CN107794519B - A kind of curved draped method based on nano spray plating - Google Patents
A kind of curved draped method based on nano spray plating Download PDFInfo
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- CN107794519B CN107794519B CN201711080453.XA CN201711080453A CN107794519B CN 107794519 B CN107794519 B CN 107794519B CN 201711080453 A CN201711080453 A CN 201711080453A CN 107794519 B CN107794519 B CN 107794519B
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- spray plating
- nano spray
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- plating liquid
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/42—Coating with noble metals
- C23C18/44—Coating with noble metals using reducing agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/10—Intaglio printing ; Gravure printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/26—Printing on other surfaces than ordinary paper
- B41M1/30—Printing on other surfaces than ordinary paper on organic plastics, horn or similar materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/009—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using thermal means, e.g. infrared radiation, heat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/02—Dusting, e.g. with an anti-offset powder for obtaining raised printing such as by thermogravure ; Varnishing
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Thermal Sciences (AREA)
- Toxicology (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemically Coating (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The curved draped method based on nano spray plating that the invention discloses a kind of, it is characterised in that: the following steps are included: Step 1: surface preparation;Step 2: nano spray plating: preparing the nano spray plating solution for being free of silver nitrate, using spray gun by the nano spray plating solution spraying to workpiece surface, conventional cleaning is dried;Step 3: curved draped: a) production of water coating transfer film;B) film paper enters water;C) it transfers;D) it washes;E) it dries;F) gloss oil;G) dry.The present invention uses the nano spray plating solution without silver nitrate as curved draped bottom, and curved draped figure layer adhesive force can be made to greatly improve, can be widely applied to the industries such as bathroom.
Description
Technical field
The present invention relates to the technical field of surface treatment more particularly to a kind of curved draped methods based on nano spray plating.
Background technique
Nano spray plating is that silver ammino solution is sprayed on workpiece surface using spray gun and forms bloom mirror surface using silver mirror reaction
A process.Using the technology spray product, have excellent adhesive force, anti-impact force, corrosion resistance, against weather,
Wearability and marresistance have good rustless property, are generally used for sanitary ware industry, domestic and international full-sized car manufacturer and big
The surface treatment of the sophisticated products such as type electric appliance manufacturer can also be used as the sprayings such as incrustation and the protection of other industries, technique
Simply, environmentally protective, widely used, be a kind of high-new process for treating surface.
It is curved draped, it is using coating transfer technique (Cubic Transfer) using the water in a kind of dissolve easily in water
Property film carries
Picture and text, since aqueous membrane tension is splendid, it is easy to be wound in product surface formed picture and text layer, product surface just as
Spray painting equally obtains completely different appearance.It is coated on the workpiece of any shape, solves stereo product printing for manufacturer
Problem.It is curved draped also to add different lines, such as dermatoglyph wood grain emerald line and marble line in product surface, while also may be used
Keep away the diastema often occurred in the general space of a whole page stamp of color.In the prior art, the curved draped pattern for making attachment is easy to because slight
Scraping and it is damaged.
In view of this, the present inventor studies and devises a kind of curved draped method based on nano spray plating, this case is thus
It generates.
Summary of the invention
The curved draped method based on nano spray plating that the purpose of the present invention is to provide a kind of, the present invention use nano spray plating
As curved draped bottom, so that curved draped figure layer adhesive force is stronger.
To achieve the goals above, the technical scheme adopted by the invention to solve the technical problem is that:
A kind of curved draped method based on nano spray plating, comprising the following steps:
Step 1: surface preparation: carrying out surface preparation to workpiece to be processed, remove the ash on workpiece to be processed surface
Dirt, grease;For plastic workpiece, electrostatic precipitation processes are carried out;For there are the metal works of corrosion, the oxidation on its surface is removed
Object;
Step 2: nano spray plating: the nano spray plating solution for being free of silver nitrate is prepared, using spray gun by the nano spray plating
Solution spraying is to workpiece surface, conventional cleaning drying;
Step 3: curved draped: a) production of water coating transfer film, needed for being stamped in the method for macromolecule membrane gravure
Picture and text;B) film paper enters water, and upward transfer film picture and text, tile 1-2min in water, to its flattening;C) transfer, by workpiece close to
The film of activation, picture and text layer are slowly transferred on workpiece, and 20-35 DEG C of water temperature, transfer speed is uniform;D) it washes, by workpiece
It takes out, mixes up hydraulic pressure, residual film and floating layer are cleaned on cleaning machine;E) it dries, is carried out on dryer, 40-60 DEG C of temperature;F) light
Oil, transfer object surface spray one layer of gloss oil, protect the decorative pattern of object surface, keep body surface glossy;G) dry.
