CN101790609B - Fabric material for sports - Google Patents
Fabric material for sports Download PDFInfo
- Publication number
- CN101790609B CN101790609B CN200880104538XA CN200880104538A CN101790609B CN 101790609 B CN101790609 B CN 101790609B CN 200880104538X A CN200880104538X A CN 200880104538XA CN 200880104538 A CN200880104538 A CN 200880104538A CN 101790609 B CN101790609 B CN 101790609B
- Authority
- CN
- China
- Prior art keywords
- cloth
- sliver
- woven fabric
- silk material
- silk
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004744 fabric Substances 0.000 title claims abstract description 172
- 239000000463 material Substances 0.000 title claims abstract description 94
- 239000002759 woven fabric Substances 0.000 claims abstract description 83
- 239000000835 fiber Substances 0.000 claims abstract description 51
- 229920000728 polyester Polymers 0.000 claims abstract description 39
- 230000035699 permeability Effects 0.000 claims abstract description 12
- 229920005749 polyurethane resin Polymers 0.000 claims description 41
- 238000007334 copolymerization reaction Methods 0.000 claims description 23
- 229920000515 polycarbonate Polymers 0.000 claims description 13
- 239000004417 polycarbonate Substances 0.000 claims description 13
- 238000005299 abrasion Methods 0.000 claims description 11
- 238000007598 dipping method Methods 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 8
- 238000010586 diagram Methods 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 abstract description 4
- 229920002803 thermoplastic polyurethane Polymers 0.000 abstract description 3
- 239000002131 composite material Substances 0.000 abstract 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 28
- 229920005989 resin Polymers 0.000 description 27
- 239000011347 resin Substances 0.000 description 27
- 238000000034 method Methods 0.000 description 23
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 19
- 239000004753 textile Substances 0.000 description 17
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 description 15
- 238000012360 testing method Methods 0.000 description 12
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 239000003431 cross linking reagent Substances 0.000 description 10
- -1 polybutylene terephthalate Polymers 0.000 description 10
- 230000008569 process Effects 0.000 description 10
- 238000012545 processing Methods 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 238000004043 dyeing Methods 0.000 description 8
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 230000033001 locomotion Effects 0.000 description 7
- 230000008520 organization Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 150000003961 organosilicon compounds Chemical class 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 230000008859 change Effects 0.000 description 5
- 239000003153 chemical reaction reagent Substances 0.000 description 5
- 230000007812 deficiency Effects 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 238000001802 infusion Methods 0.000 description 5
- 229920002635 polyurethane Polymers 0.000 description 5
- 239000004814 polyurethane Substances 0.000 description 5
- 238000002203 pretreatment Methods 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 239000012948 isocyanate Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- 238000006424 Flood reaction Methods 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000004651 carbonic acid esters Chemical class 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 230000002940 repellent Effects 0.000 description 3
- 239000005871 repellent Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 125000006267 biphenyl group Chemical group 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000006482 condensation reaction Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- DMEGYFMYUHOHGS-UHFFFAOYSA-N cycloheptane Chemical group C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000012797 qualification Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000011342 resin composition Substances 0.000 description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 1
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Natural products OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 101001075931 Halobacterium salinarum (strain ATCC 700922 / JCM 11081 / NRC-1) 50S ribosomal protein L6 Proteins 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- TXXWBTOATXBWDR-UHFFFAOYSA-N n,n,n',n'-tetramethylhexane-1,6-diamine Chemical compound CN(C)CCCCCCN(C)C TXXWBTOATXBWDR-UHFFFAOYSA-N 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229920002215 polytrimethylene terephthalate Polymers 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 210000000697 sensory organ Anatomy 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Images
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D1/00—Woven fabrics designed to make specified articles
- D03D1/0035—Protective fabrics
- D03D1/0041—Cut or abrasion resistant
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/30—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the fibres or filaments
- D03D15/37—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the fibres or filaments with specific cross-section or surface shape
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
- D03D15/43—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads with differing diameters
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
- D03D15/44—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads with specific cross-section or surface shape
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
- D03D15/44—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads with specific cross-section or surface shape
- D03D15/46—Flat yarns, e.g. tapes or films
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/573—Tensile strength
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/06—Load-responsive characteristics
- D10B2401/063—Load-responsive characteristics high strength
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2507/00—Sport; Military
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2507/00—Sport; Military
- D10B2507/04—Sails
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3065—Including strand which is of specific structural definition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3472—Woven fabric including an additional woven fabric layer
- Y10T442/3504—Woven fabric layers comprise chemically different strand material
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Woven Fabrics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Laminated Bodies (AREA)
Abstract
A fabric material useful for sports, such as paraglider, hang glider and yacht sail. The invention provides a composite fabric including a ground fabric of polyester fiber woven fabric and an infused adhering layer of silicone copolymerized urethane resin infused in and adhering to the ground fabric. The composite fabric is characterized in that the ground fabric has a mass of 20 to 80 g/m2, and that the content of infused adhering layer relative to the mass of the ground fabric is in the range of 5 to 40 mass%, and that the mass% of the composite fabric is in the range of 21 to 100 g/m2 and the air permeability of the composite fabric is 1.0 ml/cm2/sec.
Description
Technical field
The present invention relates to fabric material for sports.More detailed, the present invention relates to utilize the cloth and silk material that uses in the motion of wind like paraglider, hang glider, sailing boat (yacht sail), spinnaker, kite surfboard and stunt kite etc.
Background technology
In recent years, along with increasing of leisure, be that the tendency of interest increases with the motion.It is varied that its content also becomes, and recently, the motion of leisure types such as movement overseas and aerial sports also catches on.Use goods as these movement overseas, aerial sports, sailing boat, spinnaker, paraglider, hang glider, kite surfboard etc. are arranged, wherein use fiber fabric.In the past, used fibrous material,, used nylon fiber always from good viewpoints such as light weight, intensity as these motions.Cloth and silk is used in these motions, owing to use out of doors for a long time, thereby demanding weather fastness, therefore bring into use than the better polyester fiber of the nylon of weather fastness difference.In patent documentation 1, propose a kind of sports requsites of polyester fiber that uses and used cloth and silk; In addition; In patent documentation 2, proposed a kind of sports requsites and used cloth and silk material, it makes on organic siliconresin and the fabric of polyurethane resin attached to the anti-tearing configuration (ripstop structure) that uses polyester fiber and obtains.
But, use cloth and silk as these sports requsites, not only expect weather fastness, also expect the raising of TEAR STRENGTH and abrasion performance, under the situation of the woven fabric that carries out resin finishing, special expectation improves TEAR STRENGTH.
And, a kind of cloth and silk has been proposed in patent documentation 3, it has carried out the WATER REPELLENT TREATMENT as pre-treatment in order to improve TEAR STRENGTH before polyurethane resin processing.Through before polyurethane resin processing, carrying out WATER REPELLENT TREATMENT, the slip of fiber improves, and TEAR STRENGTH improves, but after research in confirm that it is inhomogeneous to be easy to generate adhering to of polyurethane resin like this, the fluctuation of TEAR STRENGTH is very big.
