CN106087100B - A kind of fused mass directly spinning adds the manufacture method of color silk online - Google Patents
A kind of fused mass directly spinning adds the manufacture method of color silk online Download PDFInfo
- Publication number
- CN106087100B CN106087100B CN201610410537.4A CN201610410537A CN106087100B CN 106087100 B CN106087100 B CN 106087100B CN 201610410537 A CN201610410537 A CN 201610410537A CN 106087100 B CN106087100 B CN 106087100B
- Authority
- CN
- China
- Prior art keywords
- spinning
- powder
- coloured
- online
- fused mass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
Abstract
The present invention relates to the manufacture method that a kind of fused mass directly spinning adds color silk online, it is characterised in that concretely comprises the following steps：First, the preparation of color grain, with coloured primary powder, colored pigment and ring-type polybutylene terephthalate (PBT) are raw material, using the method for melt blending, under 195~210 DEG C of melting temperatures, carry out extruding pelletization, coloured functional master batch is prepared；What the 2nd, fused mass directly spinning added color silk online is prepared color silk.The present invention reduces the generation of cyclic compound and low molecular weight compound in molecule, avoids difficulty in spinning by open loop of the catalyst dispersed in polyester fondant to CBT；Online adding technology has that process variability is good simultaneously, small lot, functionalization, it is differential easily, multi-functional for developing, multicoloured color silk new product has obvious advantage.
Description
Technical field
The present invention relates to technical field of textile production, is the system that a kind of fused mass directly spinning adds color silk online specifically
Make method.
Background technology
Colored polyester filament, obtained, had without dyeing by high-temperature fusion spinning by polyester slice and Masterbatch (toner)
Feature, shorten the production process of textile product, solve caused problem of environmental pollution in dyeing course, can also avoid dyeing from adding
Damage of the work to fibre property.Simultaneously colored polyester filament have it is resistance to soap, Exposure to Sunlight, the fastness ability such as friction it is good；And different face
The colored polyester filament of color enriches the selectivity of textile enterprise, turns into the preferred filament materials favored by market terminal product.
Chinese Patent Application No. 200710190753.3 is related to a kind of technology of producing coloured polyester filament yarn by melt direct spinning, category
Experimental branch line technical field.Its technical problem to be solved is:There is provided that a kind of cost is low, yield is high, technique is simple, aberration is easy
In the fused mass directly spinning production method controlled and fabric color fastness is good.Technical points：Before polyester fondant enters spinning manifold,
The modified feedstock after drying, melting, filtering, metering is injected, it is full and uniform through high efficiency static mixer together with polyester fondant
After mixing, enter spinning manifold jointly and carry out spinning.This method causes master batch to easily infiltrate into fibrous inside, and what it was produced has
Color polyester filament product quality is high, good color fastness, and water-fastness, wear resistence etc. is functional；And technique is simple, equipment investment is not
Greatly, it is easily controllable to add raw material, is easy to implement Automated condtrol；In addition, using the method for this technology, it can also avoid environment dirty
Dye.
Chinese Patent Application No. 201520551827.1 is related to a kind of production line of polyester POY color silk, including sets successively
Polyester slice raw material cabin, high-pressure delivery pump, dry pre-crystallized case, screw extruder and the wrapping machine put, in addition to display
The control panel of screen, vibrating detector is provided with the polyester slice raw material cabin, first is provided with the high-pressure delivery pump
Flow detector, temperature detector, moisture detector are provided with the pre-crystallized case of the drying, is set on the screw extruder
There is second flow detector, seal wire alarm is provided between the wrapping machine and the screw extruder；It can solve the problem that existing
There is the weak point in technology, integral monitoring is convenient, gets up in time with alarm, notifies that staff is timely.
Chinese Patent Application No. 201110451882.X is related to a kind of production method of terylene color silk, including following step
Suddenly：Three kinds of precursor of terylene and black blended fabric of silk and polyester preoriented yarn can be contaminated as raw material using white polyester preoriented yarn, cation fuel, successively
By filar guide, first roller, the first hot tank, twister, the second roller, network nozzle, the 3rd roller, oiling roller, stretching and
Coiling and molding, described white polyester preoriented yarn, cation fuel can contaminate the mass ratio of terylene and black blended fabric of silk and polyester preoriented yarn
For 2：2：3.The production method of its terylene color silk, has the following technical effect that：The coloured blended fabric of silk and polyester color silk of terylene produced
It is functional, steady quality, there are three kinds of mixed colors, product line density and intensity are high, and crimp property and stability to knit
Thing high resilience, feel are good.
Chinese Patent Application No. 200810244591.1 is related to automatic mixing device for colored thread, and the mixing arrangement includes soft pocket
(1), motion arm (2) and workbench (3), the center of workbench (3) set soft pocket (1), soft pocket (1) are located on workbench (3)
Periphery is in four motion arms (2) of cross installation.During work, it would be desirable to which the brush filament of mixing fills soft pocket, and start-up operation arm presses one
Fixed order is extruded or loosened repeatedly to soft pocket, that is, is imitated closing up or opening for both hands palm, brush filament in soft pocket is moved dislocation, complete
Into rubbing mixing action.Mechanical system replaces mixed silk by hand, simulates the rubbing action of both hands, makes different colours or the fiber of material
Silk in the state of disorder is not produced repeatedly, be sufficiently mixed, progressively reach equally distributed requirement, reduce labor strength,
Improve operating efficiency.
Chinese Patent Application No. 201310478850.8 is related to a kind of color silk of creep resistant polyester and preparation method thereof, bag
Include the preparation of the high viscous section of creep resistant polyester and the preparation of the color silk of creep resistant polyester；Polyester is viscosified by solid phase polycondensation,
Then blending reaction is carried out with fluoro epoxide and obtains the high viscous section of the creep resistant polyester；Gained creep resistant polyester is high viscous
Section is through metering mixing black agglomerate, extrusion, the color silk for cooling down, oil, stretching and winding obtained creep resistant polyester.Gained resists
The color silk of creep polyester has certain creep-resistant property, hydrolytic Resistance and stability, can be used in height for a long time
In warm high humidity environment, there is huge prospect in fields such as car belt, military suitcase cloth, hanging belts.
Chinese Patent Application No. 201110263686.X is related to a kind of production method of differential terylene color yarns, first by work(
Energy property polyester slice pre-crystallized 20min-60min at a temperature of 144 DEG C~146 DEG C, then in 149 DEG C~151 DEG C of temperature
Lower dry 4-6h, moisture content≤17ppm of dried functional polyester chip, then Masterbatch is dried into 1-2h, then will be dry
After dry Masterbatch is sufficiently mixed with the functional polyester chip dried, it is added in extrusion spinning by screw press machine, is squeezed by screw rod
Press the spinneret of spinning-drawing machine to carry out spinning, then it is rolled fall bucket after into post-processing obtain differential terylene color yarns.In work(
Masterbatch is added in the polyester section of energy property and is spun into color silk, takes Masterbatch and functional polyester chip before screw extruder
The mode of dynamic mixing or static mixing is uniformly mixed, then the production of color silk is carried out using spinneret.This process increases product
Color fastness and stability, reduce production cost, reduce environmental pollution.