It further include preparing surfactant solution in the step 2, in spraying nanometer as the preferred embodiment of embodiment
Before spraying plating solution, surfactant solution is sprayed into workpiece surface;
As the preferred embodiment of embodiment, the preparation method of the surfactant solution is, every to prepare 5 kilograms of activation
Liquid takes 76-84 grams of stannous chloride, 59-67 milliliters of the hydrochloric acid that volume fraction is 38%, 4750-5250 milliliters of distilled water, will be above-mentioned
Three is uniformly mixed, and activating solution is made, and stands 8 hours, for use.
As the preferred embodiment of embodiment, in the step 2, the preparation method of the nano spray plating solution is, prepares the
A kind of nano spray plating liquid: 2.5 kilograms of the first nano spray plating liquid of every preparation take 1.235-1.365 grams of silver sulfate, sulfate of ammoniac 3.8-
4.2 grams, 2375-2625 milliliters of distilled water, above-mentioned three is uniformly mixed, the first nano spray plating liquid is made, for use;Prepare the
Two kinds of nano spray plating liquid: 2.5 kilograms of second of nano spray plating liquid of every preparation take 10.45-11.55 grams of sodium hydroxide, volume fraction
For 190-210 milliliters of ammonium hydroxide of 25%, 2375-2625 milliliters of distilled water, above-mentioned three is uniformly mixed, is made second nanometer
Plating liquid, for use;Prepare the third nano spray plating liquid: 5 kilograms of the third nano spray plating liquid of every preparation take hydrazine sulfate 47.5-
It 52.5 grams, 4750-5250 milliliters of distilled water, is uniformly mixed both above-mentioned, the third nano spray plating liquid is made, for use.
As the preferred embodiment of embodiment, in the step 3 a), the macromolecule membrane is polyvinyl alcohol film.
As the preferred embodiment of embodiment, in the step 3 b), after its flattening after, further include spray can make film dissolve but
The activator of film curing ink is not destroyed.
Since present invention employs above-mentioned technical solutions, so that the invention has the following advantages:
The present inventor is in production practice, it has unexpectedly been found that is draped over one's shoulders using the nano spray plating solution without silver nitrate as curved surface
The bottom covered can make curved draped figure layer adhesive force greatly improve, the development of curved draped technology is greatly facilitated.
Specific embodiment
1 metal of embodiment flower shines curved draped
A kind of metal flower solarization curved draped method of product, comprising the following steps:
Step 1: surface preparation:
Metal flower is shone and carries out surface preparation, removes dust, grease that metal flower shines, the oxide on surface;
Step 2: nano spray plating:
Surfactant solution is prepared, surfactant solution is sprayed into metal flower and shines surface;The surfactant
The preparation method of solution is 5 kilograms of activating solutions of every preparation, take 76 grams of stannous chloride, volume fraction be 38% 59 milliliters of hydrochloric acid,
4750 milliliters of distilled water, above-mentioned three is uniformly mixed, activating solution is made, stands 8 hours, for use;
The nano spray plating solution for being free of silver nitrate is prepared, is spent the nano spray plating solution spraying to metal using spray gun
Shine surface, conventional cleaning drying;The preparation method of the nano spray plating solution is to prepare the first nano spray plating liquid: every preparation
2.5 kilograms of the first nano spray plating liquid, take 1.235 grams of silver sulfate, and 3.8 grams of sulfate of ammoniac, 2375 milliliters of distilled water, by above-mentioned three
It is uniformly mixed, the first nano spray plating liquid is made, for use;Prepare second of nano spray plating liquid: every to prepare 2.5 kilograms and receive for second
Rice plating liquid takes 10.45 grams of sodium hydroxide, and volume fraction is 190 milliliters of ammonium hydroxide of 25%, 2375 milliliters of distilled water, will be above-mentioned
Three is uniformly mixed, and second of nano spray plating liquid is made, for use;Prepare the third nano spray plating liquid: it is every prepare 5 kilograms the third
Nano spray plating liquid takes 47.5 grams of hydrazine sulfate, 4750 milliliters of distilled water, is uniformly mixed both above-mentioned, the third nanometer of spray is made
Plating solution, for use;
Step 3: curved draped:
A) production of water coating transfer film stamps required picture and text in the method for polyvinyl alcohol film gravure;B) film paper enters
Water, upward transfer film picture and text, tile 1-2min in water, to its flattening;Spraying can be such that film dissolves but not destroy film curing ink
Activator;C) it transfers, metal flower is shone into the film close to activation, picture and text layer is slowly transferred on workpiece, water temperature 20-35
DEG C, transfer speed is uniform;D) it washes, metal flower is shone and is taken out, hydraulic pressure is mixed up, residual film and floating layer are cleaned on cleaning machine;e)
Drying, carries out, 40-60 DEG C of temperature on dryer;F) gloss oil, transfer object surface spray one layer of gloss oil, protect the flower of object surface
Line keeps body surface glossy;G) dry.
