CN101848950A - 不含苯乙烯的不饱和聚酯树脂组合物 - Google Patents
不含苯乙烯的不饱和聚酯树脂组合物 Download PDFInfo
- Publication number
- CN101848950A CN101848950A CN200880114955A CN200880114955A CN101848950A CN 101848950 A CN101848950 A CN 101848950A CN 200880114955 A CN200880114955 A CN 200880114955A CN 200880114955 A CN200880114955 A CN 200880114955A CN 101848950 A CN101848950 A CN 101848950A
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- CN
- China
- Prior art keywords
- coating
- resin combination
- composition
- alcohol
- comonomer
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/20—Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
- C08G63/21—Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups in the presence of unsaturated monocarboxylic acids or unsaturated monohydric alcohols or reactive derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
- C09D167/07—Unsaturated polyesters having carbon-to-carbon unsaturation having terminal carbon-to-carbon unsaturated bonds
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
Abstract
Description
组分 | 商业标号 | 供应商 |
富马酸 | - | Arkema |
衣康酸 | - | Iwata Chemical |
组分 | 商业标号 | 供应商 |
四氢邻苯二甲酸酐 | - | Lonza |
三羟甲基丙烷 | - | Perstop |
乙二醇 | - | Ineos |
丙二醇 | - | Lyondell |
三甘醇 | - | IQA |
三羟甲基丙烷二烯丙基醚 | TMPDE 80 | Perstop |
苯甲醇 | - | Brenntag |
甲基丙烯酸异冰片酯 | SR423A | Sartomer |
二甲基丙烯酸1,4-丁二醇酯 | SR-214 | Sartomer |
组分 | 商业标号 | 供应商 |
Borchi Gol Lac 80 | - | Borchers |
乙酸乙酯 | - | BP |
6%的辛酸钴 | Co 6 Hex-Cem | OMG |
甲乙酮过氧化物 | Peroxan ME 50L | Pergam |
实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5(对比例) | 实施例6(对比例) | 实施例7 | |
富马酸 摩尔*重量 | 0.75740g | 1.001000g | 1.001000g | 1.001000g | 0.50950g | 1.001600g | 1.001900g |
衣康酸 摩尔*重量 | 0.501070g | ||||||
四氢邻苯 摩尔*二甲酸酐 重量 | 0.25324g | ||||||
三羟甲基 摩尔丙烷 重量 | 0.22250g | 0.22250g | 0.65750g | ||||
乙二醇 摩尔重量 | 0.30161g | 0.30306g | 0.60513g | 0.30306g | |||
丙二醇 摩尔重量 | 0.35230g | 0.35437g | 0.60629g | 0.35437g | |||
三甘醇 摩尔重量 | 0.22280g | 0.22280g | |||||
三羟甲基 摩尔丙烷二烯 重量丙基醚 | 0.561020g | 0.561020g | 0.601150g | 0.601150g | 0.601520g | 0.501476g | 0.431520g |
苯甲醇 摩尔重量 | 0.65598g | 0.65598g | 0.40370g | 0.40370g | 0.40703g | 0.50745g | 0.40703g |
实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5(对比例) | 实施例6(对比例) | 实施例7 | |
酸值(mg KOH/g) | 27 | 26 | 20 | 27 | 30.5 | 39 | 25 |
粘度(mPa.s) | 15000 | 17000 | 30000 | 17000 | 6200 | 275 | 21000 |
加德纳颜色 | 1.3 | 1.5 | 0.7 | 0.7 | 4.4 | 1.0 | 1.0 |
Tg(℃) | -6 |
实施例8 | 实施例9(对比例) | 实施例10 | 实施例11(对比例) | |
根据实施例7的不饱和聚酯树脂 | 100.00 | 100.00 | 100.00 | 100.00 |
甲基丙烯酸异冰片酯SR423A | 10.00 | 20.00 | ||
二甲基丙烯酸1,4-丁二醇酯SR-214 | 10.00 | 20.00 | ||
总计: | 110.00 | 110.00 | 120.00 | 120.00 |
1 | 表面破裂或泛白 |
2 | 刮痕非常明显可见 |
3 | 刮痕清晰可见 |
4 | 稍有刮痕的表面(几乎不可见) |
5 | 没有刮痕 |
Claims (37)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07380309A EP2058343B1 (en) | 2007-11-08 | 2007-11-08 | Styrene-free unsaturated polyester resin composition |
EP07380309.0 | 2007-11-08 | ||
PCT/EP2008/009053 WO2009059706A1 (en) | 2007-11-08 | 2008-10-27 | Styrene-free unsaturated polyester resin composition |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101848950A true CN101848950A (zh) | 2010-09-29 |
CN101848950B CN101848950B (zh) | 2012-11-07 |
Family
ID=39171456
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2008801149552A Expired - Fee Related CN101848950B (zh) | 2007-11-08 | 2008-10-27 | 不含苯乙烯的不饱和聚酯树脂组合物 |
Country Status (7)
Country | Link |
---|---|
EP (2) | EP2058343B1 (zh) |
CN (1) | CN101848950B (zh) |
AT (1) | ATE538148T1 (zh) |
DK (2) | DK2058343T3 (zh) |
ES (2) | ES2379646T3 (zh) |
PL (2) | PL2058343T3 (zh) |
WO (1) | WO2009059706A1 (zh) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105566577A (zh) * | 2015-04-16 | 2016-05-11 | 湖南省金海科技有限公司 | 一种无苯乙烯低挥发份不饱和聚酯树脂的制造方法 |
CN107663264A (zh) * | 2017-09-21 | 2018-02-06 | 广东溢达纺织有限公司 | 一种不含苯乙烯的不饱和聚酯树脂及其制备方法与应用 |
