CN101805488B - 一种透明abs材料及其制备方法 - Google Patents
一种透明abs材料及其制备方法 Download PDFInfo
- Publication number
- CN101805488B CN101805488B CN2010101533950A CN201010153395A CN101805488B CN 101805488 B CN101805488 B CN 101805488B CN 2010101533950 A CN2010101533950 A CN 2010101533950A CN 201010153395 A CN201010153395 A CN 201010153395A CN 101805488 B CN101805488 B CN 101805488B
- Authority
- CN
- China
- Prior art keywords
- static inhibitor
- abs
- temperature
- transparent
- transparent abs
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000463 material Substances 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 12
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 12
- 239000002216 antistatic agent Substances 0.000 claims abstract description 9
- 230000003068 static effect Effects 0.000 claims description 35
- 239000003112 inhibitor Substances 0.000 claims description 32
- 238000002156 mixing Methods 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 10
- 238000005516 engineering process Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 206010013786 Dry skin Diseases 0.000 claims description 5
- 125000002091 cationic group Chemical group 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000005469 granulation Methods 0.000 claims description 5
- 230000003179 granulation Effects 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- 229920002614 Polyether block amide Polymers 0.000 claims description 3
- 150000001408 amides Chemical group 0.000 claims description 3
- 150000002466 imines Chemical group 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- 239000011521 glass Substances 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 38
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 38
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 38
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 230000035939 shock Effects 0.000 description 4
- 230000005540 biological transmission Effects 0.000 description 3
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000005252 bulbus oculi Anatomy 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/918—Thermal treatment of the stream of extruded material, e.g. cooling characterized by differential heating or cooling