Chinese Patent Application No. 200920107461.3 is related to one kind has light color silk greatly, is by the coloured list of multi-ribbon
The tow of silk composition, monofilament disordered arrangements, the shape of cross section of monofilament is trilobal, and reflective particles are evenly distributed with monofilament,
The shape of cross section of tow is circle.By being distributed reflective particles in monofilament, and combine shape after trilobal monofilament disordered arrangements
Into a three-dimensional tow reflection space, make to play a part of being mutually reflected between three blades, by different directions irradiate light
Effectively to external reflectance, the reflective visual effect of finished product is substantially increased, reflecting effect is good, reflectivity is high, brightness is strong, avoids
The shortcomings that common light silk reflecting effect is poor in the past, and the color that monofilament itself is carried, it is anti-even more under the irradiation of light
Distinctive bright and color is projected, is especially suitable for weaving that a variety of colors is bright-coloured, ornamental strong clothes.
Chinese Patent Application No. 201520551799.3 is related to a kind of flow production line for polyester POY color silk, bag
Include the polyester slice raw material cabin set gradually, high-pressure delivery pump, dry pre-crystallized case, screw extruder and wrapping machine, in addition to
Control panel, the control panel carry the first display screen, second display screen and the 3rd display screen, and the control panel includes control
Molding block, the first data memory module, the second data memory module, 2G/3G/4G communication modules, time block, standby battery
Module, wireless launcher, APP/APK modules；The control module is connected with the APP/APK modules, the APP/APK modules
It is connected with the 2G/3G/4G communication modules, to be independently arranged, the inside of the 3rd display screen carries the 3rd display screen
Wireless receiver and communication sink, siren is carried on the top of the 3rd display screen；The present apparatus can solve the problem that existing skill
Weak point in art, integral monitoring is convenient, gets up in time with alarm, notifies that staff is timely.
Chinese Patent Application No. 201010123030.3 is related to a kind of high-hygroscopic colored fiber with high hygroscopic property, bag
Include:Account for the coloured polyester principal component of gross weight 60%~90% and account for the water-soluble polyester accessory ingredient of gross weight 10%~40%,
The content of Masterbatch is between 0.1%~50% wherein in coloured polyester principal component, described high-hygroscopic colored fiber it is transversal
Face is shaped as " rice " font, and " rice " word therein is made up of coloured polyester principal component, and the flap groove between " rice " word is by water-soluble
Property polyester accessory ingredient form.Its advantage is:Above-mentioned high-hygroscopic colored fiber weave cotton cloth after again after final finishing is water-soluble, water-soluble polyester
Accessory ingredient will be dissolved in buck, and multiple tracks clearly flap groove occurs on the surface of colored fibre, have very strong moisture absorption
Performance, and colored fibre fabric makes the dress of colored fibre fabric more comfortable, environmentally friendly without dyeing in addition.
Chinese Patent Application No. 201080035727.3 is related to a kind of fluorescence colored fibre, and the fluorescence colored fibre is marked
Note has the first luminescent substance and is made up of at least to some extent adhesive, is related to the thin slice including colored fibre and is related to
File with the colored fibre.In addition, further relating to the method for manufacturing fluorescence colored fibre, manufacture with fluorescence colored fibre
The method of thin slice and the method for manufacturing the file with fluorescence colored fibre.Fluorescence colored fibre is marketable securities or insurance documentation
Provide a kind of special anti-counterfeiting characteristic put forgery and can simply manufactured.
Chinese Patent Application No. 201210094824.0 is related to the production technology of modified cation colored fibre, is related to weaving
The production and processing technology technical field of technical field, particularly staple fibre.It will modified Masterbatch section and modified cation
After section mixing, by spinneret spinneret after hot melt, color fibre is formed directly with, avoids traditional high-temperature pressure dyeing band
Come highly energy-consuming, high pollution phenomenon.This technique avoids caused high pollution in process of production, and reduces because of high temperature, height
The energy resource consumption that pressure zone comes, greatlys save printing and dyeing cost, so as to increase the benefit.
Chinese Patent Application No. 200920039326.X is related to a kind of skin core type color fiber, for defending material product, safely,
Environmental protection.The skin core type color fiber, including cortex and sandwich layer, sandwich layer coloring.The sandwich layer is coated in cortex.Cortex is preferred
For transparent color, can be showed in favor of the color of sandwich layer through cortex.Satisfactory material is a lot, such as PE.Institute
State skin core type color fiber section can be it is variously-shaped, it is preferably circular.Preferably, the cortex is PE, sandwich layer
For PP.As preferred, the fiber number of skin core type color fiber is 1.5-7dtex.Using the complex structure of filament of core-skin type, sandwich layer is
Colored fibre, coated by cortex, this fiber is used to defend material product, dyestuff will not be with direct body contact, fool proof, ring
Protect.Meanwhile skin core type color fiber is directly made through specific spinning pack using sandwich layer and cortical material, technique is simple, easy
In realization.
Chinese Patent Application No. 200910048276.6 is related to a kind of anion terylene colored fiber and its preparation and application,
Component includes:Terylene anion master batch, pigment particles for terylene, terylene are cut into slices into fine polyester, and its weight ratio is:1~10: 1~10: 80
~98；(1) terylene is dried in vacuo into the section of fine polyester, anion powder and section is blended, melt extrusion, cooling,
And pelletizing；(2) by terylene anion master batch, into fine polyester section vacuumizes for pigment particles for terylene and terylene, and heating and thermal insulation, (3) are entered
Extruder heating melting, compression；(4) distribution pipe, static mixer and measuring pump are sent into, forms melt body thread, is cooled down, cladding,
Spinning produces.The anion colored fibre softness high resilience of this method, style is close with wool fabric, and it is light soft to maintain terylene
The characteristics of suitable, with transmitting anion and there can be a variety of colors；Preparation method is simple to operate, and production technology is easily real
It is existing, printing and dyeing cost is reduced, is suitable for industrialized production.
Chinese Patent Application No. 201210419736.3 is related to a kind of low-melting point polyester core-sheath colored fibre and its life
Production method.Fiber includes core and skin material, and core includes fibre-grade PET and Masterbatch, and skin material includes low-melting point polyester, the color
Master batch includes the component of following parts by weight：The parts by weight of fibre-grade PBT65~80, the parts by weight of bottle level PET 5~20, dispersant 5~15
Parts by weight and the parts by weight of toner 3~15.Its Masterbatch used uses fibre-grade PBT, is aided with bottle level PET as carrier, compares
Fibre-grade PET, at the same temperature, there is more preferable fluidity of molten, add mixed effect between the two and improve
Spinning properties；Painted from core segment, appearance is covered with transparent low-melting point polyester, and the composite fibre of manufactured skin-core structure, tool
There is high color fastness, it is colour-fast in use；Method technical process is simple, is adapted to industrialized production.
Chinese Patent Application No. 201410742846.2 is related to a kind of heat-resisting colored terylene high strength yarn, and described is heat-resisting
Colored terylene high strength yarn includes the layer of polyester fiber of the superiors, the synthetic fiber layer in intermediate layer and the combination of undermost cotton fiber layer
Form, the layer of polyester fiber is polyester slice, and the synthetic fiber layer is Fypro, and described layer of polyester fiber accounts for resistance to
The 45%-51% of the colored terylene high strength yarn totality component of heat, described synthetic fiber layer account for heat-resisting colored terylene high strength yarn
The 10%-15% of overall component, described cotton fiber layer account for the 38%-41% of heat-resisting colored terylene high strength yarn totality component.
It provides a kind of heat-resisting colored terylene high strength yarn, flexible good, good hand touch, steady quality, it is heat-resisting, pulling force is strong the advantages that.