Patent documentation 1: No. 2653919 communique of Japan Patent
Patent documentation 2: TOHKEMY 2005-97787 communique
Patent documentation 3: the special fair 4-59139 communique of Japan
Summary of the invention
The present invention provides a kind of sports requsites of wind that utilizes to use cloth and silk material, and being included in the polyester fiber is that dipping adheres to the resinoid cloth and silk of polyurethane of organosilicon copolymerization on the woven fabric of main composition composition, and its TEAR STRENGTH is good.
The inventor furthers investigate with the resin on the cloth and silk for being attached to sports requsites; The result finds through using the polyurethane resin of organosilicon copolymerization; Not only given play to good TEAR STRENGTH, and abrasion intensity also improve, accomplished the present invention based on this viewpoint.
Fabric material for sports of the present invention comprises the compound cloth and silk that contains base cloth and dipping adhesion layer; Above-mentioned base cloth constitutes by containing the woven fabric of polyester fiber as main component; Above-mentioned dipping adhesion layer dipping is attached on the above-mentioned base cloth; And the polyurethane resin that contains the organosilicon copolymerization is characterized in that as main component the quality of above-mentioned base cloth is 20～80g/m
2, the quality of above-mentioned dipping adhesion layer is 5～40 quality % with respect to the quality of above-mentioned base cloth, and the quality of above-mentioned compound cloth and silk is 21～100g/m
2, the air permeability of above-mentioned compound cloth and silk is 1.0ml/cm
2Below/second.
Sports requsites of the present invention is with in the cloth and silk material, and the polyurethane resin of preferred above-mentioned organosilicon copolymerization comprises the polycarbonate-based polyurethane resin of organosilicon copolymerization.
Sports requsites of the present invention is with in the cloth and silk material, and preferred above-mentioned base cloth has the above TEAR STRENGTH of 29.42N (3.0kgf).
Sports requsites of the present invention is with in the cloth and silk material, and preferred above-mentioned base cloth has the percentage elongation more than the above TENSILE STRENGTH of 294.1N (30kgf)/5cm and 10%, and has the abrasion intensity more than 75 times.
Sports requsites of the present invention is with in the cloth and silk material; (unit: (unit: dtex) woven fabric strengthens with the many warp thread of polyester fiber fineness degree sliver B and weft yarn formation 2～5 times fineness dtex) preferred above-mentioned base cloth by containing many polyester fiber master sliver A and the fineness with above-mentioned main sliver A with woven fabric; In the sliver Pareto diagram separately of above-mentioned warp thread and weft yarn; In the above-mentioned main sliver A of per 2～50 parallel disposed adjacent; Dispose 1 above-mentioned fineness degree sliver B, constitute clathrate at above-mentioned base cloth in woven fabric thus and strengthen woven tissue.
Sports requsites of the present invention is with in the cloth and silk material, and the cross section of preferred above-mentioned polyester fiber has the flat concaveconvex shape that makes 2～6 circles overlap each other and connect along its major axis.
Fabric material for sports of the present invention, its TEAR STRENGTH and abrasion good strength particularly can provide paraglider, sailing boat, kite surfboard etc. to utilize the fabric material for sports of wind.
Description of drawings
Fig. 1 is the organization chart of woven fabric tissue of an example of the expression woven fabric that is used as base cloth in the fabric material for sports of the present invention.
Fig. 2 is the figure of the preferred shape of cross section of the contained polyester woven fabric of the base cloth of illustration fabric material for sports of the present invention; Wherein, being 2 circles of expression (a) overlaps and the sectional view of an example of the flat concavo-convex cross sectional shape that connects along the major axis in cross section each other; (b) being 3 circles of expression overlaps and the sectional view of an example of the flat concavo-convex cross sectional shape that connects along the major axis in cross section each other; (c) being 4 circles of expression overlaps and the sectional view of an example of the flat concavo-convex cross sectional shape that connects along the major axis in cross section each other; (d) being 5 circles of expression overlaps and the sectional view of an example of the flat concavo-convex cross sectional shape that connects along the major axis in cross section each other; Being 6 circles of expression (e) overlaps and the sectional view of an example of the flat concavo-convex cross sectional shape that connects along the major axis in cross section each other.
The specific embodiment
Sports requsites of the present invention contains the urethane resin layer of base cloth and organosilicon copolymerization with cloth and silk material; Said base cloth constitutes by containing the woven fabric of polyester fiber as main component, and the urethane resin layer of said organosilicon copolymerization floods attached to this base cloth with on the woven fabric.Preferred above-mentioned base cloth is formed by polyester with polyester fiber; Said polyester be contain terephthalic acid (TPA) and/or naphthalenedicarboxylic acid as the aromatic dicarboxylic acid of main component with contain ethylene glycol, 1, ammediol and/or tetramethylene glycol obtain as diol component as the diol component of main component.Use polymer as preferred fiber among the present invention, use PETG, polybutylene terephthalate (PBT), polytrimethylene terephthalate and PEN etc.These polyester polymers also can contain M-phthalic acid, adipic acid, oxo benzoic acid, diethylene glycol (DEG), propylene glycol, trimellitic acid, pentaerythrite etc. more than a kind as copolymer composition.
Above-mentioned base cloth woven fabric is with containing additives such as stabilizing agent, colouring agent, antistatic additive in the polyester woven fabric.
The fineness of preferred polyester fiber of the present invention (line density) is 15～300dtex, and more preferably 20～200dtex further is preferably 30～170dtex.When fineness deficiency 15dtex, as the intensity difference of woven fabric, can't bring into play as the performance of sports requsites with cloth and silk material, on the other hand, when fineness surpassed 300dtex, cloth and silk weight became overweight, had the situation that is not suitable for sports requsites.The filament fineness (below be called DPF) that is preferred for polyester fiber of the present invention is 1.5～3.5dtex.When the not enough 1.5dtex of DPF, the cloth and silk material of being made by this fiber produces and becomes too soft and the unfavorable condition of fracture easily, in addition, if the situation that DPF greater than 3.5dtex, then exists the cloth and silk material made by this fiber to become too thick and stiff.
It is above with more than 10% that the TENSILE STRENGTH of the employed polyester fiber of base cloth woven fabric of cloth and silk material of the present invention and tensile elongation preferably are respectively 4.8cN/dtex, more preferably is respectively 5.0～15.0cN/dtex and 10～30%.Usually, for polyester fiber, if its TENSILE STRENGTH increases, then tensile elongation has the tendency of reduction.Even the TENSILE STRENGTH of polyester fiber is more than the 4.8cN/dtex; When its tensile elongation less than 10%; Use for example spinnaker of sports requsites that such polyester fiber makes, at the full wind of drum suddenly, when receiving big blast, exist this apparatus to be out of shape (elongation) immediately; Absorb the energy of wind and the performance that is used and become insufficient, the situation of fracture easily becomes.In addition, even the tensile elongation of polyester fiber is more than 10%, when its TENSILE STRENGTH deficiency 4.8cN/dtex, there is the situation of fracture easily in the cloth and silk material that contains this polyester fiber when receiving rapid blast.
