CN101891433B - 仿釉面外墙保温饰面砖及其制备方法 - Google Patents

仿釉面外墙保温饰面砖及其制备方法 Download PDF

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CN101891433B
CN101891433B CN2010102325620A CN201010232562A CN101891433B CN 101891433 B CN101891433 B CN 101891433B CN 2010102325620 A CN2010102325620 A CN 2010102325620A CN 201010232562 A CN201010232562 A CN 201010232562A CN 101891433 B CN101891433 B CN 101891433B
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王艳锦
王建春
张春山
王博儒
王博征
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Linyi Higginson Building Ceramics Co., Ltd.
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
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    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5076—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
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    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
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Abstract

本发明涉及一种仿釉面外墙保温饰面砖及其制备方法。该外墙保温饰面砖是由保温层基体和与保温层基体制成一体的仿釉面层构成，其中：仿釉面层是由苯酐-丙二醇树酯、氧化硅微粒、硅酸盐水泥、硅溶胶、无机短纤维、硬脂酸、过硫酸铵、安息香、纳米级氧化钛超细微粉和纳米级氧化硅超细微粉配制而成，并通过本发明的制备方法，使保温层和装饰层接合牢固，强度高，能有效地避免装饰层的开裂脱落，其装饰层具有质量轻，耐老化，使用寿命长，隔水防潮，外观效果好，节能环保，节省资源等优点。