Chinese Patent Application No. 201410743627.6 is related to a kind of elastic good colored terylene high strength yarn, described elasticity
Good colored terylene high strength yarn includes the regenerated celulose fibre layer of the superiors, the thickener in intermediate layer and undermost natural plant
Fibres layer combines, and the regenerated celulose fibre layer is CUP, and the natural plant fibre layer is tencel, described
Regenerated celulose fibre layer account for the 15%-20% of the good colored terylene high strength yarn totality component of elasticity, described thickener accounts for
The 19%-25% of the good colored terylene high strength yarn totality component of elasticity, described natural plant fibre layer account for good coloured of elasticity
The 60%-65% of high-tenacity terylene yarn totality component.It provides a kind of elasticity good colored terylene high strength yarn, has intensity high, resistance to
The advantages that heat is good and elastic strong.
Chinese Patent Application No. 201410743336.7 is related to a kind of mould proof colored terylene high strength yarn, and described is mould proof
Colored terylene high strength yarn includes the scattered fibrous layer of the superiors, the viscose filament yarn in intermediate layer and the combination of undermost chemical fibre layer
Form, the scattered fibrous layer is wood fibre, and the chemical fibre layer is polyvinyl chloride fibre, and described scattered fibrous layer accounts for
The 60%-70% of mould proof colored terylene high strength yarn totality component, described viscose filament yarn account for mould proof colored terylene high strength yarn
The 9%-16% of overall component, described chemical fibre layer account for the 20%-25% of mould proof colored terylene high strength yarn totality component.
A kind of mould proof colored terylene high strength yarn is provided, there is smooth nice and cool, ventilative, antistatic, antiultraviolet, it is lucuriant in design and mould proof
The advantages that.
Chinese Patent Application No. 201510297066.6 is related to a kind of production method of colored terylene industrial yarn, and this method is adopted
Spin One-step production route with section, when PET melt is through melt pipe, by injection port on melt pipe add color oil and
Auxiliary agent makes color oil and PET melt uniformly mix into PET melt, then through multiple new type static mixers in melt pipe, mixes
PET melt is redistributed to spinning manifold and each spinning position.The coloured high-strength polyester industrial yarns uniform color that is obtained by this method,
Lovely luster, the cycle is short, and energy consumption is low.
Chinese Patent Application No. 200810123780.3 is related to a kind of processing method of coloured terylene monofilament, it is characterized in that will
The dehydration of polyester chip drying, insulation, heating, carry out solid phase polycondensation (thickening), intrinsic viscosity reaches 0.8DEL/G-1.0DEL/G；
Production method is spun using section and carries out spinning production；Add color grain in polycondensation process, and fully with it is dry sliced uniformly
Mixing；In spinning process, the multifilament sprayed from spinneret passes through ring wind quenching, and sub-wire is carried out before drawing-off and forms monofilament；
Technique is simple, easy to operate, and cost is relatively low, is adapted to large-scale production, monofilament strand is dry uniform, and fracture strength is high, and durability is good.
Chinese Patent Application No. 201110425927.6 is related to a kind of production technology of coloured polyester staple, the production
Technique uses regenerative PET material as raw material, successively by pre-treatment, drum dried, melt spinning, cooling and shaping, winding, drawing-off,
Crimp, oil, thermal finalization, obtaining finished product after cut-out, regenerative PET material is first is dried 7.5h-8.5h by wherein drum dried, then is added
Enter Masterbatch and toner, Masterbatch final mass fraction is 2%-10%, and total drying time is 9.5h-10.5h；In melt spinning
The screw rod and manifold spin manifold temperature of screw extruder are 265 DEG C -275 DEG C, the hole diameter of spinneret 0.2mm, hole count 3500,
The layout of spinneret is 14 circles；It is molded by ring wind quenching, ring blowing temperature is 22 DEG C -26 DEG C, and ring blowing speed is 4.0m/s-
5.0m/s；Total draft multiple is 3.0-3.2 times；Heat setting temperature is 168 DEG C -172 DEG C, heat-setting time 13min-17min.
Production technology can reduce cost, be advantageous to environmental protection, obtained finished product line density is smaller, color fastness is high, feel is smooth.
Chinese Patent Application No. 201110380139.X is related to a kind of manufacture method of colored dacron fine-denier fiber, and it is special
Sign is to comprise the following steps：(a) terylene and color grain section are prepared；(b) it is dried by crystallizing and drying machine；(c)
Melted after drying by screw extruder, obtain blend melt；(d) blend melt is controlled by terylene spinning measuring pump
The volume of melt；(e) blend melt is subjected to spinning through filament spinning component；(f) tow after spinning is passed through into air-cooled cooling；(g) will
The finish that tow after cooling is measured by oil agent metering pump oils；(h) tow after oiling is wound by fully automatic high-speed
Machine is wound into spinning cake；(i) spinning cake after winding is placed between balance and be balanced；(j) by the spinning cake after balance normal
Carry out adding bullet on elasticizer.This method realizes colouring, color fastness, sunlight fastness, thermosetting jail directly in spinning process
Spend, uniform color, colour rendering are good, and ensure that spinning characteristics.
Chinese Patent Application No. 200910048275.1 is related to a kind of preparation method of nano-pearl colored polyester fiber, bag
Include:(1) thick pearl powder is obtained after pearl being sheared and ground, then thick pearl powder is mixed with water, crushed by high pressure,
Obtain the aqueous dispersions for the pearl powder that particle diameter is 50~100 nanometers, add heat stabilizer, antioxidant and emulsifying agent, dry at
Reason；(2) after being well mixed at normal temperatures with compatilizer, then add mixture in terylene chips, made through double screw extruder
Grain；(3) nano-pearl terylene chips and the blending of terylene chips and color grain are subjected to spinning.This method is in conventional spinning equipment
On can complete, tow strip is dry uniform, and color and luster is evenly distributed, and fabric is smooth, has the characteristics of gloss is soft, applied to garment collar
Domain, furnishing fields and industrial field, while Masterbatch is blended can prepare the fiber with various color and lusters, obtained fiber is to people
Body has good nutrition, health-care effect.
Chinese Patent Application No. 97105904.7 is related to the manufacture method of a kind of flame-resistant terylene and fire-retardant colored polyester fiber,
Belong to artificial fire protection flame retarding long filament technology, for manufacturing flame-resistant terylene and fire-retardant colored polyester fiber.It is characterized in that this method includes
With phosphniline dichloro flame retardant intermediate, the preparation of phosphorous polymer type fire retardant, fire-retardant master granule or fire-retardant are obtained through direct oxidation
The preparation of color grain and colourless flame retardant polyester fiber or fire-retardant colored polyester fiber spin four steps.It is simple with technique,
Be not required to solvent processing it is pollution-free, fire-retardant master granule fusing point is up to 190~260 DEG C, can directly be blended on various spinning-drawing machines and spin with PET
The advantages that making fire-retardant colourless and colored polyester fiber.
The content of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide the system that a kind of fused mass directly spinning adds color silk online
Make method.
The purpose of the present invention is achieved through the following technical solutions：
A kind of fused mass directly spinning adds the manufacture method of color silk online, concretely comprises the following steps：
The preparation of one color grain
With coloured primary powder, colored pigment and ring-type polybutylene terephthalate (PBT) are raw material, using melt blending
Method, under 195~210 DEG C of melting temperatures, carry out extruding pelletization, coloured functional master batch is prepared；
Mass fraction of the described coloured primary powder in coloured functional master batch is 6~25%；
Mass fraction of the described colored pigment in coloured functional master batch is 2~5%；
Ring-type polybutylene terephthalate (PBT) CBT is white solid particle at normal temperatures, the meeting when temperature reaches 190 DEG C
Become the same liquid of water, PBT viscosity is its 5000 times under identical viscosity.And CBT has well with PBT, PET, PTT
Compatibility, wettability is strong.In-situ polymerization can occur when being heated to 220 DEG C, that is, generate PBT material.