2 ceramic cup of embodiment it is curved draped
A kind of curved draped method of ceramic cup, comprising the following steps:
Step 1: surface preparation:
Surface preparation is carried out to ceramic cup, removes electrostatic, dust, the grease on ceramic cup surface;
Step 2: nano spray plating:
Surfactant solution is prepared, surfactant solution is sprayed into workpiece surface;The surfactant solution
Preparation method be 5 kilograms of activating solutions of every preparation, take 80 grams of stannous chloride, volume fraction be 38% 62 milliliters of hydrochloric acid, distillation
5000 milliliters of water, above-mentioned three is uniformly mixed, activating solution is made, stands 8 hours, for use.
The nano spray plating solution for being free of silver nitrate is prepared, using spray gun by the nano spray plating solution spraying to ceramic cup
Surface, conventional cleaning drying;The preparation method of the nano spray plating solution is to prepare the first nano spray plating liquid: every to prepare 2.5
Kilogram the first nano spray plating liquid takes 1.3 grams of silver sulfate, 4 grams of sulfate of ammoniac, 2450 milliliters of distilled water, above-mentioned three is mixed equal
It is even, the first nano spray plating liquid is made, for use;Prepare second of nano spray plating liquid: 2.5 kilograms of second of nano spray platings of every preparation
Liquid takes 11 grams of sodium hydroxide, and volume fraction is 200 milliliters of ammonium hydroxide of 25%, 2450 milliliters of distilled water, above-mentioned three is mixed equal
It is even, second of nano spray plating liquid is made, for use;Prepare the third nano spray plating liquid: 5 kilograms of the third nano spray platings of every preparation
Liquid takes 50 grams of hydrazine sulfate, 5000 milliliters of distilled water, is uniformly mixed both above-mentioned, the third nano spray plating liquid is made, for use.
Step 3: curved draped: a) production of water coating transfer film stamps institute in the method for polyvinyl alcohol film gravure
Need picture and text;B) film paper enters water, and upward transfer film picture and text, tile 1-2min in water, to its flattening;Spray can make film dissolve but
The activator of film curing ink is not destroyed;C) it transfers, by ceramic cup close to the film of activation, picture and text layer is slowly transferred to ceramic cup
On, 20-35 DEG C of water temperature, transfer speed is uniform;D) it washes, ceramic cup is taken out, hydraulic pressure is mixed up, residual film is cleaned on cleaning machine
With floating layer;E) it dries, is carried out on dryer, 40-60 DEG C of temperature;F) gloss oil, transfer object surface spray one layer of gloss oil, protect object
The decorative pattern on surface keeps body surface glossy;G) dry.
3 plastic tub of embodiment it is curved draped
A kind of curved draped method of plastic tub, comprising the following steps:
Step 1: surface preparation:
Surface preparation is carried out to plastic tub, removes electrostatic, dust, the grease on plastic tub surface;
Step 2: nano spray plating:
It prepares surfactant solution and surfactant solution is sprayed into plastic tub before spraying nano spray plating solution
Surface;The preparation method of the surfactant solution is that 5 kilograms of activating solutions of every preparation take 84 grams of stannous chloride, volume fraction
67 milliliters of hydrochloric acid, 5250 milliliters of distilled water for 38%, above-mentioned three is uniformly mixed, and activating solution is made, and stands 8 hours, to
With;
The nano spray plating solution for being free of silver nitrate is prepared, using spray gun by the nano spray plating solution spraying to plastic tub
Surface, conventional cleaning drying;The preparation method of the nano spray plating solution is to prepare the first nano spray plating liquid: every to prepare 2.5
Kilogram the first nano spray plating liquid, takes 1.365 grams of silver sulfate, 4.2 grams of sulfate of ammoniac, 2625 milliliters of distilled water, above-mentioned three is mixed
It closes uniformly, the first nano spray plating liquid is made, for use;Prepare second of nano spray plating liquid: every to prepare 2.5 kilograms second nanometer
Plating liquid, takes 11.55 grams of sodium hydroxide, and volume fraction is 210 milliliters of ammonium hydroxide of 25%, and 2625 milliliters of distilled water, by above-mentioned three
Person is uniformly mixed, and second of nano spray plating liquid is made, for use;Prepare the third nano spray plating liquid: it is every prepare 5 kilograms the third receive
Rice plating liquid takes 52.5 grams of hydrazine sulfate, 5250 milliliters of distilled water, is uniformly mixed both above-mentioned, the third nano spray plating is made
Liquid, for use.