The woven of the employed woven fabric of base cloth of cloth and silk material of the present invention organized not restriction especially, but preferably has the woven tissue that clathrate strengthens machine-knitted structure.
Above-mentioned clathrate among the present invention strengthens machine-knitted structure; Strengthened by main sliver A and woven fabric and to constitute with fineness degree sliver B, the fineness of above-mentioned fineness degree sliver B is 2～5 times of fineness of above-mentioned main sliver A, and in the sliver Pareto diagram separately of the warp thread of woven fabric and weft yarn; In per 20～50 main sliver A that are arranged in parallel with each other; Be arranged with 1 fineness degree sliver B, thus, on the base cloth woven fabric, form clathrate and strengthen machine-knitted structure.
Fig. 1 is that the clathrate that has of expression cloth and silk material of the present invention strengthens the figure of the base cloth of woven tissue with an example of the woven tissue of woven fabric.In Fig. 1; In the sliver Pareto diagram of base cloth with the warp thread of woven fabric 10 of cloth and silk material of the present invention; Constitute the repetition warp thread through 10 main sliver A and 1 fineness degree sliver B and arrange unit 1; Be adjacent to form by 2 main sliver A and 1 repetition warp thread arrangement unit 2 that fineness degree sliver B constitutes on its right, this warp thread is arranged alternately repeated arrangement of unit 1 and 2.In addition; In the sliver Pareto diagram of weft yarn; Constitute repetition weft yarn arrangement unit 3 through 8 main sliver A and 1 fineness degree sliver B, thereunder constitute repetition weft yarn arrangement unit 4 through 2 main sliver A and 1 fineness degree sliver B, above-mentioned weft yarn arrangement unit 3 and 4 is repeated arrangement alternately.As shown in Figure 1, because therefore warp thread and weft yarn weave in warp thread that comprises many main sliver A and weft yarn, dispose fineness degree sliver B regularly in the main sliver A of each regulation radical, thus, constitute the woven tissue of cancellate enhancing.
Above-mentioned fineness degree sliver B closes the sliver that yarn forms with 2～5 above-mentioned main sliver A.Through such fineness degree sliver B is inweaved on the warp thread direction of woven fabric and weft direction at base cloth regularly, can play a role as reinforcing material for the woven fabric that obtains, can demonstrate big opposing effect for the distortion and the fracture of woven fabric.
When 2 times of the yarn fineness of the not enough main sliver A of the yarn fineness of above-mentioned fineness degree sliver B; The reinforced effects of this fineness degree sliver B is insufficient, in addition, if greater than 5 times; Though then the reinforced effects of this fineness degree sliver B improves, the flexibility of resulting woven fabric has the tendency of reduction.In addition; During 2 of the number deficiency of the main sliver A that between 2 fineness degree sliver B, arranges; Above-mentioned 2 fineness degree sliver B play and the identical effect of the situation of closing yarn of using them; The flexibility of the woven fabric that obtains is reduced, have the anti-blast characteristic of utilizing the sports requsites of making as the cloth and silk material of base cloth with this woven fabric inadequate situation that becomes.
In addition; If the number of the main sliver A that between 2 fineness degree sliver B, arranges is more than 50; Then the interval of 2 fineness degree sliver B becomes excessive, so mutual concertedness reduces between the sliver of these 2 fineness degree sliver B, has its reinforced effects to woven fabric inadequate situation that becomes.In polyester fiber woven fabric used in the present invention; Preferred fineness degree sliver B is 5～50% with respect to the weight ratio of whole slivers; When its less than 5%, insufficient by the woven fabric reinforced effects that the fineness degree sliver brings, in addition; If it is greater than 50%, then there are the feel of resulting woven fabric and the situation of degraded appearance.
In cloth and silk material of the present invention, be necessary that dipping adheres to resin to reduce gas permeability in the base cloth that is made up of the polyester fiber woven fabric.Also can use on non-cracking ground even receive big blast, be necessary to make cloth and silk itself to have the retractility of appropriateness in order to make the full wind of making by cloth and silk material of the present invention of sports requsites drum.Therefore, the resin of giving base cloth must be the resin of the character that can keep such, considers the optimization polyurethane resin from viewpoints such as versatility, economy, operability.When resins such as use acrylic resin, Corvic, though can reduce gas permeability, the hardening of cloth and silk material own, when therefore receiving big blast at the full wind of drum, the retractility of cloth and silk itself diminishes and might rupture, and is therefore not preferred.
Polyurethane resin has ethers polyurethane resin, ester class polyurethane resin, carbonates polyurethane resin etc.; But during these polyurethane resins of known use; If before resin finishing, do not carry out WATER REPELLENT TREATMENT, then can't obtain good TEAR STRENGTH as pre-treatment.The inventor has carried out deep research to the polyurethane resin that uses among the present invention, and the result finds before giving polyurethane resin, to there is no need to carry out pre-treatment through using the polycarbonate-based polyurethane resin of organosilicon copolymerization, can have high TEAR STRENGTH.And find, through using such resin, abrasion intensity is improved.
The polycarbonate-based polyurethane resin of organosilicon copolymerization is in preparation during polycarbonate-based polyurethane resin, makes the particularly resin that forms of organopolysiloxane copolymerization and modification of itself and organo-silicon compound.
The polycarbonate polyurethane resin composition can prepare through the condensation reaction of PCDL, organic multiple isocyanate, aklylene glycol and diamine compound.As PCDL, can enumerate 1,6-hexyl carbonate glycol, polyhexamethylene carbonic acid ester glycol, polytetramethylene carbonic acid ester glycol, poly-5-methylene carbonate glycol, gather heptamethylene carbonic acid ester glycol etc.Wherein, preferred 1,6-hexyl carbonate glycol.As organic multiple isocyanate; Can enumerate dicyclohexyl methyl hydride-4, aliphatic or alicyclic diisocyanates such as 4-vulcabond, hexamethylene diisocyanate, IPDI, two (isocyanates methyl) cyclohexane, lysine isocyanates; And Toluene-2,4-diisocyanate; 4-vulcabond, Toluene-2,4-diisocyanate; 6-vulcabond, diphenyl methane-4; 4 '-vulcabond, diphenyl methane-2,4 '-vulcabond, PPDI, ditolyl vulcabond, 1, aromatic diisocyanates such as 5-naphthalene diisocyanate, xylene diisocyanate.Wherein, preferred dicyclohexyl methyl hydride-4,4-vulcabond.As aklylene glycol, can enumerate 1,6-hexylene glycol, 1,4-butanediol, 1,5-pentanediol etc.Wherein, preferred 1, the 6-hexylene glycol.As diamine compound, can enumerate IPD, toluenediamine, tetramethyl hexamethylene diamine, hexamethylene diamine etc., wherein, preferred IPD.
