/min, add cocamidopropyl propyl amide amine oxide, disperse stir 15-20 minute;
6) by stirrer adjustment of rotational speed to 100-300 rev/min, add stickies control enzyme, disperse stir 15-20 minute;
7) canned after standing froth breaking.
Further, above-mentioned non-setting adhesive removing residual glue stain cleanser production technique, step 1) to the mixing speed described in step 4) is 1400 revs/min.
Further, above-mentioned non-setting adhesive removing residual glue stain cleanser production technique, the acid described in step 4) is hydrochloric acid, described alkali is sodium hydroxide.
Compared with prior art, technical scheme tool provided by the invention has the following advantages:
1, in technical scheme provided by the invention, adopt stickies control enzyme, the ester bond of gluing thing is ruptured, basal component loses/reduce stickiness, and be difficult to regroup in system.
2, in technical scheme provided by the invention, adopt sultaine type amphoterics as auxiliary agent, rapid osmotic is between cleaned object surface and removing residual glue stain, by continuing the effects such as infiltration, absorption, emulsification, solubilising, dispersion, the surface tension and the surface free energy that reduce gluing thing, make it to separate with body surface.Also possess good decontamination, sterilization simultaneously, press down mould, anti-static function.
3, in technical scheme provided by the invention, pass through to use the External Force Acting of the instrument wipings such as hairbrush, fabric (glasses wiping cloth (rags), shawl, scouring pad), help auxiliary agent rapid osmotic, absorption, emulsification, solubilising, dispersion, the surface tension and the surface free energy that reduce gluing thing, make it to separate, come off with cleaned object surface fast.
4, in technical scheme provided by the invention, auxiliary agent employing sultaine type amphoterics and cocamidopropyl propyl amide amphoterics are composite, produce more abundant, fine and smooth foam, in increasing sanitising agent specific surface area, can optimize coverage effect, reduce consumption, delay sanitising agent and stay, adhere to the time at the outstanding of cleaned object vertical surface, bright and clean inclined-plane, strengthen infiltration, absorption, emulsification, solubilising, dispersion effect.
5, technical scheme provided by the invention is non-corrosiveness environmental friendliness formula, the toxic substances such as not leaded, arsenic, mercury, not containing methyl alcohol, ethanol, benzene homologues, acetone, turpentine wet goods organic solvent, do not hinder hand, do not hinder clothing, non-volatility peculiar smell, smell delicate fragrance, to human body skin, optic nerve, respiratory system nonirritant; Can not cause secondary to destroy to object material itself, lacquer painting; Major ingredient can, by Soil Microorganism natural degradation, can not cause environmental pollution.
6, the auxiliary agent in technical scheme provided by the invention also has good decontamination, sterilization concurrently, presses down mould, anti-static function.Can effectively clean household electrical appliance, family property woodenware, glass-ceramic container, plastifying material, vehicle body lacquer painting, metal, leather surface because using the residual non-setting adhesive glue stain such as scotch tape, double sticky tape, foam tape, cartoon paster, all things subsides, trade mark.Be applicable in family, office, automobile etc. to health requirements higher and the enclosed environment that often need to close the doors and windows in.
Embodiment
Provide the specific embodiment of the present invention below, but claim protection domain of the present invention is not limited to this, the modification of anyone limited number of time making within the scope of the claims in the present invention, still within claim protection domain of the present invention.
Embodiment 1
A kind of non-setting adhesive removing residual glue stain cleanser provided by the invention, made by following component: the graceful stickies control enzyme of Bark Optimyze5250.001kg, deionized water 90kg, dodecyl azochlorosulfonate propyl lycine 7.999kg, cocamidopropyl propyl amide amine oxide 0.5kg, isothiazolinone 0.5kg, essence (described essence is the essence that washing composition is conventional, as green apple essence) 1kg.
Embodiment 2
Another kind of non-setting adhesive removing residual glue stain cleanser provided by the invention, made by following component: the graceful stickies control enzyme of Bark Optimyze5300.05kg, deionized water 73.7kg, sultaine type tensio-active agent 20kg, cocamidopropyl propyl amide amine oxide 5kg, isothiazolinone 0.25kg, green apple essence 1kg.
Embodiment 3
Another kind of non-setting adhesive removing residual glue stain cleanser provided by the invention, made by following component: the graceful stickies control enzyme of Bark Optimyze5400.1kg, deionized water 58.5kg, dodecyl hydroxypropyl sultaine 10kg, myristamide propyl group hydroxypropyl sultaine 10.8kg, cocamidopropyl propyl amide amine oxide 20kg, isothiazolinone 0.1kg, lemon flavour 0.5kg.