Step 3: curved draped: a) production of water coating transfer film stamps institute in the method for polyvinyl alcohol film gravure
Need picture and text;B) film paper enters water, and upward transfer film picture and text, tile 1-2min in water, to its flattening;Spray can make film dissolve but
The activator of film curing ink is not destroyed;C) it transfers, by plastic tub close to the film of activation, picture and text layer is slowly transferred to ceramic cup
On, 20-35 DEG C of water temperature, transfer speed is uniform;D) it washes, plastic tub is taken out, hydraulic pressure is mixed up, residual film is cleaned on cleaning machine
With floating layer;E) it dries, is carried out on dryer, 40-60 DEG C of temperature;F) gloss oil, transfer object surface spray one layer of gloss oil, protect object
The decorative pattern on surface keeps body surface glossy;G) dry.
The directly curved draped method of comparative example 1
A kind of metal flower solarization curved draped method of product, comprising the following steps:
Step 1: surface preparation: using the method such as embodiment 1.
Step 2: curved draped: using the method such as embodiment 1.
Curved draped method of the comparative example 2 based on the nano spray plating with silver nitrate
A kind of metal flower solarization curved draped method of product, comprising the following steps:
Step 1: surface preparation:
Using the method for such as embodiment 1;
Step 2: nano spray plating:
Surfactant solution is prepared, using the method for such as embodiment 1;
The nano spray plating solution spraying is shone surface to metal flower using spray gun by preparation of nano spraying plating solution, conventional
Cleaning and drying;The preparation method of the nano spray plating solution is to prepare the first nano spray plating liquid: every to prepare 2.5 kilogram first
Kind of nano spray plating liquid, takes 11.4 grams of silver nitrate, and 1.235 grams of silver sulfate, 3.8 grams of sulfate of ammoniac, 2375 milliliters of distilled water, by above-mentioned three
Person is uniformly mixed, the first nano spray plating liquid is made, for use;Prepare second of nano spray plating liquid: it is every prepare 2.5 kilograms second
Nano spray plating liquid takes 10.45 grams of sodium hydroxide, and volume fraction is 190 milliliters of ammonium hydroxide of 25%, 2375 milliliters of distilled water, will be upper
It states three to be uniformly mixed, second of nano spray plating liquid is made, for use;Prepare the third nano spray plating liquid: 5 kilograms of thirds of every preparation
Kind nano spray plating liquid takes 47.5 grams of hydrazine sulfate, 4750 milliliters of distilled water, is uniformly mixed both above-mentioned, the third nanometer is made
Plating liquid, for use;
Step 3: curved draped: using the method such as embodiment 1.
It is standardized according to ASTM D3359 and carries out cross recess test.Specifically, using knife with the interval of 1mm by sample levels
Cut 11 rows and 11 column vertically to form the grid of respectively 100 grids with 1mm x 1mm (length x width) size
Lattice.Then, the CT-24 adhesive tape produced by Nichiban company is attached on the surface of rasterizing, is then removed to measure
The state that surface is removed with adhesive tape is stated, and according to following criterion evaluation measurement result.
Standard for assessing cross score adhesive strength is as follows:
5B: the region not being stripped;
4B: the area of stripping area is less than the 5% of the gross area;
3B: the area of stripping area is the 5% to 15% of the gross area;
2B: the area of stripping area is the 15% to 35% of the gross area;
1B: the area of stripping area is the 35% to 65% of the gross area;
0B: the area of stripping area is greater than the 65% of the gross area.
The test of 1 adhesive strength of table
Group | Adhesive strength |
Embodiment 1 | 5B |
Comparative example 1 | 2B |
Comparative example 2 | 3B |
The above is only the preferred embodiment of the present invention, the range implemented of the present invention that therefore, it cannot be limited according to, i.e., according to
Equivalent changes and modifications made by the invention patent range and description, should still be within the scope of the present invention.
