CN101811906B - Fertilizer for enhancing chlorophyll content of plant and preparation method thereof - Google Patents

Fertilizer for enhancing chlorophyll content of plant and preparation method thereof Download PDF

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Publication number
CN101811906B
CN101811906B CN 200910219150 CN200910219150A CN101811906B CN 101811906 B CN101811906 B CN 101811906B CN 200910219150 CN200910219150 CN 200910219150 CN 200910219150 A CN200910219150 A CN 200910219150A CN 101811906 B CN101811906 B CN 101811906B
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Prior art keywords
organic acid
fertilizer
coch
acid salt
plant
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Expired - Fee Related
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CN 200910219150
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CN101811906A (en
Inventor
王耀
赵福泰
王建锋
巨江理
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SHAANXI YONGTAI BIOENGINEERING CO Ltd
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SHAANXI YONGTAI BIOENGINEERING CO Ltd
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Abstract

The invention discloses a fertilizer for enhancing the chlorophyll content of a plant. The fertilizer comprises the following components in percentage by mass: 1 to 4 percent of organic acid or organic acid salt, 1 to 12 percent of surfactant OP-10, 1 to 20 percent of penetrant and 30 to 85 percent of water. The invention also discloses a method for preparing the fertilizer. The method comprises the following steps: adding water and stirring; adding the organic acid or the organic acid salt into the water while stirring; stirring the mixture for 20 to 90 minutes until the organic acid or the organic acid salt is fully dissolved; adding the penetrant into the mixture, stirring the mixture for 10 to 60 minutes; and adding the surfactant into the mixture, stirring the mixture for 10 to 30 minutes and stopping stirring to obtain the fertilizer. The fertilizer has the advantages of improving photosynthesis, promoting transfer of sugar and starch and activation of various enzymes in the plant, reducing invasion of plant diseases and insect pests, having remarkable prevention effect on marssonina mali, strengthening tree vigor and improving disease resistance.

Description

A kind of fertilizer that improves chlorophyll content of plant and preparation method thereof
Technical field
The invention belongs to the vegetable manure technical field, be specifically related to a kind of fertilizer that improves chlorophyll content of plant and preparation method thereof.
Background technology
Green plants utilizes solar energy, assimilation carbonic acid gas (CO 2) and water (H 2O) make organic substance and releasing oxygen (O 2) process, be called photosynthesis.Blade is photosynthetic major organs, and the chloroplast most important organelle that is photosynthesis, and chlorophyll can absorb solar energy, and the help of the mat ferment moisture synthesis of glucose that makes carbonic acid gas and absorb from plant root.Synthetic organic matter is main resources and the whole energy sources that plant is rely and grows in the photosynthesis, also is other organic matter and energy sources that directly or indirectly rely on plant to live.If plant leaf blade lacks chlorophyll, photosynthesis is affected so, photosynthetic product reduces, namely plant rely the main resources of growth and all energy sources reduce, directly influence is that crop yield reduction, fruit quality descend, resistance weakens.At present, artificial external source is replenished chlorophyllous produce market to plant and is had no sale.
Summary of the invention
The purpose of this invention is to provide a kind of fertilizer that improves chlorophyll content of plant, can manually replenish the synthetic precursor composition of chlorophyll to plant is organic acid or organic acid salt.
Another object of the present invention provides the preparation method of above-mentioned fertilizer.
The technical solution adopted in the present invention is, a kind of fertilizer that improves chlorophyll content of plant, by mass percentage, formed by following component: 1%~40% organic acid or organic acid salt, the bleeding agent of 1%~12% Surfactant OP-10,1%~20%, 30%~85% water; Above each component mass percent summation is 100%.
Its characteristics further are, a kind of fertilizer that improves chlorophyll content of plant, by mass percentage, formed by following component: 5%~34% organic acid or organic acid salt, the bleeding agent of 1%~8% Surfactant OP-10,4%~15%, 50%~80% water; Above each component mass percent summation is 100%.