- B29C48/9185—Thermal treatment of the stream of extruded material, e.g. cooling characterized by differential heating or cooling in the direction of the stream of the material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/397—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using a single screw
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92514—Pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92561—Time, e.g. start, termination, duration or interruption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92904—Die; Nozzle zone
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明公开了一种透明ABS材料及其制备方法。透明ABS材料，按重量百分比由下述组分组成：ABS90-95％；主抗静电剂2-5％；辅抗静电剂1-3％；高温抗氧剂1-2％。本发明透明ABS材料保持了ABS的易加工成型性、耐腐蚀性、耐化学性好等优异特性，还具备优异的透明性，而且抗静电效果非常优异，具有永久抗静电性能，在许多领域能代替传统玻璃，在电器、仪表、汽车、医用器械及电子行业中应用前景十分广阔。
Description
[技术领域]
本发明涉及高分子材料技术领域，尤其涉及一种透明ABS材料及其制备方法。
[背景技术]
丙烯腈-丁二烯-苯乙烯共聚物(Acrylonitrile ButadieneStyrene，ABS)，为目前产量最大，应用最广泛的聚合物。它将PS，SAN，BS的各种性能有机地统一起来，兼具韧、硬、刚相均衡的优良力学性能。有极好的冲击强度、尺寸稳定性好、电性能、耐磨性、抗化学药品性、染色性，成型加工和机械加工较好。但是ABS的分子结构决定了其为不良的导体，在使用过程中容易积累大量的静电荷。而静电吸引力容易吸附空气中的灰尘以及一些脏物，影响制品的美观；尤其当静电积累到一定程度，可能会产生静电火花放电，引起一些灾难性事故。
随着社会经济的发展，人们对材料表面的美观要求越来越高，开发具有透感的材料是目前的一个趋势。德国拜耳公司使用模克隆聚碳酸酯透明塑料制作成了全身透明的“eXasis”汽车，它在07年3月日内瓦车展上首次亮相时，吸引了很多人的眼球。现在大多数材料是透明而不抗静电，而抗静电又不透明。所以开发既能透明而又能抗静电的新型材料有重要的研究价值和社会效益。
[发明内容]
本发明要解决的技术问题是提供一种透光性能与抗静电性能都较好的透明ABS材料。
本发明另一个要解决的技术问题是提供上述ABS材料的制备方法。
为了解决上述技术问题，本发明采用的技术方案是，一种透明ABS材料，按重量百分比由下述组分组成：
ABS 90-95％；
主抗静电剂 2-5％；
辅抗静电剂 1-3％；
高温抗氧剂 1-2％。
其中，所述的透明ABS材料，所述ABS相对密度为1.06-1.10％，丙烯腈含量10-15％，丁二烯含量10-15％，苯乙烯含量70-80％，透射率为88％-90％。所述的主抗静电剂为具有聚醚结构、酰胺结构的永久性抗静电剂，优选具有聚醚酰胺亚胺结构的永久性抗静电剂。所述的辅抗静电剂为季铵盐阳离子表面活性剂与非离子型表面活性剂组成的复合物或磺酸盐型的抗静电剂。所述的高温抗氧剂为四-(2，4-二叔丁基苯基)-4，4′-联苯基双亚磷酸酯。
一种上述透明ABS材料制备方法的技术方案是，包括以下步骤：
A)将ABS原料在80℃至90℃干燥3至4小时，并按上述配比称取原料；
B)先将主抗静电剂，辅助抗静电剂以及高温抗氧剂进行预混合2-3分钟，然后将烘干的ABS以及预混合后的物料加入到高速配料搅拌机中，混合5至8分钟；
C)将B步骤中混合好的预混合料置于单螺杆机中熔融挤出造粒。其工艺为：单螺杆一段温度170-280℃、二段温度180-190℃、三段温度190-200℃，模具温度30-60℃，停留时间1-2分钟、压力为10-15MPa。
本发明透明ABS材料保持了ABS的易加工成型性、耐腐蚀性、耐化学性好等优异特性，还具备优异的透明性，而且抗静电效果非常优异，具有永久抗静电性能。
传统的玻璃材料不能满足工业上的轻质、高强度、高韧性、易加工的要求，本发明透明ABS材料在许多领域能代替传统玻璃，可以用来制作各种顶盖、壳体(如收音机、计算机和录音机的外壳，灯罩，透明箱，电视接收机屏板等)；玩具；装饰品；工业包装；汽车零部件；注射器及透明电动工具等。因此，本发明透明ABS材料在电器、仪表、汽车、医用器械及电子行业中应用前景十分广阔。
[具体实施方式]
在以下实施例中，ABS相对密度为1.06-1.10％，丙烯腈含量10-15％，丁二烯含量10-15％，苯乙烯含量70-80％，透射率为88％-90％，可以选用日本电气化学C1-301，奇美的858，东丽的920，三星的UT-0100；
主抗静电剂为具有聚醚结构和酰胺结构的永久性抗静电剂。可以选用日本三洋化成工业株式会社NC6321，NC6321是具有聚醚酰胺亚胺结构的永久性抗静电剂。主抗静电除了选用聚醚结构以外，还可以选用阳离子型的抗静电剂609。
辅抗静电剂为季铵盐阳离子表面活性剂与非离子型表面活性剂组成的复合物，为内加永久型抗静电剂。可以选用的液体抗静电剂APN004。APN004为一种季铵盐阳离子表面活性剂与非离子型表面活性剂组成的复合物。还可以选用磺酸盐型的辅助抗静电剂SKP-01和MJ-22。
