CN105624700B - A kind of acidity aluminium alloy adhesive remover and its preparation method and application - Google Patents
A kind of acidity aluminium alloy adhesive remover and its preparation method and application Download PDFInfo
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- CN105624700B CN105624700B CN201511000435.7A CN201511000435A CN105624700B CN 105624700 B CN105624700 B CN 105624700B CN 201511000435 A CN201511000435 A CN 201511000435A CN 105624700 B CN105624700 B CN 105624700B
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- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 62
- 239000000853 adhesive Substances 0.000 title claims abstract description 34
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000002253 acid Substances 0.000 claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 238000001125 extrusion Methods 0.000 claims abstract description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 14
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 230000002378 acidificating effect Effects 0.000 claims abstract description 14
- 239000013530 defoamer Substances 0.000 claims abstract description 14
- 239000008367 deionised water Substances 0.000 claims abstract description 14
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 14
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 14
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 14
- 239000010703 silicon Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 13
- 239000013556 antirust agent Substances 0.000 claims abstract description 13
- 239000010452 phosphate Substances 0.000 claims abstract description 13
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 13
- 239000006184 cosolvent Substances 0.000 claims abstract description 10
- 239000000126 substance Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 24
- 235000019441 ethanol Nutrition 0.000 claims description 23
- 238000003756 stirring Methods 0.000 claims description 19
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 13
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 13
- 239000003292 glue Substances 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- 238000009434 installation Methods 0.000 claims description 7
- 238000007789 sealing Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 230000003014 reinforcing effect Effects 0.000 claims description 4
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 claims description 3
- 239000004744 fabric Substances 0.000 claims description 3
- 238000001935 peptisation Methods 0.000 claims description 3
- 229940057402 undecyl alcohol Drugs 0.000 claims description 3
- 229910000714 At alloy Inorganic materials 0.000 claims description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract description 5
- 230000006378 damage Effects 0.000 abstract description 3
- 238000004064 recycling Methods 0.000 abstract description 3
- 238000011084 recovery Methods 0.000 abstract description 2
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 239000000956 alloy Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009432 framing Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- -1 polyoxy Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/12—Light metals
- C23G1/125—Light metals aluminium
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Detergent Compositions (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of acid aluminium alloy adhesive removers and its preparation method and application, belong to aluminium alloy extrusions recovery technology field.Technical scheme main points are：A kind of acidity aluminium alloy adhesive remover, is prepared by the raw material of following parts by weight：40 60 parts of 10 20 parts of acidic sol agent fluosilicic acid, 5 15 parts of emulsifier isomery alcohol ether, 10 30 parts of cosolvent low molecule alcohol substance, 5 20 parts of antirust agent phosphate, 15 parts of organic silicon defoamer and deionized water.Preparation method the invention also discloses the acidity aluminium alloy adhesive remover and its application in aluminium alloy extrusions is dismantled.The acid aluminium alloy adhesive remover of the present invention reduces the destruction that can suffer from when aluminum alloy frame is removed to greatest extent, can effectively promote the recycling rate of waterused of aluminium alloy extrusions.
Description
Technical field
The invention belongs to aluminium alloy extrusions recovery technology fields, and in particular to a kind of acidity aluminium alloy adhesive remover and its preparation
Methods and applications.
Background technology
Because aluminum alloy materials have the characteristics that density is small, material is hard, easy processing and corrosion-resistant, it is largely used to make each
Kind door and window, show window, building curtain wall or large-scale outdoor advertising curtain Frame lamp, it is closely bound up with daily life.It is and near
With the progress of aluminium alloy production technology over year, the aluminum alloy materials haveing excellent performance are more noticeable, in broader field
In show up prominently, obtained further applying.
Each class framework that aluminium alloy extrusions makes is spliced and is installed this procedure, can generally use such as lower section
Method：First, the end connection of all kinds of section bars of aluminium alloy can use thin diameter rivet to carry out preliminary riveted, produce using rectangle as
Main frame shape can deform under stress condition；Then, the frame produced can install plastics or rubber additional in edge groove
It finalizes the design almost, prevents that aluminum alloy frame is hit power during installation using the flexible modeling work gluing conjunction of low-intensity
Deformation；Finally, a large amount of silicone types or polysulfur type high-strength plastic work glue can be used to be fixed on frame and want installation site, is typically
On wall or other facilities, bonding reinforcing is carried out to contact site with high-strength plastic work glue, and sticks high strength composite
Sealing strip, after the spontaneous curing when 5-8 is small, aluminium alloy extrusions will strong bond in institute installation position.
