CN101781587A - 用动物油脂和鲜薯类制备生物柴油的方法 - Google Patents
用动物油脂和鲜薯类制备生物柴油的方法 Download PDFInfo
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- CN101781587A CN101781587A CN200910227842A CN200910227842A CN101781587A CN 101781587 A CN101781587 A CN 101781587A CN 200910227842 A CN200910227842 A CN 200910227842A CN 200910227842 A CN200910227842 A CN 200910227842A CN 101781587 A CN101781587 A CN 101781587A
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- Prior art keywords
- animal
- fatty acid
- fresh potatoes
- ionic liquid
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- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 38
- 239000003225 biodiesel Substances 0.000 title claims abstract description 17
- 244000017020 Ipomoea batatas Species 0.000 title claims abstract description 9
- 235000002678 Ipomoea batatas Nutrition 0.000 title claims abstract description 9
- 235000019737 Animal fat Nutrition 0.000 title abstract description 5
- 241001465754 Metazoa Species 0.000 claims abstract description 47
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 42
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 41
- 229930195729 fatty acid Natural products 0.000 claims abstract description 41
- 239000000194 fatty acid Substances 0.000 claims abstract description 41
- 239000002608 ionic liquid Substances 0.000 claims abstract description 30
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 22
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 108090000790 Enzymes Proteins 0.000 claims abstract description 14
- 102000004190 Enzymes Human genes 0.000 claims abstract description 14
- 229940088598 enzyme Drugs 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 230000032050 esterification Effects 0.000 claims abstract description 13
- 238000005886 esterification reaction Methods 0.000 claims abstract description 13
- 108010059892 Cellulase Proteins 0.000 claims abstract description 10
- 240000004808 Saccharomyces cerevisiae Species 0.000 claims abstract description 10
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004202 carbamide Substances 0.000 claims abstract description 10
- 229940106157 cellulase Drugs 0.000 claims abstract description 10
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 8
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 8
- 230000000694 effects Effects 0.000 claims abstract description 7
- 229940045136 urea Drugs 0.000 claims abstract description 6
- 244000061456 Solanum tuberosum Species 0.000 claims description 51
- 235000002595 Solanum tuberosum Nutrition 0.000 claims description 51
- 235000012015 potatoes Nutrition 0.000 claims description 32
- 239000004519 grease Substances 0.000 claims description 31
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 30
- 239000003760 tallow Substances 0.000 claims description 22
- 239000000706 filtrate Substances 0.000 claims description 16
- 241001494479 Pecora Species 0.000 claims description 15
- 235000011187 glycerol Nutrition 0.000 claims description 15
- 238000002360 preparation method Methods 0.000 claims description 15
- 238000000855 fermentation Methods 0.000 claims description 13
- 230000004151 fermentation Effects 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 239000003921 oil Substances 0.000 claims description 11
- 239000004382 Amylase Substances 0.000 claims description 9
- 239000002551 biofuel Substances 0.000 claims description 9
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- -1 1-ethyl-3-methyl imidazolium tetrafluoroborate Chemical compound 0.000 claims description 8
- BXNRKCXZILSQHE-UHFFFAOYSA-N propane-1,2,3-triol;sulfuric acid Chemical compound OS(O)(=O)=O.OCC(O)CO BXNRKCXZILSQHE-UHFFFAOYSA-N 0.000 claims description 8
- 235000006708 antioxidants Nutrition 0.000 claims description 7
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 230000009466 transformation Effects 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 5
- 238000007171 acid catalysis Methods 0.000 claims description 5
- 239000006227 byproduct Substances 0.000 claims description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 5
- 239000008117 stearic acid Substances 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims description 4
- 238000009835 boiling Methods 0.000 claims description 4
- 238000004821 distillation Methods 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 239000012530 fluid Substances 0.000 claims description 4
- 235000011837 pasties Nutrition 0.000 claims description 4
- 238000001556 precipitation Methods 0.000 claims description 4
- 108090000623 proteins and genes Proteins 0.000 claims description 4
- 102000004169 proteins and genes Human genes 0.000 claims description 4
- 239000001117 sulphuric acid Substances 0.000 claims description 4
- 235000011149 sulphuric acid Nutrition 0.000 claims description 4
- 238000010792 warming Methods 0.000 claims description 4
- 239000002351 wastewater Substances 0.000 claims description 4
- 229930003427 Vitamin E Natural products 0.000 claims description 3
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 claims description 3
- 235000019154 vitamin C Nutrition 0.000 claims description 3
- 239000011718 vitamin C Substances 0.000 claims description 3
- 235000019165 vitamin E Nutrition 0.000 claims description 3
- 229940046009 vitamin E Drugs 0.000 claims description 3
- 239000011709 vitamin E Substances 0.000 claims description 3