高温抗氧剂为四-(2，4-二叔丁基苯基)-4，4′-联苯基双亚磷酸酯，可使用瑞士汽巴公司的P-EPQ。
下面通过实施例对本发明进行进一步阐述：
实施例一：
将ABS原料在80℃干燥3小时，并按如下重量百分比称取原料：ABS 90％，主抗静电剂5％，辅抗静电剂3％，高温抗氧剂2％；
先将主抗静电剂，辅助抗静电剂以及高温抗氧剂进行预混合2-3分钟，然后将烘干的ABS以及预混合后的物料加入到高速配料搅拌机中，混合5至8分钟；
将混合好的物料置于单螺杆机中熔融挤出造粒。其工艺为：单螺杆一段温度170-280℃、二段温度180-190℃、三段温度190-200℃，模具温度30-60℃，停留时间1-2分钟、压力为10-15MPa。
实施例二：
将ABS原料在80℃干燥3小时，并按如下重量百分比称取原料：ABS 93％，主抗静电剂5％，辅抗静电剂1％，高温抗氧剂1％；
先将主抗静电剂，辅助抗静电剂以及高温抗氧剂进行预混合2-3分钟，然后将烘干的ABS以及预混合后的物料加入到高速配料搅拌机中，混合5至8分钟；
将混合好的物料置于单螺杆机中熔融挤出造粒。其工艺为：单螺杆一段温度170-280℃、二段温度180-190℃、三段温度190-200℃，模具温度30-60℃，停留时间1-2分钟、压力为10-15MPa。
实施例三：
将ABS原料在80℃干燥3小时，并按如下重量百分比称取原料：ABS 95％、主抗静电剂2％、辅抗静电剂2％、高温抗氧剂1％；
先将主抗静电剂，辅助抗静电剂以及高温抗氧剂进行预混合2-3分钟，然后将烘干的ABS以及预混合后的物料加入到高速配料搅拌机中，混合5至8分钟；
将混合好的物料置于单螺杆机中熔融挤出造粒。其工艺为：单螺杆一段温度170-280℃、二段温度180-190℃、三段温度190-200℃，模具温度30-60℃，停留时间1-2分钟、压力为10-15MPa。
性能的测试和表征均依据ASTM相关标准；测试条件均为23℃、53％相对湿度。
拉伸强度/断裂伸长率：ASTM D638；
弯曲强度/弯曲模量：ASTM D790；
悬臂梁缺口冲击强度：ASTM D256；
熔融指数；ASTM D1238
热变形温度：ASTM D648(1.82Mpa条件下)；
透光率：ASTM D1003
表面电阻：IEC 60093
下表是奇美ABS 758，日本东丽ABS TP90与本发明的透明性抗静电ABS的性能对照表
| 测试项目 | 实施例1 | 实施例2 | 实施例3 | ABS 758 | TP90 |
| 常温冲击强度(J/m) | 157 | 159 | 161 | 147 | 98 |
| 拉伸强度(MPa) | 40.7 | 41.2 | 42.4 | 33 | 40 |
| 伸长率(％) | 50 | 47 | 45 | 50 | 10 |
| 弯曲强度(MPa) | 53.9 | 54.2 | 55.9 | 56 | 61 |
| 弯曲模量(MPa) | 1500 | 1521 | 1560 | 1500 | 1780 |
| 熔流指数(g/10min)220℃/10kg | 35 | 38 | 40 | 34 | 30 |
| 透光率(％) | 75 | 77 | 78 | 89 | 35 |
| 表面电阻(欧姆) | 1010 | 1011 | 1012 | 1015 | 1011 |
通过对比可以看到本发明透明ABS材料的有益效果是：
1.本发明透明ABS材料的综合性能优异。跟奇美透明ABS 758相比，不仅力学性能(抗冲击性能)、流动性更佳，更为重要的是在保持良好透光性的基础上具有优异的表面电阻；跟日本东丽抗静电ABS TP90相比，不仅力学性能(抗冲击性能)、流动性更佳，更为重要的是在具有良好表面电阻的同时，具有TP90不可比拟的透光性。
2.本发明透明ABS材料综合了TP90的抗静电效果和奇美758的透光性，在电子电器，汽车仪表，透明电动工具，医用器械等方面都有广阔的用途。
Claims (3)
1.一种透明ABS材料，其特征在于，按重量百分比由下述组分组成：
ABS 90-95％；
主抗静电剂 2-5％；
辅抗静电剂 1-3％；
高温抗氧剂 1-2％；
所述的主抗静电剂为具有聚醚结构和酰胺结构的永久性抗静电剂；所述的辅抗静电剂为季铵盐阳离子表面活性剂与非离子型表面活性剂组成的复合物或磺酸盐型的抗静电剂；所述的高温抗氧剂为四-(2，4-二叔丁基苯基)-4，4′-联苯基双亚磷酸酯。
2.根据权利要求1所述的透明ABS材料，其特征在于，所述的主抗静电剂为具有聚醚酰胺亚胺结构的永久性抗静电剂。
3.一种权利要求1所述的透明ABS材料的制备方法，其特征在于，包括以下步骤：
A)将ABS原料在80℃至90℃干燥3至4小时，并按权利要求1的配比称取原料；
B)先将主抗静电剂，辅助抗静电剂以及高温抗氧剂进行预混合2-3分钟，然后将烘干的ABS以及预混合后的物料加入到高速配料搅拌机中，混合5至8分钟；
C)将B步骤中混合好的预混合料置于单螺杆机中熔融挤出造粒；其工艺为：单螺杆一段温度170-280℃、二段温度180-190℃、三段温度190-200℃，模具温度30-60℃，停留时间1-2分钟、压力为10-15MPa。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101533950A CN101805488B (zh) | 2010-04-16 | 2010-04-16 | 一种透明abs材料及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101533950A CN101805488B (zh) | 2010-04-16 | 2010-04-16 | 一种透明abs材料及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101805488A CN101805488A (zh) | 2010-08-18 |
