CN101850376B - Method and die for forward extrusion and variable diameter bending extrusion of magnesium alloy semi-solid billets - Google Patents
Method and die for forward extrusion and variable diameter bending extrusion of magnesium alloy semi-solid billets Download PDFInfo
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Abstract
Description
技术领域 technical field
本发明属于镁合金的挤压变形领域,特别涉及一种提高镁合金力学性能的挤压变形加工方法和加工模具。The invention belongs to the field of extrusion deformation of magnesium alloys, in particular to an extrusion deformation processing method and a processing die for improving the mechanical properties of magnesium alloys.
背景技术 Background technique
镁合金由于具有较高的比强度、比刚度、减震性、耐磨性、导热性、电磁屏蔽性,易切削性和易回收性等良好的综合性能,而成为汽车、航空航天及电子通讯等行业的重要新型材料。在能源、资源日益严峻和环保问题日趋突出的今天,镁合金被誉为“21世纪的绿色工程结构材料”,具有良好综合性能的轻质镁合金正成为全球关注的热点。随着镁合金结构件应用比例的不断增大,对镁合金成形技术的要求也越来越高。Magnesium alloys have become an important component of automobiles, aerospace and electronic communications due to their high specific strength, specific stiffness, shock absorption, wear resistance, thermal conductivity, electromagnetic shielding, easy cutting and easy recycling and other good comprehensive properties. Important new materials in other industries. Today, with increasingly severe energy and resource issues and increasingly prominent environmental protection issues, magnesium alloys are known as "green engineering structural materials in the 21st century", and lightweight magnesium alloys with good comprehensive properties are becoming a global focus. With the increasing application proportion of magnesium alloy structural parts, the requirements for magnesium alloy forming technology are also getting higher and higher.
镁合金的成形方法主要分为液态铸造和塑性变形两大类。由于镁属于密排六方晶体结构,滑移系较少,室温塑性较差,现在90%左右的镁合金工程结构件都是通过铸造方法制造。镁合金铸造方法有:砂型铸造、金属型重力铸造、熔模铸造、挤压铸造、低压铸造和压力铸造。这些铸造方法都需要专用的镁合金熔化炉,并且需采用覆盖剂或保护气体以防止熔化过程中镁的氧化燃烧,故资金投入大,而且存在严重的环境保护和安全隐患问题。同时,对于镁合金的主要成型方法-压力铸造方法而言,虽可成形复杂制件,但在成形厚大及不均匀铸件时存在缩孔、缩松、气孔等缺陷,从而降低了零件的力学性能。而镁合金塑性加工,虽可提高制件性能,但由于受其塑性变形能力的限制而只能生产形状极为简单的制件。The forming methods of magnesium alloys are mainly divided into two categories: liquid casting and plastic deformation. Since magnesium belongs to the close-packed hexagonal crystal structure, there are few slip systems, and the plasticity at room temperature is poor. Now about 90% of magnesium alloy engineering structural parts are manufactured by casting. Magnesium alloy casting methods include: sand casting, metal gravity casting, investment casting, squeeze casting, low pressure casting and pressure casting. These casting methods all require a special magnesium alloy melting furnace, and need to use a covering agent or protective gas to prevent the oxidative combustion of magnesium during the melting process, so the capital investment is large, and there are serious environmental protection and safety hazards. At the same time, for the main forming method of magnesium alloy - die casting method, although complex parts can be formed, there are defects such as shrinkage cavity, shrinkage porosity, and pores when forming thick and uneven castings, which reduces the mechanical properties of the parts. performance. The plastic processing of magnesium alloy can improve the performance of parts, but due to the limitation of its plastic deformation ability, it can only produce parts with extremely simple shapes.
半固态成形技术具有铸造和塑性加工两者的优点,即能用较小的力近净成形(仅需少量加工或不再加工,就可成型用作机械构件)出复杂形状的优质镁合金制件。Semi-solid forming technology has the advantages of both casting and plastic processing, that is, it can use a small force to form a high-quality magnesium alloy with a small force (only a small amount of processing or no processing can be used as a mechanical component). pieces.