With the development of society, all kinds of facilities are faced with removal or dismounting, because aluminium alloy extrusions has higher exploitation value
Value and utilization rate, so the recycling of aluminium alloy extrusions is particularly important.Instantly the method for aluminium alloy is recycled there are larger drawback, usually
Manpower or mechanical means can be used to carry out manual demolition from installation by force, cause the section bar after most of remove because by strong
Large impact power and serious deformation and destruction occurs, can not again be reused as suitable section bar；Remove work also more
It is cumbersome, a large amount of manpower and materials are wasted, it is even more hidden there is serious safety in face of the dismounting of large aluminum alloy profiles structural framing
Suffer from；Aluminium alloy extrusions frame door and window even can cause wall to damage because of being removed using brute force attack means in some buildings
It is bad, influence the beautiful or even safe of building.
In conclusion largely aluminium alloy extrusions to people’s lives while great convenience is brought, also because dismounting
Process is more intractable to have brought certain difficulty.Main reasons is that the adhesiveness of high-strength plastic work glue is too strong, so
The present invention for this problem, remove and maximize and recycle, and provides one kind by the safety to realize aluminium alloy extrusions frame
The special adhesive remover of aluminium alloy extrusions.
The content of the invention
Acid aluminium alloy adhesive remover reasonable the technical problem to be solved by the present invention is to provide a kind of formula and easy to use
And its preparation method and application.
It is of the invention to adopt the following technical scheme that solve above-mentioned technical problem, a kind of acidity aluminium alloy adhesive remover, feature
It is that is be prepared by the raw material of following parts by weight：10-20 parts of acidic sol agent fluosilicic acid, emulsifier isomery alcohol ether 5-15
Part, 10-30 parts of cosolvent low molecule alcohol substance, 5-20 parts of antirust agent phosphate, 1-5 parts of organic silicon defoamer and deionized water
40-60 parts, wherein isomery alcohol ether is heterogeneous ten alcohol polyoxyethylene ether, isomery undecyl alcohol polyoxyethylene ether or isomerous tridecanol polyoxy
Vinethene, low molecule alcohol substance are ethyl alcohol, methanol or ethylene glycol.
It further limits, the acid aluminium alloy adhesive remover is prepared by the raw material of following parts by weight：It is acid
15 parts of glue fluosilicic acid, 10 parts of emulsifier heterogeneous ten alcohol polyoxyethylene ether, 13.5 parts of cosolvent methanol, antirust agent phosphate 10
50 parts of part, 1.5 parts of organic silicon defoamer and deionized water.
The preparation method of acidity aluminium alloy adhesive remover of the present invention, it is characterised in that concretely comprise the following steps：It is stirred in band
Reaction kettle in add in the deionized water of 40-60 parts by weight and the acidic sol agent fluosilicic acid of 10-20 parts by weight, after stirring and dissolving
Add in antirust agent phosphate, the emulsifier isomery alcohol ether of 5-15 parts by weight and the cosolvent of 10-30 parts by weight of 5-20 parts by weight
Low molecule alcohol substance after stirring is completely dissolved, adds the organic silicon defoamer of 1-5 parts by weight, stirs to being completely dissolved, so
200 mesh filter screens are crossed afterwards obtains transparent yellow liquid acidity aluminium alloy adhesive remover.
It further limits, the preparation method of the acid aluminium alloy adhesive remover, it is characterised in that concretely comprise the following steps：In band
The deionized water of 50 parts by weight and the acidic sol agent fluosilicic acid of 15 parts by weight are added in the reaction kettle of stirring, is added after stirring and dissolving
Enter the hydrotropy of the antirust agent phosphate of 10 parts by weight, the emulsifier heterogeneous ten alcohol polyoxyethylene ether of 10 parts by weight and 13.5 parts by weight
Agent methanol after stirring is completely dissolved, adds the organic silicon defoamer of 1.5 parts by weight, stirs to being completely dissolved, then crosses 200
Mesh filter screen obtains transparent yellow liquid acidity aluminium alloy adhesive remover.