| CN101805488B true CN101805488B (zh) | 2012-12-19 |
Family
ID=42607451
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010101533950A Expired - Fee Related CN101805488B (zh) | 2010-04-16 | 2010-04-16 | 一种透明abs材料及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101805488B (zh) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102311609A (zh) * | 2010-09-29 | 2012-01-11 | 深圳市科聚新材料有限公司 | 一种绿色透明abs复合材料及其制备方法 |
| CN103724920B (zh) * | 2013-12-06 | 2016-06-22 | 苏州贤聚科技股份有限公司 | 一种永久抗静电透明abs及其制备方法 |
| CN104962030A (zh) * | 2015-07-12 | 2015-10-07 | 陆思烨 | 一种天然抗菌耐老化abs材料及其制备方法 |
| CN106317756A (zh) * | 2016-09-29 | 2017-01-11 | 四川天视车镜有限责任公司 | 一种抗变形的汽车后视镜外壳材料及制备方法 |
| CN106589774A (zh) * | 2016-12-16 | 2017-04-26 | 东至天孚化工有限公司 | 一种化工小试分液漏斗放液用塑料活塞加工材料 |
| CN108752846A (zh) * | 2018-06-20 | 2018-11-06 | 安徽江淮汽车集团股份有限公司 | 一种车载净化器风道出口的abs复合材料及其制备方法 |
| CN110922666A (zh) * | 2019-12-12 | 2020-03-27 | 山东东宏管业股份有限公司 | 一种可染色永久抗静电阻燃聚烯烃材料及其制备方法与应用 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101130683A (zh) * | 2007-08-06 | 2008-02-27 | 海信集团有限公司 | 空调风扇用抗菌防尘材料及其制作方法 |
| CN101506300A (zh) * | 2006-09-12 | 2009-08-12 | 第一毛织株式会社 | 具有优异的冲击强度和流动性的透明abs树脂组合物 |
-
2010
- 2010-04-16 CN CN2010101533950A patent/CN101805488B/zh not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101506300A (zh) * | 2006-09-12 | 2009-08-12 | 第一毛织株式会社 | 具有优异的冲击强度和流动性的透明abs树脂组合物 |
| CN101130683A (zh) * | 2007-08-06 | 2008-02-27 | 海信集团有限公司 | 空调风扇用抗菌防尘材料及其制作方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101805488A (zh) | 2010-08-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101805488B (zh) | 一种透明abs材料及其制备方法 | |
| KR101328296B1 (ko) | 유리섬유 강화 폴리카보네이트 난연 수지 조성물 | |
| CN102108187B (zh) | 一种高灼热丝环保型阻燃增强pbt/abs合金材料及其制备方法 | |
| CN103044901B (zh) | 一种高流动性无卤阻燃增强尼龙复合材料及其制备方法 | |
| CN101759976B (zh) | 一种专用于笔记本外壳专用的pc/abs合金材料 | |
| CN102617997B (zh) | 一种玻璃纤维增强pbt/pet复合材料及其制备方法 | |
| CN102051032A (zh) | 一种笔记本外壳专用pc/abs合金 | |
| KR20080024042A (ko) | 내충격성 및 유동성이 우수한 투명 ａｂｓ 수지 조성물 | |
| CN102030957A (zh) | 一种高光泽耐划伤抗静电abs合金 | |
| CN101787191A (zh) | 一种pc/abs合金及其制备方法 | |
| JP2013053211A (ja) | 熱可塑性エラストマー組成物 | |
| CN104945834A (zh) | 马来酰亚胺型耐热abs合金及其制取方法 | |