半固态坯的制备是半固态成形的基础和关键。目前其主要制备方法有:机械搅拌法、电磁搅拌法、近液相线铸造法、应变诱发熔化激活法(SIMA)等。由于镁合金的易氧化特性,给液态法制备镁合金半固态坯料带来了困难,而SIMA法工艺简单、设备费用投入少,避免了熔体在高温时易氧化的弊端,所以SIMA法在镁合金半固态坯料制备中日益受到重视。已有的SIMA法主要是镦粗、等通道转角挤压,其中镦粗法不仅变形不均匀,而且坯料的尺寸受到很大的限制;等径道转角挤压制备的镁合金半固态坯料由于受到模具和设备的限制,每次只能制备长度较短的坯料,并且要经过多道次挤压以获得大的等效应变。The preparation of semi-solid blank is the basis and key of semi-solid forming. At present, its main preparation methods include: mechanical stirring method, electromagnetic stirring method, near-liquidus casting method, strain-induced melting activation method (SIMA) and so on. Due to the easy oxidation characteristics of magnesium alloys, it is difficult to prepare magnesium alloy semi-solid billets by liquid method, while SIMA method has simple process and low equipment investment, which avoids the disadvantage of easy oxidation of melt at high temperature, so SIMA method is used in magnesium alloys. The preparation of alloy semi-solid billets has been paid more and more attention. The existing SIMA methods are mainly upsetting and equal channel angular extrusion, in which the upsetting method not only deforms unevenly, but also greatly limits the size of the billet; the magnesium alloy semi-solid billet prepared by equal channel angular extrusion is subject to Due to the limitations of molds and equipment, only short billets can be prepared each time, and multiple passes of extrusion are required to obtain large equivalent strains.
中国专利文献CN100360700C(专利申请号03132471.1)公开了一种镁合金不等径弯道挤压-剪切诱导等温球化半固态坯复合制备方法,将坯料进行不等径弯道挤压,挤压比保持在1.5~2.0之间,弯道挤压角为90°,反复循环3~4次。但是这种方法需经过多道次挤压才能够将镁合金晶粒细化到较小尺寸,工序多,生产效率低,生产成本高;且每道次的挤压时间相对较长,若提高挤压速度会使产品的质量下降。Chinese patent document CN100360700C (patent application number 03132471.1) discloses a composite preparation method of magnesium alloy unequal-diameter bend extrusion-shear-induced isothermal spheroidization semi-solid billet, the billet is subjected to unequal-diameter bend extrusion, extrusion The ratio is kept between 1.5 and 2.0, the corner extrusion angle is 90°, and the cycle is repeated 3 to 4 times. However, this method requires multiple passes of extrusion to refine the magnesium alloy grains to a smaller size, with many procedures, low production efficiency, and high production costs; and the extrusion time of each pass is relatively long. Extrusion speed will reduce the quality of the product.
发明内容 Contents of the invention
本发明的目的是提供一种可以连续制备镁合金半固态坯的正挤压及变径弯曲挤压方法和模具。The purpose of the present invention is to provide a forward extrusion and variable diameter bending extrusion method and die which can continuously prepare magnesium alloy semi-solid billets.
