CN1332276A - Health type viscose fiber with high wet modulus and its production process and use - Google Patents
Health type viscose fiber with high wet modulus and its production process and use Download PDFInfo
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- CN1332276A CN1332276A CN 01126469 CN01126469A CN1332276A CN 1332276 A CN1332276 A CN 1332276A CN 01126469 CN01126469 CN 01126469 CN 01126469 A CN01126469 A CN 01126469A CN 1332276 A CN1332276 A CN 1332276A
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Abstract
The present invention is composed of cellulose and chitin with weight ration 2-9:0.02-2. Alkalifying and etiolating cellulose and chitin obtain the xanthogenate of cellulose and chitin. Dissolving the said xanthogenate of cellulose and chitin in sodium of hydroxide and water makes spinning dope. Using wet spinning or wet pipe forming methods, after drawing procedure makes the fiber. The physical and mechanical performance of the fiber can be enhanced after treatment with simple technique. The fiber can fabricate textile and cloth providing features of antibiosis, stopping itch and bleeding, odor dispelling. Fibrous membrane made by mixed cellulose with chitin as raw material can be used in artificial organs or water purifier.
Description
Technical field:
The present invention relates to a kind of artificial fibre, specifically a kind of health type viscose fiber with high wet modulus, manufacturing technology and be used to make the purposes of health care fabric or hollow-fibre membrane.
Background technology:
Chitin was found from mould by French scientist Braconnot as far back as 1811, but owing in the common solvents such as chitin is water insoluble, rare bronsted lowry acids and bases bronsted lowry, limited its application performance.Up to 20th century the fifties, just chemical constitution, performance and the manufacture method to chitin had more thorough understanding, finds that chitin can adopt the yellow method to make xanthate acid and be dissolved in the diluted alkaline, thereby enlarged the scope of its application.
Chitin and derivative thereof are with health role, and along with improving constantly of living standard and quality, people are also growing to the demand of health care fabric, and the health care fibre material that is used to make health care fabric has become important research project.
Summary of the invention:
The purpose of this invention is to provide a kind of health type viscose fiber with high wet modulus.
Another object of the present invention provides the manufacture method of above-mentioned health type viscose fiber with high wet modulus.
Purpose of the present invention also provides the purposes of above-mentioned health type viscose fiber with high wet modulus, promptly is used to make health care fabric or hollow-fibre membrane etc.
Health type viscose fiber with high wet modulus of the present invention is made up of cellulose and chitin, and its weight ratio is followed successively by 2～9: 0.02～2.The fiber dry strength of this viscose is 2.5～3CN/dtex, and wet strength is 2～2.5CN/dtex, and ductility is 12～15%.
The manufacture method of health type viscose fiber with high wet modulus of the present invention, system is made up of cellulose xanthate, chitin xanthate acid, NaOH and water, their weight ratio is followed successively by 2～9: 0.02～2: 4～15: 75～90, to become spinning solution after the above-mentioned substance blend, adopt that forming process makes fiber in wet spinning or the wet method pipe, again through comprise the commonly used stretching of one or more combination such as jet stretch, godet stretchings, Pyatyi stretching, plasticization drawing, air bath after-drawing or retraction in being stretching in, concise, dry and form.
Concrete manufacture method of the present invention comprises following method: under-10 ℃～95 ℃, chitin generated the alkali chitin in 1～5 hour through 10～50% sodium hydrate aqueous solution alkalization, pressed dry back and CS
2Generated chitin xanthate acid, wherein chitin, NaOH and CS in 1～2 hour 0～30 ℃ of reaction
2Weight ratio be 0.02～2: 0.08～8: 0.06～1.8.
At room temperature, the cotton pulp dregs of rice were generated alkali cellulose in 0.5～2 hour through the alkalization of 10～50% the NaOH aqueous solution, the last pressing dry at room temperature aging 10～20 hours, again with CS
2React and generated cellulose xanthate in 0.5～2 hour, wherein the cotton pulp dregs of rice are 1: 3～30 with above-mentioned sodium hydroxide solution weight ratio, adopt more NaOH to this reaction less than influencing.
With the above-mentioned abundant blend of chitin xanthate acid, cellulose xanthate, NaOH and water, their weight ratio is followed successively by 0.02～2: 2～9: 4～15: 75～90, become heterogeneous spinning solution after the blend.