When carrying out this condensation reaction, preferably, can make the organo-silicon compound with 1000～12000 molecular weight, preferred organopolysiloxane compound copolymerization.The preferred one of which of an above-mentioned organo-silicon compound end group has 2-CH
2OH base (primary alconol residue), another end group right and wrong are reactive, for example, and the preferred compound that uses with following chemical constitution.
[wherein, R representes alkyl, and n representes 2～130 integer, and Me representes methyl]
In the organo-silicon compound of following formula, has 2-CH in the end group in left side
2OH base (primary alconol residue), the end group-SiMe on right side
3It is non-reactive group.Copolymerization with organo-silicon compound in, when its two end groups all are the primary alconol residue,, then have the inadequate situation of TEAR STRENGTH of resulting cloth and silk material if use for example following organo-silicon compound.
In the polycarbonate-based polyurethane resin of organosilicon copolymerization used in the present invention, the content of organosilicon copolymer composition is preferably 3～15 quality % with respect to the quality of polycarbonate-based polyurethane resin composition, more preferably 5～10 quality %.In addition, the molecular weight of the polycarbonate-based polyurethane resin of organosilicon copolymerization is preferably 30,000～500,000, and more preferably 50,000～350,000.
In the polycarbonate-based polyurethane resin of organosilicon copolymerization; If silicone ingredients contain quantity not sufficient 3 quality %, then exist the cloth and silk material that obtains mechanical strength, particularly wear and tear the inadequate situation of intensity, in addition; If it surpasses 15 quality %; Then the friction of cloth and silk material reduces, and between cloth and silk, is easy to generate slip, has the unfavorable condition of coiling property variation.In addition, the molecular weight deficiency of the polycarbonate-based polyurethane resin of organosilicon copolymerization 30,000 o'clock produces the unfavorable condition that can't fully improve TEAR STRENGTH sometimes, and in addition, if it surpasses 500,000, then viscosity increases, and produces the unfavorable condition of dipping property reduction sometimes.
The quality of the base cloth woven fabric in the cloth and silk material of the present invention, for the fracture strength that keeps cloth and silk material and TEAR STRENGTH in proper level, be preferably 20～80g/m
2, 30～75g/m more preferably
2If the mass deficiency 20g/m of base cloth woven fabric
2, then can't obtain sufficient fracture strength, fracture easily becomes when receiving high blast.In addition, it surpasses 80g/m
2The time, because the adhesion amount of resin becomes the ratio ground of a certain degree to increase with the woven fabric quality, so the quality of cloth and silk becomes excessive, not only the gliding ability of resulting sports requsites reduces, and the carrying inconvenience that also becomes.
In cloth and silk material of the present invention, the resin adhesion amount is 5～40 quality % with respect to the woven fabric quality optimization, more preferably 10～35 quality %.If resin adhesion amount less than 5 quality % though the TEAR STRENGTH of the cloth and silk material that then obtains improves, can't reduce gas permeability fully; This cloth and silk material drum is expired wind and can be utilized the performance of its blast insufficient, for example, and under the situation of kite surfboard or paraglider; Gliding ability reduces and becomes dangerous; In addition, under the lateen situation, utilize the performance of wind to reduce efficiently.On the other hand, when the resin adhesion amount surpassed 40 quality %, the quality of resulting cloth and silk material became excessive, and its processing operability significantly reduces, thereby not preferred.
Cloth and silk material of the present invention, if its quality is excessive, the gliding ability of the sports requsites that then not only obtains reduces, and also inconvenient during carrying, and in addition, for example spinnaker use cloth and silk material, and excessive cloth and silk quality causes its processing operability significantly to reduce.But if the cloth and silk quality is too small, then the fracture strength of this cloth and silk material and TEAR STRENGTH are not enough.Therefore, preferred cloth and silk weight of the present invention is 20～100g/m
2, 30～80g/m more preferably
2
Even for cloth and silk material of the present invention also can not torn after using repeatedly, its TEAR STRENGTH is necessary for more than the 29.42N (3.0kgf), is preferably 39.2N (4.0kgf)～98.0N (10.0kgf).During the not enough 29.42N of TEAR STRENGTH (3.0kgf), by the sports requsites that this cloth and silk is made, for example the kite surfboard is when gliding, and when perhaps spinnaker received high blast at the full wind of drum, the possibility of tearing uprised.
In addition, it is above with more than 10% that the TENSILE STRENGTH of cloth and silk material of the present invention and percentage elongation must be respectively 294.1N (30kgf)/5cm, preferably is respectively 400～700N/5cm and 10～25%.Usually, the fracture strength of cloth and silk material and percentage elongation according to the structure of woven fabric with have or not resin finishing etc. to change, if but improve TENSILE STRENGTH, then percentage elongation has the tendency of reduction.Even TENSILE STRENGTH is more than the 294.1N/5cm, when percentage elongation less than 10%, the toughness of this cloth and silk material is insufficient, therefore at the sports requsites of making by cloth and silk material at the full wind of drum suddenly, when receiving high blast, the danger of fracture uprises quickly.On the other hand, during TENSILE STRENGTH is not enough 294.1N/5cm, the sports requsites of being made by this cloth and silk material is because its low TENSILE STRENGTH, and when receiving high blast, fracture easily becomes.Therefore, two characteristics of percentage elongation that satisfy simultaneously more than the above TENSILE STRENGTH of 294.1N/5cm and 10% are important on the anti-breaking property that improves cloth and silk material.
And the air permeability of cloth and silk material is necessary for 1.0ml/cm among the present invention
2Below/second, be preferably 0.1ml/cm
2/ second below, 0.01ml/cm more preferably
2Below/second.The gas permeability of cloth and silk material surpasses 1.0ml/cm
2During/second, this cloth and silk material drum is expired wind and can be utilized the performance of its blast insufficient, and for example under the situation of kite surfboard or paraglider, gliding ability reduces and becomes dangerous, in addition, under the lateen situation, utilizes the performance reduction of wind efficiently.
And for fear of by using tearing of causing repeatedly or rupturing, the abrasion intensity of cloth and silk material of the present invention is necessary for more than 75 times, more preferably more than 100 times.This be because, if abrasion undercapacity 75 times, then when using repeatedly, at the sports requsites of making by the cloth and silk material full wind of drum and when receiving high blast, the danger that ruptures at worn out position increases suddenly quickly.