CN107686675A (zh) * | 2017-09-27 | 2018-02-13 | 广州市阿蒂尔新材料科技有限公司 | 环保不易燃的原子灰组合物及其制备方法和施工方法 |
CN107955113A (zh) * | 2017-11-29 | 2018-04-24 | 华南理工大学 | 一种无苯乙烯的柔韧型不饱和聚酯树脂及其制备方法 |
CN109689810A (zh) * | 2016-07-13 | 2019-04-26 | 伊利诺斯工具制品有限公司 | 用于车身修复的对金属基材具有改进的粘附性的不饱和聚酯组合物 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2024102302A1 (en) * | 2022-11-10 | 2024-05-16 | Lanxess Corporation | Multifunctional boosters for antimicrobial preservatives and applications thereof |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE888519A (fr) * | 1981-04-22 | 1981-10-22 | Gni I P Institutlakokrasochnoi | Composition pour peintures et vernis |
DE3837783A1 (de) | 1988-11-08 | 1990-05-10 | Bayer Ag | Verfahren zur herstellung von beschichtungen |
DE3900257A1 (de) | 1989-01-06 | 1990-07-12 | Bayer Ag | Hydrophile, (meth)acryloylgruppen aufweisende polyurethane, deren verwendung als reaktive emulgatoren fuer radikalisch haertbare kunstharze, ein in wasser dispergierbares gemisch radikalisch haertbarer kunstharze und ein waessriges beschichtungsmittel auf basis eines solchen gemischs |
DE4314866A1 (de) | 1993-05-05 | 1994-11-10 | Bayer Ag | Radikalisch härtbare Lackkomposition und ihre Verwendung als Möbellack |
US6048822A (en) * | 1995-09-01 | 2000-04-11 | Toyo Boseki Kabushiki Kaisha | Polyester resin and sublimation transfer image receiver using same |
GB0007728D0 (en) * | 2000-03-31 | 2000-05-17 | Ppg Ind Ohio Inc | Coating composition |
-
2007
- 2007-11-08 ES ES07380309T patent/ES2379646T3/es active Active
- 2007-11-08 DK DK07380309.0T patent/DK2058343T3/da active
- 2007-11-08 EP EP07380309A patent/EP2058343B1/en not_active Not-in-force
- 2007-11-08 PL PL07380309T patent/PL2058343T3/pl unknown
- 2007-11-08 AT AT07380309T patent/ATE538148T1/de active
-
2008
- 2008-10-27 PL PL08847664T patent/PL2215136T3/pl unknown
- 2008-10-27 WO PCT/EP2008/009053 patent/WO2009059706A1/en active Application Filing
- 2008-10-27 ES ES08847664T patent/ES2389877T3/es active Active
- 2008-10-27 EP EP08847664A patent/EP2215136B1/en not_active Not-in-force
- 2008-10-27 CN CN2008801149552A patent/CN101848950B/zh not_active Expired - Fee Related
- 2008-10-27 DK DK08847664.3T patent/DK2215136T3/da active
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105566577A (zh) * | 2015-04-16 | 2016-05-11 | 湖南省金海科技有限公司 | 一种无苯乙烯低挥发份不饱和聚酯树脂的制造方法 |
CN109689810A (zh) * | 2016-07-13 | 2019-04-26 | 伊利诺斯工具制品有限公司 | 用于车身修复的对金属基材具有改进的粘附性的不饱和聚酯组合物 |
CN107663264A (zh) * | 2017-09-21 | 2018-02-06 | 广东溢达纺织有限公司 | 一种不含苯乙烯的不饱和聚酯树脂及其制备方法与应用 |
CN107663264B (zh) * | 2017-09-21 | 2019-09-10 | 广东溢达纺织有限公司 | 一种不含苯乙烯的不饱和聚酯树脂及其制备方法与应用 |
CN107686675A (zh) * | 2017-09-27 | 2018-02-13 | 广州市阿蒂尔新材料科技有限公司 | 环保不易燃的原子灰组合物及其制备方法和施工方法 |
CN107955113A (zh) * | 2017-11-29 | 2018-04-24 | 华南理工大学 | 一种无苯乙烯的柔韧型不饱和聚酯树脂及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
EP2058343A1 (en) | 2009-05-13 |
PL2215136T3 (pl) | 2012-11-30 |
PL2058343T3 (pl) | 2012-05-31 |
ES2389877T3 (es) | 2012-11-02 |
ES2379646T3 (es) | 2012-04-30 |
EP2215136B1 (en) | 2012-06-20 |
EP2215136A1 (en) | 2010-08-11 |
EP2058343B1 (en) | 2011-12-21 |
DK2058343T3 (da) | 2012-03-26 |
CN101848950B (zh) | 2012-11-07 |
WO2009059706A1 (en) | 2009-05-14 |
ATE538148T1 (de) | 2012-01-15 |
DK2215136T3 (da) | 2012-08-13 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
ASS | Succession or assignment of patent right |
Owner name: ARKEMA COATING RESINS LTD. Free format text: FORMER OWNER: CRAY VALLEY IBERICA S.A. Effective date: 20120419 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20120419 Address after: Madrid Applicant after: Arkema Coatings Resins S A U Address before: Spain Shengsailuoni Applicant before: Cray Valley Iberica |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20121107 Termination date: 20181027 |