Description

仿釉面外墙保温饰面砖及其制备方法
技术领域
本发明属于建筑物墙体保温材料技术领域，是一种仿釉面外墙保温饰面砖及其制备方法。 
背景技术
随着民用建筑节能设计“标准”的进一步规范和国务院《民用建筑节能条例》的实施，对新型建筑材料和墙体保温体系提出了更高的要求，要求既要有良好的保温性能，又要有突出的抗压、抗拉、抗老化性能；既要有可靠的防护性能，从根本上堵绝火灾隐患，又要具有防水抗渗、使用寿命永久的特性；既要绿色环保，无毒无害，又要美观高雅，装饰环境；既要避免传统外墙保温系统工序复杂，无法监控，质量无保证的难题，又要工序简捷、便于施工，质量有保证。目前，市场上出售的外墙装饰材料，大都采用在保温墙体上涂敷涂料等，用于防护和装饰，这种涂料层隔热、防水、自洁性能不好，容易沾染灰尘、污渍，装饰效果不够理想，特别是抗老化性能差，一般3～5年便出现褪色或变色、起皱等问题，使用寿命短，维修处理难度大。除此之外还存在一个难以克服的问题，就是施工程序繁杂、施工环节质量难以控制，由此造成外墙工程质量难以保证。有的采用粘接瓷砖作为饰面防护层，其装饰防护性能有不同程度的改进，但是这种方式隔热保温层和饰面防护层相互之间结合牢度差，表层的瓷砖自重较大，不仅加大了墙体的整体重量，而且容易开裂脱落，带来多种不良后果。 
发明内容
本发明的目的是克服现有技术中的不足，提供一种能够简化施工程序，保障工程质量，集隔热保温和表面装饰功能于一体，强度高、接合牢，而且节能环保的仿釉面外墙保温饰面砖及其制备方法。 
实现本发明的目的所采取的技术方案是：该外墙保温饰面砖是由保温层基体和与保温层基体制成一体的仿釉面层构成，其中：仿釉面层是由以下重量份的原料配比制成：苯酐-丙二醇树脂30～40份、氧化硅40～60份、硅酸盐水泥30～40份、硅溶胶5～10份、无机短纤维0.2～0.3份、硬脂酸3～4份、过硫酸铵1.6～1.8份、安息香0.5～1份、纳米级氧化钛超细微粉0.1～0.2份、纳米级氧化硅超细微粉0.1～0.2份。 
本发明仿釉面外墙保温饰面砖的制备方法按下述步骤进行： 
1)按所述配比分别取硬脂酸和硅酸盐水泥，将硬脂酸置入加热容器内，加热至65～75℃使之溶化为液态硬脂酸，将硅酸盐水泥倒入反应釜内进行搅拌，在搅拌过程中用喷雾器将液态硬脂酸喷洒在硅酸盐水泥中，使硬脂酸与硅酸盐水泥呈混合微粒状； 
2)在反应釜内按所述配比加入过硫酸铵，并按过硫酸铵∶去离子水＝1∶4～5的重量配比加入去离子水，再按所述配比加入安息香，搅拌混合均匀； 
3)在反应釜内按所述配比加入苯酐-丙二醇树脂，搅拌混合均匀； 
4)在反应釜内按所述配比加入粒度为10～30目的氧化硅、纳米级氧化钛、纳米级氧化硅和无机短纤维，搅拌混合均匀，并根据外观需要添加颜料进行调色，充分搅拌均匀后，制成糊状面层料； 
5)按照常规方法制备保温层基体，然后将制备的糊状面层料均匀摊铺在保温层基体的上表面，摊铺厚度为3～4mm，然后利用波长为400～700纳米的光源进行光照釉化，光照时间1～5分钟，自然固化后，即制成一体型仿釉面外墙保温饰面砖。 
按照上述方案制成的仿釉面外墙保温饰面砖，适用于外墙体的外保温饰面，集保温和表面装饰功能于一体，而且能简化施工程序，保障工程质量，其保温层和仿釉面装饰层接合牢固，强度高，可有效地避免装饰层的开裂脱落，特别是仿釉面装饰层具有质量轻，耐老化，使用寿命长，隔水防潮，外观效果好，节能环保，节省资源等优点。 
具体实施方式
参看图1、图2，本发明的仿釉面外墙保温饰面砖及其制备方法，是由发明人在长期实践经验总结的基础上，并通过大量的试验研究获得，该外墙保温饰面砖是由保温层基体和与保温层基体制成一体的仿釉面层构成，其中：保温层可采用常规的无机轻质材料如膨胀珍珠岩、粉煤灰、炉渣等制成，仿釉面层是由以下重量份的原料配比而成：苯酐-丙二醇树脂30～40份、氧化硅40～60份、硅酸盐水泥30～40份、硅溶胶5～10份、无机短纤维0.2～0.3份、硬脂酸3～4份、过硫酸铵1.6～1.8份、安息香0.5～1份、纳米级氧化钛超细微粉0.1～0.2份、纳米级氧化硅超细微粉0.1～0.2份。该仿釉面层采用过硫酸铵，苯酐-丙二醇树脂与硅酸盐水泥及硬脂酸，通过波长为400～700纳米的光照射，并在各种原料的协同作用下，形成质硬、光亮的表面，具有结合牢，质量轻，耐老化，使用寿命长，隔水防潮等优点，可与各种保温层基体相接合。 
下面结合实施例对本发明仿釉面外墙保温饰面砖的制备方法做进一步说明。 
实施例1 
在仿釉面外墙保温饰面砖中，仿釉面层各组分原料的重量份配比为：苯酐-丙二醇树脂30份、氧化硅40份、硅酸盐水泥30份、硅溶胶5份、无机短纤维0.2份、硬脂酸3份、安息香0.5份、过硫酸铵1.6份、纳米级氧化钛超细微粉0.1份、纳米级氧化硅超细微粉0.1份。
仿釉面外墙保温饰面砖的制备方法是：首先按所述配比分别取硬脂酸和硅酸盐水泥，将硬脂酸置入加热容器内，加热至65℃使之溶化为液态硬脂酸，将硅酸盐水泥倒入反应釜内进行搅拌，在搅拌过程中用喷雾器将液态硬脂酸变成雾状喷洒在硅酸盐水泥中，制成由硬脂酸包覆的硅酸盐水泥微粒，按所述配比加入过硫酸铵和安息香，并按过硫酸铵∶去离子水＝1∶4～5的重量配比加入去离子水，搅拌混合均匀后，再按所述配比加入苯酐-丙二醇树脂，搅拌混合均匀；然后按所述配比加入粒度为10～30目的氧化硅、纳米级氧化钛、纳米级氧化硅和无机短纤维，搅拌混合均匀，并根据外观需要添加颜料进行调色，充分搅拌均匀后，制成糊状面层料，最后将制备的糊状面层料摊铺在按常规方法制备的保温层基体上表面，摊铺厚度为3～4mm，并利用波长为400～700纳米的光源进行光照釉化，光照时间3分钟，自然固化后，即制成一体型仿釉面外墙保温饰面砖。 
实施例2 
仿釉面外墙保温饰面砖中仿釉面层各组分原料的重量份配比为：苯酐-丙二醇树脂35份、氧化硅50份、硅酸盐水泥35份、硅溶胶7份、无机短纤维0.25份、硬脂酸3.5份、过硫酸铵1.7份、安息香0.7份、纳米级氧化钛超细微粉0.15份、纳米级氧化硅超细微粉0.15份。该仿釉面外墙保温饰面砖的制备方法与实施例1基本相同，区别在于：制备硅酸盐水泥颗粒时的加热温度为70℃；过硫酸铵∶去离子水的重量配比为：过硫酸铵∶去离子水＝1∶4.5；糊状面层料向保温层的上表面摊铺时的摊铺厚度为3～4mm；最后对仿釉面层的表面的照射光波的波长为500纳米，光照时间为4分钟。 
实施例3 
仿釉面外墙保温饰面砖中仿釉面层各组分原料的重量份配比为：苯酐-丙二醇树脂40份、氧化硅60份、硅酸盐水泥40份、硅溶胶10份、无机短纤维0.3份、硬脂酸4份、过硫酸铵1.8份、安息香1份、纳米级氧化钛超细微粉0.2份、纳米级氧化硅超细微粉0.2份。该仿釉面外墙保温饰面砖的制备方法与实施例1基本相同，区别在于：制备硅酸盐水泥颗粒时的加热温度为75℃；制备催化剂溶液时，过硫酸铵∶去离子水的重量配比为：过硫酸铵∶去离子水＝1∶5；糊状面层料向保温层的上表面摊铺时的摊铺厚度为3～4mm；最后对仿釉面层的表面的照射光波的波长为700纳米，光照时间为5分钟。 