实现本发明目的的技术方案是一种制备镁合金半固态坯的正挤压及变径弯曲挤压模具,包括上模板、凸模、凹模、凹模套、垫块、下模板和压板;凹模套坐落并固定在下模板上,且凹模套的下表面与下模板的上表面相接触;凹模套中部空间的下部放置垫块;凹模设有位于上端的进料口;凹模设置在垫块的上方,且位于凹模套中部空间中;凸模呈阶梯型,其上端与上模板固定连接,使用时凸模的下端对准凹模的进料口;压板的中央设有一通孔,压板固定在凹模套和凹模的上表面上,且其中央的通孔与凹模的进料口相对齐;凹模的型腔包括正挤压通道和变径弯曲挤压通道;正挤压通道包括第一直道和第二直道,第一直道的进料口也即凹模的进料口;第一直道自凹模顶端向下沿轴向延伸,经过圆锥台状过渡段与第二直道相连,其中第一直道的截面积大于第二直道的截面积;变径弯曲挤压通道是一挤压弯道,其弯道挤压角为90°~150°,变径弯曲挤压通道的截面积从上部的首端至下部的尾端逐渐变小;凹模套内设置等径出口通道,等径出口通道是一直道出口通道,在凹模套内顺着变径弯曲挤压通道的延伸方向向外延伸,其截面积与变径弯曲挤压通道的最小截面积相同。The technical solution for realizing the purpose of the present invention is a forward extrusion and variable diameter bending extrusion die for preparing a magnesium alloy semi-solid billet, including an upper die, a punch, a die, a die cover, a spacer, a lower die and a pressing plate; The die sleeve is located and fixed on the lower template, and the lower surface of the die sleeve is in contact with the upper surface of the lower template; the lower part of the space in the middle of the die sleeve is placed with a pad; the die is provided with a feed port at the upper end; the die It is set above the pad and located in the middle space of the die sleeve; the punch is stepped, and its upper end is fixedly connected with the upper template. When in use, the lower end of the punch is aligned with the feed port of the die; the center of the pressing plate is provided with a The through hole, the pressure plate is fixed on the upper surface of the die sleeve and the die, and the through hole in the center is aligned with the feed port of the die; the cavity of the die includes a positive extrusion channel and a variable diameter curved extrusion channel ;The positive extrusion channel includes the first straight road and the second straight road, and the feeding port of the first straight road is also the feeding port of the die; The shape transition section is connected with the second straight road, wherein the cross-sectional area of the first straight road is larger than that of the second straight road; the variable-diameter curved extrusion channel is an extrusion bend, and the extrusion angle of the bend is 90°-150° , the cross-sectional area of the variable-diameter curved extrusion channel gradually becomes smaller from the head end of the upper part to the tail end of the lower part; an equal-diameter outlet channel is set in the die sleeve, and the equal-diameter outlet channel is a straight outlet channel, which runs along the Extending outward along the extension direction of the variable-diameter curved extrusion channel, its cross-sectional area is the same as the minimum cross-sectional area of the variable-diameter curved extrusion channel.
上述凹模套的左部和右部各开有一个贯通上下的通孔,通孔内放置与通孔高度相同的陶瓷管,电热丝设置在陶瓷管内。The left part and the right part of the above-mentioned die cover respectively have a through hole through the upper and lower sides, and a ceramic tube with the same height as the through hole is placed in the through hole, and the heating wire is arranged in the ceramic tube.