In the manufacturing of cloth and silk material of the present invention, polyurethane resin adopts infusion process or rubbing method to the not special qualification of the adding method of base cloth woven fabric.In addition, also can carry out infusion process, two kinds of methods of rubbing method.No matter which kind of method must make polyurethane resin fully soak into and flood in the inside of base cloth woven fabric and adhere to, thereby give resulting cloth and silk material sufficient rerum natura, for example TENSILE STRENGTH, TEAR STRENGTH, abrasion intensity, air permeability.
In addition, polyurethane resin floods when adhering to the base cloth woven fabric with liquid state, and this liquid resin can be a water system, also can be non-water system.
Base cloth of the present invention does not have special qualification with the cross sectional shape of the contained polyester fiber of woven fabric, can have polygons such as common round-shaped, triangle, square shape, hexagonal configuration, elliptical shape, flat pattern, or have 2 abnormity (irregular) shapes such as shape with upper process.In these special-shaped shapes, preferably have flat pattern, the maximum long axis length of flattened cross-sectional shape is with respect to the ratio of minimum minor axis length at this moment, and promptly flat ratio is preferably 3～6, further is preferably 3～4.In such flattened cross-sectional shape, preferably its flat pattern is preferred 2～6, more preferably 3～5 flat concaveconvex shapes that circle is overlapped each other and connected along the major axis in cross section.When the number of the circle that connects is 2～6, for such flat pattern, have 2～6 protuberances and 1～5 recess in each side of its major axis, these protuberances become symmetric shape about major axis in its both sides with recess.In so flat concavo-convex cross sectional shape, if the number of circle connected to one another is 2～6, then its cross-sectional area is big with the difference of area of circle that with its major axis is diameter, and the air permeability of resulting woven fabric suitably reduces.On the other hand; If the number of circle connected to one another is more than 7; The fusion warp thread formability that then has the fiber of such shape of cross section reduces, and produces sometimes on the sliver of the flat concavo-convex shape of cross section that obtains the uneven problem of dyeing takes place easily.
In above-mentioned flat concavo-convex shape of cross section, the diameter of preferred circle connected to one another is equal to each other, and protuberance that preferably is mutually symmetrical about major axis and recess are with respect to the meet at right angles ratio W of ground width measured of major axis
1/ W
2Be 1.1: 3.0, further be preferably 1.1: 2.0.And when the diameter of above-mentioned circle connected to one another differed from one another, preferably its maximum gauge was 1～5 times of minimum diameter, is preferably 1～2 times.
Embodiment
Through following embodiment the present invention is described in more detail.In addition, the rerum natura of putting down in writing among the embodiment is measured through following method.
(1) TEAR STRENGTH
Measure according to JIS L 1096-1999 8.15.1A-1 method (single tongue method).Wherein, draw speed was made as 10cm/ minute.
(2) TENSILE STRENGTH and percentage elongation
Measure according to JIS L 1096-1999 8.12.1A method (galley proof method).Wherein, the spacing jig of test film is made as 10cm, and the width of test film is made as 5cm, and draw speed was made as 10cm/ minute, intensity and percentage elongation when measuring fracture.
(3) air permeability
Measure according to JIS L 1096-1999 8.27.1A method (Fu Leize type method).
(4) abrasion intensity
Measure according to JIS L 1096-1999 8.17.1A-1 method (universal planar process).Wherein, extrusion load is made as 4.45N, and air pressure is made as 2.76 * 10
4Pa, the pouncing paper of use is made as P600-Cw.
(5) level dyeing property
For the uniformity of the cloth and silk material that dyes with the outward appearance of woven fabric, by 3 group members are discussed and carry out examination by sensory organs, judge according to following rank.
The outward appearance of rank product dyed thereby
3 (well) level dyeing is not found to dye inhomogeneous
It is inhomogeneous that 2 (good basically) find that part dyes
1 (bad) finds that all dyeing is inhomogeneous
Use has the 44dtex of circular section shape, the PETG long fiber sliver that the monofilament number is 20 (Supreme Being people's fiber company system " テ ト ロ Application " (trade mark), TENSILE STRENGTH 5.8cN/dtex, percentage elongation 25%), makes following woven fabric.Woven fabric is organized as plain weave; Woven density is 110/25.4mm of warp thread, 93/25.4mm of weft yarn; About unit organization; The structure of warp thread, weft yarn all is: arrange the PETG multifilament of 18 above-mentioned 44dtex in order, arrange then that multifilament textile with 3 above-mentioned 44dtex closes yarn and 1 fineness degree sliver obtaining.The weight per unit area of the woven fabric that obtains is 42g/m
2
This woven fabric after cleaning processing under 96 ℃ continuously, is carried out preboarding under 180 ℃.Afterwards, use the liquid-flow dyeing machine processing of under 130 ℃ temperature, dyeing, after carrying out dried under 120 ℃, under 150 ℃, single face is carried out calender process.
Then, the resin finishing liquid that will have the composition of table 1 record is imparted on the above-mentioned woven fabric through infusion process, implements 120 ℃ drying and 160 ℃ heat treatment then, obtains cloth and silk material.The weight per unit area of resulting cloth and silk material is 48g/m
2The determination test result is as shown in table 6.
[table 1]
| The chemical reagent and the resin that use | Use amount (part) |
| The polycarbonate-based polyurethane resin of organosilicon copolymerization | 100 |
| DMF | 30 |
| MEK | 30 |
| Crosslinking agent | 3.5 |
| |
3 |
The polyurethane resin of [notes] organosilicon copolymerization: ラ ッ Network ス キ Application US-2384 (trade mark), セ ィ コ one changes into corporate system
DMF: dimethyl formamide, solvent
MEK: methyl ethyl ketone, solvent
Crosslinking agent: コ ロ ネ one ト HL (trade mark), Japanese polyurethane corporate system
Antitack agent: ァ デ ィ テ ィ Block No.5 (trade mark), big Japanese ink chemical industrial company system
In embodiment 2, preparation has the resin finishing liquid of the composition of table 2 record, carries out the single face coating on the woven fabric cloth and silk material that in embodiment 1, obtains, and carries out 120 ℃ heat treatment, obtains cloth and silk material.The weight of resulting cloth and silk material is 52g/m
2The determination test result is as shown in table 6.