Claims (1)

1.一种仿釉面外墙保温饰面砖，是由保温层基体和与保温层基体制成一体的仿釉面层构成，其特征在于：仿釉面层是由以下重量份的原料配比制成：苯酐-丙二醇树脂30～40份、氧化硅40～60份、硅酸盐水泥30～40份、硅溶胶5～10份、无机短纤维0.2～0.3份、硬脂酸3～4份、过硫酸铵1.6～1.8份、安息香0.5～1份、纳米级氧化钛超细微粉0.1～0.2份、纳米级氧化硅超细微粉0.1～0.2份；
仿釉面外墙保温饰面砖的制备方法是：
1)按所述配比分别取硬脂酸和硅酸盐水泥，将硬脂酸置入加热容器内，加热至65～75℃使之溶化为液态硬脂酸，将硅酸盐水泥倒入反应釜内进行搅拌，在搅拌过程中用喷雾器将液态硬脂酸喷洒在硅酸盐水泥中，使硬脂酸与硅酸盐水泥呈混合微粒状；
2)在反应釜内按所述配比加入过硫酸铵，并按过硫酸铵∶去离子水＝1∶4～5的重量配比加入去离子水，再按所述配比加入安息香，搅拌混合均匀；
3)在反应釜内按所述配比加入苯酐-丙二醇树脂，搅拌混合均匀；
4)在反应釜内按所述配比加入粒度为10～30目的氧化硅、纳米级氧化钛、纳米级氧化硅和无机短纤维，搅拌混合均匀，并根据外观需要添加颜料进行调色，充分搅拌均匀后，制成糊状面层料；
5)按照常规方法制备保温层基体，然后将制备的糊状面层料均匀摊铺在保温层基体的上表面，摊铺厚度为3～4mm，然后利用波长为400～700纳米的光源进行光照釉化，光照时间1～5分钟，自然固化后，即制成一体型仿釉面外墙保温饰面砖；所述仿釉面外墙保温饰面砖的制备方法，在制备过程中按所述配比加入有硅溶胶。
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CN102677850B (zh) * 2012-05-29 2013-11-13 信阳天意节能技术有限公司 外墙真空无机保温装饰板及其制备方法
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