CN103849496B - A kind of adhesive sticker removing residual glue stain cleanser and production technology thereof - Google Patents
A kind of adhesive sticker removing residual glue stain cleanser and production technology thereof Download PDFInfo
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- CN103849496B CN103849496B CN201410103073.3A CN201410103073A CN103849496B CN 103849496 B CN103849496 B CN 103849496B CN 201410103073 A CN201410103073 A CN 201410103073A CN 103849496 B CN103849496 B CN 103849496B
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Abstract
The invention discloses a kind of cleaning agent cleaning adhesive sticker removing residual glue stain and production technology thereof, it is desirable to provide a kind of environmental friendliness formula, production technology is simple, can effectively remove cleaning agent and the production technology thereof of adhesive sticker glue stain on various utensil；It is characterized in that: the cleaning agent of this cleaning adhesive sticker removing residual glue stain, it is made up of the component of following mass percent: stickies control enzyme 0.001%～0.1%, deionized water 50%～90%, sulfobetaine type surfactant 5%～40%, cocamidopropyl propyl amide amine oxide 0.5%～20%, preservative 0.1%～0.5%, essence 0.1%～1%, component sum is 100%；Belong to cleaning agent technical field.
Description
Technical field
The open a kind of cleaning agent of the present invention and production technology thereof, specifically, be a kind of adhesive sticker removing residual glue stain cleanser
And production technology, belong to cleaning agent technical field.
Background technology
We daily life, work in it is frequently necessary to use adhesive tape, two-sided tape, foam tape, adhesive sticker
Cartoon paster, all things patch, trade mark ... these adhesive sticker goods, bringing convenient while, also bring some and are tired of
Angry, with the glue stain of residual after mistake wipe not fall, clip where where bond to, wipe more black and more black, wipe spend a sheet of ... by methyl alcohol, second
Although the organic solvents such as alcohol, benzene homologues, acetone, turpentine oil and the detergent product containing organic solvent can quickly remove residual
Glue stain, but these organic solvents and problems can be produced, such as containing the detergent product of organic solvent:
1, it evaporate into immediately in air, respiratory tract after being sucked by people, can be stimulated, even stimulate optic nerve, then cause health
Hidden danger.Particularly in family, office, automobile etc. to health requirements higher and it is frequently necessary to the enclosed environment closed the doors and windows
In.
2, direct contact can damage human body skin.
3, dissolve the paint of cleaned object surface, also can dissolve conventional plastic cement article surface, cleaned article are made
Become to destroy.
4, easily to environment.
These problems cause inconvenience to the life of people, how to develop a kind of non-corrosiveness environmental friendliness, the most leaded,
The noxious material such as arsenic, mercury, without organic solvents such as methyl alcohol, ethanol, benzene homologues, acetone, turpentine oil, does not hurts hands, does not hinder clothing, nothing
Volatility peculiar smell, smell delicate fragrance, to human body skin, optic nerve, respiratory system nonirritant；Will not be to object material itself, paint
Face causes secondary to destroy；Main Ingredients and Appearance can not resulted in environmental pollution by Soil Microorganism natural degradation, and tool goes
Dirty, be sterilized, press down mould, anti-static function, can effectively clean household electrical appliance, family property woodenware, glass-ceramic container, plastifying material, car
Body lacquer painting, metal, leather surface are because using adhesive tape, two-sided tape, foam tape, cartoon paster, all things patch, trade mark etc. residual
The cleaning products of the adhesive sticker glue stain stayed, becomes the focus of some hobbies person research.
Summary of the invention
For above-mentioned deficiency, it is an object of the invention to provide a kind of environmental friendliness formula, can effectively remove various utensil
On adhesive sticker removing residual glue stain cleanser, present invention also offers the production technology of this cleaning agent.
For solving the problems referred to above, the previous technical scheme that the present invention provides is such that this adhesive sticker removing residual glue stain cleaning
Agent, is made up of the component of following mass percent: stickies control enzyme 0.001%～0.1%, deionized water 50%～90%, sulfo group
Betaine type amphoteric surfactant 5%～40%, cocamidopropyl propyl amide amine oxide 0.5%～20%, preservative 0.1%～0.5%, essence
0.1%～1%, component sum is 100%.