The organic acid chemical structural formula is:
R-COOH
In the formula, R is: CH 3CH 2, CH 3CO, CH 3COCH 2CH 2, CH 3CHNH 2Or H 2NCH 2COCH 2CH 2
The chemical structural formula of organic acid salt is:
R-COOA
In the formula, R is: CH 3CH 2, CH 3CO, CH 3COCH 2CH 2, CH 3CHNH 2Or H 2NCH 2COCH 2CH 2
A is: Fe, Zn, Mn, Cu, Ca or Mg.
Bleeding agent is that concentration is that 98% ethylene glycol, concentration are that 95% HP-1 or concentration are a kind of in 98% the dimethyl sulfoxide (DMSO), or any two kinds of mixtures that mixed as 1: 1 take mass ratio.
Another technical scheme of the present invention is, a kind of preparation method who improves chlorophyll content of plant fertilizer carries out according to the following steps:
Step 1,
By mass percentage, take by weighing 1%~40% organic acid or organic acid salt, the bleeding agent of 1%~12% Surfactant OP-10,1%~20%, 30%~85% water; Above each component mass percent summation is 100%;
Or by mass percentage, take by weighing 5%~34% organic acid or organic acid salt, the bleeding agent of 1%~8% Surfactant OP-10,4%~15%, 50%~80% water; Above each component mass percent summation is 100%.
Step 2,
In reactor, add entry, begin to stir, when stirring, in water, add first organic acid or organic acid salt, stir and dissolved fully to organic acid or organic acid salt in 20~90 minutes; Continuation adds bleeding agent in whipping process again, stirs 10~60 minutes again, adds at last surfactant when stirring, and stirs to stop after 10~30 minutes, namely makes fertilizer of the present invention.
The organic acid chemical structural formula is:
R-COOH
In the formula, R is: CH 3CH 2, CH 3CO, CH 3COCH 2CH 2, CH 3CHNH 2Or H 2NCH 2COCH 2CH 2
The chemical structural formula of organic acid salt is:
R-COOA
In the formula, R is: CH 3CH 2, CH 3CO, CH 3COCH 2CH 2, CH 3CHNH 2Or H 2NCH 2COCH 2CH 2
A is: Fe, Zn, Mn, Cu, Ca or Mg.
Bleeding agent is that concentration is that 98% ethylene glycol, concentration are that 95% HP-1 or concentration are a kind of in 98% the dimethyl sulfoxide (DMSO), or any two kinds of mixtures that mixed as 1: 1 take mass ratio.
The invention has the beneficial effects as follows, 1, improve photosynthesis, increase photosynthetic product, promote the absorption of nutriment and pass on, be conducive to growing of plant; 2, promote the transfer of sugar and starch; 3, promote the activation of plurality of enzymes in the plant corpus; 4, reduce the invasion and attack of damage by disease and insect, especially apple marssonina leaf spot is had significant preventive effect; 5, strengthen the resistance of plant; 6, improve protein content; 7, improve crop quality and shelf characteric; 8, promote the flower bud differentiation of fruit tree, reduce fruit drop, improve single fruit weight, improve quality, increase fruit mercolized wax matter layer thickness, prolong the fruit storage life; 9, strengthen tree vigo(u)r, improve resistance against diseases.
Embodiment
Embodiment 1
By mass percentage, take by weighing 34% organic acid CH 3COCH 2CH 2-COOH, 1%OP-10,15% concentration are 98% ethylene glycol, 50% water; Above component mass percent summation is 100%;
In reactor, add entry, begin to stir, when stirring, in water, add first organic acid CH 3COCH 2CH 2-COOH stirs and dissolved fully to organic acid in 20 minutes; Continuation adds ethylene glycol in whipping process again, stirs 50 minutes again, adds at last Surfactant OP-10 when stirring, and stirs to stop after 20 minutes, can make fertilizer of the present invention.