一种制备镁合金半固态坯的正挤压及变径弯曲挤压方法,其中所使用的挤压模具包括上模板、凸模、凹模、凹模套、垫块、下模板和压板;凹模套坐落并固定在下模板上,且凹模套的下表面与下模板的上表面相接触;凹模套中部空间的下部放置垫块;凹模设有位于上端的进料口;凹模设置在垫块的上方,且位于凹模套中部空间中;凸模呈阶梯型,其上端与上模板固定连接,使用时凸模的下端对准凹模的进料口;压板的中央设有一通孔,压板固定在凹模套和凹模的上表面上,且其中央的通孔与凹模的进料口相对齐;凹模的型腔包括正挤压通道和变径弯曲挤压通道;正挤压通道包括第一直道和第二直道,第一直道的进料口也即凹模的进料口;第一直道自凹模顶端向下沿轴向延伸,经过圆锥台状过渡段与第二直道相连,其中第一直道的截面积大于第二直道的截面积;变径弯曲挤压通道是一挤压弯道,其弯道挤压角为90°~150°,变径弯曲挤压通道的截面积从上部的首端至下部的尾端逐渐变小;凹模套内设置等径出口通道,等径出口通道是一直道出口通道,在凹模套内顺着变径弯曲挤压通道的延伸方向向外延伸,其截面积与变径弯曲挤压通道的最小截面积相同;所述的挤压方法包括以下步骤:①镁铸坯的机械加工:将镁合金圆柱形铸坯加工成与上述凹模的上端内径相对应的圆柱形坯料;②坯料的预变形:对经过步骤①机械加工的坯料进行预热,使之升温至260℃~300℃;将上述挤压模具固定在通用挤压机的工作台上,对挤压模具进行预热,使挤压模具的温度比坯料预热温度低40℃~60℃;将预热的坯料放入挤压模具的凹模内,在液压机的带动下使得挤压模具的凸模通过挤压模具的压板中间的通孔将坯料压入凹模的正挤压通道的第一直道和截面积小于第一直道的第二直道而压缩变形,挤压比为15~30;凸模继续下行,正挤压后的坯料被压入变径弯曲挤压通道内进行弯道挤压及转角大于90°的剪切变形;下一块坯料在被压入正挤压通道和变径弯曲挤压通道的过程中,将前一次滞留在凹模中的坯料压入挤压模具的凹模套的等径出口通道而挤出凹模,继续挤压则将坯料挤出凹模套而得到预变形的镁合金棒料;上述过程连续进行;③将经过步骤②预变形的镁合金棒料按照需要定尺切割;④等温热处理:使步骤③定尺切割后的镁合金棒料在氩气氛围中在电阻炉中加热至半固态温度520℃~580℃,保温10min~30min获得镁合金半固态坯,其中炉温以先快后慢的升温速度加热至半固态温度。A forward extrusion and variable diameter bending extrusion method for preparing a magnesium alloy semi-solid billet, wherein the extrusion die used includes an upper die, a punch, a die, a die set, a pad, a lower die and a pressing plate; The mold sleeve is located and fixed on the lower template, and the lower surface of the die sleeve is in contact with the upper surface of the lower template; the lower part of the middle space of the die sleeve is placed with a pad; the die is provided with a feed port at the upper end; the die is set It is above the pad and located in the middle space of the die sleeve; the punch is stepped, and its upper end is fixedly connected with the upper template. When in use, the lower end of the punch is aligned with the feed port of the die; the center of the pressure plate is provided with a Hole, the pressure plate is fixed on the upper surface of the die sleeve and the die, and the through hole in the center is aligned with the feed port of the die; the cavity of the die includes a positive extrusion channel and a variable diameter curved extrusion channel; The positive extrusion channel includes a first straight road and a second straight road. The feed port of the first straight road is also the feed port of the die; the first straight road extends axially downward from the top of the die and passes through the The transition section is connected with the second straight road, wherein the cross-sectional area of the first straight road is larger than that of the second straight road; the variable-diameter curved extrusion channel is an extrusion bend, and the extrusion angle of the bend is 90°-150°, The cross-sectional area of the variable-diameter curved extrusion channel gradually decreases from the head end of the upper part to the tail end of the lower part; an equal-diameter outlet channel is arranged in the die sleeve, and the equal-diameter outlet channel is a straight outlet channel, which runs along the The extension direction of the variable-diameter curved extrusion channel extends outwards, and its cross-sectional