Application of the acidity aluminium alloy adhesive remover of the present invention in aluminium alloy extrusions is dismantled, it is characterised in that specific mistake
Cheng Wei：The acidity aluminium alloy adhesive remover is directly coated to aluminum alloy frame frame section and mounting surface strip of paper used for sealing junction, the acidic aluminum
Alloy adhesive remover is constantly penetrated into the modeling work glue of reinforcing, makes modeling work peptization swollen or dissolving causes sealing strip to come off, then aluminium is closed
Golden frame is completely removed from installation place or largely removed, and then picks the acidity aluminium alloy adhesive remover with hairbrush or cloth, aluminium is closed
It is got rid of completely with the modeling work glue of other abutting edges at metal type material rivet.
The acid aluminium alloy adhesive remover of the present invention reduce to greatest extent can suffer from when aluminum alloy frame is removed it is broken
It is bad, it can effectively promote the recycling rate of waterused of aluminium alloy extrusions.
Specific embodiment
The above of the present invention is described in further details by the following examples, but this should not be interpreted as to this
The scope for inventing above-mentioned theme is only limitted to following embodiment, and all technologies realized based on the above of the present invention belong to this hair
Bright scope.
Embodiment
Raw material is weighed respectively according to following proportioning（Kilogram）：
1st, acidic sol agent fluosilicic acid 15, emulsifier heterogeneous ten alcohol polyoxyethylene ether 10, cosolvent methanol 13.5, antirust agent
Phosphate 10, organic silicon defoamer 1.5 and deionized water 50；
2nd, acidic sol agent fluosilicic acid 10, emulsifier isomery undecyl alcohol polyoxyethylene ether 15, cosolvent ethyl alcohol 10, antirust agent
Phosphate 20, organic silicon defoamer 1 and deionized water 60；
3rd, acidic sol agent fluosilicic acid 20, emulsifier isomerous tridecanol polyoxyethylene ether 5, cosolvent ethylene glycol 30, antirust
Agent phosphate 5, organic silicon defoamer 5 and deionized water 40；
4th, acidic sol agent fluosilicic acid 16, emulsifier heterogeneous ten alcohol polyoxyethylene ether 12, hydrotropy methanol 15, antirust agent phosphoric acid
Ester 15, organic silicon defoamer 3 and deionized water 45.
Production method is as follows：
Deionized water and acidic sol agent fluosilicic acid are added in the reaction kettle with stirring, antirust agent is added in after stirring and dissolving
Phosphate, emulsifier and cosolvent after stirring is completely dissolved, add organic silicon defoamer, stir to being completely dissolved, then mistake
200 mesh filter screens obtain transparent yellow liquid acidity aluminium alloy adhesive remover.
Specifically used process is as follows：
The acidity aluminium alloy adhesive remover is directly coated to aluminum alloy frame frame section and mounting surface strip of paper used for sealing junction, the acidity
Aluminium alloy adhesive remover is constantly penetrated into the modeling work glue of reinforcing, makes modeling work peptization swollen or dissolving causes sealing strip to come off, then by aluminium
Alloy framework is completely removed from installation place or largely removed, and then the acidity aluminium alloy adhesive remover is picked with hairbrush or cloth, by aluminium
It is got rid of completely with the modeling work glue of other abutting edges at alloy profile rivet.
Basic principle, main features and advantages embodiment above describes the present invention, the technical staff of the industry should
Understand, the present invention is not limited to the above embodiments, and the above embodiments and description only describe the originals of the present invention
Reason, under the scope for not departing from the principle of the invention, various changes and modifications of the present invention are possible, these changes and improvements are each fallen within
In the scope of protection of the invention.
Claims (5)
1. a kind of acidity aluminium alloy adhesive remover, it is characterised in that be prepared by the raw material of following parts by weight：Acidic sol
10-20 parts of agent fluosilicic acid, 5-15 parts of emulsifier isomery alcohol ether, 10-30 parts of cosolvent low molecule alcohol substance, antirust agent phosphate
40-60 parts of 5-20 parts, 1-5 parts of organic silicon defoamer and deionized water, wherein isomery alcohol ether are heterogeneous ten alcohol polyoxyethylene ether, different
Structure undecyl alcohol polyoxyethylene ether or isomerous tridecanol polyoxyethylene ether, low molecule alcohol substance are ethyl alcohol, methanol or ethylene glycol.