Embodiment 2
By mass percentage, take by weighing 40% organic acid H 2NCH 2COCH 2CH 2-COOH, 10%OP-10,20% concentration are 95% HP-1,30% water; Above component mass percent summation is 100%;
In reactor, add entry, begin to stir, when stirring, in water, add first organic acid H 2NCH 2COCH 2CH 2-COOH stirs and dissolved fully to organic acid in 70 minutes; Continuation adds HP-1 in whipping process again, stirs 30 minutes again, adds at last Surfactant OP-10 when stirring, and stirs to stop after 10 minutes, can make fertilizer of the present invention.
Embodiment 3
By mass percentage, take by weighing 8% organic acid CH 3CO-COOH, 8%OP-10,4% concentration are 98% dimethyl sulfoxide (DMSO), 80% water; Above each component mass percent summation is 100%;
In reactor, add entry, begin to stir, when stirring, in water, add first organic acid CH 3CO-COOH stirs and dissolved fully to organic acid in 30 minutes; Continuation adds dimethyl sulfoxide (DMSO) in whipping process again, stirs 60 minutes again, adds at last Surfactant OP-10 when stirring, and stirs to stop after 30 minutes, can make fertilizer of the present invention.
Embodiment 4
By mass percentage, take by weighing 10% organic acid CH 3CHNH 2-COOH, 3%OP-10,10% concentration are 98% ethylene glycol, 77% water; Above component mass percent summation is 100%;
In reactor, add entry, begin to stir, when stirring, in water, add first organic acid CH 3CHNH 2-COOH stirs and dissolved fully to organic acid in 20 minutes; Continuation adds ethylene glycol in whipping process again, stirs 50 minutes again, adds at last Surfactant OP-10 when stirring, and stirs to stop after 20 minutes, can make fertilizer of the present invention.
Embodiment 5
By mass percentage: take by weighing 1% organic acid salt (CH 3CO-COO) 2Fe, 12%OP-10,2% bleeding agent, 85% water; Above each component mass percent summation is 100%;
Bleeding agent is that concentration is that 98% dimethyl sulfoxide (DMSO) and concentration are that 95% HP-1 is the mixture that mixes at 1: 1 in mass ratio;
In reactor, add entry, begin to stir, when stirring, in water, add first organic acid salt (CH 3CO-COO) 2Fe stirs and dissolved fully to organic acid salt in 50 minutes; Continuation adds bleeding agent in whipping process again, stirs 20 minutes again, adds at last Surfactant OP-10 when stirring, and stirs to stop after 25 minutes, can make fertilizer of the present invention.
Embodiment 6
By mass percentage, take by weighing 5% organic acid salt (CH 3COCH 2CH 2-COO) 2Zn, 7%OP-10,8% bleeding agent, 80% water; Above each component mass percent summation is 100%;
Bleeding agent is that concentration is that 98% dimethyl sulfoxide (DMSO) and concentration are that 98% ethylene glycol is the mixture that mixes at 1: 1 in mass ratio;
In reactor, add entry, begin to stir, when stirring, in water, add first organic acid salt (CH 3COCH 2CH 2-COO) 2Zn stirs and dissolved fully to organic acid salt in 90 minutes; Continuation adds bleeding agent in whipping process again, stirs 25 minutes again, adds at last Surfactant OP-10 when stirring, and stirs to stop after 18 minutes, can make fertilizer of the present invention.
Embodiment 7
By mass percentage, take by weighing 35% organic acid salt (CH 3COCH 2CH 2-COO) 2Mg, 1%OP-10,1% bleeding agent, 63% water; Above each component mass percent summation is 100%;
Bleeding agent is that concentration is that 95% HP-1 and concentration are that 98% ethylene glycol is the mixture that mixes at 1: 1 in mass ratio;
In reactor, add entry, begin to stir, when stirring, in water, add first organic acid salt (CH 3COCH 2CH 2-COO) 2Mg stirs and dissolved fully to organic acid salt in 80 minutes; Continuation adds bleeding agent in whipping process again, stirs 10 minutes again, adds at last Surfactant OP-10 when stirring, and stirs to stop after 30 minutes, can make fertilizer of the present invention.