Coloured ring-type polybutylene terephthalate (PBT) CBT master batch fusing points are low in online adding procedure, and viscosity is low, enter
It is beneficial to mix with polyester fondant after main melt pipe to disperse, while improves pigment and inorganic addO-on therapy in polyester fondant
It is scattered, while the catalyst added in polyester polymerization process can be catalyzed CBT ring-opening polymerisations, after CBT ring-opening polymerisations, obtain
Polybutylene terephthalate, it has similar molecular structure to polyester, and compatibility is good, avoids colored components adding procedure
In phenomenon of phase separation, cause difficulty in spinning；CBT ring opening process is controllable simultaneously, passes through catalysis dispersed in polyester fondant
Open loop of the agent to CBT, the generation of cyclic compound and low molecular weight compound in molecule is reduced, avoids difficulty in spinning；Simultaneously
Online adding technology has that process variability is good, small lot, functionalization, it is differential easily, it is multi-functional for developing, it is multicoloured
Color silk new product has obvious advantage.
Two fused mass directly spinnings add the preparation of color silk online
The spinning of pipeline injection is added online using fused mass directly spinning, using the coloured functional master batch that step 1 is prepared as pipe
Road injects raw material, using normal polyester melt as main melt, coloured functional master batch melt is injected into master by pipeline injected system
In melt, then mixed by pipeline static mixer, then conveyed through melt pipe, then through being filtered before spinning, enter spinning
Silk component, carries out melt spinning, through ring wind quenching, oils, and drawing-off, winding obtains fused mass directly spinning and adds color silk online；
Described coloured functional master batch and the ratio ratio of normal polyester are 1:6~1:11；
The winding speed that described fused mass directly spinning adds color silk online is 3500~4500 ms/min, ring blowing wind speed
For 0.35~0.5 m/min, ring blowing temperature is 25~28 DEG C, and ring blowing air tube length degree is 120~165 centimetres, draw ratio
For 1.8~2.2 times.
Injected system before online addition pump, the online addition that can not only play the polyester of Large Copacity are modified, simultaneously
Also meet small lot, the modification of multiple batches of product, simultaneously because the function melt of injection residence time in pipeline is short, therefore drop
Solution is few, and the influence to main molten body is relatively low, meets the modification of the spinning in later stage.
Described coloured primary raw powder's production technology, it is concretely comprised the following steps：
With jade powder, the natural gypsum, lucidum soaked juice is raw material, and the natural gypsum and jade powder are first proportionally added into ball milling
In machine, using the method for dry powder ball mill, it is ground and mixed mineral powder is prepared, carries out jade powder and the natural gypsum
Sufficiently mixing, and the jade powder in process of lapping, mineral in the natural gypsum are into abundant contact and displacement, after control grinding
The average grain diameter of powder is 15~20 microns.Then mixed mineral powder after grinding is immersed in lucidum soaked juice, during dipping
Between be 10~20 days, then take out naturally dry, obtain pre-processing mixed mineral powder, then pretreated mixed mineral powder
Body is in nitrogen atmosphere, high-temperature calcination under the conditions of 1000~1200 DEG C, and calcination time is 2~3h, is then in raising temperature
1500~1800 DEG C of 2~3h of calcining, finally carry out 15~20min of rapid calcining, after having calcined under the conditions of 2200~2500 DEG C
Taken as cooling source using liquid nitrogen and rapidly cooled down, being cooled to room temperature in 5~10s obtains function powder, then screens out average grain diameter
For 0.2~5.0 micron of coloured primary powder.
The mass fraction of the raw material of described coloured primary powder is as follows：
Loading is 65~75% during described dry ball milling, and zirconium strain particle diameter is 3~5mm, and grinding rotating speed is 3000
~4500rpm, 3~4h of milling time, it is 40~45 DEG C to control grinding temperature；
Jade powder and the natural gypsum are all very excellent natural minerals, its excellent far infrared transmission, anion
The functions such as transmitting, physics magnetic therapy are used in the fields such as health care；Jade powder contain the selenium of needed by human body, zinc, nickel, cobalt,
More than 30 kinds of manganese, magnesium, calcium etc. trace element beneficial to human body, the startup ripple and the startup ripple of human body cell that it is distributed are same
Fluctuation status, human body cell make human cell tissue have more vigor as the fluctuation given out from jade is empathized and is resonated,
And promote blood to follow bad, enhancing metabolism and enter to exclude bodily waste, there is excellent effect to health and health care；
The natural gypsum has excellent natural anima simultaneously, and with the formaldehyde isoreactivity molecule in absorption air, lifts ambient air
Quality, reduce the content of active oxygen atom；Natural powder has loose porous knot through more than 1000 DEG C of high-temperature firing simultaneously
Structure, its molecule is fine and closely woven porous, and quality is hard.With strong adsorption capacity, air can be purified, to eliminate peculiar smell, moisture absorption mould proof, antibacterial
Expelling parasite, while can be dried absorbing sweat with human contact, promote blood circulation of human body and metabolism, fatigue-relieving；
Lucidum extracting liquid is containing a variety of elements and material beneficial to human body, passes through leaching of the natural powder in extract solution
Stain, enable the deposition and absorption of beneficial element and mineralogical composition in natural powder, it is micro- so as to be fixed in mineral material
The rare element of amount can both be used as catalyst action, promote the calcining of natural minerals composition, while after calcining can also being improved
The activity of mineralogical composition, have the function that for the far infrared transmission and anion function for lifting material very big；
Using the method for dry powder ball mill, natural mineral material is ground, is mineral in mineral material into filling
Tap is touched and displacement, avoids later stage calcining difficulty, reduces powder reaction contact area, improve level of activity in calcination process,
Beneficial to the abundant contact and displacement of mineralogical composition, mineralogical composition is mutually adulterated, improve surface-active, further lift material
Far infrared transmission effect and health-care effect；
The process progressively calcined using multistage, the fully calcined of powder and activation are realized, is especially put beneficial to mineralogical composition
The calcining for changing rear material produces the mineral powders of higher active far infrared transmission and anion emission function；
Using liquid nitrogen rapidly cooling technology, material is rapidly cooled down, can farthest retain the active-energy in,
The portion of energy of high-temperature calcination is set to be converted to lasting far infrared and anion emission function crystal, while rapidly cooling can make
Material internal stress is concentrated on a large scale, and is made to reveal in material cooling procedure and crushed, and is produced micro mist, is avoided the need for follow-up
Crushing process again, and cause the transfer of far infrared and anion emission function in process of lapping, while in rapidly cooling procedure
In, irregular mineral powder of the self-destruction crushing process generation with point effect, and the micro-nano tip of irregular mineral powder
Effect has high surface-active, can not only absorb free radical, can bury in oblivion the living radical of human skin, spins
Skin senescence is knitted, while can also be catalyzed and produce the anion beneficial to human body, and point effect can also be catalyzed formaldehyde etc. and have
The degraded of evil gas；Point effect can accumulate certain micro- electrostatic, be released by micro as the accumulation point of electrostatic simultaneously
The electrostatic of concentration of local is put, the effect of acupuncture can be played, the cell of human body surface can be stimulated, promotes the blood of human body surface
Circulation, lifting blood of human body health, plays a role in health care.