[table 2]
| The chemical reagent and the resin that use | Use amount (part) |
| The polycarbonate-based polyurethane resin of organosilicon copolymerization | 100 |
| |
10 |
| Crosslinking agent | 3.5 |
| |
3 |
The polyurethane resin of [notes] organosilicon copolymerization: ラ ッ Network ス キ Application US-2384 (trade mark), セ ィ コ one changes into corporate system
DMF: dimethyl formamide, solvent
Crosslinking agent: コ ロ ネ one ト HL (trade mark), Japanese polyurethane corporate system
Antitack agent: ァ デ ィ テ ィ Block No.5 (trade mark), big Japanese ink chemical industrial company system
In embodiment 3, use 44dtex, monofilament number are 20 PETG long fiber sliver (Supreme Being people's fiber company system " テ ト ロ Application " (trade mark), TENSILE STRENGTH 5.8cN/dtex, percentage elongation 25%), make following woven fabric.Woven fabric is organized as plain weave; Woven density is 166/25.4mm of warp thread, 93/25.4mm of weft yarn; About unit organization, the structure of warp thread is: the PETG multifilament of 10 above-mentioned 44dtex is arranged in order, arranged then that multifilament textile with 4 above-mentioned 44dtex closes yarn and 1 fineness degree sliver obtaining; Arrange the multifilament textile of 2 above-mentioned 44dtex then, arrange the 1 fineness degree sliver that yarn constitutes that closes then by the multifilament textile of above-mentioned 4 44dtex.The structure of weft yarn is: the PETG multifilament of 8 above-mentioned 44dtex is arranged in order; Arrange then that multifilament textile with 4 above-mentioned 44dtex closes yarn and 1 fineness degree sliver obtaining; Arrange the multifilament textile of 2 above-mentioned 44dtex then, arrange the 1 fineness degree sliver that yarn constitutes that closes then by the multifilament textile of above-mentioned 4 44dtex.The weight per unit area of resulting woven fabric is 59g/m
2The weight per unit area of resulting cloth and silk material is 66g/m
2The determination test result is as shown in table 6.
Embodiment 4
In embodiment 4, the woven fabric cloth and silk material that in using embodiment 3, obtains, other and embodiment 2 likewise make cloth and silk material.The weight per unit area of resulting cloth and silk material is 70g/m
2The determination test result is as shown in table 6.
Embodiment 5
In embodiment 5, likewise make cloth and silk material with embodiment 2.Wherein, base cloth is made with woven fabric as follows.Use has the 84dtex of circular section shape, the PETG long fiber sliver that the monofilament number is 36 (Supreme Being people's fiber company system " テ ト ロ Application " (trade mark), TENSILE STRENGTH 5.7cN/dtex, percentage elongation 25%), the woven fabric below making.Woven fabric is organized as plain weave; Woven density is 80 pieces/inch on warp thread, 80/25.4mm of weft yarn; About unit organization, the structure of warp thread and weft yarn all is: the PETG multifilament of 20 above-mentioned 84dtex is arranged in order, arranged then that multifilament textile with 3 above-mentioned 84dtex closes yarn and 1 fineness degree sliver obtaining; Arrange the multifilament textile of 2 above-mentioned 84dtex then, arrange the 1 fineness degree sliver that yarn constitutes that closes then by the multifilament textile of above-mentioned 3 84dtex.The weight per unit area of resulting woven fabric is 75g/m
2The weight of resulting cloth and silk material is 85g/m
2The determination test result is as shown in table 6.
Embodiment 6
In embodiment 6, likewise make woven fabric with embodiment 3, it is carried out the processing identical with embodiment 2.Wherein, the resin adhesion amount that single face is coated with becomes 3 times of embodiment 4.The weight per unit area of resulting cloth and silk material is 81g/m
2The determination test result is as shown in table 6.
Comparative example 1
In comparative example 1; Use has the 44dtex of circular section shape, the PETG long fiber that the monofilament number is 20 (Supreme Being people's fiber company system " テ ト ロ Application " (trade mark); TENSILE STRENGTH 5.8cN/dtex, percentage elongation 25%), make following woven fabric.Woven fabric is organized as plain weave; Woven density is 110/25.4mm of warp thread, 93/25.4mm of weft yarn; About unit organization; The structure of warp thread, weft yarn all is: arrange the PETG multifilament of 18 above-mentioned 44dtex in order, arrange then that multifilament textile with 3 above-mentioned 44dtex closes yarn and 1 fineness degree sliver obtaining.The weight per unit area of resulting woven fabric is 42g/m
2
This woven fabric after cleaning processing under 96 ℃ continuously, is carried out preboarding under 180 ℃.Afterwards, use the liquid-flow dyeing machine processing of under 130 ℃ temperature, dyeing, after carrying out dried under 120 ℃, under 150 ℃, single face is carried out calender process.
Then, as the pre-treatment of polyurethane resin processing, preparation has the resin finishing liquid of the composition of table 3, be imparted to it on above-mentioned woven fabric through infusion process after, carry out drying and heat treatment.
[table 3]
| The chemical reagent and the resin that use | Use amount (g/l) |
| Deicer | 50 |
| Penetrant | 30 |
[notes] deicer: ァ サ ヒ ガ one De AG-710, Asahi Glass corporate system penetrant: isopropyl alcohol (IPA)
Afterwards, the resin finishing liquid that will have the composition of table 4 floods on the woven fabric that has carried out above-mentioned pre-treatment through infusion process and adheres to, and likewise carries out drying and heat treatment with embodiment 1 afterwards, obtains cloth and silk material.
[table 4]
| The chemical reagent and the resin that use | Use amount (part) |
| Ester class polyurethane resin | 100 |
| DMF | 30 |
| MEK | 30 |
| Crosslinking agent | 3.5 |
| |
3 |
[notes] ester class polyurethane resin: ラ ッ Network ス キ Application U-1468 (trade mark), セ ィ コ one changes into corporate system
DMF: dimethyl formamide, solvent
MEK: methyl ethyl ketone, solvent
Crosslinking agent: コ ロ ネ one ト HL (trade mark), Japanese polyurethane corporate system
Antitack agent: ァ デ ィ テ ィ Block No.5 (trade mark), big Japanese ink chemical industrial company system
At last, the resin finishing liquid of the prescription of preparation table 5 having carried out implementing 120 ℃ heat treatment after the single face coating, obtains cloth and silk material.The weight per unit area of resulting cloth and silk material is 51g/m
2The result of determination test is as shown in table 6.
[table 5]
| The chemical reagent and the resin that use | Use amount (part) |
| Ester class polyurethane resin | 100 |
| |
10 |
| Crosslinking agent | 3.5 |
| |
3 |
[notes] ester class polyurethane resin: ラ ッ Network ス キ Application U-1468 (trade mark), セ ィ コ one changes into corporate system
DMF: dimethyl formamide, solvent
Crosslinking agent: コ ロ ネ one ト HL (trade mark), Japanese polyurethane corporate system
Antitack agent: ァ デ ィ テ ィ Block No.5 (trade mark), big Japanese ink chemical industrial company system
Comparative example 2
In comparative example 2, likewise make cloth and silk material with comparative example 1.Wherein, base cloth is made with woven fabric as follows.Use 44dtex, monofilament number are 20 PETG long fiber (Supreme Being people's fiber company system " テ ト ロ Application " (trade mark), TENSILE STRENGTH 5.8cN/dtex, percentage elongation 25%), make following woven fabric.Woven fabric is organized as plain weave; Woven density is 110/25.4mm of warp thread, 110/25.4mm of weft yarn; About unit organization, the structure of warp thread and weft yarn all is: the PETG multifilament of 20 above-mentioned 44dtex is arranged in order, arranged then that multifilament textile with 3 above-mentioned 44dtex closes yarn and 1 fineness degree sliver obtaining; Arrange the multifilament textile of 2 above-mentioned 44dtex then, arrange the 1 fineness degree sliver that yarn constitutes that closes then by the multifilament textile of above-mentioned 3 44dtex.The weight per unit area of resulting woven fabric is 43g/m
2The weight per unit area of resulting cloth and silk material is 49g/m
2The result of determination test is as shown in table 6.