Above-mentioned adhesive sticker removing residual glue stain cleanser, described stickies control enzyme is by esterase, lipase mixed preparing
Form.
Further, above-mentioned adhesive sticker removing residual glue stain cleanser, described stickies control enzyme is Bark graceful gluing thing
Control that enzyme Optimyze525 or Optimyze530 or Optimyze540 be serial or French import stickies control enzyme
One of them of SupfineZ160 or SupfineZ272 or imported from America biology enzyme stickies control agent AM-201.
Further, above-mentioned adhesive sticker removing residual glue stain cleanser, described sulfobetaine type surfactant is ten
Dialkyl group ethyoxyl sulfobetaines or dodecyl hydroxypropyl sulfobetaines or dodecyl azochlorosulfonate propyl lycine or
Person's myristamide propyl group hydroxypropyl sulfobetaines or decyl hydroxypropyl sulfobetaines one of them or arbitrarily
Combination.
Further, above-mentioned adhesive sticker removing residual glue stain cleanser, described preservative is OIT.
Further, above-mentioned adhesive sticker removing residual glue stain cleanser, described essence is that essence commonly used by washing agent.
The latter technique scheme of the present invention is to provide the production technology of this cleaning agent, this adhesive sticker removing residual glue stain cleanser
Production technology, comprises the steps: successively
1) each component is weighed；
2) deionized water, preservative and sulfobetaine type surfactant are added in agitator, stir at normal temperatures
Within 20 minutes, obtain mixed liquor A to being thoroughly mixed；
3) determination step 2) temperature of mixed liquor, essence, at normal temperatures stirring 10 minutes are added when temperature is less than 40 DEG C
Mixed liquid B is obtained to being thoroughly mixed；
4) testing pH value after mixed liquid B stands 30 minutes, addition is sour or alkali adjustment pH value is to 5～12, carries out homogeneous and stirs
Mix；
5) by mixer adjustment of rotational speed to 800-1000 rev/min, cocamidopropyl propyl amide amine oxide, dispersion stirring are added
15-20 minute；
6) by mixer adjustment of rotational speed to 100-300 rev/min, adding stickies control enzyme, dispersion stirring 15-20 divides
Clock；
7) canned after standing froth breaking.
Further, above-mentioned adhesive sticker removing residual glue stain cleanser production technology, step 1) is to the stirring described in step 4)
Rotating speed is 1400 revs/min.
Further, above-mentioned adhesive sticker removing residual glue stain cleanser production technology, the acid described in step 4) is hydrochloric acid, described
Alkali be NaOH.
Compared with prior art, the technical scheme that the present invention provides has the advantage that
1, the technical scheme that the present invention provides uses stickies control enzyme, make the ester bond of gluing thing rupture, substantially
Component loses/reduces stickiness, and is difficult to regroup in systems.
2, the technical scheme that the present invention provides uses sulfobetaine type amphoteric surfactant as auxiliary agent, quickly ooze
Thoroughly between cleaned object surface and removing residual glue stain, by persistently permeating, adsorb, emulsify, solubilising, dispersion etc. act on, reduction
The surface tension of gluing thing and surface free energy, be allowed to separate with body surface.It is also equipped with preferable decontamination simultaneously, is sterilized, presses down
Mould, anti-static function.
3, by using the instrument such as hairbrush, fabric (glasses wiping cloth (rags), shawl, scouring pad) in the technical scheme that the present invention provides
The External Force Acting of wiping, help auxiliary agent rapid osmotic, adsorb, emulsify, solubilising, dispersion, the surface tension of reduction gluing thing and table
Face free energy, is allowed to quickly separate with cleaned object surface, come off.