Compared with prior art, the positive effect of the present invention is：
Polyester can only be dyed with disperse dyes due to itself polarity, therefore the color fastness of itself is poor, and this skill
The mode that art scheme is added online by using easily directly spinning, exploitation have coloured polyester color yarn, solve polyster fibre dyeing
Problem, while industrial water consumption is big in the dyeing course of disperse dyes in itself, energy consumption is big, big for environment pollution, while plurality of color
The matching of silk also improves the performance of fiber；The present invention has by using the function powder with healthcare function, exploitation
The healthcare function powder such as antibacterial, anion emission and far infrared transmission, the multifunctional development of fiber is realized, both met terylene fibre
The dyeing demand of dimension, while health care and the functional requirement of polyester fiber are also met, taking, home textile and industrial fibre neck
Domain has a extensive future.
Brief description of the drawings
The process chart of Fig. 1 present invention.
Embodiment
A kind of fused mass directly spinning of the present invention presented below adds the embodiment of the manufacture method of color silk online.
Embodiment 1
A kind of fused mass directly spinning adds the manufacture method of color silk online, concretely comprises the following steps：
The preparation of one color grain
With coloured primary powder, colored pigment and ring-type polybutylene terephthalate (PBT) are raw material, using melt blending
Method, under 195~210 DEG C of melting temperatures, carry out extruding pelletization, coloured functional master batch is prepared；
Mass fraction of the described coloured primary powder in coloured functional master batch is 6%；
Mass fraction of the described colored pigment in coloured functional master batch is 2%；
Ring-type polybutylene terephthalate (PBT) CBT is white solid particle at normal temperatures, the meeting when temperature reaches 190 DEG C
Become the same liquid of water, PBT viscosity is its 5000 times under identical viscosity.And CBT has well with PBT, PET, PTT
Compatibility, wettability is strong.In-situ polymerization can occur when being heated to 220 DEG C, that is, generate PBT material.
Coloured ring-type polybutylene terephthalate (PBT) CBT master batch fusing points are low in online adding procedure, and viscosity is low, enter
It is beneficial to mix with polyester fondant after main melt pipe to disperse, while improves pigment and inorganic addO-on therapy in polyester fondant
It is scattered, while the catalyst added in polyester polymerization process can be catalyzed CBT ring-opening polymerisations, after CBT ring-opening polymerisations, obtain
Polybutylene terephthalate, it has similar molecular structure to polyester, and compatibility is good, avoids colored components adding procedure
In phenomenon of phase separation, cause difficulty in spinning；CBT ring opening process is controllable simultaneously, passes through catalysis dispersed in polyester fondant
Open loop of the agent to CBT, the generation of cyclic compound and low molecular weight compound in molecule is reduced, avoids difficulty in spinning；Simultaneously
Online adding technology has that process variability is good, small lot, functionalization, it is differential easily, it is multi-functional for developing, it is multicoloured
Color silk new product has obvious advantage.
Two fused mass directly spinnings add the preparation of color silk online
The spinning of pipeline injection is added online using fused mass directly spinning, using the coloured functional master batch that step 1 is prepared as pipe
Road injects raw material, using normal polyester melt as main melt, coloured functional master batch melt is injected into master by pipeline injected system
In melt, then mixed by pipeline static mixer, then conveyed through melt pipe, then through being filtered before spinning, enter spinning
Silk component, carries out melt spinning, through ring wind quenching, oils, and drawing-off, winding obtains fused mass directly spinning and adds color silk online；
Described coloured functional master batch and the ratio ratio of normal polyester are 1:6.
The winding speed that described fused mass directly spinning adds color silk online is 3500~4500 ms/min, ring blowing wind speed
For 0.35~0.5 m/min, ring blowing temperature is 25~28 DEG C, and ring blowing air tube length degree is 120~165 centimetres, draw ratio
For 1.8~2.2 times.
Described coloured primary raw powder's production technology, it is concretely comprised the following steps：
With jade powder, the natural gypsum, lucidum soaked juice is raw material, and the natural gypsum and jade powder are first proportionally added into ball milling
In machine, using the method for dry powder ball mill, it is ground and mixed mineral powder is prepared, carries out jade powder and the natural gypsum
Sufficiently mixing, and the jade powder in process of lapping, mineral in the natural gypsum are into abundant contact and displacement, after control grinding
The average grain diameter of powder is 15~20 microns.Then mixed mineral powder after grinding is immersed in lucidum soaked juice, during dipping
Between be 10~20 days, then take out naturally dry, obtain pre-processing mixed mineral powder, then pretreated mixed mineral powder
Body is in nitrogen atmosphere, high-temperature calcination under the conditions of 1000~1200 DEG C, and calcination time is 2~3h, is then in raising temperature
1500~1800 DEG C of 2~3h of calcining, finally carry out 15~20min of rapid calcining, after having calcined under the conditions of 2200~2500 DEG C
Taken as cooling source using liquid nitrogen and rapidly cooled down, being cooled to room temperature in 5~10s obtains with far infrared transmission, anion emission with
The function powder of the functions such as antibacterial, then screen out the coloured primary powder that average grain diameter is 0.2~5.0 micron.
The mass fraction of the raw material of described coloured primary powder is as follows：
Loading is 65~75% during described dry ball milling, and zirconium strain particle diameter is 3~5mm, and grinding rotating speed is 3000
~4500rpm, 3~4h of milling time, it is 40~45 DEG C to control grinding temperature.
Embodiment 2
A kind of fused mass directly spinning adds the manufacture method of color silk online, concretely comprises the following steps：
The preparation of one color grain
With coloured primary powder, colored pigment and ring-type polybutylene terephthalate (PBT) are raw material, using melt blending
Method, under 195~210 DEG C of melting temperatures, carry out extruding pelletization, coloured functional master batch is prepared；
Mass fraction of the described coloured primary powder in coloured functional master batch is 14%；
Mass fraction of the described colored pigment in coloured functional master batch is 3%；
Ring-type polybutylene terephthalate (PBT) CBT is white solid particle at normal temperatures, the meeting when temperature reaches 190 DEG C
Become the same liquid of water, PBT viscosity is its 5000 times under identical viscosity.And CBT has well with PBT, PET, PTT
Compatibility, wettability is strong.In-situ polymerization can occur when being heated to 220 DEG C, that is, generate PBT material.
Coloured ring-type polybutylene terephthalate (PBT) CBT master batch fusing points are low in online adding procedure, and viscosity is low, enter
It is beneficial to mix with polyester fondant after main melt pipe to disperse, while improves pigment and inorganic addO-on therapy in polyester fondant
It is scattered, while the catalyst added in polyester polymerization process can be catalyzed CBT ring-opening polymerisations, after CBT ring-opening polymerisations, obtain
Polybutylene terephthalate, it has similar molecular structure to polyester, and compatibility is good, avoids colored components adding procedure
In phenomenon of phase separation, cause difficulty in spinning；CBT ring opening process is controllable simultaneously, passes through catalysis dispersed in polyester fondant
Open loop of the agent to CBT, the generation of cyclic compound and low molecular weight compound in molecule is reduced, avoids difficulty in spinning；Simultaneously
Online adding technology has that process variability is good, small lot, functionalization, it is differential easily, it is multi-functional for developing, it is multicoloured
Color silk new product has obvious advantage.