Comparative example 3
In comparative example 3, likewise make cloth and silk material with comparative example 1.Wherein, base cloth is made with woven fabric as follows.Use 84dtex, monofilament number are 36 PETG long fiber (Supreme Being people's fiber company system " テ ト ロ Application " (trade mark), TENSILE STRENGTH 5.7cN/dtex, percentage elongation 25%), make following woven fabric.Woven fabric is organized as plain weave; Woven density is 80 pieces/inch on warp thread, 80 pieces/inch of weft yarns; About unit organization, the structure of warp thread and weft yarn all is: the PETG multifilament of 20 above-mentioned 84dtex is arranged in order, arranged then that multifilament textile with 3 above-mentioned 84dtex closes yarn and 1 fineness degree sliver obtaining; Arrange the multifilament textile of 2 above-mentioned 84dtex then, arrange the 1 fineness degree sliver that yarn constitutes that closes then by the multifilament textile of above-mentioned 3 84dtex.The weight of resulting woven fabric is 75g/m
2The weight per unit area of resulting cloth and silk material is 85g/m
2The determination test result is as shown in table 6.
Embodiment 7
Likewise make cloth and silk material with embodiment 1.Wherein, use to have Fig. 2-shown in (c), with respect to major axis each side have 3 protuberances flat concavo-convex cross sectional shape (flat ratio: 3.5, W
1/ W
2: 1.4), fineness is that 33dtex, monofilament number are PETG long fiber sliver (Supreme Being people's fiber company system " テ ト ロ Application " (trade mark) of 12; TENSILE STRENGTH 5.8cN/dtex, percentage elongation 23%) replaces being used to make the polyester long fiber sliver with circular cross-section of base cloth with woven fabric.The weight per unit area of resulting woven fabric is 35g/m
2The determination test result is as shown in table 6.
Embodiment 8
Likewise make cloth and silk material with embodiment 7.Wherein, when making base cloth and use woven fabric, use to have Fig. 2-the flat concavo-convex cross section (c) put down in writing (flat ratio: 3.4, W
1/ W
2: the polyester long fiber sliver that polyester long fiber sliver 1.4) (total fineness: 84dtex, several 36 of monofilament) replacement has circular cross-section.In the woven manufacturing of base cloth with woven fabric; The woven plain weave tissue that is organized as; The warp thread sliver is made as 80/25.4mm; The weft yarn sliver is made as 80/25.4mm, and the structure of warp thread and weft yarn all is: in per 18 above-mentioned polyester long fiber slivers, what 4 above-mentioned polyester long fiber slivers were set closes 1 on yarn.The weight per unit area of resulting woven fabric is 75g/m
2The mensuration result of resulting cloth and silk material is as shown in table 6.
Embodiment 9
Likewise make cloth and silk material with embodiment 7.Wherein, the long stapled cross sectional shape of polyester that will have the flat concavo-convex cross sectional shape of Fig. 2-(c) change into the cross sectional shape shown in Fig. 2-(b) (flat ratio: 3.1, W
1/ W
2: 1.6).The mensuration result of resulting cloth and silk material is as shown in table 6.
Likewise make cloth and silk material with embodiment 7.Wherein, the long stapled cross sectional shape of polyester that will have the flat concavo-convex cross sectional shape of Fig. 2-(c) change into the cross sectional shape shown in Fig. 2-(d) (flat ratio: 4.6, W
1/ W
2: 1.4).The mensuration result of resulting cloth and silk material is as shown in table 6.
Embodiment 11
Likewise make cloth and silk material with embodiment 7.Wherein, with the long stapled cross sectional shape of polyester shown in Fig. 2-(c) change into the cross sectional shape shown in Fig. 2-(e) (flat ratio: 8.5, W
1/ W
2: 1.2).The mensuration result of resulting cloth and silk material is as shown in table 6.
Comparative example 5
In comparative example 5, likewise make cloth and silk material with embodiment 1.Wherein, base cloth is implemented the single face calender process with woven fabric.In addition, change the composition of the resin finishing liquid of table 1 record as follows.
MEK 60 parts by mass
U135 100 parts by mass
ST90 40 parts by mass
Crosslinking agent 40 parts by mass
[notes]
U135: trade mark, polyurethane resin, セ ィ コ one changes into corporate system
ST90: trade mark, organic siliconresin
Crosslinking agent: コ ロ ネ one ト HL10 (trade mark)
The mensuration result of resulting cloth and silk material is as shown in table 6.
Utilize possibility on the industry
Mechanical strengths such as the TEAR STRENGTH of cloth and silk material of the present invention, TENSILE STRENGTH, abrasion intensity are good; Air permeability is low and have a suitable quality (weight per unit area); Therefore; Can be used for sports requsites, for example paraglider, hang glider, sailing boat, spinnaker, kite surfboard and stunt kite etc. have high practicality on industry.
Claims (5)
1. a sports requsites is used cloth and silk material; It constitutes by containing the compound cloth and silk of base cloth with the dipping adhesion layer; Said base cloth constitutes by containing the woven fabric of polyester fiber as main component, and said dipping adhesion layer dipping is attached on the said base cloth, and the polyurethane resin that contains the organosilicon copolymerization is for as main component; Said cloth and silk material is characterised in that
The quality of said base cloth is 20～80g/m
2,
The quality of said dipping adhesion layer is 5～40 quality % with respect to the quality of said base cloth, and,
The quality of said compound cloth and silk is 21～100g/m
2, and the air permeability of said compound cloth and silk is 1.0ml/cm
2Below/second,
And the polyurethane resin of said organosilicon copolymerization is made up of the polycarbonate-based polyurethane resin of organosilicon copolymerization.
2. cloth and silk material as claimed in claim 1, wherein, said base cloth has the above TEAR STRENGTH of 29.42N (3.0kgf).
3. cloth and silk material as claimed in claim 1, wherein, said base cloth has the percentage elongation more than the above TENSILE STRENGTH of 294.1N (30kgf)/5cm and 10%, and has the abrasion intensity more than 75 times.