4, in the technical scheme that the present invention provides, auxiliary agent uses sulfobetaine type amphoteric surfactant and coconut oleoyl amine
Propyl group amphoteric surfactant compounds, and produces more abundant, fine and smooth foam, permissible while increasing cleaning agent specific surface area
Optimize coverage effect, reduce consumption, delay cleaning agent in cleaned object vertical plane, outstanding the staying of bright and clean inclined-plane, attachment time, increase
Permeate by force, adsorb, emulsify, solubilising, dispersion effect.
5, the technical scheme that the present invention provides is the noxious materials such as non-corrosiveness environmental friendliness formula, the most leaded, arsenic, mercury,
Without organic solvents such as methyl alcohol, ethanol, benzene homologues, acetone, turpentine oil, do not hurt hands, do not hinder clothing, non-volatility peculiar smell, smell
Delicate fragrance, to human body skin, optic nerve, respiratory system nonirritant；Secondary will be caused to destroy object material itself, lacquer painting；
Main Ingredients and Appearance can not resulted in environmental pollution by Soil Microorganism natural degradation.
6, the auxiliary agent in the technical scheme that the present invention provides also has preferable decontamination concurrently, is sterilized, presses down mould, anti-static function.
Can effectively clean household electrical appliance, family property woodenware, glass-ceramic container, plastifying material, vehicle body lacquer painting, metal, leather surface because making
The adhesive sticker glue stain remained with adhesive tape, two-sided tape, foam tape, cartoon paster, all things patch, trade mark etc..It is applicable to house
Front yard, office, in automobile etc. to health requirements higher and it is frequently necessary in the enclosed environment closed the doors and windows.
Detailed description of the invention
The detailed description of the invention of the present invention is given below, but the claims of the present invention is not limited to this, appoint
The amendment of the limited number of time that who is made within the scope of the invention as claimed, still the present invention claims it
In.
Embodiment 1
A kind of adhesive sticker removing residual glue stain cleanser that the present invention provides, is made up of following component: the graceful stickies control of Bark
Enzyme Optimyze5250.001kg, deionized water 90kg, dodecyl azochlorosulfonate propyl lycine 7.999kg, cocamidopropyl propyl amide oxygen
Change amine 0.5kg, OIT 0.5kg, essence (described essence is the essence that washing agent is conventional, such as green apple essence) 1kg.
Embodiment 2
The another kind of adhesive sticker removing residual glue stain cleanser that the present invention provides, is made up of following component: Bark graceful gluing thing control
Enzyme Optimyze5300.05kg processed, deionized water 73.7kg, sulfobetaine type surfactant 20kg, cocamidopropyl propyl amide
Amine oxide 5kg, OIT 0.25kg, green apple essence 1kg.
Embodiment 3
The another kind of adhesive sticker removing residual glue stain cleanser that the present invention provides, is made up of following component: Bark graceful gluing thing control
Enzyme Optimyze5400.1kg processed, deionized water 58.5kg, dodecyl hydroxypropyl sulfobetaines 10kg, myristamide third
Base hydroxypropyl sulfobetaines 10.8kg, cocamidopropyl propyl amide amine oxide 20kg, OIT 0.1kg, lemon extract
0.5kg。
Embodiment 4
The another kind of adhesive sticker removing residual glue stain cleanser that the present invention provides, is made up of following component: France's import sicker
Control enzyme SupfineZ1600.02kg, deionized water 60kg, dodecyl ethyoxyl sulfobetaines 4.64kg, dodecyl
Hydroxypropyl sulfobetaines 5kg, dodecyl azochlorosulfonate propyl lycine 5kg, myristamide propyl group hydroxypropyl sulfobetaines
5kg, decyl hydroxypropyl sulfobetaines 5kg, cocamidopropyl propyl amide amine oxide 14.2kg, OIT 0.3kg, essence
0.8kg。
Embodiment 5
The another kind of adhesive sticker removing residual glue stain cleanser that the present invention provides, is made up of following component: France's import sicker
Control enzyme SupfineZ2720.08kg, deionized water 50kg, decyl hydroxypropyl sulfobetaines 40kg, cocamidopropyl propyl amide
Amine oxide 9.42kg, OIT 0.3kg, essence 0.2kg.
Embodiment 6
The another kind of adhesive sticker removing residual glue stain cleanser that the present invention provides, is made up of following component: imported from America biology enzyme
Stickies control agent AM-2010.06kg, deionized water 58.94kg, dodecyl azochlorosulfonate propyl lycine 10kg, myristamide
Propyl group hydroxypropyl sulfobetaines 20kg, cocamidopropyl propyl amide amine oxide 10kg, OIT 0.4kg, strawberry essence
0.6kg。
In embodiment 1 to 6, the cleaning agent production technology of any one cleaning adhesive sticker removing residual glue stain is:
1) each component is weighed by any one group of data in embodiment 1 to 6；
2) deionized water, preservative and sulfobetaine type surfactant are added in agitator, at normal temperatures, with
1400 revs/min of stirrings obtain mixed liquor A to being thoroughly mixed in 20 minutes；
3) determination step 2) temperature of mixed liquor, add essence when temperature is less than 40 DEG C, at normal temperatures, with 1400 turns/
Minute stirring obtains mixed liquid B to being thoroughly mixed in 10 minutes；
4) testing pH value after mixed liquid B stands 30 minutes, addition hydrochloric acid is sour or NaOH adjustment pH value is to 5～12,
Preferable ph 8, carries out homogeneous stirring, and speed of agitator is 1400 revs/min；
5) by mixer adjustment of rotational speed to 800-1000 rev/min, preferably 900 revs/min, cocamidopropyl propyl amide oxygen is added
Change amine, dispersion stirring 15-20 minute；
6) by mixer adjustment of rotational speed to 100-300 rev/min, preferably 200 revs/min, stickies control enzyme is added, point
Dissipate stirring 15-20 minute；
7) canned after standing froth breaking.
In order to better illustrate advantages of the present invention, the present invention is given below and tests proof example:
By at different ambient temperatures, use different formula consumptions, at different attachment surfaces and in the scheduled time, to not
The glue stain (adhesive) of stack pile and composition (rubber-based and acrylic compounds) has carried out three groups of experiments respectively, demonstrates the present invention and produces
Removing residual glue stain can be disposed by product the most completely, and experimental technique and related data are as follows:
(1) experimental technique:
Choose representative water tumbler and meal dish (glass ceramics utensil), micro-wave oven and computer (family expenses-office electrical equipment),
Desk and wardrobe door (woodenware and lacquer painting), Auto Instrument desk and vehicle body (plastifying material and lacquer painting) attachment surface, will not do as far as possible
Glue thing tears, then by foam cleaner even application, be covered in above removing residual glue stain, stand about 5～15 minutes, then use
Cotton or Glass cleaning cloth or brush or wire ball firmly arbitrarily carry out horizontal, longitudinal direction, spiral shell on the premise of not damaging body surface
Rotation shape wiping, until glue stain comes off.
(2) conclusion:
1, during the minimum in main component takes " basic recipe and use scale ", within the shortest contrived experiment time, ring
Border temperature (upper limit 65 DEG C) is the highest more is conducive to stickies control enzyme to play a role, and elimination effect is the best；When environment temperature is less than
During contrived experiment temperature 15 DEG C, extend time of repose and i.e. can reach design elimination effect.
2, during the peak in main component takes " basic recipe and use scale ", within the shortest contrived experiment time,
Also design elimination effect is can reach during minimum contrived experiment temperature 15 DEG C；When main component consumption is more than " basic recipe and consumption
Table " in peak time, the synergy of elimination effect is inconspicuous.
3, the surface of object (such as glass-ceramic container) it is eliminated the brightest and the cleanest more be conducive to auxiliary agent rapid osmotic, absorption, breast
Change, solubilising, dispersion, elimination effect is the best；Object (such as the glass-ceramic container) elimination effect that hardness height is difficult to be worn is more preferable
And can not be affected by environment temperature and time of repose and directly remove.
4, glue stain (adhesive) thickness chosen in this experiment is the minimum of conventional adhesive sticker products adhesion agent coating layer thickness
Value and maximum, in the range of this experimental design, glue stain (adhesive) thickness is inconspicuous on cleaning effect impact.
5, the organic solvent contained in all kinds of adhesive sticker adhesives is to the most common plastifying material such as PE/PET/PVC system
Product and household electrical appliance, family property woodenware, plastifying material, vehicle body, the lacquer painting of leather all have stronger dissolution, this cleaning agent pair
The grey white seal that the plastifying material surface being dissolved and household electrical appliance, family property woodenware, plastifying material, vehicle body, leather lacquer painting produce
Mark does not have repair.
(3) " experimental data statistical form "
1, adhesive chemical type: rubber-based
2, adhesive chemical type: acrylic compounds
Claims (9)
1. an adhesive sticker removing residual glue stain cleanser, it is characterised in that be made up of the component of following mass percent: gluing thing control
Enzyme 0.001%～0.1% processed, deionized water 50%～90%, sulfobetaine type surfactant 5%～40%, cocounut oil acyl
Amine propyl group amine oxide 0.5%～20%, preservative 0.1%～0.5%, essence 0.1%～1%, component sum is 100%.
Adhesive sticker removing residual glue stain cleanser the most according to claim 1, it is characterised in that described stickies control enzyme is
Bark graceful stickies control enzyme Optimyze 525 or Optimyze530 or Optimyze540 series or stickies control enzyme
One of them of Supfine Z160 or SupfineZ272 or biology enzyme stickies control agent AM-201.
Adhesive sticker removing residual glue stain cleanser the most according to claim 1, it is characterised in that described sulfobetaine type table
Face activating agent is dodecyl ethyoxyl sulfobetaines or dodecyl hydroxypropyl sulfobetaines or dodecyl sulphur
CAB or myristamide propyl group hydroxypropyl sulfobetaines or decyl hydroxypropyl sulfobetaines are wherein
One of or any combination.
Adhesive sticker removing residual glue stain cleanser the most according to claim 1, it is characterised in that described preservative is isothiazole
Quinoline ketone.
Adhesive sticker removing residual glue stain cleanser the most according to claim 1, it is characterised in that described essence is that washing agent is normal
Use essence.
6. the technique of production adhesive sticker removing residual glue stain cleanser described in claim 1, it is characterised in that include following step successively
Rapid:
1) mass percent as described in claim 1 weighs each component；
2) deionized water, preservative and sulfobetaine type surfactant are added in agitator, at normal temperatures stirring 20 points
Clock obtains mixed liquor A to being thoroughly mixed；
3) determination step 2) temperature of mixed liquor, essence is added when temperature is less than 40 DEG C, stirring at normal temperatures 10 minutes is to the completeest
Entirely it is mixed to get mixed liquid B；
4) testing pH value after mixed liquid B stands 30 minutes, addition is sour or alkali adjustment pH value is to 5～12, carries out homogeneous stirring；
5) by mixer adjustment of rotational speed to 800-1000 rev/min, cocamidopropyl propyl amide amine oxide, dispersion stirring 15-20 are added
Minute；
6) by mixer adjustment of rotational speed to 100-300 rev/min, stickies control enzyme, dispersion stirring 15-20 minute are added；
7) canned after standing froth breaking.
The production technology of adhesive sticker removing residual glue stain cleanser the most according to claim 6, it is characterised in that step 2) to step
Rapid 4) speed of agitator described in is 1400 revs/min.
The production technology of adhesive sticker removing residual glue stain cleanser the most according to claim 6, it is characterised in that step 4) described
Acid be hydrochloric acid.
The production technology of adhesive sticker removing residual glue stain cleanser the most according to claim 6, it is characterised in that step 4) described
Alkali be NaOH.
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107868709A (en) * | 2017-11-03 | 2018-04-03 | 常州市雄图纺织有限公司 | A kind of adhesive sticker cleaning agent |
| CN114226302B (en) * | 2021-12-14 | 2024-01-12 | 深圳创维－Rgb电子有限公司 | Cleaning method and fixing part of liquid crystal glass |
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