area is the same as the minimum cross-sectional area of the variable-diameter curved extrusion channel; the extrusion method includes the following steps: ①Machining of the magnesium casting billet: the magnesium alloy The cylindrical billet is processed into a cylindrical billet corresponding to the inner diameter of the upper end of the above-mentioned die; ② Pre-deformation of the billet: Preheat the billet that has been machined in step ① to raise the temperature to 260 ° C ~ 300 ° C; The extrusion die is fixed on the worktable of the general extruder, and the extrusion die is preheated so that the temperature of the extrusion die is 40°C to 60°C lower than the billet preheating temperature; put the preheated billet into the extrusion die In the die, under the drive of the hydraulic press, the punch of the extrusion die presses the blank into the through hole in the middle of the pressing plate of the extrusion die. The first straight path and cross-sectional area of the positive extrusion channel of the die are smaller The extrusion ratio is 15-30; the punch continues to go down, and the billet after being extruded is pressed into the variable-diameter curved extrusion channel for curved extrusion and shearing with a rotation angle greater than 90°. shearing deformation; the next piece of blank is pressed into the process of the forward extrusion channel and the reduced-diameter curved extrusion channel, and the previous blank that was retained in the die is pressed into the equal-diameter outlet channel of the die sleeve of the extrusion die. Extrude the die, and continue to extrude the billet out of the die sleeve to obtain a pre-deformed magnesium alloy bar; the above process is carried out continuously; ③cut the pre-deformed magnesium alloy bar through
上述步骤④所述先快后慢地升温至坯料的半固态温度,是先以每分钟升高13℃~15℃的速度使炉温升到镁合金坯料的半固态温度前20℃~30℃,接着以每分钟升高1℃~2℃的速度使炉温缓慢升至半固态温度。In the
上述步骤②坯料的预变形过程中,凸模的挤压速度为每分钟30毫米。During the pre-deformation process of the blank in the
本发明具有积极的效果:(1)本发明所制成的镁合金半固态坯料晶粒尺寸细小、均匀且接近于球状。(2)本发明预变形抗力小、变形量大且均匀、安全可靠、无三废污染。(3)本发明中在正挤压部分实现了很大的塑性变形,在随后的弯道挤压及转角大于90度的剪切中进一步加大了变形,且在整个横截面中的变形趋于均匀一致,解决了传统SIMA法不能连续制备大尺寸半固态坯的问题,满足了半固态触变成形制件的大规模连续化生产的需要。(4)本发明方法还可实现低温挤压成型的工业化生产,不仅提高生产效率,且挤压后的镁合金材料具有抗挤压强度高、屈服强度高、延伸性能好的力学性能。The invention has positive effects: (1) The grain size of the magnesium alloy semi-solid billet produced by the invention is small, uniform and close to spherical. (2) The present invention has small pre-deformation resistance, large and uniform deformation, safety and reliability, and no three-waste pollution. (3) In the present invention, a large plastic deformation is realized in the forward extrusion part, and the deformation is further increased in the subsequent bend extrusion and shearing with a turning angle greater than 90 degrees, and the deformation in the entire cross section tends to It is uniform and consistent, which solves the problem that the traditional SIMA method cannot continuously prepare large-size semi-solid billets, and meets the needs of large-scale continuous production of semi-solid thixoformed parts. (4) The method of the present invention can also realize the industrialized production of low-temperature extrusion molding, which not only improves the production efficiency, but also the extruded magnesium alloy material has high extrusion strength, high yield strength, and good mechanical properties of elongation.