4. like each described cloth and silk material in the claim 1～3; Wherein, (unit: (unit: dtex) woven fabric strengthens with the many warp thread of polyester fiber fineness degree sliver B and weft yarn formation 2～5 times fineness dtex) said base cloth by containing many polyester fiber master sliver A and the fineness with said main sliver A with woven fabric; In the sliver Pareto diagram separately of said warp thread and weft yarn; In the said main sliver A of per 2～50 parallel disposed adjacent, dispose 1 said fineness degree sliver B, constitute clathrate at said base cloth in woven fabric thus and strengthen woven tissue.
5. like each described cloth and silk material in the claim 1～3, wherein, the cross section of said polyester fiber has the flat pattern that makes 2～6 circles overlap each other and connect along its major axis.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007262051 | 2007-10-05 | ||
| JP2007-262051 | 2007-10-05 | ||
| PCT/JP2008/068088 WO2009044880A1 (en) | 2007-10-05 | 2008-10-03 | Fabric material for sports |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101790609A CN101790609A (en) | 2010-07-28 |
| CN101790609B true CN101790609B (en) | 2012-10-03 |
Family
ID=40526300
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200880104538XA Active CN101790609B (en) | 2007-10-05 | 2008-10-03 | Fabric material for sports |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20110130061A1 (en) |
| EP (1) | EP2184399B8 (en) |
| JP (1) | JP5069751B2 (en) |
| KR (1) | KR101515659B1 (en) |
| CN (1) | CN101790609B (en) |
| AU (1) | AU2008308002B2 (en) |
| CA (1) | CA2694570C (en) |
| HK (1) | HK1143410A1 (en) |
| TW (1) | TWI463054B (en) |
| WO (1) | WO2009044880A1 (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009203592A (en) * | 2008-02-29 | 2009-09-10 | Seikoh Chem Co Ltd | Coating material for fabric |
| US9920460B2 (en) * | 2009-06-18 | 2018-03-20 | Toray Industries, Inc. | Down-proof woven fabric |
| GB2472070A (en) * | 2009-07-23 | 2011-01-26 | Dyson Technology Ltd | A flexible hose |
| GB2472069A (en) * | 2009-07-23 | 2011-01-26 | Dyson Technology Ltd | A flexible hose made of rip-stop fabric |
| FR2950903B1 (en) | 2009-10-05 | 2012-09-21 | Porcher Ind | LIGHTWEIGHT FABRIC COATED, IN PARTICULAR FOR SAILING |
| JP6205114B2 (en) * | 2012-09-13 | 2017-09-27 | 小松精練株式会社 | Breathable fiber fabric and method for producing the same |
| TWI510357B (en) * | 2013-02-08 | 2015-12-01 | Shu Chieh Wang | Composite laminated structure for shoe stiffener and preparing method thereof |
| KR200490951Y1 (en) * | 2018-12-12 | 2020-01-29 | 곽우근 | Cotton Fabric with Enhanced Agreeableness |
| FR3114820B1 (en) * | 2020-10-05 | 2023-08-04 | Porcher Ind | Lightweight coated fabric, especially for Spinnaker |
| FR3114821B1 (en) * | 2020-10-05 | 2022-12-30 | Porcher Ind | Lightweight coated fabric, especially for flying wings |
| CN112848389B (en) * | 2020-12-21 | 2022-06-24 | 中南大学 | Method for rapidly forming hybrid fiber reinforced thermoplastic composite structure |
| FR3118969B1 (en) * | 2021-01-15 | 2024-04-26 | Porcher Ind | Polyester fabric for boat traction structure |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006063466A (en) * | 2004-08-25 | 2006-03-09 | Teijin Techno Products Ltd | Coated fabric |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01108039A (en) * | 1987-10-21 | 1989-04-25 | Teijin Ltd | Manufacture of basic textile for paraglider |
| US4973510A (en) * | 1987-09-02 | 1990-11-27 | Teijin Limited | Coated sheet material and process for producing same |
| JPS6461243A (en) * | 1987-09-02 | 1989-03-08 | Teijin Ltd | Base fabric for paraglider |
| JPH0241475A (en) * | 1988-07-29 | 1990-02-09 | Teijin Ltd | Base fabric for paraglider |
| ATE147446T1 (en) * | 1991-07-08 | 1997-01-15 | Teijin Ltd | WEBWARE FOR SPORTS GOODS THAT SWELL IN THE WIND |
| JP3329856B2 (en) * | 1992-10-08 | 2002-09-30 | 株式会社クラレ | Polyurethane elastic fiber |
| JP3133957B2 (en) * | 1997-04-25 | 2001-02-13 | アキレス株式会社 | Synthetic leather with excellent wear resistance |
| JP2002103495A (en) * | 2000-09-27 | 2002-04-09 | Toyo Cloth Co Ltd | Functional material |
| JP3895227B2 (en) * | 2002-07-24 | 2007-03-22 | 帝人ファイバー株式会社 | Apparel-related products |
| JP4369190B2 (en) | 2003-09-25 | 2009-11-18 | 帝人ファイバー株式会社 | Sale cross |
-
2008
- 2008-10-03 KR KR1020107004197A patent/KR101515659B1/en active IP Right Grant
- 2008-10-03 CA CA2694570A patent/CA2694570C/en active Active
- 2008-10-03 TW TW97138217A patent/TWI463054B/en active
- 2008-10-03 CN CN200880104538XA patent/CN101790609B/en active Active
- 2008-10-03 WO PCT/JP2008/068088 patent/WO2009044880A1/en active Application Filing
- 2008-10-03 EP EP20080835183 patent/EP2184399B8/en active Active
- 2008-10-03 AU AU2008308002A patent/AU2008308002B2/en active Active
- 2008-10-03 JP JP2009536119A patent/JP5069751B2/en active Active
- 2008-10-03 US US12/674,561 patent/US20110130061A1/en not_active Abandoned
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006063466A (en) * | 2004-08-25 | 2006-03-09 | Teijin Techno Products Ltd | Coated fabric |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101790609A (en) | 2010-07-28 |
| HK1143410A1 (en) | 2010-12-31 |
| EP2184399A1 (en) | 2010-05-12 |
| EP2184399B8 (en) | 2013-09-25 |
| EP2184399B1 (en) | 2013-08-14 |
| US20110130061A1 (en) | 2011-06-02 |
| TW200936839A (en) | 2009-09-01 |
| EP2184399A4 (en) | 2011-05-11 |
| CA2694570C (en) | 2016-03-15 |
| TWI463054B (en) | 2014-12-01 |
| CA2694570A1 (en) | 2009-04-09 |
| AU2008308002A1 (en) | 2009-04-09 |
| JP5069751B2 (en) | 2012-11-07 |
| KR101515659B1 (en) | 2015-04-27 |
| WO2009044880A1 (en) | 2009-04-09 |
| AU2008308002B2 (en) | 2012-08-30 |
| KR20100065149A (en) | 2010-06-15 |
| JPWO2009044880A1 (en) | 2011-02-10 |
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