Embodiment 8
By mass percentage, take by weighing 40% organic acid salt (CH 3CH 2-COO) 2Ca, 5%OP-10,10% bleeding agent, 45% water; Above each component mass percent summation is 100%;
Bleeding agent is that concentration is that 98% dimethyl sulfoxide (DMSO) and concentration are that 98% ethylene glycol is the mixture that mixes at 1: 1 in mass ratio;
In reactor, add entry, begin to stir, when stirring, in water, add first organic acid salt (CH 3CH 2-COO) 2Ca stirs and dissolved fully to organic acid salt in 85 minutes; Continuation adds bleeding agent in whipping process again, stirs 45 minutes again, adds at last Surfactant OP-10 when stirring, and stirs to stop after 25 minutes, can make fertilizer of the present invention.
Mechanism of action of the present invention is, by plant leaf surface being sprayed fertilizer of the present invention, replenishing the synthetic precursor composition of chlorophyll to plant is organic acid or organic acid salt, then in plant corpus, produce chlorophyll through series of biochemical reactions, thereby increase the amount of plant corpus inner chlorophyll, improve photosynthesis, produce more organic matter, directly required for plant growth, also can be exchanged into sucrose, starch, toss about in bed the plant nutrient substances such as synthetic protein and lipid.
Below in conjunction with experiment fertilizer efficiency of the present invention is described in further detail:
In April, 2007~November, the complex experiment basic point is tested in loess plateau, Xibei Univ. of Agricultural ﹠ Forest Science ﹠ Technology Qian County.Test soil is black mature soil, soil organic matter content 10.8gkg -1, available nitrogen is 39mgkg -1, available phosphorus is 12.3m gkg -1, effectively potassium is 102mgkg -18 years apple cultivation time, apple density is 2m * 3m, and quality is red rich No. one, and fertilization for apple is every strain urea 0.35kg, and phosphate fertilizer is superphosphate, every strain 0.40kg, and potash fertilizer is potassium sulphate, every strain 0.45kg.
Test minutes four groups, three groups for spraying fertilizer provided by the invention, concentration respectively 0.3%, 0.50% and 0.7%, another group is control group (spray clear water).The time of spraying is full-bloom stage and young fruit period secondary.Per 6 strain apple trees are one group, repeat 3 times, measure the indexs such as fruit tree leaf amount of growth, shoot growth amount, apple production and sugar content.
Result of the test shows:
One, the leaves of four groups of tests on the apple trees are observed, and the every strain of arbitrary extracting sets 200 leaves, measures length and the Breadth Maximum of every leaf, calculate the mean value of every group of monolithic leaf length and Breadth Maximum, add up as shown in table 1:
Table 1, apple tree spray the leaf growth situation behind the fertilizer of the present invention
Process Length of blade (cm) Blade Breadth Maximum (cm) Leaf color Blade gloss
CK 8.4 5.8 Green Thin, mattness
0.3% 9.4 5.9 Dark green Thick, surperficial glossy
0.5% 9.5 7.0 Dark green Thick, surperficial glossy
0.7% 9.6 6.6 Dark green Thick, surperficial glossy
Two, vertical footpath and the transverse diameter of the apple on four groups of test apple trees are measured, and calculated the mean value of the vertical footpath of every group of single apple and transverse diameter; Distinguish again individual plant apple production in four groups of apple trees of weighing, calculate the mean value of every group of individual plant apple production, add up as shown in table 2:
Table 2, spray behind the fertilizer of the present invention impact on fruit individuality and single plant yield
Process The vertical footpath of fruit (cm) Fruit transverse diameter (cm) Single plant yield (kg) Volume increase (%)
CK 5.96 6.65 25.0
0.3% 6.51 6.64 29.2 16.8
0.5% 6.46 7.19 33.7 34.8
0.7% 5.58 7.00 38.2 52.8
Statistics shows, sprays fertilizer of the present invention with respect to spray clear water control group, and the single plant yield of apple has increased by 16.8%~52.8%.