Two fused mass directly spinnings add the preparation of color silk online
The spinning of pipeline injection is added online using fused mass directly spinning, using the coloured functional master batch that step 1 is prepared as pipe
Road injects raw material, using normal polyester melt as main melt, coloured functional master batch melt is injected into master by pipeline injected system
In melt, then mixed by pipeline static mixer, then conveyed through melt pipe, then through being filtered before spinning, enter spinning
Silk component, carries out melt spinning, through ring wind quenching, oils, and drawing-off, winding obtains fused mass directly spinning and adds color silk online；
Described coloured functional master batch and the ratio ratio of normal polyester are 1:8；
The winding speed that described fused mass directly spinning adds color silk online is 3500~4500 ms/min, ring blowing wind speed
For 0.35~0.5 m/min, ring blowing temperature is 25~28 DEG C, and ring blowing air tube length degree is 120~165 centimetres, draw ratio
For 1.8~2.2 times.
Injected system before online addition pump, the online addition that can not only play the polyester of Large Copacity are modified, simultaneously
Also meet small lot, the modification of multiple batches of product, simultaneously because the function melt of injection residence time in pipeline is short, therefore drop
Solution is few, and the influence to main molten body is relatively low, meets the modification of the spinning in later stage.
Described coloured primary raw powder's production technology, it is concretely comprised the following steps：
With jade powder, the natural gypsum, lucidum soaked juice is raw material, and the natural gypsum and jade powder are first proportionally added into ball milling
In machine, using the method for dry powder ball mill, it is ground and mixed mineral powder is prepared, carries out jade powder and the natural gypsum
Sufficiently mixing, and the jade powder in process of lapping, mineral in the natural gypsum are into abundant contact and displacement, after control grinding
The average grain diameter of powder is 15~20 microns.Then mixed mineral powder after grinding is immersed in lucidum soaked juice, during dipping
Between be 10~20 days, then take out naturally dry, obtain pre-processing mixed mineral powder, then pretreated mixed mineral powder
Body is in nitrogen atmosphere, high-temperature calcination under the conditions of 1000~1200 DEG C, and calcination time is 2~3h, is then in raising temperature
1500~1800 DEG C of 2~3h of calcining, finally carry out 15~20min of rapid calcining, after having calcined under the conditions of 2200~2500 DEG C
Taken as cooling source using liquid nitrogen and rapidly cooled down, being cooled to room temperature in 5~10s obtains with far infrared transmission, anion emission with
The function powder of the functions such as antibacterial, then screen out the coloured primary powder that average grain diameter is 0.2~5.0 micron.
The mass fraction of the raw material of described coloured primary powder is as follows：
Loading is 65~75% during described dry ball milling, and zirconium strain particle diameter is 3~5mm, and grinding rotating speed is 3000
~4500rpm, 3~4h of milling time, it is 40~45 DEG C to control grinding temperature.
Embodiment 3
A kind of fused mass directly spinning adds the manufacture method of color silk online, concretely comprises the following steps：
The preparation of one color grain
With coloured primary powder, colored pigment and ring-type polybutylene terephthalate (PBT) are raw material, using melt blending
Method, under 195~210 DEG C of melting temperatures, carry out extruding pelletization, coloured functional master batch is prepared；
Mass fraction of the described coloured primary powder in coloured functional master batch is 25%；
Mass fraction of the described colored pigment in coloured functional master batch is 5%；
Ring-type polybutylene terephthalate (PBT) CBT is white solid particle at normal temperatures, the meeting when temperature reaches 190 DEG C
Become the same liquid of water, PBT viscosity is its 5000 times under identical viscosity.And CBT has well with PBT, PET, PTT
Compatibility, wettability is strong.In-situ polymerization can occur when being heated to 220 DEG C, that is, generate PBT material.
Coloured ring-type polybutylene terephthalate (PBT) CBT master batch fusing points are low in online adding procedure, and viscosity is low, enter
It is beneficial to mix with polyester fondant after main melt pipe to disperse, while improves pigment and inorganic addO-on therapy in polyester fondant
It is scattered, while the catalyst added in polyester polymerization process can be catalyzed CBT ring-opening polymerisations, after CBT ring-opening polymerisations, obtain
Polybutylene terephthalate, it has similar molecular structure to polyester, and compatibility is good, avoids colored components adding procedure
In phenomenon of phase separation, cause difficulty in spinning；CBT ring opening process is controllable simultaneously, passes through catalysis dispersed in polyester fondant
Open loop of the agent to CBT, the generation of cyclic compound and low molecular weight compound in molecule is reduced, avoids difficulty in spinning；Simultaneously
Online adding technology has that process variability is good, small lot, functionalization, it is differential easily, it is multi-functional for developing, it is multicoloured
Color silk new product has obvious advantage.
Two fused mass directly spinnings add the preparation of color silk online
The spinning of pipeline injection is added online using fused mass directly spinning, using the coloured functional master batch that step 1 is prepared as pipe
Road injects raw material, using normal polyester melt as main melt, coloured functional master batch melt is injected into master by pipeline injected system
In melt, then mixed by pipeline static mixer, then conveyed through melt pipe, then through being filtered before spinning, enter spinning
Silk component, carries out melt spinning, through ring wind quenching, oils, and drawing-off, winding obtains fused mass directly spinning and adds color silk online；
Described coloured functional master batch and the ratio ratio of normal polyester are 1:11；
The winding speed that described fused mass directly spinning adds color silk online is 3500~4500 ms/min, ring blowing wind speed
For 0.35~0.5 m/min, ring blowing temperature is 25~28 DEG C, and ring blowing air tube length degree is 120~165 centimetres, draw ratio
For 1.8~2.2 times.
Described coloured primary raw powder's production technology, it is concretely comprised the following steps：
With jade powder, the natural gypsum, lucidum soaked juice is raw material, and the natural gypsum and jade powder are first proportionally added into ball milling
In machine, using the method for dry powder ball mill, it is ground and mixed mineral powder is prepared, carries out jade powder and the natural gypsum
Sufficiently mixing, and the jade powder in process of lapping, mineral in the natural gypsum are into abundant contact and displacement, after control grinding
The average grain diameter of powder is 15~20 microns.Then mixed mineral powder after grinding is immersed in lucidum soaked juice, during dipping
Between be 10~20 days, then take out naturally dry, obtain pre-processing mixed mineral powder, then pretreated mixed mineral powder
Body is in nitrogen atmosphere, high-temperature calcination under the conditions of 1000~1200 DEG C, and calcination time is 2~3h, is then in raising temperature
1500~1800 DEG C of 2~3h of calcining, finally carry out 15~20min of rapid calcining, after having calcined under the conditions of 2200~2500 DEG C
Taken as cooling source using liquid nitrogen and rapidly cooled down, being cooled to room temperature in 5~10s obtains with far infrared transmission, anion emission with
The function powder of the functions such as antibacterial, then screen out the coloured primary powder that average grain diameter is 0.2~5.0 micron.
The mass fraction of the raw material of described coloured primary powder is as follows：
Loading is 65~75% during described dry ball milling, and zirconium strain particle diameter is 3~5mm, and grinding rotating speed is 3000
~4500rpm, 3~4h of milling time, it is 40~45 DEG C to control grinding temperature.