Embodiment 4
Another kind of non-setting adhesive removing residual glue stain cleanser provided by the invention, made by following component: French import stickies control enzyme SupfineZ1600.02kg, deionized water 60kg, dodecyl oxyethyl group sultaine 4.64kg, dodecyl hydroxypropyl sultaine 5kg, dodecyl azochlorosulfonate propyl lycine 5kg, myristamide propyl group hydroxypropyl sultaine 5kg, decyl hydroxypropyl sultaine 5kg, cocamidopropyl propyl amide amine oxide 14.2kg, isothiazolinone 0.3kg, essence 0.8kg.
Embodiment 5
Another kind of non-setting adhesive removing residual glue stain cleanser provided by the invention, made by following component: French import stickies control enzyme SupfineZ2720.08kg, deionized water 50kg, decyl hydroxypropyl sultaine 40kg, cocamidopropyl propyl amide amine oxide 9.42kg, isothiazolinone 0.3kg, essence 0.2kg.
Embodiment 6
Another kind of non-setting adhesive removing residual glue stain cleanser provided by the invention, made by following component: imported from America biological enzyme stickies control agent AM-2010.06kg, deionized water 58.94kg, dodecyl azochlorosulfonate propyl lycine 10kg, myristamide propyl group hydroxypropyl sultaine 20kg, cocamidopropyl propyl amide amine oxide 10kg, isothiazolinone 0.4kg, strawberry flavour 0.6kg.
In embodiment 1 to 6, the sanitising agent production technique of any one clean non-setting adhesive removing residual glue stain is:
1) take each component by any one group of data in embodiment 1 to 6;
2) deionized water, sanitas and sultaine type tensio-active agent are added in agitation vat, at normal temperatures, stir 20 minutes to being mixed to get mixed liquor A completely with 1400 revs/min;
3) determination step 2) temperature of mixed solution, add essence in temperature during lower than 40 ℃, at normal temperatures, stir 10 minutes to being mixed to get mixed liquid B completely with 1400 revs/min;
4) mixed liquid B leaves standstill and tests pH value after 30 minutes, adds hydrochloric acid acid or sodium hydroxide to adjust pH value to 5～12, and preferably pH value 8, carries out homogeneous stirring, and mixing speed is 1400 revs/min;
5) by stirrer adjustment of rotational speed to 800-1000 rev/min, preferably 900 revs/min, add cocamidopropyl propyl amide amine oxide, disperse stir 15-20 minute;
6) by stirrer adjustment of rotational speed to 100-300 rev/min, preferably 200 revs/min, add stickies control enzyme, disperse stir 15-20 minute;
7) canned after standing froth breaking.
Provide advantage of the present invention the present invention below and experimental results show that example in order better to illustrate:
By at varying environment temperature, adopt different formula consumptions, at different attachment surfaces and in the scheduled time, glue stain (tackiness agent) to different thickness and composition (rubber-based and acrylic acid or the like) has been carried out respectively three groups of experiments, verified that product of the present invention can completely steep removing residual glue to dispose in the short period of time, experimental technique and related data are as follows:
(1) experimental technique:
Choose representative water tumbler and meal dish (glass-ceramic utensil), microwave oven and computer (family expenses-office electrical equipment), desk and wardrobe door (woodenware and lacquer painting), Auto Instrument desk and vehicle body (plastifying material and lacquer painting) attachment surface, as far as possible non-setting adhesive paste is torn, then foam cleaner is evenly sprayed, is covered in above removing residual glue stain, leave standstill approximately 5～15 minutes, again with cotton or Glass cleaning cloth or brush or wire ball firmly arbitrarily carries out laterally under the prerequisite of not damaging body surface, longitudinally, spirrillum wiping, until glue stain comes off.
(2) conclusion:
1,, get the Schwellenwert in " basic recipe with scale " during in main component, within the shortest contrived experiment time, the more high stickies control enzyme that is more conducive to of envrionment temperature (65 ℃ of the upper limits) plays a role, and removes effect better; When envrionment temperature is during lower than 15 ℃ of contrived experiment temperature, extend time of repose and can reach design and remove effect.
2,, get the maximum in " basic recipe with scale " during in main component, within the shortest contrived experiment time, in the time of 15 ℃ of minimum contrived experiment temperature, also can reach design and remove effect; In the time that main component consumption is greater than the maximum in " basic recipe and use scale ", the synergy of removing effect is not obvious.
3, be eliminated that the surface of object (as glass-ceramic container) is more bright and clean is more conducive to auxiliary agent rapid osmotic, absorption, emulsification, solubilising, dispersion, remove effect better; The high object (as glass-ceramic container) that is difficult for being worn of hardness is removed better effects and if not directly removed by the impact of envrionment temperature and time of repose.
4, glue stain (tackiness agent) thickness of choosing in this experiment is minimum value and the maximum value of conventional non-setting adhesive products adhesion agent coat-thickness, and in this experimental design scope, glue stain (tackiness agent) thickness is not obvious on cleaning effect impact.