附图说明Description of drawings
图1为本发明的正挤压及变径弯曲挤压的模具示意图;图2为图1的A-A向剖视图;图3为图2的半凹模的B向视图;图4为实施例2中AZ91D镁合金坯料等温处理时的加热温度曲线;图5为实施例2中预变形后AZ91D镁合金坯料的边部微观组织图;图6为实施例2中预变形后AZ91D镁合金坯料的心部微观组织图;图7为实施例2中AZ91D镁合金坯料用本发明挤压产生的晶粒细化效果图;图8为实施例3中AZ91D镁合金坯料用本发明挤压产生的晶粒细化效果图;图9为实施例4中AZ91D镁合金坯料用本发明挤压产生的晶粒细化效果图;图10为实施例5中AZ91D镁合金坯料用本发明挤压产生的晶粒细化效果图。Fig. 1 is the schematic diagram of the die of forward extrusion and variable diameter bending extrusion of the present invention; Fig. 2 is the A-A sectional view of Fig. 1; Fig. 3 is the B-direction view of the half die of Fig. 2; Fig. 4 is the
上述附图中的标记如下:上模板1,凸模2,凹模3,半凹模30,正挤压通道31,第一直道31-1,第二直道31-2,变径弯曲挤压通道32,凹模套4,等径出口通道41,电热丝42,陶瓷管43,垫块5,下模板6,压板7。The marks in the above drawings are as follows: upper template 1,
具体实施方式 Detailed ways
(实施例1、制备镁合金半固态坯的正挤压及变径弯曲挤压模具)见图1至图3,本实施例的制备镁合金半固态坯的正挤压及变径弯曲挤压加工模具包括上模板1、凸模2、凹模3、凹模套4、电热丝42、陶瓷管43、垫块5、下模板6和压板7。(Example 1, forward extrusion and variable diameter bending extrusion die for preparing magnesium alloy semi-solid billet) see Fig. 1 to Fig. 3, the forward extrusion and variable diameter bending extrusion for preparing magnesium alloy semi-solid billet of this embodiment The processing mold comprises an upper template 1, a
凹模套4坐落并固定在下模板6上,且凹模套4的下表面与下模板6的上表面相接触;凹模套4中部空间的下部放置垫块5。凹模3设有位于上端的进料口,凹模3设置在垫块5的上方,位于凹模套4中部空间中,且凹模3与凹模套4间隙配合;凸模2呈阶梯型,其上端与上模板1固定连接,使用时凸模2的下端对准凹模3的进料口,凹模3与凸模2的凹凸模间隙选取单边为0.05mm。压板7的中央设有一通孔,压板7固定在凹模套4和凹模3的上表面,且其中央的通孔与凹模3的进料口相对齐。The
上述凹模套4的左部和右部各开有一个贯通上下的通孔,通孔内放置与通孔高度相同的陶瓷管43,电热丝42设置在陶瓷管43内。The left part and the right part of the above-mentioned
上述凹模3的整体型腔是由两个完全对称的半凹模30组成,每个半凹模30均设有半个挤压通道,其形状为半圆形凹槽,两个半凹模30由各自的设有凹槽的一侧相向贴合,构成一个完整的凹模3,再用螺栓固定而成,两个半凹模30通过压板7与凹模套4固定。The overall cavity of the above-mentioned
凹模3的型腔包括正挤压通道31和变径弯曲挤压通道32,正挤压通道31在变径弯曲挤压通道32的上方且两通道相通。正挤压通道31包括第一直道31-1和第二直道31-2,第一直道31-1的进料口也即凹模3的进料口,第一直道31-1自凹模3顶端向下沿轴向延伸,经过圆锥台状过渡段与第二直道31-2相连,其中第一直道31-1的截面积大于第二直道31-2的截面积;变径弯曲挤压通道32是一挤压弯道,自第二直道31-2的最下端起向凹模3的斜下方向延伸直至与凹模套4的等径出口通道41相接,变径弯曲挤压通道32的截面积从最上部的首端即第二直道31-2的最下端至与凹模套4相接的尾端逐渐变小,其弯道挤压角(也即弯道的弯曲角度)为120°;上述凹模套4的等径出口通道41是一直道出口通道,在凹模套4内顺着变径弯曲挤压通道32的延伸方向向外延伸,其截面积与变径弯曲挤压通道32的最小截面积相同。The die cavity of the die 3 includes a positive extrusion channel 31 and a diameter-reducing
(实施例2、制备镁合金半固态坯的正挤压及变径弯曲挤压方法)见图4至图7,本实施例制备镁合金半固态坯的正挤压及变径道角挤压方法所用的挤压模具,采用实施例1所得到的模具,本实施例所处理的是AZ91D镁合金铸坯,制备镁合金半固态坯的方法包括以下步骤:①镁铸坯的机械加工:将镁合金圆柱形铸坯加工成与凹模3的上端内径相对应的圆柱形坯料,坯料的直径是50mm,高度为120mm。(Example 2, forward extrusion and variable diameter bending extrusion method for preparing magnesium alloy semi-solid billet) see Figure 4 to Figure 7, the forward extrusion and variable diameter corner extrusion for preparing magnesium alloy semi-solid billet in this embodiment The used extrusion die of the method adopts the die obtained in Example 1, and what the present embodiment deals with is the AZ91D magnesium alloy billet, and the method for preparing the magnesium alloy semi-solid billet comprises the following steps: 1. the machining of the magnesium billet: The magnesium alloy cylindrical billet is processed into a cylindrical blank corresponding to the inner diameter of the upper end of the