Perhaps in the time of-10～95 ℃, be that 2～9: 0.02～2 the cotton pulp dregs of rice, chitin are immersed in 10～50% the sodium hydrate aqueous solution 0.1～5 hour with weight ratio, bath raio is 1: 15～25, be depressed into 2.5～5 times of pulverizing of dry weight, wore out 8～30 hours in the time of 10～40 ℃, vacuumize, add CS
25～40 ℃ of following yellows 1～4 hour, it is 0.02～2: 2～9 that adding NaOH and water-soluble, blend are made into chitin xanthate acid, cellulose xanthate, NaOH and water weight ratio: 4～15: 75～95 spinning solution, described water are soft water or frozen water.High polymer weight is generally 4～10% better in the spinning solution.
The DP of aforesaid cellulose cotton pulp can be 400～1300, chemical cellulose content 〉=90% in the pulp; Chitin η=20～350cps, granularity≤4mm, purity 〉=90%, protein≤0.5%, ash≤1%.
Can adopt in wet spinning or the wet method pipe method of forming to make fiber, with above-mentioned spinning solution in spinning head is pressed into 5～70 ℃ coagulating bath, described coagulating bath is by 28～150g/L sulfuric acid, 40～350g/L sodium sulphate and 0.8～80g/L zinc sulfate are formed, through after the spinning, chitin xanthate acid and cellulose xanthate are under the effect of acid, be regenerated as the koplon that chitin and cellulose are formed, also can be made into common Pori's nosik (Polynosic) type, the health viscose of permanent curl type.Wherein the solution circulated amount is 10～100 liters/minute. ingot.
Above-mentioned health viscose can make chitin mainly be distributed in the appearance of fiber by the control spinning technique, to give full play to the health care of chitin, improves the mechanical property of fiber.Above-mentioned fiber is through (plus or minus) jet stretch, godet stretching, Pyatyi stretching, plasticization drawing, air bath after-drawing or suitable retraction etc.Adopt above-mentioned one or more, several or all combination stretch, making total drawing ratio is 20～200%, spinning speed 10～120m/min carries out refining processing through various solution, thoroughly to remove the various impurity in the fiber.The blended fiber of new spinning is finished fiber after the oven dry that oils.The physical and mechanical properties of fiber is similar to the viscose of suitable kind.
Described refining processing generally is the step with hot water wash, alkali cleaning, washing, pickling, washing, bleaching and washing.
Health type viscose fiber with high wet modulus of the present invention, not only manufacture method is easy, is suitable for suitability for industrialized production.And, by its fabric of making, microbiology class such as Gram-positives such as staphylococcus aureus, Escherichia coli, negative bacterium had certain antibiotic validity, through repeatedly washing, still have certain antibacterial action, promptly have antibiotic durability (washing stability).Adopt the made fabric feeling of blended fiber full.The fabric of health care fibre cellulose fiber can be made into various clothes, particularly underskirt, have certain antipruritic, smelly, hemostasis effects such as (little hemorrhage because of scratching) disappears.Blended fiber can be made underwear, handkerchief, can be made into various garment materials through blending or pure spinning.Also can be made into film and be used for many-sided purposes such as manufacture of intraocular internal organs, hydrotreater.
The specific embodiment:
The present invention will be helped further to understand by following embodiment, but this can not be placed restrictions on Bright content.
Embodiment 1:
Be 0.3 part of chitin and 6 parts of concentration that 45% the NaOH aqueous solution adds in the container Row alkalization 2 hours, 20 ℃ of alkalization temperatures. The alkali chitin that generates is through squeezing to 4 of dry weight Doubly. Drop into after crushed and carry out yellow in the xanthating machine. Add 4 parts of trash ices, take out true in the xanthating machine Add CS after empty20.2 part, 100 minutes yellow time, temperature-20 ℃. Yellow adds after finishing Enter 4 parts of water and dissolved 3 hours, solution temperature is 10 ℃, the chitin xanthate acid of making Solution left standstill is stand-by.
Other gets 6 parts of Cotton Pulps (DP=900) and 120 parts of concentration is that 20% NaOH is water-soluble Liquid adds in the container and alkalized 1 hour, and temperature is 20 ℃, the alkali cellulose warp of generation Squeeze to 3 times of dry weight, after crushed 20 ℃ of lower wearing out 16 hours, then at xanthating machine Middle yellow 60 minutes, temperature is 20 ℃. CS2Addition is 2.3 parts. Yellow adds after finishing Enter 79.7 parts of dilute alkaline aqueous solutions, make the cellulose xanthate acid be dissolved into solution, temperature is 15 ℃, It is little to add the stand-by chitin xanthate acid solution continuation stirring 2 of above-mentioned preparation after stirring 3 hours The time after make the cellulose blend solution (or claim blend viscose glue) of chitin. Viscose glue after filtration Afterwards in temperature was 18 ℃ container, deaeration and maturation were 18 hours under vacuum.
Above-mentioned viscose glue is pressed through candle shape filter and spinning head after the measuring pump metering and is entered coagulating bath. Solidifying Consist of Gu bathe: sulfuric acid 60g/L; Zinc sulfate 60g/L; Sodium sulphate 120g/L. Strand is through drawing After stretching 90%, carry out post processing with various body lotions.
The dry strength that makes health type viscose fiber with high wet modulus is 2.8cN/dtex, and wet strength is 2.1cN/dtex; Ductility is 14%; And have functions such as antibiotic, antipruritic, smelly eliminating, hemostasis.
Embodiment 2
With the raw material of cellulose 2～9kg, chitin 0.02～2kg, at-10～95 ℃, 10～50% Flood 10～300min in the sodium hydroxide solution, bath raio is 1: 15～25, squeezes to dry weight 2.5～5 times, through shattering, aging through 8～30 hours under 10～40 ℃. Vacuumize then, Add 20～90% (for raw material) CS2, under 5～25 ℃ through 1～4 hour yellow, The yellow bath raio should be decided on the method and the raw material that adopt. Add again an amount of alkali lye and soft water or broken Ice dissolves, and namely gets high polymer content and be 4～10% spinning solution. Being total to of two kinds of high polymers Mixed can when yellow, dissolving, carrying out; After also can making solution respectively, carry out again the solution blend. Adopt then wet spinning to make the blend koplon.
Spinning solution is pressed in the coagulating bath, and spinning pressure is 0.2～0.6Mpa, sulphur in the coagulating bath Acid content is 28～150g/L, and sodium sulphate content is 40～350g/L, zinc sulfate content 0.8～10g/L. 5～70 ℃ of coagulation bath temperatures, body lotion internal circulating load 10～100L/min. ingot can be made Get the high wet modulus type, also can be made into plain edition, Pori's nosik (Polynosic) type, permanent The health viscose rayon of curled. By the control spinning technique, make chitin and derivative thereof Mainly be distributed in the appearance of blended fiber, to give full play to the health care merit of chitin and derivative thereof Can, and the mechanical property that improves fiber.
Claims (7)
1. a health type viscose fiber with high wet modulus is characterized in that being made up of cellulose and chitin, and its weight ratio is followed successively by 2～9: 0.02～2.
2. the manufacture method of a health type viscose fiber with high wet modulus as claimed in claim 1 is characterized in that perhaps the method for (4) and (5) is made by following (1), (2), (3) and (5):
(1) under-10 ℃～95 ℃, chitin generated the alkali chitin in 1～5 hour through 10～15% sodium hydrate aqueous solution alkalization, pressed dry back and CS
2Generated chitin xanthate acid, wherein chitin, NaOH and CS in 1～2 hour 0～-30 ℃ of reaction
2Weight ratio be 0.02～2: 0.08～8: 0.06～1.8;
(2) at room temperature, the cotton pulp dregs of rice generated alkali cellulose in 0.2～2 hour through 10～50% sodium hydrate aqueous solution alkalization, at room temperature wore out 10～20 hours after pressing dry, again with CS
2React 0.5～2 hour generation cellulose xanthate, wherein the weight ratio of the cotton pulp dregs of rice and sodium hydrate aqueous solution is 1: 3～30;
(3) be to carry out blend at 0.02～2: 2～9: 4～15: 75～90 by weight with (1) and (2) described chitin xanthate acid, cellulose xanthate, NaOH and water, become spinning solution;
(4) in the time of-10～95 ℃ be that 2～9: 0.02～2 the cotton pulp dregs of rice, chitin are immersed in 10～50% the sodium hydrate aqueous solution 0.1～5 hour with weight ratio, bath raio is 1: 5～25, press dry, pulverize, 10～40 ℃ aging 8～30 hours, add CS
25～40 ℃ of following yellows 1～4 hour, add NaOH and become spinning solution with water-soluble;
(5) (3) or (4) described spinning solution is pressed into through spinning head to bathe temperature be that described coagulating bath is made up of 28～150g/L sulfuric acid, 40～350g/L sodium sulphate and 0.8～80g/L zinc sulfate in 5～70 ℃ the coagulating bath.
3. the manufacture method of health type viscose fiber with high wet modulus as claimed in claim 2, the combination that it is characterized in that again one or more in comprising jet stretch, godet stretching, Pyatyi stretching, plasticization drawing, air bath after-drawing or being retracted in stretches, concise, oil, dry, wherein total drawing ratio is 20～200%.
4. the manufacture method of health type viscose fiber with high wet modulus as claimed in claim 3, it is characterized in that described concise be hot water wash, alkali cleaning, washing, pickling, washing, bleaching and washing.
5. the manufacture method of health type viscose fiber with high wet modulus as claimed in claim 2 is characterized in that adding CS
2Before vacuumize earlier.
6. the purposes of a health type viscose fiber with high wet modulus as claimed in claim 1, it is characterized in that being used to make antibiotic, antipruritic, fabric, handkerchief or underwear or clothes smelly, hemostasis disappear.
7. one kind can be spun into hollow-fibre membrane as claim 1 and the 2 described spinning solutions of being made up of cellulose and chitin, it is characterized in that being used for the film of using of manufacture of intraocular internal organs and water purifier.
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| Application Number | Priority Date | Filing Date | Title |
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| CNB011264691A CN1164807C (en) | 2001-08-14 | 2001-08-14 | Health type viscose fiber with high wet modulus and its production process and use |
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| Application Number | Priority Date | Filing Date | Title |
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| CNB011264691A CN1164807C (en) | 2001-08-14 | 2001-08-14 | Health type viscose fiber with high wet modulus and its production process and use |
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| CN1332276A true CN1332276A (en) | 2002-01-23 |
| CN1164807C CN1164807C (en) | 2004-09-01 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1302012C (en) * | 2004-10-18 | 2007-02-28 | 保定天鹅股份有限公司 | Xanthating method used in viscous fiber production |
| CN101805934A (en) * | 2010-04-02 | 2010-08-18 | 山东海龙股份有限公司 | Ice-cold viscose fiber and preparation method thereof |
| CN101545150B (en) * | 2009-04-30 | 2011-01-05 | 郑睿敏 | Method for manufacturing modal fiber |
| CN101591814B (en) * | 2009-05-25 | 2011-03-16 | 郑睿敏 | Method for manufacturing high wet modulus fiber |
| CN102817092A (en) * | 2012-08-01 | 2012-12-12 | 太仓市天翔化纤有限公司 | Health-care viscose fibers |
| CN106757462A (en) * | 2016-12-15 | 2017-05-31 | 山东银鹰化纤有限公司 | A kind of preparation method for inhaling color Hollow Viscose Fiber |
| CN109267165A (en) * | 2018-07-26 | 2019-01-25 | 阜宁澳洋科技有限责任公司 | A kind of koplon and preparation method thereof |
-
2001
- 2001-08-14 CN CNB011264691A patent/CN1164807C/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1302012C (en) * | 2004-10-18 | 2007-02-28 | 保定天鹅股份有限公司 | Xanthating method used in viscous fiber production |
| CN101545150B (en) * | 2009-04-30 | 2011-01-05 | 郑睿敏 | Method for manufacturing modal fiber |
| CN101591814B (en) * | 2009-05-25 | 2011-03-16 | 郑睿敏 | Method for manufacturing high wet modulus fiber |
| CN101805934A (en) * | 2010-04-02 | 2010-08-18 | 山东海龙股份有限公司 | Ice-cold viscose fiber and preparation method thereof |
| CN101805934B (en) * | 2010-04-02 | 2012-11-07 | 山东海龙股份有限公司 | Ice-cold viscose fiber and preparation method thereof |
| CN102817092A (en) * | 2012-08-01 | 2012-12-12 | 太仓市天翔化纤有限公司 | Health-care viscose fibers |
| CN106757462A (en) * | 2016-12-15 | 2017-05-31 | 山东银鹰化纤有限公司 | A kind of preparation method for inhaling color Hollow Viscose Fiber |
| CN109267165A (en) * | 2018-07-26 | 2019-01-25 | 阜宁澳洋科技有限责任公司 | A kind of koplon and preparation method thereof |
| CN109267165B (en) * | 2018-07-26 | 2021-08-27 | 阜宁澳洋科技有限责任公司 | High wet modulus viscose fiber and preparation method thereof |
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| CN1164807C (en) | 2004-09-01 |
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