Claims (5)
1. a kind of curved draped method based on nano spray plating, it is characterised in that: the following steps are included:
Step 1: surface preparation: carrying out surface preparation to workpiece to be processed, remove dust, the oil on workpiece to be processed surface
Rouge;For plastic workpiece, electrostatic precipitation processes are carried out;For there are the metal works of corrosion, the oxide on its surface is removed;
Step 2: nano spray plating: preparing the nano spray plating solution for being free of silver nitrate, the preparation method of the nano spray plating solution
To prepare the first nano spray plating liquid: 2.5 kilograms of the first nano spray plating liquid of every preparation take 1.235-1.365 grams of silver sulfate,
3.8-4.2 grams of sulfate of ammoniac, 2375-2625 milliliters of distilled water, above-mentioned three is uniformly mixed, the first nano spray plating liquid is made,
For use;Prepare second of nano spray plating liquid: 2.5 kilograms of second of nano spray plating liquid of every preparation take sodium hydroxide 10.45-11.55
Gram, volume fraction is 190-210 milliliters of ammonium hydroxide of 25%, 2375-2625 milliliters of distilled water, above-mentioned three is uniformly mixed, and is made
Second of nano spray plating liquid is obtained, for use;Prepare the third nano spray plating liquid: 5 kilograms of the third nano spray plating liquid of every preparation take sulphur
47.5-52.5 grams of sour hydrazine, is uniformly mixed both above-mentioned, the third nano spray plating liquid is made by 4750-5250 milliliters of distilled water,
Using spray gun by the nano spray plating solution spraying to workpiece surface, conventional cleaning is dried;
Step 3: curved draped: a) production of water coating transfer film stamps required figure in the method for macromolecule membrane gravure
Text;B) film paper enters water, and upward transfer film picture and text, tile 1-2min in water, to its flattening;C) it transfers, by workpiece close to work
The film of change, picture and text layer are slowly transferred on workpiece, and 20-35 DEG C of water temperature, transfer speed is uniform;D) it washes, workpiece is taken
Out, hydraulic pressure is mixed up, residual film and floating layer are cleaned on cleaning machine;E) it dries, is carried out on dryer, 40-60 DEG C of temperature;F) light
Oil, transfer object surface spray one layer of gloss oil, protect the decorative pattern of object surface, keep body surface glossy;G) dry.
2. a kind of curved draped method based on nano spray plating as described in claim 1, it is characterised in that: the step 2
In, it further include preparing surfactant solution surfactant solution is sprayed to workpiece table before spraying nano spray plating solution
Face;
3. a kind of curved draped method based on nano spray plating as claimed in claim 2, it is characterised in that: the surface-active
The preparation method of agent solution is 5 kilograms of activating solutions of every preparation, takes 76-84 grams of stannous chloride, the hydrochloric acid that volume fraction is 38%
59-67 milliliters, 4750-5250 milliliters of distilled water, above-mentioned three is uniformly mixed, and activating solution is made, and stands 8 hours, for use.
4. a kind of curved draped method based on nano spray plating as described in claim 1, it is characterised in that: the step 3 a)
In, the macromolecule membrane is polyvinyl alcohol film.
5. a kind of curved draped method based on nano spray plating as described in claim 1, it is characterised in that: the step 3 b)
In, it further include spraying the activator that film can be made to dissolve but do not destroy film curing ink after its flattening.
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CN1072529C (en) * | 1999-12-28 | 2001-10-10 | 李光 | Technology for coating decorative film on curved surface |
CN1935075A (en) * | 2005-09-19 | 2007-03-28 | 丁永林 | Curved draped water transfer plastic-shell thermos bottle |
CN101200149B (en) * | 2006-12-12 | 2010-05-19 | 比亚迪股份有限公司 | Method for forming embossed hologram |
CN101637997A (en) * | 2009-07-21 | 2010-02-03 | 陈富荣 | Application of water transfer printing technology in printing color patterns on zipper products |
KR20120061531A (en) * | 2010-12-03 | 2012-06-13 | 한국전자통신연구원 | Method and device of forming a metal pattern |
CN102719813B (en) * | 2011-03-30 | 2014-06-04 | 东莞星晖真空镀膜塑胶制品有限公司 | Nanometer spray plating technology |
CN102825938A (en) * | 2011-09-29 | 2012-12-19 | 黄燕腾 | Manufacturing method of deplated water transfer printing film |
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Address after: 362499 part two F-5 block of Yutian valve base, Chengxiang Town, Chengxiang Town, Anxi County, Fujian Patentee after: Fujian Huangqiu sanitary Technology Co., Ltd Address before: 362499 part two F-5 block of Yutian valve base, Chengxiang Town, Chengxiang Town, Anxi County, Fujian Patentee before: Fujian Huang ball bathroom industry and Trade Co., Ltd. |