Three, to the length of all innovations on four groups of test apple trees with slightly measure, calculate the long and thick mean value of every group of single innovation, add up as shown in table 3:
Table 3, spray fertilizer apple new life's of the present invention shoot growth quantitative change
Process Innovation long (cm) Innovation thick (cm)
CK 85.1 0.635
0.3% 58.7 0.612
0.5% 57.6 0.515
0.7% 43.2 0.476
Statistics shows, apple tree sprays the shoot growth amount generation significant change of apple new life behind the fertilizer of the present invention, and innovation shortens and attenuates, and has saved a large amount of organic nutrients.
Four, to four groups of test apple trees, 100 leaves are set in the every strain of arbitrary extracting, weigh after drying, and calculate the mean value of every group of 100 leaf dry weights, add up as shown in table 4:
Table 4, spray fertilizer of the present invention to the impact of Apple Leaves dry weight
Process Blinds dry weight (g)
CK 25
0.3% 30
0.5% 36
0.7% 32
Statistics shows, sprays fertilizer of the present invention with respect to spray clear water control group, and Apple Leaves blinds dry weight obviously increases, and illustrates that blade Determination of Chlorophyll and organic nutrient obviously increase.
Five, the sugar content of all apples on four groups of test apple trees is measured, is calculated the mean value of every group of single apple sugar content, add up as shown in table 5:
Table 5, spray fertilizer of the present invention the apple sugar content is changed
Process Sugar content (%)
CK 15%
0.3% 17%
0.5% 16%
0.7% 18%
Statistics shows, spray fertilizer of the present invention after the apple sugar content increase, sugar content improves 1.2%~3.1%, has improved the quality of apple.

Claims (4)

1. a fertilizer that improves chlorophyll content of plant is characterized in that, by mass percentage, is comprised of following component: 1%~40% organic acid or organic acid salt, the bleeding agent of 1%~12% Surfactant OP-10,1%~20%, 30%~85% water; Above each component mass percent summation is 100%;
Described organic acid chemical structural formula is:
R-COOH
In the formula, R is: CH 3CH 2, CH 3CO, CH 3COCH 2CH 2, CH 3CHNH 2Or H 2NCH 2COCH 2CH 2
The chemical structural formula of described organic acid salt is:
R-COOA
In the formula, R is: CH 3CH 2, CH 3CO, CH 3COCH 2CH 2, CH 3CHNH 2Or H 2NCH 2COCH 2CH 2
A is: Fe, Zn, Mn, Cu, Ca or Mg;
Described bleeding agent is that concentration is that 98% ethylene glycol, concentration are that 95% HP-1 or concentration are a kind of in 98% the dimethyl sulfoxide (DMSO), or any two kinds of mixtures that mix take mass ratio as 1:1.
2. a kind of fertilizer that improves chlorophyll content of plant according to claim 1 is characterized in that, by mass percentage, formed by following component: 5%~34% organic acid or organic acid salt, the bleeding agent of 1%~8% Surfactant OP-10,4%~15%, 50%~80% water; Above each component mass percent summation is 100%.
3. described a kind of preparation method who improves chlorophyll content of plant fertilizer according to claim 1 is characterized in that, carries out according to the following steps:
Step 1,
By mass percentage, take by weighing 1%~40% organic acid or organic acid salt, the bleeding agent of 1%~12% Surfactant OP-10,1%~20%, 30%~85% water; Above each component mass percent summation is 100%;
Described organic acid chemical structural formula is:
R-COOH
In the formula, R is: CH 3CH 2, CH 3CO, CH 3COCH 2CH 2, CH 3CHNH 2Or H 2NCH 2COCH 2CH 2
The chemical structural formula of described organic acid salt is:
R-COOA
In the formula, R is: CH 3CH 2, CH 3CO, CH 3COCH 2CH 2, CH 3CHNH 2Or H 2NCH 2COCH 2CH 2
A is: Fe, Zn, Mn, Cu, Ca or Mg;
Described bleeding agent is that concentration is that 98% ethylene glycol, concentration are that 95% HP-1 or concentration are a kind of in 98% the dimethyl sulfoxide (DMSO), or any two kinds of mixtures that mix take mass ratio as 1:1;
Step 2,
In reactor, add entry, begin to stir, when stirring, in water, add first organic acid or organic acid salt, stir and dissolved fully to organic acid or organic acid salt in 20~90 minutes; Continuation adds bleeding agent in whipping process again, stirs 10~60 minutes again, adds at last surfactant when stirring, and stirs to stop after 10~30 minutes, namely makes the fertilizer of raising chlorophyll content of plant.
4. described a kind of preparation method who improves chlorophyll content of plant fertilizer according to claim 3 is characterized in that, carries out according to the following steps:
Step 1,
By mass percentage, take by weighing 5%~34% organic acid or organic acid salt, the bleeding agent of 1%~8% Surfactant OP-10,4%~15%, 50%~80% water; Above each component mass percent summation is 100%;
Described organic acid chemical structural formula is:
R-COOH
In the formula, R is: CH 3CH 2, CH 3CO, CH 3COCH 2CH 2, CH 3CHNH 2Or H 2NCH 2COCH 2CH 2
The chemical structural formula of described organic acid salt is:
R-COOA
In the formula, R is: CH 3CH 2, CH 3CO, CH 3COCH 2CH 2, CH 3CHNH 2Or H 2NCH 2COCH 2CH 2
A is: Fe, Zn, Mn, Cu, Ca or Mg;
Described bleeding agent is that concentration is that 98% ethylene glycol, concentration are that 95% HP-1 or concentration are a kind of in 98% the dimethyl sulfoxide (DMSO), or any two kinds of mixtures that mix take mass ratio as 1:1;
Step 2,
In reactor, add entry, begin to stir, when stirring, in water, add first organic acid or organic acid salt, stir and dissolved fully to organic acid or organic acid salt in 20~90 minutes; Continuation adds bleeding agent in whipping process again, stirs 10~60 minutes again, adds at last surfactant when stirring, and stirs to stop after 10~30 minutes, namely makes the fertilizer of raising chlorophyll content of plant.
CN 200910219150 2009-11-25 2009-11-25 Fertilizer for enhancing chlorophyll content of plant and preparation method thereof Expired - Fee Related CN101811906B (en)

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102424628B (en) * 2011-09-06 2013-09-11 陕西喜嘉旺生物科技有限责任公司 Fertilizer for increasing autologous nutrition of plants and preparation method thereof
CN104058798A (en) * 2014-06-10 2014-09-24 陕西喜嘉旺生物科技有限责任公司 Organic magnesium fertilizer and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1084151A (en) * 1993-10-11 1994-03-23 戴希泽 A kind of fruit tree leaves leaven
CN1110896A (en) * 1994-04-26 1995-11-01 刘建新 High efficient composite fertilizer with farm chemicals for forest and fruit trees
CN1834067A (en) * 2005-03-15 2006-09-20 广东省生态环境与土壤研究所 Special boron/molybdic fertilizer for peanut and prepn. thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1084151A (en) * 1993-10-11 1994-03-23 戴希泽 A kind of fruit tree leaves leaven
CN1110896A (en) * 1994-04-26 1995-11-01 刘建新 High efficient composite fertilizer with farm chemicals for forest and fruit trees
CN1834067A (en) * 2005-03-15 2006-09-20 广东省生态环境与土壤研究所 Special boron/molybdic fertilizer for peanut and prepn. thereof

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