②坯料的预变形:将经过步骤①机械加工的圆柱形坯料在箱式电阻炉中预热,预热温度为280℃,保温20min。将实施例1的挤压模具固定在通用挤压机的工作台上,而使得凸模2可以相对于凹模3进行上下相对滑动。再将设置在模具中的电热丝42接通电源,而对挤压模具进行预热,使模具温度达到220℃。将预热的圆柱形坯料放入挤压模具的凹模3中,在液压机的带动下使得挤压模具的凸模2通过挤压模具的压板7中间的通孔将坯料压入正挤压通道31的第一直道31-1和截面积小于第一直道31-1的第二直道31-2中,挤压速度为每分钟30毫米,从而产生大的压缩变形,挤压比(挤压前制品的总横断面积与挤压后制品的总横断面积之比)为15~30(本实施例为17);凸模2继续下行,经过正挤压(运动方向与所受挤压力的方向相同)后的坯料被压入变径弯曲挤压通道32内,在变径变形以及120度弯道挤压剪切变形(在一段通道中行进的同时所发生的弯曲变形)中进一步加大变形;当凸模2下行至第一直道31-1的下端而无法再下行时,凸模2上行,将下一圆柱形坯料放入凹模3中,然后凸模2下行挤压下一块圆柱形坯料,下一块圆柱形坯料在被压入正挤压通道31和变径弯曲挤压通道32的过程中,将前一次滞留在凹模3中的坯料压入挤压模具的凹模套4的等径出口通道41而挤出凹模3,继续挤压则将坯料挤出凹模套4而得到预变形的镁合金棒料;上述过程连续进行,电热丝42一直通电,使得预变形过程中坯料的温度保持280℃,预变形时的等效应变(一股应变状态下各应变分量经适当组合而形成的与单向应变等效的应变)为5.1。② Pre-deformation of the billet: Preheat the cylindrical billet machined in step ① in a box-type resistance furnace at a preheating temperature of 280°C and keep it warm for 20 minutes. The extrusion die of Example 1 is fixed on the workbench of a general-purpose extruder, so that the
③将经过步骤②预变形的镁合金棒料按照需要定尺切割(在轴向上进行一定长度的切割)。③ Cutting the pre-deformed magnesium alloy bar in
④等温热处理:使步骤③定尺切割后的镁合金棒料在氩气氛围中在电阻炉中以先快后慢的方式加热至半固态温度565℃,然后保温20min获得镁合金半固态坯;具体升温方法是:加热时炉温通过调压器改变电压控制,以每分钟升高13.5℃的速度使炉温升到镁合金坯料的半固态温度前20℃~30℃(本实施例为30℃),接着以每分钟升高1℃的速度使炉温缓慢升至半固态温度,也即等温温度。④ Isothermal heat treatment: heat the magnesium alloy bar after
见图5和图6,上述步骤②中的预变形的目的是获得足够的诱发应变,该步骤是获得均匀细小近球形半固态坯的基础和关键;在预变形工艺中将挤压、变径挤压与剪切变形挤压技术巧妙地复合,在一次挤出中同时实现了正挤压变形、转角大于90°的变径剪切变形,其等效应变可达5以上。(SIMA应变诱发熔化激活法工艺原理:利用传统的铸造方法获得铸件,将该金属坯料在回复再结晶的温度范围内进行热挤压变形,破碎铸态枝晶组织,在坯料的组织中储存部分变化能,最后可按需要将经过变形的金属坯料切成一定的大小,迅速将其加热到固液两相区并适当保温,通过变形能的释放,即可获得具有触变性的球状半固态浆料。因此,上面所说的足够的诱发应变,可以理解为在坯料组织中储存足够的变化能)。See Figure 5 and Figure 6, the purpose of the pre-deformation in the
见图4,上述步骤④等温热处理的目的是获得所需要的固液相比例及使初生相球形化。半固态等温处理时的加热速度采取先快后慢的原则,是因为快的加热速度虽可以有效地提高生产效率,但会引起坯料内的温度不均匀分布,且液体没有足够的时间浸润晶粒边界,导致液体外流,使半固态坯料的流动性变差;而当加热速度较慢时,不仅影响生产效率,而且晶粒容易粗化长大,当加热温度较高时,坯料难以保持其自身的形状。因此,加热速度的选择原则应在保证均匀加热的同时,以最快的速度加热到设定的温度,又能避免坯料在高温下保持较长时间而引起的晶粒长大等不利因素,因而采取先快后慢的原则。As shown in Figure 4, the purpose of the
本发明结合了大挤压比挤压变形和变径弯曲挤压变形的优点,镁合金坯料在凹模的变径弯曲挤压通道流动挤压变形过程中,金属内部组织呈现出一定的方向性,使晶粒被拉长甚至发生破碎,增加了再结晶形核率(在单位时间、单位体积内母相中形成的晶核数目),细化了晶粒。The invention combines the advantages of large extrusion ratio extrusion deformation and variable-diameter bending extrusion deformation. During the flow extrusion deformation process of the magnesium alloy billet in the variable-diameter bending extrusion channel of the die, the internal structure of the metal presents a certain directionality. , so that the grains are elongated or even broken, increasing the recrystallization nucleation rate (the number of crystal nuclei formed in the parent phase per unit time and unit volume), and refining the grains.