Embodiment 4
A kind of fused mass directly spinning adds the manufacture method of color silk online, concretely comprises the following steps：
The preparation of one color grain
With coloured primary powder, colored pigment and ring-type polybutylene terephthalate (PBT) are raw material, using melt blending
Method, under 195~210 DEG C of melting temperatures, carry out extruding pelletization, coloured functional master batch is prepared；
Mass fraction of the described coloured primary powder in coloured functional master batch is 10%；
Mass fraction of the described colored pigment in coloured functional master batch is 4%；
Ring-type polybutylene terephthalate (PBT) CBT is white solid particle at normal temperatures, the meeting when temperature reaches 190 DEG C
Become the same liquid of water, PBT viscosity is its 5000 times under identical viscosity.And CBT has well with PBT, PET, PTT
Compatibility, wettability is strong.In-situ polymerization can occur when being heated to 220 DEG C, that is, generate PBT material.
Coloured ring-type polybutylene terephthalate (PBT) CBT master batch fusing points are low in online adding procedure, and viscosity is low, enter
It is beneficial to mix with polyester fondant after main melt pipe to disperse, while improves pigment and inorganic addO-on therapy in polyester fondant
It is scattered, while the catalyst added in polyester polymerization process can be catalyzed CBT ring-opening polymerisations, after CBT ring-opening polymerisations, obtain
Polybutylene terephthalate, it has similar molecular structure to polyester, and compatibility is good, avoids colored components adding procedure
In phenomenon of phase separation, cause difficulty in spinning；CBT ring opening process is controllable simultaneously, passes through catalysis dispersed in polyester fondant
Open loop of the agent to CBT, the generation of cyclic compound and low molecular weight compound in molecule is reduced, avoids difficulty in spinning；Simultaneously
Online adding technology has that process variability is good, small lot, functionalization, it is differential easily, it is multi-functional for developing, it is multicoloured
Color silk new product has obvious advantage.
Two fused mass directly spinnings add the preparation of color silk online
The spinning of pipeline injection is added online using fused mass directly spinning, using the coloured functional master batch that step 1 is prepared as pipe
Road injects raw material, using normal polyester melt as main melt, coloured functional master batch melt is injected into master by pipeline injected system
In melt, then mixed by pipeline static mixer, then conveyed through melt pipe, then through being filtered before spinning, enter spinning
Silk component, carries out melt spinning, through ring wind quenching, oils, and drawing-off, winding obtains fused mass directly spinning and adds color silk online；
Described coloured functional master batch and the ratio ratio of normal polyester are 1:9；
The winding speed that described fused mass directly spinning adds color silk online is 3500~4500 ms/min, ring blowing wind speed
For 0.35~0.5 m/min, ring blowing temperature is 25~28 DEG C, and ring blowing air tube length degree is 120~165 centimetres, draw ratio
For 1.8~2.2 times；
Coloured primary raw powder's production technology is the same as embodiment 2
Embodiment 5
A kind of fused mass directly spinning adds the manufacture method of color silk online, concretely comprises the following steps：
The preparation of one color grain
With coloured primary powder, colored pigment and ring-type polybutylene terephthalate (PBT) are raw material, using melt blending
Method, under 195~210 DEG C of melting temperatures, carry out extruding pelletization, coloured functional master batch is prepared；
Mass fraction of the described coloured primary powder in coloured functional master batch is 19%；
Mass fraction of the described colored pigment in coloured functional master batch is 4%；
Ring-type polybutylene terephthalate (PBT) CBT is white solid particle at normal temperatures, the meeting when temperature reaches 190 DEG C
Become the same liquid of water, PBT viscosity is its 5000 times under identical viscosity.And CBT has well with PBT, PET, PTT
Compatibility, wettability is strong.In-situ polymerization can occur when being heated to 220 DEG C, that is, generate PBT material.
Coloured ring-type polybutylene terephthalate (PBT) CBT master batch fusing points are low in online adding procedure, and viscosity is low, enter
It is beneficial to mix with polyester fondant after main melt pipe to disperse, while improves pigment and inorganic addO-on therapy in polyester fondant
It is scattered, while the catalyst added in polyester polymerization process can be catalyzed CBT ring-opening polymerisations, after CBT ring-opening polymerisations, obtain
Polybutylene terephthalate, it has similar molecular structure to polyester, and compatibility is good, avoids colored components adding procedure
In phenomenon of phase separation, cause difficulty in spinning；CBT ring opening process is controllable simultaneously, passes through catalysis dispersed in polyester fondant
Open loop of the agent to CBT, the generation of cyclic compound and low molecular weight compound in molecule is reduced, avoids difficulty in spinning；Simultaneously
Online adding technology has that process variability is good, small lot, functionalization, it is differential easily, it is multi-functional for developing, it is multicoloured
Color silk new product has obvious advantage.
Two fused mass directly spinnings add the preparation of color silk online
The spinning of pipeline injection is added online using fused mass directly spinning, using the coloured functional master batch that step 1 is prepared as pipe
Road injects raw material, using normal polyester melt as main melt, coloured functional master batch melt is injected into master by pipeline injected system
In melt, then mixed by pipeline static mixer, then conveyed through melt pipe, then through being filtered before spinning, enter spinning
Silk component, carries out melt spinning, through ring wind quenching, oils, and drawing-off, winding obtains fused mass directly spinning and adds color silk online；
Described coloured functional master batch and the ratio ratio of normal polyester are 1:8；
The winding speed that described fused mass directly spinning adds color silk online is 3500~4500 ms/min, ring blowing wind speed
For 0.35~0.5 m/min, ring blowing temperature is 25~28 DEG C, and ring blowing air tube length degree is 120~165 centimetres, draw ratio
For 1.8~2.2 times.
Coloured primary raw powder's production technology is the same as embodiment 1.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
Member, without departing from the inventive concept of the premise, can also make some improvements and modifications, these improvements and modifications also should be regarded as
In protection scope of the present invention.
Claims (6)
1. a kind of fused mass directly spinning adds the manufacture method of color silk online, it is characterised in that concretely comprises the following steps：
First, the preparation of color grain
With coloured primary powder, colored pigment and ring-type polybutylene terephthalate (PBT) are raw material, using the side of melt blending
Method, under 195~210 DEG C of melting temperatures, extruding pelletization is carried out, coloured functional master batch is prepared；
With jade powder, the natural gypsum, lucidum soaked juice is raw material, and the natural gypsum and jade powder are first proportionally added into ball mill
In, using the method for dry powder ball mill, it is ground and mixed mineral powder is prepared, is filled jade powder and the natural gypsum
Point mixing, and the jade powder in process of lapping, the mineral in the natural gypsum are into abundant contact and displacement, powder after control grinding
The average grain diameter of body is 15~20 microns；Then mixed mineral powder after grinding is immersed in lucidum soaked juice, dip time
For 10~20 days, naturally dry is then taken out, obtains pre-processing mixed mineral powder, then pretreated mixed mineral powder
In nitrogen atmosphere, high-temperature calcination under the conditions of 1000~1200 DEG C, calcination time is 2~3h, is then 1500 improving temperature
~1800 DEG C of 2~3h of calcining, finally carry out 15~20min of rapid calcining, with liquid after having calcined under the conditions of 2200~2500 DEG C
Nitrogen is taken for cooling source and rapidly cooled down, and being cooled to room temperature in 5~10s obtains function powder, then screens out average grain diameter as 0.2
~5.0 microns of coloured primary powder；
2nd, fused mass directly spinning adds the preparation of color silk online
Add pipeline injection spinning online using fused mass directly spinning, injected by pipeline of the coloured functional master batch that step 1 is prepared
Raw material, using normal polyester melt as main melt, coloured functional master batch melt is set to be injected into main molten body by pipeline injected system,
Then mixed by pipeline static mixer, then conveyed through melt pipe, then through being filtered before spinning, enter filament spinning component,
Melt spinning is carried out, through ring wind quenching, is oiled, drawing-off, winding obtains fused mass directly spinning and adds color silk online.