| US20040024106A1 (en) | Polymer resin for ion beam or ion injection treatment to give surface conductiveness | |
| CN103289347A (zh) | 一种abs/pc复合材料及其制备方法 | |
| CN104650552A (zh) | 高性能低成本pc/pbt次料回收组合物 | |
| KR101790410B1 (ko) | 난연성 열가소성 수지 조성물 및 이로부터 형성된 성형품 | |
| CN104710744A (zh) | 增韧高抗冲改性pc/pet合金材料及其制备方法 | |
| CN104119666A (zh) | 一种导电ppo料及其制备方法 | |
| CN109810457B (zh) | 一种聚甲基丙烯酸甲酯树脂/丁二烯接枝聚合物组合物及其制备方法 | |
| CN104497463A (zh) | Hips复合材料及其制备方法 | |
| CN103421245A (zh) | 一种增强型无卤阻燃pp/ppo合金及其制备方法 | |
| KR101642201B1 (ko) | 열가소성 수지 조성물 및 이의 제조방법 | |
| CN114230999A (zh) | 一种无卤阻燃抗静电聚碳酸酯树脂组合物及其制备方法 | |
| CN104119653A (zh) | 阻燃聚酯复合材料及其制备方法 | |
| CN104312128A (zh) | 一种抗静电pc/abs合金材料及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Transparent ABS material and preparation method thereof Effective date of registration: 20150817 Granted publication date: 20121219 Pledgee: China Everbright Bank Shenzhen branch Pledgor: Shenzhen Keju New Material Co., Ltd. Registration number: 2015990000679 |
|
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20161202 Granted publication date: 20121219 Pledgee: China Everbright Bank Shenzhen branch Pledgor: Shenzhen Keju New Material Co., Ltd. Registration number: 2015990000679 |
|
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Transparent ABS material and preparation method thereof Effective date of registration: 20170106 Granted publication date: 20121219 Pledgee: Bank of Shizuishan Limited by Share Ltd Yinchuan branch Pledgor: Anhui science and Technology Co., Ltd.|Shenzhen branch poly new materials Co., Ltd.|Xu Dong Registration number: 2016990001133 |
|
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20180904 Granted publication date: 20121219 Pledgee: Bank of Shizuishan Limited by Share Ltd Yinchuan branch Pledgor: Polymer Science (Anhui) New Material Co., Ltd.|Shenzhen Keju New Material Co., Ltd.|Xu Dong Registration number: 2016990001133 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Transparent ABS material and preparation method thereof Effective date of registration: 20181119 Granted publication date: 20121219 Pledgee: Bank of Shizuishan Limited by Share Ltd Yinchuan branch Pledgor: Shenzhen Keju New Material Co., Ltd.|Polymer Science (Anhui) New Material Co., Ltd. Registration number: 2018440020071 |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20121219 Termination date: 20190416 |