- 238000011010 flushing procedure Methods 0.000 claims description 2
- 239000002994 raw material Substances 0.000 abstract description 5
- 239000002699 waste material Substances 0.000 abstract description 5
- 238000005265 energy consumption Methods 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000002028 Biomass Substances 0.000 abstract description 2
- 239000003054 catalyst Substances 0.000 abstract description 2
- 239000003513 alkali Substances 0.000 abstract 1
- 102000004139 alpha-Amylases Human genes 0.000 abstract 1
- 108090000637 alpha-Amylases Proteins 0.000 abstract 1
- 229940024171 alpha-amylase Drugs 0.000 abstract 1
- 238000006555 catalytic reaction Methods 0.000 abstract 1
- 230000002478 diastatic effect Effects 0.000 abstract 1
- 235000019197 fats Nutrition 0.000 description 29
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 11
- 239000002253 acid Substances 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 235000015277 pork Nutrition 0.000 description 8
- NJMWOUFKYKNWDW-UHFFFAOYSA-N 1-ethyl-3-methylimidazolium Chemical compound CCN1C=C[N+](C)=C1 NJMWOUFKYKNWDW-UHFFFAOYSA-N 0.000 description 5
- 150000002632 lipids Chemical class 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000002283 diesel fuel Substances 0.000 description 3
- 125000004494 ethyl ester group Chemical group 0.000 description 3
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 3
- 239000010773 plant oil Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 108010093096 Immobilized Enzymes Proteins 0.000 description 2
- 239000004367 Lipase Substances 0.000 description 2
- 102000004882 Lipase Human genes 0.000 description 2
- 108090001060 Lipase Proteins 0.000 description 2
- 230000001476 alcoholic effect Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 235000019421 lipase Nutrition 0.000 description 2
- 238000005809 transesterification reaction Methods 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 208000031226 Hyperlipidaemia Diseases 0.000 description 1
- 208000008589 Obesity Diseases 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229930003268 Vitamin C Natural products 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000006353 environmental stress Effects 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000020824 obesity Nutrition 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Landscapes
- Fats And Perfumes (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN200910227842XA CN101781587B (zh) | 2009-12-15 | 2009-12-15 | 用动物油脂和鲜薯类制备生物柴油的方法 |
Applications Claiming Priority (1)
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CN200910227842XA CN101781587B (zh) | 2009-12-15 | 2009-12-15 | 用动物油脂和鲜薯类制备生物柴油的方法 |
Publications (2)
Publication Number | Publication Date |
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CN101781587A true CN101781587A (zh) | 2010-07-21 |
CN101781587B CN101781587B (zh) | 2013-04-03 |
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CN200910227842XA Expired - Fee Related CN101781587B (zh) | 2009-12-15 | 2009-12-15 | 用动物油脂和鲜薯类制备生物柴油的方法 |
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CN (1) | CN101781587B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102746948A (zh) * | 2012-08-03 | 2012-10-24 | 彭敏 | 一种利用废弃油脂制备脂肪酸的方法 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017187237A1 (en) * | 2016-04-27 | 2017-11-02 | Ahmed Mohammed Idris | A method for preparing biodiesel (methyl ester) from animal tallow oil and a biodiesel thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101230364A (zh) * | 2008-02-25 | 2008-07-30 | 清华大学 | 一种利用异养小球藻高密度发酵生产生物柴油的方法 |
CN101280328A (zh) * | 2008-05-27 | 2008-10-08 | 清华大学 | 一种从自养到异养两步培养小球藻生产生物柴油的方法 |
CN101445741A (zh) * | 2007-11-26 | 2009-06-03 | 北京有容建业科技发展有限责任公司 | 一种微生物柴油的生物合成法 |
-
2009
- 2009-12-15 CN CN200910227842XA patent/CN101781587B/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101445741A (zh) * | 2007-11-26 | 2009-06-03 | 北京有容建业科技发展有限责任公司 | 一种微生物柴油的生物合成法 |
CN101230364A (zh) * | 2008-02-25 | 2008-07-30 | 清华大学 | 一种利用异养小球藻高密度发酵生产生物柴油的方法 |
CN101280328A (zh) * | 2008-05-27 | 2008-10-08 | 清华大学 | 一种从自养到异养两步培养小球藻生产生物柴油的方法 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102746948A (zh) * | 2012-08-03 | 2012-10-24 | 彭敏 | 一种利用废弃油脂制备脂肪酸的方法 |
CN102746948B (zh) * | 2012-08-03 | 2013-08-07 | 彭敏 | 一种利用废弃油脂制备脂肪酸的方法 |
Also Published As
Publication number | Publication date |
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CN101781587B (zh) | 2013-04-03 |
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Owner name: SICHUAN HUAXIN ENERGY GROUP CO., LTD. Free format text: FORMER OWNER: ZHANG JIANWANG Effective date: 20140126 |
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Free format text: CORRECT: ADDRESS; FROM: 036000 SHUOZHOU, SHAANXI PROVINCE TO: 610000 CHENGDU, SICHUAN PROVINCE |
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TR01 | Transfer of patent right |
Effective date of registration: 20140126 Address after: 610000, No. 25, No. 6-1, 6 air road, 6, Sichuan, Wuhou District, Chengdu Patentee after: SICHUAN HUAXIN ENERGY GROUP CO., LTD. Address before: 036000 Shanxi city of Shuozhou province Career Technical College building 3 unit 102 building Patentee before: Zhang Jianwang |
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130403 Termination date: 20171215 |
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CF01 | Termination of patent right due to non-payment of annual fee |