5, the organic solvent containing in all kinds of non-setting adhesive tackiness agents all has stronger solvency action to general common plastifying material as the lacquer painting of PE/PET/PVC goods and household electrical appliance, family property woodenware, plastifying material, vehicle body, leather, and this sanitising agent does not have repair to the greyish white trace of dissolved plastifying material surface and household electrical appliance, family property woodenware, plastifying material, vehicle body, the generation of leather lacquer painting.
(3) " experimental data cartogram "
1, sizing agent chemical type: rubber-based
2, sizing agent chemical type: acrylic acid or the like
Claims (10)
1. a non-setting adhesive removing residual glue stain cleanser, it is characterized in that, component by following mass percent is made: stickies control enzyme 0.001%～0.1%, deionized water 50%～90%, sultaine type tensio-active agent 5%～40%, cocamidopropyl propyl amide amine oxide 0.5%～20%, sanitas 0.1%～0.5%, essence 0.1%～1%, component sum is 100%.
2. non-setting adhesive removing residual glue stain cleanser according to claim 1, is characterized in that, described stickies control enzyme is to be formed by esterase and lipase mixed preparing.
3. non-setting adhesive removing residual glue stain cleanser according to claim 1 and 2, it is characterized in that, described stickies control enzyme is one of them of Bark graceful stickies control enzyme Optimyze525 or Optimyze530 or Optimyze540 series or French import stickies control enzyme SupfineZ160 or SupfineZ272 or imported from America biological enzyme stickies control agent AM-201.
4. non-setting adhesive removing residual glue stain cleanser according to claim 1, it is characterized in that, described sultaine type tensio-active agent is one of them or arbitrary combination of dodecyl oxyethyl group sultaine or dodecyl hydroxypropyl sultaine or dodecyl azochlorosulfonate propyl lycine or myristamide propyl group hydroxypropyl sultaine or decyl hydroxypropyl sultaine.
5. non-setting adhesive removing residual glue stain cleanser according to claim 1, is characterized in that, described sanitas is isothiazolinone.
6. non-setting adhesive removing residual glue stain cleanser according to claim 1, is characterized in that, described essence is the conventional essence of washing composition.
7. the technique of the non-setting adhesive removing residual glue stain cleanser described in production claim 1, is characterized in that, comprises the steps: successively
1) take each component by mass percent claimed in claim 1;
2) deionized water, sanitas and sultaine type tensio-active agent are added in agitation vat, stir at normal temperatures 20 minutes to being mixed to get mixed liquor A completely;
3) determination step 2) temperature of mixed solution, add essence in temperature during lower than 40 ℃, stir at normal temperatures 10 minutes to being mixed to get mixed liquid B completely;
4) mixed liquid B leaves standstill and tests pH value after 30 minutes, adds acid or alkali to adjust pH value to 5～12, carries out homogeneous stirring;
5) by stirrer adjustment of rotational speed to 800-1000 rev/min, add cocamidopropyl propyl amide amine oxide, disperse stir 15-20 minute;
6) by stirrer adjustment of rotational speed to 100-300 rev/min, add stickies control enzyme, disperse stir 15-20 minute;
7) canned after standing froth breaking.
8. the production technique of non-setting adhesive removing residual glue stain cleanser according to claim 7, is characterized in that, step 1) to the mixing speed described in step 4) is 1400 revs/min.
9. the production technique of non-setting adhesive removing residual glue stain cleanser according to claim 7, is characterized in that, the acid described in step 4) is hydrochloric acid.
10. the production technique of non-setting adhesive removing residual glue stain cleanser according to claim 7, is characterized in that, the alkali described in step 4) is sodium hydroxide.
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| CN201410103073.3A CN103849496B (en) | 2014-03-19 | 2014-03-19 | A kind of adhesive sticker removing residual glue stain cleanser and production technology thereof |
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| CN201410103073.3A CN103849496B (en) | 2014-03-19 | 2014-03-19 | A kind of adhesive sticker removing residual glue stain cleanser and production technology thereof |
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| CN103849496B CN103849496B (en) | 2016-08-17 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107868709A (en) * | 2017-11-03 | 2018-04-03 | 常州市雄图纺织有限公司 | A kind of adhesive sticker cleaning agent |
| CN114226302A (en) * | 2021-12-14 | 2022-03-25 | 深圳创维－Rgb电子有限公司 | Cleaning method and fixing component for liquid crystal glass |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107868709A (en) * | 2017-11-03 | 2018-04-03 | 常州市雄图纺织有限公司 | A kind of adhesive sticker cleaning agent |
| CN114226302A (en) * | 2021-12-14 | 2022-03-25 | 深圳创维－Rgb电子有限公司 | Cleaning method and fixing component for liquid crystal glass |
| CN114226302B (en) * | 2021-12-14 | 2024-01-12 | 深圳创维－Rgb电子有限公司 | Cleaning method and fixing part of liquid crystal glass |
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| CN103849496B (en) | 2016-08-17 |
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