2. acidity aluminium alloy adhesive remover according to claim 1, it is characterised in that be the raw material preparation by following parts by weight
It forms：It is 15 parts of acidic sol agent fluosilicic acid, 10 parts of emulsifier heterogeneous ten alcohol polyoxyethylene ether, 13.5 parts of cosolvent methanol, anti-
50 parts of 10 parts of rust agent phosphate, 1.5 parts of organic silicon defoamer and deionized water.
3. a kind of preparation method of acid aluminium alloy adhesive remover described in claim 1, it is characterised in that concretely comprise the following steps：In band
The deionized water of 40-60 parts by weight and the acidic sol agent fluosilicic acid of 10-20 parts by weight are added in the reaction kettle of stirring, stirring is molten
Antirust agent phosphate, the emulsifier isomery alcohol ether of 5-15 parts by weight and the helping for 10-30 parts by weight of 5-20 parts by weight are added in after solution
Solvent low molecule alcohol substance after stirring is completely dissolved, adds the organic silicon defoamer of 1-5 parts by weight, stirs to completely molten
Then solution crosses 200 mesh filter screens and obtains transparent yellow liquid acidity aluminium alloy adhesive remover.
4. the preparation method of acidity aluminium alloy adhesive remover according to claim 3, it is characterised in that concretely comprise the following steps：In band
The deionized water of 50 parts by weight and the acidic sol agent fluosilicic acid of 15 parts by weight are added in the reaction kettle of stirring, is added after stirring and dissolving
Enter the hydrotropy of the antirust agent phosphate of 10 parts by weight, the emulsifier heterogeneous ten alcohol polyoxyethylene ether of 10 parts by weight and 13.5 parts by weight
Agent methanol after stirring is completely dissolved, adds the organic silicon defoamer of 1.5 parts by weight, stirs to being completely dissolved, then crosses 200
Mesh filter screen obtains transparent yellow liquid acidity aluminium alloy adhesive remover.
5. application of the acidity aluminium alloy adhesive remover described in claim 1 in aluminium alloy extrusions is dismantled, it is characterised in that specific
Process is：The acidity aluminium alloy adhesive remover is directly coated to aluminum alloy frame frame section and mounting surface strip of paper used for sealing junction, the acidity
Aluminium alloy adhesive remover is constantly penetrated into the modeling work glue of reinforcing, makes modeling work peptization swollen or dissolving causes sealing strip to come off, then by aluminium
Alloy framework is completely removed from installation place or largely removed, and then the acidity aluminium alloy adhesive remover is picked with hairbrush or cloth, by aluminium
It is got rid of completely with the modeling work glue of other abutting edges at alloy profile rivet.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511000435.7A CN105624700B (en) | 2015-12-29 | 2015-12-29 | A kind of acidity aluminium alloy adhesive remover and its preparation method and application |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511000435.7A CN105624700B (en) | 2015-12-29 | 2015-12-29 | A kind of acidity aluminium alloy adhesive remover and its preparation method and application |
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| CN105624700A CN105624700A (en) | 2016-06-01 |
| CN105624700B true CN105624700B (en) | 2018-05-25 |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106435613A (en) * | 2016-07-31 | 2017-02-22 | 谢跃民 | Aluminum alloy wire washing agent and preparation method thereof |
| CN109106615B (en) * | 2018-09-06 | 2021-08-17 | 武汉市思泰利医疗器械发展有限公司 | Skin adhesive stripping agent |
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| CN105112927A (en) * | 2015-09-14 | 2015-12-02 | 夏良文 | Novel aluminum product wax removing agent and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110088720A1 (en) * | 2009-10-20 | 2011-04-21 | General Electric Company | Methods for cleaning substrates |
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|---|---|---|---|---|
| US2867514A (en) * | 1955-09-12 | 1959-01-06 | Amchem Prod | Method of deoxidizing an aluminum surface |
| CN101285193A (en) * | 2007-04-09 | 2008-10-15 | 比亚迪股份有限公司 | Acidic solution for treating surface of magnesium alloy and processing method |
| CN101899365A (en) * | 2009-05-27 | 2010-12-01 | 宁波百仕高联合工业有限公司 | Adhesive remover and preparation method thereof |
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| CN105624700A (en) | 2016-06-01 |
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