(实施例3、制备镁合金半固态坯的正挤压及变径弯曲挤压方法)见图8,本实施例与实施例2的不同之处在于:步骤②中,经过步骤①机械加工的坯料在箱式电阻炉中预热,预热温度为300℃,保温15min,对挤压模具进行预热时模具温度为240℃,坯料的预变形温度即坯料在预变形过程中的温度为300℃。(Example 3, forward extrusion and variable diameter bending extrusion method for preparing magnesium alloy semi-solid billet) see Fig. 8, the difference between this embodiment and
本实施例较实施例2提高了预变形温度,会使得平均晶粒直径变大,但本实施例减少了预变形保温时间,相应的又使平均晶粒直径变小;相较实施例1,本实施例预变形温度的升高和预变形保温时间的减少均会使晶粒形状系数(固体颗粒的外表面积与体积和固体颗粒相同的圆球的外表面积之比;由于体积相同而形状不同的物体中,以圆球的外表面积最小,因此形状系数恒大于1;形状系数的大小,说明颗粒相撞与圆球的差异程度,若其值越接近1,则其形状也就越接近于圆球)变大,亦即晶粒的形状愈不规则。Compared with
(实施例4、制备镁合金半固态坯的正挤压及变径弯曲挤压方法)见图9,本实施例与实施例3的不同之处在于:步骤②预变形过程中,经过步骤①机械加工的坯料在箱式电阻炉中预热,预热温度为300℃,保温10min。(Example 4, the forward extrusion and variable-diameter bending extrusion method of preparing magnesium alloy semi-solid billet) see Figure 9, the difference between this embodiment and Example 3 is:
步骤④坯料的等温热处理过程中,将步骤④定尺切割后的坯料在氩气氛围中在电阻炉中加热至580℃,保温20min;具体方法是:加热时炉温通过调压器改变电压控制,炉温升到580℃的方法是:先以每分钟升高13.5℃的速度使炉温升到560℃,接着以每分钟升高1℃的速度使炉温缓慢升至半固态温度,也即等温温度。During the isothermal heat treatment process of the blank in
相较实施例3,本实施例晶粒的形状系数接近1;因为虽然本实施例预变形保温时间较短导致形状系数有一定的变大,但是等温热处理的温度较高,在相同的等温保温时间内,坯料的加热温度越高,晶粒的形状系数越小而大大减小了形状系数。Compared with Example 3, the shape factor of the crystal grains in this example is close to 1; because although the pre-deformation holding time in this example is shorter, the shape factor has a certain increase, but the temperature of the isothermal heat treatment is higher. During the isothermal holding time, the higher the heating temperature of the billet, the smaller the shape factor of the grains, which greatly reduces the shape factor.
(实施例5、制备镁合金半固态坯的正挤压及变径弯曲挤压方法)见图10,本实施例与实施例4的不同之处在于:步骤④坯料的等温热处理过程中,将步骤③定尺切割后的坯料在氩气氛围中在电阻炉中加热至580℃,保温30min。(Example 5, the forward extrusion and variable-diameter bending extrusion method of preparing magnesium alloy semi-solid billet) see Fig. 10, the difference between this embodiment and
与实施例4相比,本实施例晶粒的形状系数更接近1;因为相同的等温温度,等温时间越长,晶粒的形状系数越小。Compared with Example 4, the shape factor of the grains in this example is closer to 1; because of the same isothermal temperature, the longer the isothermal time, the smaller the shape factor of the grains.
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