2. a kind of fused mass directly spinning as claimed in claim 1 adds the manufacture method of color silk online, it is characterised in that described
The step of one in, mass fraction of the described coloured primary powder in coloured functional master batch be 6~25%.
3. a kind of fused mass directly spinning as claimed in claim 1 adds the manufacture method of color silk online, it is characterised in that described
The step of one in, mass fraction of the described colored pigment in coloured functional master batch be 2~5%.
4. a kind of fused mass directly spinning as claimed in claim 1 adds the manufacture method of color silk online, it is characterised in that described
The step of one in, the mass percent of the raw material of described coloured primary powder is as follows：
Jade powder 6~9.5%
The natural gypsum 2.8~3.5%
Lucidum extracting liquid surplus.
5. a kind of fused mass directly spinning as claimed in claim 1 adds the manufacture method of color silk online, it is characterised in that described
The step of two in, the ratio of described coloured functional master batch and normal polyester is 1:6~1:11.
6. a kind of fused mass directly spinning as claimed in claim 1 adds the manufacture method of color silk online, it is characterised in that described
The step of two in, described fused mass directly spinning add online color silk winding speed be 3500~4500 ms/min, ring blowing air
Speed is 0.35~0.5 m/min, and ring blowing temperature is 25~28 DEG C, and draw ratio is 1.8~2.2 times.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610410537.4A CN106087100B (en) | 2016-06-12 | 2016-06-12 | A kind of fused mass directly spinning adds the manufacture method of color silk online |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610410537.4A CN106087100B (en) | 2016-06-12 | 2016-06-12 | A kind of fused mass directly spinning adds the manufacture method of color silk online |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106087100A CN106087100A (en) | 2016-11-09 |
| CN106087100B true CN106087100B (en) | 2017-12-08 |
Family
ID=57845138
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610410537.4A Active CN106087100B (en) | 2016-06-12 | 2016-06-12 | A kind of fused mass directly spinning adds the manufacture method of color silk online |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106087100B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107513775A (en) * | 2017-09-29 | 2017-12-26 | 太仓市梓怡纺织有限公司 | The preparation method of colored fiber |
| CN109371489A (en) * | 2018-10-11 | 2019-02-22 | 江苏江南高纤股份有限公司 | Colored terylene polyester fondant Direct Spinning method and system |
| CN109402777A (en) * | 2018-10-15 | 2019-03-01 | 广东省化学纤维研究所 | A kind of coloured composite fibre long filament of low melting point and preparation method thereof |
| CN109439572B (en) * | 2018-11-01 | 2021-10-01 | 山东尚科环境工程有限公司 | Microbial agent for sewage treatment, attachment carrier thereof and preparation method thereof |
| CN109735939B (en) * | 2018-12-27 | 2020-10-16 | 江苏恒力化纤股份有限公司 | Melt direct spinning on-line addition colored polyester fiber and preparation method thereof |
| CN110438580A (en) * | 2019-07-30 | 2019-11-12 | 福建百宏聚纤科技实业有限公司 | A kind of environment-friendly type terylene long filament and its manufacturing method |
| CN110565178A (en) * | 2019-08-28 | 2019-12-13 | 无锡索力得科技发展有限公司 | production method of permanent flame-retardant polyester industrial yarn |
| TW202242032A (en) * | 2021-04-23 | 2022-11-01 | 財團法人紡織產業綜合研究所 | Liquid color masterbatch composition and fabricating method for colored fiber |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101956243A (en) * | 2010-06-02 | 2011-01-26 | 成钢 | Nano element anion far infrared fabric underwear for curing diabetes mellitus |
| CN104153035A (en) * | 2014-07-24 | 2014-11-19 | 江苏红豆实业股份有限公司 | Cool flame-retardant recycled polyester filament fiber and production method thereof |
| CN104532377A (en) * | 2014-12-29 | 2015-04-22 | 浙江金霞新材料科技有限公司 | Method for making cool colored special-shaped super fine denier polyester filaments |
| CN105256462A (en) * | 2015-09-29 | 2016-01-20 | 屠明鑫 | Mint fragrant type health-care mattress capable of releasing negative ions and manufacturing method thereof |
-
2016
- 2016-06-12 CN CN201610410537.4A patent/CN106087100B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101956243A (en) * | 2010-06-02 | 2011-01-26 | 成钢 | Nano element anion far infrared fabric underwear for curing diabetes mellitus |
| CN104153035A (en) * | 2014-07-24 | 2014-11-19 | 江苏红豆实业股份有限公司 | Cool flame-retardant recycled polyester filament fiber and production method thereof |
| CN104532377A (en) * | 2014-12-29 | 2015-04-22 | 浙江金霞新材料科技有限公司 | Method for making cool colored special-shaped super fine denier polyester filaments |
| CN105256462A (en) * | 2015-09-29 | 2016-01-20 | 屠明鑫 | Mint fragrant type health-care mattress capable of releasing negative ions and manufacturing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106087100A (en) | 2016-11-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106087100B (en) | A kind of fused mass directly spinning adds the manufacture method of color silk online | |
| CN105908269B (en) | Manufacturing method of special-shaped hollow warmth keeping polyester drawn textured yarn | |
| CN101805934B (en) | Ice-cold viscose fiber and preparation method thereof | |
| CN105926060B (en) | Melt direct spinning superfine denier polyester filament and making method thereof | |
| CN106149091A (en) | A kind of preparation method of the antibacterial coloured environment-friendly polyester fiber of high fire-retardance | |
| CN108221078A (en) | A kind of manufacturing method of polyester filament | |
| CN102011214B (en) | Sheath-core composite fiber and production method thereof | |
| CN103361997A (en) | Silkworm pupa protein, cotton and polyester blended fabric | |
| CN104562258A (en) | Microcapsule phase change temperature adjusting fibers and preparation method of fabric thereof | |
| CN100595360C (en) | Method for variation production of multifunctional dacron fancy composite yarn by traversing gas cylinder | |
| CN101532200A (en) | Production technique of peal silk bedding article and clothing fabric | |
| CN109137138A (en) | A kind of novel waterproof air previous antibacterial fabric and preparation method thereof | |
| CN109898210A (en) | A kind of slim inflaming retarding fabric and preparation method thereof | |
| CN105755613B (en) | A kind of sun washs compound sea-island fibre and preparation method thereof | |
| CN102425015B (en) | Method for preparing fibers with performance of sheep wool and imitated wool fabric | |
| CN105887231B (en) | A kind of manufacture method of fused mass directly spinning high strength polyester filament yarn | |
| CN102409430B (en) | Cross cool easy cation-dyeable polyester (ECDP) fiber and production method thereof | |
| CN201395655Y (en) | Step type modularized acrylic fiber production system | |
| CN102851785A (en) | Ice-cold fiber and its making method | |
| CN104294396B (en) | Fused mass directly spinning adds the preparation method of antibacterial polyester skin-core structure fiber online | |
| CN1240887C (en) | Process for making synthetic fiber colored cloth with high color stability | |
| CN106521966B (en) | It is a kind of functionality polyamide fibre FDY fiber and finishing agent preparation method | |
| CN204198908U (en) | A kind of lustrous polyester fiber and spinning spinnerets used thereof | |
| CN104342777B (en) | A kind of polyester monofilament with far-infrared functional and preparation method thereof | |
| CN108149341A (en) | A kind of easily dye island PTT long filaments and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |