CN101805934B - Ice-cold viscose fiber and preparation method thereof - Google Patents
Ice-cold viscose fiber and preparation method thereof Download PDFInfo
- Publication number
- CN101805934B CN101805934B CN201010140262XA CN201010140262A CN101805934B CN 101805934 B CN101805934 B CN 101805934B CN 201010140262X A CN201010140262X A CN 201010140262XA CN 201010140262 A CN201010140262 A CN 201010140262A CN 101805934 B CN101805934 B CN 101805934B
- Authority
- CN
- China
- Prior art keywords
- viscose
- mica
- preparation
- spinning
- cool
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920000297 Rayon Polymers 0.000 title claims abstract description 79
- 238000002360 preparation method Methods 0.000 title claims abstract description 35
- 239000000835 fiber Substances 0.000 title claims abstract description 24
- 239000010445 mica Substances 0.000 claims abstract description 84
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 84
- 239000000843 powder Substances 0.000 claims abstract description 52
- 238000009987 spinning Methods 0.000 claims abstract description 43
- 239000002002 slurry Substances 0.000 claims abstract description 35
- 230000001112 coagulating effect Effects 0.000 claims abstract description 29
- 239000003292 glue Substances 0.000 claims abstract description 29
- 239000003398 denaturant Substances 0.000 claims abstract description 16
- 239000002270 dispersing agent Substances 0.000 claims abstract description 16
- 239000004094 surface-active agent Substances 0.000 claims abstract description 13
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 8
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 8
- 241001330002 Bambuseae Species 0.000 claims abstract description 8
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 8
- 239000011425 bamboo Substances 0.000 claims abstract description 8
- 238000001914 filtration Methods 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 18
- 238000000465 moulding Methods 0.000 claims description 16
- 230000008569 process Effects 0.000 claims description 13
- 235000019270 ammonium chloride Nutrition 0.000 claims description 11
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 10
- 230000037396 body weight Effects 0.000 claims description 10
- 230000035800 maturation Effects 0.000 claims description 10
- 238000012805 post-processing Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- -1 amine cation Chemical class 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 8
- 238000004061 bleaching Methods 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 229920002678 cellulose Polymers 0.000 claims description 5
- 239000001913 cellulose Substances 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 238000007598 dipping method Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229920000768 polyamine Polymers 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- 238000010298 pulverizing process Methods 0.000 claims description 5
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 5
- 235000011152 sodium sulphate Nutrition 0.000 claims description 5
- 229910052626 biotite Inorganic materials 0.000 claims description 3
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052629 lepidolite Inorganic materials 0.000 claims description 3
- 229910052627 muscovite Inorganic materials 0.000 claims description 3
- 229910052628 phlogopite Inorganic materials 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 239000001488 sodium phosphate Substances 0.000 claims description 2
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 2
- 239000013638 trimer Substances 0.000 claims description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 abstract description 4
- 210000004243 sweat Anatomy 0.000 abstract description 4
- 230000036541 health Effects 0.000 abstract description 3
- 230000006750 UV protection Effects 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 239000002253 acid Substances 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 3
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 3
- 238000000498 ball milling Methods 0.000 description 3
- 230000015271 coagulation Effects 0.000 description 3
- 238000005345 coagulation Methods 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000032050 esterification Effects 0.000 description 3
- 238000005886 esterification reaction Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000002964 rayon Substances 0.000 description 3
- 238000004448 titration Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000007380 fibre production Methods 0.000 description 2
- 239000003507 refrigerant Substances 0.000 description 2
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical group [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
Abstract
The invention discloses a cool viscose fiber, which contains mica powder in an amount of 3-20 wt% of the dry weight of the fiber. The preparation method comprises the following steps: (1) adding a surfactant and a dispersant into mica powder to prepare mica slurry with the concentration of 16-30 wt%; (2) preparing viscose by using bamboo pulp as a raw material, wherein in the dissolving step, a dissolving denaturant is added; (3) mixing the mica slurry with 5-10 times of dissolved viscose; (4) adding the mica slurry prepared in the second time into the cured viscose glue in proportion, uniformly stirring, and then continuously defoaming and filtering to obtain a spinning solution; (5) spinning the spinning solution in a coagulating bath with spinning denaturant and spinning dispersant to form, drafting and post-treating to obtain the cold viscose fiber. The product of the invention has the health care functions of ultraviolet resistance, moisture absorption, sweat releasing and far infrared, and is particularly suitable for producing summer clothing products.
Description
Technical field
The present invention relates to the viscose technical field, relate in particular to a kind of cool viscose and preparation method thereof.
Background technology
The raising of Along with people's life & amusement level, outdoor exercises have become a kind of fashion, and people are also increasingly high to the requirement of sportswear lining, not only require comfortable and easy to wear, healthy, environmental protection, also require lining to have functional to outdoor environment.When human motion was perspired, common clothes can stick on the skin, and sweat can not in time be discharged, and the ultraviolet rate of blocking is approximately had only 70%, this can not satisfy far away people move out of doors in to the requirement of health.Therefore; In order to satisfy the superior and functionalization demand that people pursue garment material day by day; People are are researching and developing and variously can ensure outdoor exercises and healthy comfortable functional fiber; Can integrate and ice the dried soon and anti-ultraviolet function of refreshing cooling, moisture absorbing and sweat releasing, meet the functional fiber of the health demand of outdoor fashion motion.And viscose obtains people's acceptance and approval for a long time with wearability such as its excellent hygroscopicity, gas permeabilities, and therefore exploitation has the refreshing cooling of ice, moisture absorbing and sweat releasing is done soon and the viscose of anti-ultraviolet function also more and more receives people's attention.
Mica is a kind of ice-cold mineral powder, is stratiform silicate structure, and physico-chemical property is special, and chemical property own is stable: uvioresistant, high temperature resistant, hydrability strong, refraction brightness is high, and has pearly luster.Thin layer mica itself is clear, colorless fully, and its fusing point is spent up to 1300, and can not change fully in the following character of high temperature 550 degree; And the thermal conduction rate of sheet mica is high, adds nano mica surface charging lotus, so aquation is quite high; Be that moisture content is high, need more than 500 degree, just can water be removed, thus; High moisture, also drive cooling effect, so mica has a dual effect " high thermoconductivity+high endothermic effect ".
Although mica has excellent properties such as absorbing and cooling temperature, uvioresistant; Up to now, but having no talent links together mica and viscose, makes a kind of product have the advantage of two kinds of materials simultaneously; Make viscose have the refreshing function of refrigerant ice; Compare with common lining during with contact skin and can reduce temperature, the clothes comfortable feel of processing is nice and cool, even under scorching sun, wear still clearly comfortable.The cool fiber of developing in the market has only synthetic fiber.The inventor through big quantity research, combines viscose after the characteristic of having grasped two kinds of materials finally with mica, developed the mica cool viscose that has both characteristics simultaneously.
Summary of the invention
Technical problem to be solved by this invention provides a kind of cool viscose and preparation method thereof, and this product and the product through the preparation of this method have the refreshing cooling of ice, moisture absorption is ventilative and function such as uvioresistant.
For solving above-mentioned first technical problem, technical scheme of the present invention is:
Cool viscose contains the mica powder of 3～20wt% of fiber butt weight in said viscose.
Said mica powder is scattered in the surperficial and inner of said viscose; The particle diameter of said mica powder is less than 2 μ m; Said mica powder is biotite powder, muscovite powder, phlogopite powder, lepidolite powder or sericite powder.
Doing of said cool viscose is by force 1.7～3.0cN/dtex, and dried stretching is 9～18%.
For solving above-mentioned second technical problem, technical scheme of the present invention is:
The preparation method of cool viscose may further comprise the steps:
(1) mica slurry preparation: in the mica powder, add surfactant and dispersant, add deionized water again, being configured to concentration is the mica slurry of 16%～30wt%;
(2) viscose glue preparation: uses bamboo pulp to be raw material, make viscose glue, wherein in dissolving step, add and dissolve denaturant through comprising dipping, squeezing, pulverizing, experienced, yellow and dissolving step;
(3) secondary of mica slurry preparation: get by 5～10 times of mica slurry weight and to dissolve good viscose glue and mix grinding 60～140min with the mica slurry;
(4) preparation of spinning solution: carry out maturation to dissolving good viscose glue; And the mica slurry of secondary configuration accounted for the ratio of 3～20wt% of fiber butt weight in mica powder wherein; Join in the viscose glue in the maturation and stir, through deaeration continuously, filtration, obtain spinning solution then;
(5) spinning moulding:, and after strand drawing-off and post processing, make cool viscose with spinning solution spinning moulding in the coagulating bath that is added with spinning denaturant and spinning dispersant.
Wherein, when the mica slurry was prepared, the surfactant of said adding was an amine cation type surfactant, and addition is 0.1～0.5wt% of mica powder body weight; The dispersant of said adding is that silicon is cationoid surfactant or sodium phosphate trimer, and addition is 0.2～1.0wt% of mica powder body weight; Said dissolving denaturant is an alkyl polyamine, and addition is 1.2～2.0wt% of chemical cellulose weight in the viscose glue.
Preferably, when the mica slurry was prepared, the surfactant of said adding was two alkyl-dimethyl ammonium chlorides, and the dispersant of said adding is a polysiloxane quaternary ammonium.
The consisting of of coagulating bath during said spinning moulding: sulfuric acid 100～140g/l, sodium sulphate 320～350g/l; Said spinning denaturant is a polyethylene glycol, and content is 0.2～0.6wt% in coagulating bath; Said spinning dispersant is an amine cation type surfactant, and content is 0.1～0.4wt% in coagulating bath.
In said spinning step, the strand drawing-off comprises shower nozzle drawing-off → air bath drawing-off → first coagulating bath drawing-off → second coagulating bath drawing-off; Each drawing-off ratio is: shower nozzle drawing-off-10～1%, air bath drawing-off 20～65%, the first coagulating bath drawing-off 4～13%, the second coagulating bath drawing-off 3～16%.
Preferably, save bleaching process in the said post-processing step.
The mica powder that in said viscose, contains 3～20wt% of fiber butt weight; The particle diameter of said mica powder is less than 2 μ m; Said mica powder is biotite powder, muscovite powder, phlogopite powder, lepidolite powder or sericite powder; Doing of said cool viscose is by force 1.7～3.0cN/dtex, and dried stretching is 9～18%.
Owing to adopted technique scheme, the invention has the beneficial effects as follows:
1, the mica powder that uses of the present invention is the micron order mica; And dispose through secondary; In fiber, be uniformly dispersed, owing to the mica powder adds in fiber production process, so the mica powder is dispersed in the surperficial and inner of fiber; The ice-cold cooling-down effect of the cool viscose of producing does not receive the influence of clothing washing number of times, can forever keep refrigerant, smooth effect.
2, the present invention has all added dispersant in preparation of mica slurry and coagulating bath; Therefore dispersiveness and the compatibility of mica powder in viscose is good; The cool viscose of producing not only has outside the pure natural, degradable, softness, moisture absorption of bamboo fibre, viscose, the ventilative and excellent advantages such as dyeability, also has the high moisture absorption of cool fiber, absorbing and cooling temperature, uvioresistant and far health-care function.
3, the present invention prepares and has adopted viscose glue, coagulating bath complex denaturation technology in the process, and doing of prepared finished fiber is by force 1.7～3.0cN/dtex, driedly stretches 9～18%, and intensity is high, and textile processibility can be good.
4, the used coagulating bath of spinning moulding of the present invention has been cancelled human environment has been polluted big zinc sulfate, has reduced the environmental hazard of fiber production process.
5, aftertreatment technology of the present invention has saved the bleaching process of conventional production process of viscose fiber; Prevented that bleaching process from further damaging bamboo pulp and antibacterial substance wherein; Influence the function and the outward appearance of product, and reduced production cost, improved production efficiency.
The specific embodiment
Following examples only are used to explain the present invention, but do not limit protection scope of the present invention.
Embodiment 1 1.33dtex * 38mm cool viscose
(1) preparation of mica slurry: at particle diameter is in the mica powder of 0.9 μ m; The two alkyl-dimethyl ammonium chlorides of 0.3wt% that add the mica powder body weight; 0.5wt% polysiloxane quaternary ammonium with the mica powder body weight adds deionized water again, and being mixed with concentration is the mica slurry of 25wt%.
(2) viscose glue preparation: use bamboo pulp to be raw material; Through comprising that dipping, squeezing, pulverizing, experienced, yellow and dissolving step make viscose glue, in course of dissolution, add the denaturant alkyl polyamine; Addition is the 1.8wt% of chemical cellulose weight, then viscose glue is carried out maturation.
(3) secondary of mica slurry preparation: extraordinarily go into to have dissolved good viscose glue by 6 of mica slurry weight, place ball mill, ball milling 90min.
(4) preparation of spinning solution: the ratio that the mica slurry of secondary configuration is accounted for the 5wt% of fiber butt weight in mica powder wherein; Join before the deaeration in the viscose glue in the maturation and stir; Through deaeration rapidly, continuously and filtration, obtaining viscosity is 65s (being recorded by falling ball method), degree of ripeness 25ml (10%NH4Cl titration) then; Esterification degree 42 contains the modified rayon spinning solution of mica.
(5) spinning moulding: above-mentioned spinning solution is introduced spinning moulding in the coagulating bath; Coagulation bath composition and content are following: sulfuric acid 120g/l; Sodium sulphate 330g/l, the denaturant polyethylene glycol accounts for the 0.3wt% of acid bath gross weight, and the many alkyl trimethyl ammonium chlorides of dispersant account for the 0.3wt% of acid bath gross weight; The strand draft process is: shower nozzle drawing-off-10%, air bath drawing-off 60%, the first coagulating bath drawing-off 10%, the second coagulating bath drawing-off 15%; Fiber after the moulding makes cool viscose after strand drawing-off and post processing, wherein post-processing step saves bleaching process.
The dried strong 2.60cN/dtex of the cool viscose that makes driedly stretches 17.5%.
Embodiment 2 2.78dtex * 51mm cool viscose
(1) preparation of mica slurry: at particle diameter is in the mica powder of 1.2 μ m; The two alkyl-dimethyl ammonium chlorides of 0.4wt% that add the mica powder body weight; 0.7wt% polysiloxane quaternary ammonium with the mica powder body weight adds deionized water again, and being mixed with concentration is the mica slurry of 26wt%.
(2) viscose glue preparation: use bamboo pulp to be raw material; Through comprising that dipping, squeezing, pulverizing, experienced, yellow and dissolving step make viscose glue, in course of dissolution, add the denaturant alkyl polyamine; Addition is the 1.3wt% of chemical cellulose weight, then viscose glue is carried out maturation.
(3) secondary of mica slurry preparation: extraordinarily go into to have dissolved good viscose glue by 9 of mica slurry weight, place ball mill, ball milling 120min.
(4) preparation of spinning solution: the ratio that the mica slurry of secondary configuration is accounted for the 10wt% of fiber butt weight in mica powder wherein; Join before the deaeration in the viscose glue in the maturation and stir; Through deaeration rapidly, continuously and filtration, obtaining viscosity is 55s (being recorded by falling ball method), degree of ripeness 28ml (10%NH4Cl titration) then; Esterification degree 40 contains the modified rayon spinning solution of mica.
(5) spinning moulding: above-mentioned spinning solution is introduced spinning moulding in the coagulating bath; Coagulation bath composition and content are following: sulfuric acid 130g/l; Sodium sulphate 340g/l, the denaturant polyethylene glycol accounts for the 0.6wt% of acid bath gross weight, and the many alkyl trimethyl ammonium chlorides of dispersant account for the 0.2wt% of acid bath gross weight; The strand draft process is: shower nozzle drawing-off-5%, air bath drawing-off 54%, the first coagulating bath drawing-off 6%, the second coagulating bath drawing-off 10%; Fiber after the moulding makes cool viscose after strand drawing-off and post processing, wherein post-processing step saves bleaching process.
The dried strong 2.32cN/dtex of the cool viscose that makes driedly stretches 17.0%.
Embodiment 3 3.33dtex * 60mm cool viscose
(1) preparation of mica slurry: at particle diameter is in the mica powder of 1.8 μ m; The two alkyl-dimethyl ammonium chlorides of 0.5wt% that add the mica powder body weight; 0.4wt% polysiloxane quaternary ammonium with the mica powder body weight adds deionized water again, and being mixed with concentration is the mica slurry of 24wt%.
(2) viscose glue preparation: use bamboo pulp to be raw material; Through comprising that dipping, squeezing, pulverizing, experienced, yellow and dissolving step make viscose glue, in course of dissolution, add the denaturant alkyl polyamine; Addition is the 1.7wt% of chemical cellulose weight, then viscose glue is carried out maturation.
(3) secondary of mica slurry preparation: extraordinarily go into to have dissolved good viscose glue by 4 of mica slurry weight, place ball mill, ball milling 90min.
(4) preparation of spinning solution: the ratio that the mica slurry of secondary configuration is accounted for the 8wt% of fiber butt weight in mica powder wherein; Join before the deaeration in the viscose glue in the maturation and stir; Through deaeration rapidly, continuously and filtration, obtaining viscosity is 59s (being recorded by falling ball method), degree of ripeness 25ml (10%NH4Cl titration) then; Esterification degree 42 contains the modified rayon spinning solution of mica.
(5) spinning moulding: above-mentioned spinning solution is introduced spinning moulding in the coagulating bath; Coagulation bath composition and content are following: sulfuric acid 140g/l; Sodium sulphate 320g/l, the denaturant polyethylene glycol accounts for the 0.4wt% of acid bath gross weight, and the many alkyl trimethyl ammonium chlorides of dispersant account for the 0.4wt% of acid bath gross weight; The strand draft process is: shower nozzle drawing-off-8%, air bath drawing-off 39%, the first coagulating bath drawing-off 10%, the second coagulating bath drawing-off 14%; Fiber after the moulding makes cool viscose after strand drawing-off and post processing, wherein post-processing step saves bleaching process.
The dried strong 2.28cN/dtex of the cool viscose that makes driedly stretches 17.4%.
Claims (7)
1. the preparation method of cool viscose is characterized in that may further comprise the steps:
(1) mica slurry preparation: in the mica powder, add surfactant and dispersant, add deionized water again, being configured to concentration is the mica slurry of 16%～30wt%;
(2) viscose glue preparation: uses bamboo pulp to be raw material, make viscose glue, wherein in dissolving step, add and dissolve denaturant through comprising dipping, squeezing, pulverizing, experienced, yellow and dissolving step;
(3) secondary of mica slurry preparation: get by 5～10 times of mica slurry weight and to dissolve good viscose glue and mix grinding 60～140min with the mica slurry;
(4) preparation of spinning solution: carry out maturation to dissolving good viscose glue; And the mica slurry of secondary configuration accounted for the ratio of 3～20wt% of fiber butt weight in mica powder wherein; Join in the viscose glue in the maturation and stir, through deaeration continuously, filtration, obtain spinning solution then;
(5) spinning moulding:, and after strand drawing-off and post processing, make cool viscose with spinning solution spinning moulding in the coagulating bath that is added with spinning denaturant and spinning dispersant.
2. the preparation method of cool viscose as claimed in claim 1, it is characterized in that: when the mica slurry was prepared, the surfactant of said adding was an amine cation type surfactant, and addition is 0.1～0.5wt% of mica powder body weight; The dispersant of said adding is that silicon is cationoid surfactant or sodium phosphate trimer, and addition is 0.2～1.0wt% of mica powder body weight; Said dissolving denaturant is an alkyl polyamine, and addition is 1.2～2.0wt% of chemical cellulose weight in the viscose glue.
3. the preparation method of cool viscose as claimed in claim 2 is characterized in that: when the mica slurry was prepared, the surfactant of said adding was two alkyl-dimethyl ammonium chlorides, and the dispersant of said adding is a polysiloxane quaternary ammonium.
4. the preparation method of cool viscose as claimed in claim 1 is characterized in that: the consisting of of coagulating bath during said spinning moulding: sulfuric acid 100～140g/l, sodium sulphate 320～350g/l; Said spinning denaturant is a polyethylene glycol, and content is 0.2～0.6wt% in coagulating bath; Said spinning dispersant is an amine cation type surfactant, and content is 0.1～0.4wt% in coagulating bath.
5. the preparation method of cool viscose as claimed in claim 1, it is characterized in that: in said spinning step, the strand drawing-off comprises shower nozzle drawing-off → air bath drawing-off → first coagulating bath drawing-off → second coagulating bath drawing-off; Each drawing-off ratio is: shower nozzle drawing-off-10～1%, air bath drawing-off 20～65%, the first coagulating bath drawing-off 4～13%, the second coagulating bath drawing-off 3～16%.
6. like the preparation method of described any cool viscose of claim 1 to 5, it is characterized in that: save bleaching process in the said post-processing step.
7. the preparation method of cool viscose as claimed in claim 6 is characterized in that: the mica powder that in said viscose, contains 3～20wt% of fiber butt weight; The particle diameter of said mica powder is less than 2 μ m; Said mica powder is biotite powder, muscovite powder, phlogopite powder, lepidolite powder or sericite powder; Doing of said cool viscose is by force 1.7～3.0cN/dtex, and dried stretching is 9～18%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010140262XA CN101805934B (en) | 2010-04-02 | 2010-04-02 | Ice-cold viscose fiber and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010140262XA CN101805934B (en) | 2010-04-02 | 2010-04-02 | Ice-cold viscose fiber and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101805934A CN101805934A (en) | 2010-08-18 |
| CN101805934B true CN101805934B (en) | 2012-11-07 |
Family
ID=42607884
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010140262XA Active CN101805934B (en) | 2010-04-02 | 2010-04-02 | Ice-cold viscose fiber and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101805934B (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102277641A (en) * | 2010-06-12 | 2011-12-14 | 罗莱家纺股份有限公司 | Viscose cooling fiber filament and production method thereof |
| CN103726118B (en) * | 2012-02-26 | 2015-10-28 | 昆山华阳新材料股份有限公司 | For the medical fibre of X-ray-preventing |
| CN104195668B (en) * | 2014-08-19 | 2016-04-20 | 浙江华峰氨纶股份有限公司 | A kind of preparation method of multi-functional refrigerant polyurethane elastomeric fiber |
| CN104451929A (en) * | 2014-11-20 | 2015-03-25 | 江苏金太阳纺织科技有限公司 | Cooling regenerative cellulose fiber and preparation method thereof |
| CN104831374A (en) * | 2015-04-28 | 2015-08-12 | 苏州如盛化纤有限公司 | Fine-denier cool terylene FDY (Fully Drawn Yarn) filament yarn and production method thereof |
| CN104878517A (en) * | 2015-06-18 | 2015-09-02 | 青岛雪达集团有限公司 | Cool fibrous comfortable ecological knitted fabric and knitting method thereof |
| CN106222776B (en) * | 2016-07-27 | 2018-10-23 | 恒天海龙（潍坊）新材料有限责任公司 | A kind of jade is felt nice and cool regenerated celulose fibre and preparation method thereof |
| CN110835787B (en) * | 2019-12-13 | 2022-07-22 | 杭州华樾新材料有限公司 | Regenerated cellulose fiber and preparation method thereof |
| CN112663160A (en) * | 2020-12-05 | 2021-04-16 | 恒天海龙（潍坊）新材料有限责任公司 | Preparation method of flame-retardant cool cellulose fiber for summer curtain |
| CN114318570B (en) * | 2021-12-16 | 2024-04-09 | 苏州宝丽迪材料科技股份有限公司 | Preparation method and application of liquid master batch for cool viscose fiber |
| CN114351271B (en) * | 2021-12-24 | 2023-10-13 | 唐山三友集团兴达化纤有限公司 | Water-meeting transparent viscose fiber and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1332276A (en) * | 2001-08-14 | 2002-01-23 | 东华大学 | Health type viscose fiber with high wet modulus and its production process and use |
| CN1614106A (en) * | 2004-09-09 | 2005-05-11 | 上海树铭纺织科技有限公司 | Visose rayon with textile function and preparation thereof |
| CN1793447A (en) * | 2005-12-29 | 2006-06-28 | 山东海龙股份有限公司 | Method for producing viscose fiber by using zinc-free coagulating bath |
| CN1888158A (en) * | 2005-06-30 | 2007-01-03 | 上海弘康科技发展有限公司 | Far infrared antiseptic health care fiber with anion and producing method thereof |
| CN101665986A (en) * | 2009-09-28 | 2010-03-10 | 海安县中山合成纤维有限公司 | Mica chinlon cool fiber filament and production method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI119327B (en) * | 2004-06-02 | 2008-10-15 | Sateri Internat Co Ltd | Process for manufacturing silk-containing fiber |
-
2010
- 2010-04-02 CN CN201010140262XA patent/CN101805934B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1332276A (en) * | 2001-08-14 | 2002-01-23 | 东华大学 | Health type viscose fiber with high wet modulus and its production process and use |
| CN1614106A (en) * | 2004-09-09 | 2005-05-11 | 上海树铭纺织科技有限公司 | Visose rayon with textile function and preparation thereof |
| CN1888158A (en) * | 2005-06-30 | 2007-01-03 | 上海弘康科技发展有限公司 | Far infrared antiseptic health care fiber with anion and producing method thereof |
| CN1793447A (en) * | 2005-12-29 | 2006-06-28 | 山东海龙股份有限公司 | Method for producing viscose fiber by using zinc-free coagulating bath |
| CN101665986A (en) * | 2009-09-28 | 2010-03-10 | 海安县中山合成纤维有限公司 | Mica chinlon cool fiber filament and production method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101805934A (en) | 2010-08-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101805934B (en) | Ice-cold viscose fiber and preparation method thereof | |
| CN105908269B (en) | Manufacturing method of special-shaped hollow warmth keeping polyester drawn textured yarn | |
| CN106087100B (en) | A kind of fused mass directly spinning adds the manufacture method of color silk online | |
| CN105970327B (en) | A kind of health care regenerated celulose fibre containing stone needle and preparation method thereof | |
| CN105876949B (en) | A kind of fabric for sportswear and preparation method thereof | |
| CN102845844A (en) | Method for preparing far infrared healthcare underwear fabric | |
| CN102691132B (en) | Microcapsule-type aloe blending regeneration cellulose fiber and its preparation method | |
| CN107254720A (en) | A kind of far-infrared anti-biotic organic silazane fire resistance fibre and its production method | |
| CN105887279B (en) | A kind of wash-and-wear of shirt fabric and preparation method thereof | |
| CN101851803B (en) | Health-care function viscose fiber and preparation method thereof | |
| CN104233509A (en) | Down feather composite fibers with anion polyester staple fibers and production method thereof | |
| CN112553709A (en) | ES macrobio fiber containing wormwood active ingredient | |
| CN105821503A (en) | Pearl antifungal fiber containing multiple amino acids and microelement and preparing method thereof | |
| CN103898626A (en) | Polyester fiber with heat-conduction and moisture-conduction functions and production method of polyester fiber | |
| CN111155185A (en) | Functional slurry containing jade powder and pearl powder for blending textile fibers and preparation method thereof | |
| CN105996159B (en) | A kind of multifunctional movement brassiere blended yarn weaved fabric and preparation method thereof | |
| CN104532379A (en) | Preparation method of nano-antibacterial bamboo carbon fiber | |
| CN102121143A (en) | C-shaped bamboo charcoal mixed ester fibers and preparation method thereof | |
| CN105901782B (en) | A kind of preparation method of pearl antibacterial deodourizing socks | |
| CN103668519B (en) | A kind of Multifunctional cellulose fiber and preparation method thereof | |
| CN104947221A (en) | Spinnable ecological bacteriostatic down fiber and making method thereof | |
| CN104499072A (en) | Nano antibacterial bamboo charcoal fibers | |
| CN207449262U (en) | A kind of novel and multifunctional mixed goods fabric | |
| CN104928780A (en) | Heat-storage warm-keeping ecological antibacterial down fiber and preparation method thereof | |
| CN104233507A (en) | Silk composite fibers with deodorizing function and manufacturing method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20151225 Address after: Dragon Road, 261100 Shandong city of Weifang province Hanting District No. 1825 Building No. 89 Patentee after: Constant day dragon (Weifang) new material Co., Ltd. Address before: 555 Shandong Hailong Limited by Share Ltd, Hailong Road, Hanting District, Shandong, Weifang 261100, China Patentee before: Shandong Hailong Co., Ltd. |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20220520 Address after: 261106 north of Xinsha Road, Guti street, Hanting District, Weifang City, Shandong Province Patentee after: Weifang Xinlong biomaterials Co.,Ltd. Address before: 261100 building 89, 1825 Hailong Road, Hanting District, Weifang City, Shandong Province Patentee before: HENGTIAN HAILONG (WEIFANG) NEW MATERIALS CO.,LTD. |
|
| TR01 | Transfer of patent right |